H1 C1

Tent (ºC)= 100 Tsal (ºC)= 150

Tsal (ºC)= 40 Tent (ºC)= 10
-1 -1
CP (MW K )= 0.2 CP (MW K )= 0.05
Q (MW)= 12 Q (MW)= 7
DTcontr (ºC)= -5 DTcontr (ºC)= 5
Tent,despl (ºC)= 95 Tsal,despl (ºC)= 155
Tsal,despl (ºC)= 35 Tent,despl (ºC)= 15

Tdespl Thot, real CP DHhot,intervalo Hhot,graf-CC Tcold, real CP DHcold,intervalo

(ºC) (ºC) (MW K-1) (MW) (MW) (ºC) (MW K-1) (MW)
155 160 150
95 100 0 0 12 90 0.05 3
35 40 0.2 12 0 30 0.05 3
15 20 0 0 10 0.05 1
 Servicio de Calor
Q Tdespl Treal
(MW) (ºC) (ºC)
0 175 180
3 175 180

Tdesplazada (ºC)
180
160
Hcold,graf-CC DHintervalo CQNO CQSÍ 140
(MW) (MW) (MW) (MW) 120
15 0 3 =Serv. Calor 100
12 3 -3 0 =Pinch 80

9 -9 6 9 60
40
8 1 5 8 =Serv. Frío
20
0
0 2 4 6 8 10 12

Tdesplazada (ºC)
H (MW)
200
180
160
140
120
100
80
60
40
20
0
0 1 2 3 4 5 6 7 8
Q (MW)
 Servicio de Frío
Q Tdespl Treal
(MW) (ºC) (ºC)
0 25 20
8 25 20

6 8 10 12 14 16
H (MW)

3 4 5 6 7 8 9 10
Q (MW)
 H1 C1
Tent (ºC)= 100 Tsal (ºC)= 150
Tsal (ºC)= 40 Tent (ºC)= 10
-1 -1
CP (MW K )= 0.2 CP (MW K )= 0.05
Q (MW)= 12 Q (MW)= 7
DTcontr (ºC)= -10 DTcontr (ºC)= 10
Tent,despl (ºC)= 90 Tsal,despl (ºC)= 160
Tsal,despl (ºC)= 30 Tent,despl (ºC)= 20

Tdespl Thot, real CP DHhot,intervalo Hhot,graf-CC Tcold, real CP DHcold,intervalo

(ºC) (ºC) (MW K-1) (MW) (MW) (ºC) (MW K-1) (MW)
160 170 150
90 100 0 0 12 80 0.05 3.5
30 40 0.2 12 0 20 0.05 3
20 30 0 0 10 0.05 0.5
 Servicio de Calor
Q Tdespl Treal
(MW) (ºC) (ºC)
0 175 180
3.5 175 180

Tdesplazada (ºC)
Hcold,graf-CC DHintervalo CQNO CQSÍ 180
160
(MW) (MW) (MW) (MW)
140
15.5 0 3.5 =Serv. Calor
120
12 3.5 -3.5 0 =Pinch 100
9 -9 5.5 9 80
8.5 0.5 5 8.5 =Serv. Frío 60
40
20
0
0 2 4 6 8 10 12 14 1
H (MW)
Tdesplazada (ºC)

200
180
160
140
120
100
80
60
40
20
0
0 1 2 3 4 5 6 7 8
Q (MW)
 Servicio de Frío
Q Tdespl Treal
(MW) (ºC) (ºC)
0 25 20
8.5 25 20

6 8 10 12 14 16 18
H (MW)

4 5 6 7 8 9 10
Q (MW)
 H1 H2 H3
Tent (ºC)= 160 50 140
Tsal (ºC)= 40 49.9 110
-1
CP (MW K )= 0.03 50 0.05 CP (MW K-1)=
Q (MW)= 3.6 5 1.5
DTcontr (ºC)= -5 -5 -5
Tent,despl (ºC)= 155 45 135
Tsal,despl (ºC)= 35 44.9 105

N.O. Tdespl Thot, real CP CP CP DHhot,intervalo Hhot,graf-CC

(ºC) (ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW)
1 165.1 170.1
2 165 170 0 0 0 0
3 155 160 0 0 0 0
4 155 160 0 0 0 0 10.1
5 135 140 0.03 0 0 0.6 9.5
6 105 110 0.03 0 0.05 2.4 7.1
7 65 70 0.03 0 0 1.2 5.9
8 45 50 0.03 0 0 0.6 5.3
9 44.9 49.9 0.03 50 0 5.003 0.297
10 35 40 0.03 0 0 0.297 0
 C1 C2
Tsal (ºC)= 160.1 150
Tent (ºC)= 160 60 Calientes Frías
-1
CP (MW K )= 50 0.02 (MW) (MW)
Q (MW)= 5 1.8 C. Proceso = 10.1 6.8
DTcontr (ºC)= 5 5 Servicios = 5 8.3
Tsal,despl (ºC)= 165.1 155 Balance = 15.1 15.1
Tent,despl (ºC)= 165 65

Tcold, real CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO CQSÍ

(ºC) (MW K-1) (MW K-1) (MW) (MW) (MW) (MW) (MW)
160.1 15.1 0 5
160 50 0 5 10.1 5 -5 0
150 0 0 0 10.1 0 -5 0
150 0 0 0 10.1 0 -5 0
130 0 0.02 0.4 9.7 -0.2 -4.8 0.2
100 0 0.02 0.6 9.1 -1.8 -3 2
60 0 0.02 0.8 8.3 -0.4 -2.6 2.4
40 0 0 0 -0.6 -2 3
39.9 0 0 0 -5.003 3.003 8.003
30 0 0 0 -0.297 3.3 8.3
 Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl Treal
(MW) (ºC) (ºC) (MW) (ºC) (ºC)
0 175 180 0 25 20
5 175 180 8.3 25 20
Tdesplazada (ºC)

180
160
140
=Serv. Calor
120
100
=Pinch 80
=Pinch 60
40
20
0
0 2 4 6 8 10 12 14 16
H (MW)
Tdesplazada (ºC)

=Serv. Frío
200
180
160
140
120
100
80
60
40
20
0
0 1 2 3 4 5 6 7 8 9
Q (MW)
 H1 H3
Tent (ºC)= 190 Tsal (ºC)=
Tsal (ºC)= 110 Tent (ºC)=
CP (kW K-1)= 2.5 CP (kW K-1)=
Q (kW)= 200 Q (kW)=
DTcontr (ºC)= -10 DTcontr (ºC)=
Tent,despl (ºC)= 180 Tsal,despl (ºC)=
Tsal,despl (ºC)= 100 Tent,despl (ºC)=

N.O. Tdespl Thot, real CP CP DHhot,intervalo Hhot,graf-CC Tcold, real

(ºC) (ºC) (kW K-1) (kW K-1) (kW) (kW) (ºC)
1 180 190 170
2 180 190 0 0 0 200 170
3 100 110 2.5 0 200 0 90
4 100 110 2.5 0 0 90
 C1 C2
170
90 Calientes Frías
20 (kW) (kW)
1600 C. Proceso = 200 1600
10 Servicios = 1400 0
180 Balance = 1600 1600
100

Tdesplazada (ºC)
CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO CQSÍ 200
180
(kW K-1) (kW K-1) (kW) (kW) (kW) (kW) (kW)
160
0 1400 =Serv. Calor 140
0 0 0 1600 0 0 1400 120
20 0 1600 0 1400 -1400 0 =Pinch 100
80
20 0 0 0 -1400 0 =Serv. Frío
60
40
20
0
0 2

Tdesplazada (ºC)
200
180
160
140
120
100
80
60
40
20
0
0 2
Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl Treal
(kW) (ºC) (ºC) (kW) (ºC) (ºC)
0 185 190 0 25 20
1400 185 190 0 25 20
Tdesplazada (ºC)

200
180
160
140
120
100
80
60
40
20
0
0 200 400 600 800 10001200 140016001800
H (MW)
Tdesplazada (ºC)

200
180
160
140
120
100
80
60
40
20
0
0 200 400 600 800 1000 1200 1400 1600
Q (MW)
 H1 H3
Tent (ºC)= 140 Tsal (ºC)=
Tsal (ºC)= 50 Tent (ºC)=
CP (kW K-1)= 20 CP (kW K-1)=
Q (kW)= 1800 Q (kW)=
DTcontr (ºC)= -10 DTcontr (ºC)=
Tent,despl (ºC)= 130 Tsal,despl (ºC)=
Tsal,despl (ºC)= 40 Tent,despl (ºC)=

N.O. Tdespl Thot, real CP CP DHhot,intervalo Hhot,graf-CC Tcold, real

(ºC) (ºC) (kW K-1) (kW K-1) (kW) (kW) (ºC)
1 130 140 120
2 130 140 0 0 0 1800 120
3 40 50 20 0 1800 0 30
4 40 50 20 0 0 30
 C1 C2
120
30 Calientes Frías
5 (kW) (kW)
450 C. Proceso = 1800 450
10 Servicios = 0 1350
130 Balance = 1800 1800
40

Tdesplazada (ºC)
140
CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO CQSÍ
120
(kW K-1) (kW K-1) (kW) (kW) (kW) (kW) (kW)
100
0 0 =Serv. Calor
80
0 0 0 1800 0 0 0 =Pinch
60
5 0 450 1350 -1350 1350 1350
40
5 0 0 0 1350 1350 =Serv. Frío
20
0

Tdesplazada (ºC)
200
180
160
140
120
100
80
60
40
20
0
0 2
Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl Treal
(kW) (ºC) (ºC) (kW) (ºC) (ºC)
0 185 190 0 25 20
0 185 190 1350 25 20
Tdesplazada (ºC)

140
120
100
80
60
40
20
0

H (MW)
Tdesplazada (ºC)

200
180
160
140
120
100
80
60
40
20
0
0 200 400 600 800 1000 1200 1400 1600
Q (MW)
 H1 H3
Tent (ºC)= 190 140 Tsal (ºC)=
Tsal (ºC)= 110 50 Tent (ºC)=
CP (kW K-1)= 2.5 20 CP (kW K-1)=
Q (kW)= 200 1800 Q (kW)=
DTcontr (ºC)= -10 -10 DTcontr (ºC)=
Tent,despl (ºC)= 180 130 Tsal,despl (ºC)=
Tsal,despl (ºC)= 100 40 Tent,despl (ºC)=

N.O. Tdespl Thot, real CP CP DHhot,intervalo Hhot,graf-CC Tcold, real

(ºC) (ºC) (kW K-1) (kW K-1) (kW) (kW) (ºC)
1 180 190 170
2 180 190 0 0 0 2000 170
3 130 140 2.5 0 125 1875 120
4 130 140 2.5 0 0 1875 120
5 100 110 2.5 20 675 1200 90
6 100 110 2.5 20 0 1200 90
7 40 50 0 20 1200 0 30
8 40 50 0 20 0 30
 C1 C2
170 120
90 30 Calientes Frías
20 5 (kW) (kW)
1600 450 C. Proceso = 2000 2050
10 10 Servicios = 950 900
180 130 Balance = 2950 2950
100 40

Tdesplazada (ºC)
CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO CQSÍ 200
180
(kW K-1) (kW K-1) (kW) (kW) (kW) (kW) (kW)
160
0 950 =Serv. Calor 140
0 0 0 2950 0 0 950 120
20 0 1000 1950 875 -875 75 100
80
20 0 0 1950 0 -875 75
60
20 5 750 1200 75 -950 0 40
20 5 0 1200 0 -950 0 =Pinch 20
0 5 300 900 -900 -50 900 0
0
0 5 0 0 -50 900 =Serv. Frío

Tdesplazada (ºC)
200
180
160
140
120
100
80
60
40
20
0
0 1
Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl Treal
(kW) (ºC) (ºC) (kW) (ºC) (ºC)
0 185 190 0 25 20
950 185 190 900 25 20
Tdesplazada (ºC)

200
A
180
Serv Calor (kW)= 1400
160
140 Serv Frío (kW)= 0
120
100
80
60
40
20
0
0 500 1000 1500 2000 2500 3000 3500
H (MW)
Tdesplazada (ºC)

200
180
160
140
120
100
80
60
40
20
0
0 100 200 300 400 500 600 700 800 900 1000
Q (MW)
B A y B indep. A+B Pagas de másAhorro
0 1400 950 47% 32%
1350 1350 900 50% 33%
 GCC Gases del Horno
Q Tdespl Q
(MW) (ºC) (MW)
9 360 9
7.6 310 0
8 230 -0.37380192
4.8 210 -1.20766773
5.8 190
0 190
1 170
7.6 150
3 60
Tdesplazada (ºC)

Qproceso (MW)= 9
400 QCh (MW)= 1.20766773
350
QFuel (MW)= 10.2076677
300
h= 88.17%
250
200
150
100 P.V.P Coste
50 (€ (kWh)-1) (€ año-1)
0
0.04 3470607.03
-50
-2 0 2 4 6 8 10
Q (MW)
ases del Horno
Tdespl Treal
(ºC) (ºC)
1755 1800 Metano Metano
190 235 T (ºC) =
125 170 Fase =
-20 25 TRef (ºC) =
Fase Ref. =
M Cp xi ni
(g mol-1) (J mol-1 K-1) (mol mol-1) (kmol)
CH4 = 16 CH4 = 1 0.01321655
O2 = 32 34.95 O2 = 0 0
N2 = 28 33.03 N2 = 0 0
CO2 = 44 54.15 CO2 = 0 0
H2O = 18 42.75 H2O = 0 0

Suma = 1
Calculos = 0.01321655
Masa (kg) = 0.21146475
P.V.P P.C.S. Caudal CH4 Coste Entalía (kJ) =
(€ m-3(n)) (kWh m-3(n)) (m3(n) h-1) (€ año-1)
0.468 11.7 1065.78233 4239682.11
Diferencia 1.22159671 ∑8_𝑖𝑛▒∑8_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(
 DHR
Metano Aire Aire Aire (J mol-1) G.Comb G.Comb G.Comb
25 T (ºC) = 25 -772340 T (ºC) = 1800
GAS Fase = GAS XL Fase = GAS
25 TRef (ºC) = 25 (mol mol-1) TRef (ºC) = 25
GAS Fase Ref. = GAS 100% Fase Ref. = GAS
Hi xi ni Hi ni xi ni Hi
(kJ) (mol mol-1) (kmol) (kJ) coef. esteq. (mol mol-1) (kmol) (kJ)
0 0 0 0 -1 0 0
0 0.21 0.03033148 0 -2 0.00389838 241.841139
0 0.79 0.11410413 0 0 0.11410413 6689.7255
0 0 0 0 1 0.01321655 1270.32491
0 0 0 0 2 0.02643309 2005.77618

1 0.15765216
0.14443561
4.16552295 4.3769877
0 0 10207.6677
Exceso de aire calculado= 14.75%

8_𝑖𝑛▒∑8_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖) (𝑇_𝑖𝑛−𝑇_𝑟𝑒𝑓) 〗 +(𝑋_𝐿 ∑8_𝑖𝑛▒𝑛_(𝐿,𝑖𝑛) )/|𝜈_𝐿 | (−Δ𝐻_𝑅 )− ∑_𝑜𝑢𝑡▒ 〖∑ _𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖)
 G.Ch G.Ch G.Ch
T (ºC) = 235
Fase = GAS
TRef (ºC) = 25
Fase Ref. = GAS Para 1 s
Balances xi ni Hi Qproceso (kJ) Balances
(mol mol )-1
(kmol) (kJ) Base de cálculo = 1 s
0 0
0.00389838 28.6121911
0.11410413 791.460482
0.01321655 150.291962
0.02643309 237.303097

0.15765216 A (25 ºC)

0 4.3769877
-2.5921E-09 1207.66773 9000 6.5842E-07

〖∑ _𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇_𝑜𝑢𝑡−𝑇_𝑟𝑒𝑓) 〗 =0 〗

𝐻_(𝐺.𝐶𝑜𝑚𝑏)=𝐻_(𝐺.𝐶ℎ)+9000 𝑘𝑊×1𝑠
Base de cálculo = 1 s
Ch (235 ºC)

9000 kJ
G (1800 ºC)

A (25 ºC)

M (25ºC)
 GCC Gases del Horno
Q Tdespl Q
(MW) (ºC) (MW)
9 360 9
7.6 310 0
8 230 -0.37380192
4.8 210 -1.20766773
5.8 190
0 190
1 170
7.6 150
3 60
Tdesplazada (ºC)

Qproceso (MW)= 9
400 QCh (MW)= 1.20766773
350
QFuel (MW)= 10.2076677
300
h= 88.17%
250
200
150
100 P.V.P Coste
50 (€ (kWh)-1) (€ año-1)
0
0.04 3470607.03
-50
-2 0 2 4 6 8 10
Q (MW)
ases del Horno
Tdespl Treal
(ºC) (ºC)
1755 1800 Metano Metano
190 235 T (ºC) =
125 170 Fase =
-20 25 TRef (ºC) =
Fase Ref. =
M Cp xi ni
(g mol-1) (J mol-1 K-1) (mol mol-1) (kmol)
CH4 = 16 CH4 = 1 0.01321655
O2 = 32 34.95 O2 = 0 0
N2 = 28 33.03 N2 = 0 0
CO2 = 44 54.15 CO2 = 0 0
H2O = 18 42.75 H2O = 0 0

Suma = 1
Calculos = 0.01321655
Masa (kg) = 0.21146475
P.V.P P.C.S. Caudal CH4 Coste Entalía (kJ) =
(€ m-3(n)) (kWh m-3(n)) (m3(n) h-1) (€ año-1)
0.468 11.7 1065.78233 4239682.11
Diferencia 1.22159671

∑_𝑖𝑛▒∑_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖)

 DHR
Metano Aire Aire Aire (J mol-1) G.Comb G.Comb G.Comb
25 T (ºC) = 25 -772340 T (ºC) = 1800
GAS Fase = GAS XL Fase = GAS
25 TRef (ºC) = 25 (mol mol-1) TRef (ºC) = 25
GAS Fase Ref. = GAS 100% Fase Ref. = GAS
Hi xi ni Hi ni xi ni Hi
(kJ) (mol mol-1) (kmol) (kJ) coef. esteq. (mol mol-1) (kmol) (kJ)
0 0 0 0 -1 0 0
0 0.21 0.03033148 0 -2 0.00389838 241.841139
0 0.79 0.11410413 0 0 0.11410413 6689.7255
0 0 0 0 1 0.01321655 1270.32491
0 0 0 0 2 0.02643309 2005.77618

1 0.15765216
0.14443561
4.16552295 4.3769877
0 0 10207.6677
Exceso de aire calculado= 14.75%
Exceso de aire= 14.75%

𝑛▒∑_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖) (𝑇_𝑖𝑛−𝑇_𝑟𝑒𝑓) 〗 +(𝑋_𝐿 ∑_𝑖𝑛▒𝑛_(𝐿,𝑖𝑛) )/|𝜈_𝐿 | (−Δ𝐻_𝑅 )− ∑_𝑜𝑢𝑡▒ 〖∑ _𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇
 G.Ch G.Ch G.Ch
T (ºC) = 235
Fase = GAS
TRef (ºC) = 25
Fase Ref. = GAS Para 1 s
Balances xi ni Hi Qproceso (kJ) Balances
(mol mol )-1
(kmol) (kJ) Base de cálculo = 1 s
0 0
0.00389838 28.6121911
0.11410413 791.460482
0.01321655 150.291962
0.02643309 237.303097

0.15765216 A (25 ºC)

0 4.3769877
2.91038E-11 1207.66773 9000 -3.4452E-09

_𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇_𝑜𝑢𝑡−𝑇_𝑟𝑒𝑓) 〗 =0 〗

𝐻_(𝐺.𝐶𝑜𝑚𝑏)=𝐻_(𝐺.𝐶ℎ)+9000 𝑘𝑊×1𝑠
Base de cálculo = 1 s
Ch (235 ºC)

9000 kJ
G (1800 ºC)

A (25 ºC)

M (25ºC)
 GCC Gases del Horno
Q Tdespl Q
(MW) (ºC) (MW)
9 360 9
7.6 310 0
8 230 -0.37380192
4.8 210 -1.20766773
5.8 190
0 190
1 170
7.6 150
3 60
Tdesplazada (ºC)

Qproceso (MW)= 9
400 QPrecalent (MW)= 0.37380192
350
QCh (MW)= 0.83386581
300
QFuel (MW)= 9.83386581
250
200 h= 91.52%
150
100 P.V.P Coste
50 (€ (kWh)-1) (€ año-1)
0
0.04 3343514.38
-50
-2 0 2 4 6 8 10
Q (MW)
ases del Horno
Tdespl Treal
(ºC) (ºC)
1755 1800 Metano Metano
190 235 T (ºC) =
125 170 Fase =
-20 25 TRef (ºC) =
Fase Ref. =
M Cp xi ni
(g mol-1) (J mol-1 K-1) (mol mol-1) (kmol)
CH4 = 16 CH4 = 1 0.01273256
O2 = 32 34.95 O2 = 0 0
N2 = 28 33.03 N2 = 0 0
CO2 = 44 54.15 CO2 = 0 0
H2O = 18 42.75 H2O = 0 0
Ahorro
1.0380117 Suma = 1
Calculos = 0.01273256
Masa (kg) = 0.20372097
P.V.P P.C.S. Caudal CH4 Coste Entalía (kJ) =
(€ m-3(n)) (kWh m-3(n)) (m3(n) h-1) (€ año-1) Ahorro
0.468 11.7 1026.75368 4084426.15 1.0380117
Diferencia 1.22159671

∑_𝑖𝑛▒∑_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖)

 DHR
Metano Aire Aire Aire (J mol-1) G.Comb G.Comb G.Comb
25 T (ºC) = 25 -772340 T (ºC) = 1800
GAS Fase = GAS XL Fase = GAS
25 TRef (ºC) = 25 (mol mol-1) TRef (ºC) = 25
GAS Fase Ref. = GAS 100% Fase Ref. = GAS
Hi xi ni Hi ni xi ni Hi
(kJ) (mol mol-1) (kmol) (kJ) coef. esteq. (mol mol-1) (kmol) (kJ)
0 0 0 0 -1 0 0
0 0.21 0.03054352 0 -2 0.0050784 315.044709
0 0.79 0.11490181 0 0 0.11490181 6736.49183
0 0 0 0 1 0.01273256 1223.80597
0 0 0 0 2 0.02546512 1932.32522

1 0.15817789
0.14544532
4.19464316 4.39836413
0 0 10207.6677
Exceso de aire calculado= 19.94%
Exceso de aire= 19.94%

𝑛▒∑_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖) (𝑇_𝑖𝑛−𝑇_𝑟𝑒𝑓) 〗 +(𝑋_𝐿 ∑_𝑖𝑛▒𝑛_(𝐿,𝑖𝑛) )/|𝜈_𝐿 | (−Δ𝐻_𝑅 )− ∑_𝑜𝑢𝑡▒ 〖∑ _𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇
 G.Ch G.Ch G.Ch
T (ºC) = 235
Fase = GAS
TRef (ºC) = 25
Fase Ref. = GAS Para 1 s
Balances xi ni Hi Qproceso (kJ) Balances
-1
(mol mol ) (kmol) (kJ)
0 0
0.0050784 37.2728952
0.11490181 796.9934
0.01273256 144.788312
0.02546512 228.613125

0.15817789

0 4.39836413
-1.7053E-12 1207.66773 9000 0

_𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇_𝑜𝑢𝑡−𝑇_𝑟𝑒𝑓) 〗 =0 〗

𝐻_(𝐺.𝐶𝑜𝑚𝑏)=𝐻_(𝐺.𝐶ℎ)+9000 𝑘𝑊×1𝑠
 R R R
T (ºC) = 170
Fase = GAS
TRef (ºC) = 25
Fase Ref. = GAS
xi ni Hi
(mol mol-1) (kmol) (kJ)
0 0
Base de cálculo = 1 s
0.0050784 25.7360467 R (170 ºC)
0.11490181 550.304966
0.01273256 99.9728823 A (25 ºC)
0.02546512 157.851919
Base de cálculo = 1 s
Ch (235 ºC)
0.15817789 9000 kJ
G (1800 ºC)
4.39836413
833.865815

A (25 ºC)

A (T>25ºC)

M (25ºC)
Base de cálculo = 1 s
Ch (235 ºC)

9000 kJ
G (1800 ºC)

A (25 ºC)

M (25ºC)
 GCC Gases del Horno
Q Tdespl Q
(MW) (ºC) (MW)
9 360 9
7.6 310 7.6
8 230 7.42076125
4.8 210 7.28027682
5.8 190
0 190
1 170
7.6 150
3 60
Tdesplazada (ºC)

Qproceso (MW)= 1.4

400 QPrecalent (MW)= 0.17923875
350
QCh (MW)= 0.14048443
300
QFuel (MW)= 1.54048443
250
200 h= 90.88%
150
100
50
0
-50
0 1 2 3 4 5 6 7 8 9 10
Q (MW)
ases del Horno Vapor a 250ºC
Tdespl Treal Q Tdespl Treal
(ºC) (ºC) (MW) (ºC) (ºC)
1755 1800 0 245 250
310 355 7.6 245 250
125 170
-20 25

Línea auxiliar
Q Tdespl Treal
(MW) (ºC) (ºC)
7.6 310
7.6 230
 H1 H2 H3
Tent (ºC)= 377 376 180
Tsal (ºC)= 375 180 70
-1
CP (MW K )= 3.5 0.01836735 0.02181818 CP (MW K-1)=
Q (MW)= 7 3.6 2.4
DTcontr (ºC)= -58.5 -58.5 -58.5 117
Tent,despl (ºC)= 318.5 317.5 121.5
Tsal,despl (ºC)= 316.5 121.5 11.5

N.O. Tdespl Thot, real CP CP CP DHhot,intervalo Hhot,graf-CC

(ºC) (ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW)
1 318.5 377
2 318.5 377 0 0 0 0 13
3 317.5 376 3.5 0 0 3.5 9.5
4 316.5 375 3.5 0.01836735 0 3.51836735 5.98163265
5 218.5 277 0 0.01836735 0 1.8 4.18163265
6 218.5 277 0 0.01836735 0 0 4.18163265
7 188.5 247 0 0.01836735 0 0.55102041 3.63061224
8 121.5 180 0 0.01836735 0 1.23061224 2.4
9 121.5 180 0 0.01836735 0 0 2.4
10 118.5 177 0 0 0.02181818 0.06545455 2.33454545
11 78.5 137 0 0 0.02181818 0.87272727 1.46181818
12 11.5 70 0 0 0.02181818 1.46181818 0
 C1 C2 C3
Tsal (ºC)= 160 130 260
Tent (ºC)= 60 20 160 Calientes
-1
CP (MW K )= 0.024 0.00181818 0.002 (kW)
Q (MW)= 2.4 0.2 0.2 C. Proceso = 13
DTcontr (ºC)= 58.5 58.5 58.5 Servicios = 0
Tsal,despl (ºC)= 218.5 188.5 318.5 Balance = 13
Tent,despl (ºC)= 118.5 78.5 218.5

Tcold, real CP CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO

(ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW) (MW) (MW)
260 0
260 0 0 0 0 13 0 0
259 0 0 0.002 0.002 12.998 -3.498 3.498
258 0 0 0.002 0.002 12.996 -3.51636735 7.01436735
160 0 0 0.002 0.196 12.8 -1.604 8.61836735
160 0 0 0.002 0 12.8 0 8.61836735
130 0.024 0 0 0.72 12.08 0.16897959 8.44938776
63 0.024 0.00181818 0 1.72981818 10.3501818 0.49920594 7.95018182
63 0.024 0.00181818 0 0 10.3501818 0 7.95018182
60 0.024 0.00181818 0 0.07745455 10.2727273 0.012 7.93818182
20 0 0.00181818 0 0.07272727 10.2 -0.8 8.73818182
-47 0 0 0 0 -1.46181818 10.2
 Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl
Frías (MW) (ºC) (ºC) (MW) (ºC)
(kW) 0 185 190 0 203.5
2.8 0 185 190 7.93818182 203.5
10.2
13
Para las corrientes de proceso:
Δ𝑇_(𝑚𝑖𝑛,(𝑝𝑟𝑜𝑐𝑒𝑠𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜))=Δ𝑇_𝑐𝑜𝑛𝑡𝑟
Tdesplazada (ºC)

CQSÍ 350 Para las corrientes calientes y el servicio d

Δ𝑇_(𝑚𝑖𝑛,(𝑠𝑒𝑟𝑣𝑖𝑐𝑖𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜) )=Δ𝑇_𝑐𝑜𝑛𝑡𝑟
(MW) 300
Δ𝑇_𝑐𝑜𝑛𝑡𝑟^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜=Δ𝑇_(𝑚𝑖𝑛,(𝑠𝑒𝑟𝑣𝑖𝑐𝑖𝑜−
0 =Serv. Calor 250
0 =Pinch 𝑇_𝑑𝑒𝑠𝑝𝑙^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜=𝑇_𝑟𝑒𝑎𝑙^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜+
200
3.498 𝑇_𝑑𝑒𝑠𝑝𝑙^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜=252°𝐶+(10°𝐶+(−(11
150
7.01436735
100
8.61836735
50
8.61836735
8.44938776 0
0 2 4 6 8 10 12 14
7.95018182 H (MW)
7.95018182
Tdesplazada (ºC)

7.93818182
350
8.73818182
10.2 =Serv. Frío 300

250

200

150

100

50

0
0 2 4 6 8 10 12
Q (MW)
 Treal ṁagua DHvap
(ºC) (kg s-1) (kJ kg-1)
252 4.65309602 1706
252
𝑄 ̇=𝑚 ̇ Δ𝐻_𝑣𝑎𝑝

entes de proceso:
𝑐𝑒𝑠𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜))=Δ𝑇_𝑐𝑜𝑛𝑡𝑟^𝑐𝑜𝑙𝑑−Δ𝑇_𝑐𝑜𝑛𝑡𝑟^ℎ𝑜𝑡

entes calientes y el servicio de frío

𝑣𝑖𝑐𝑖𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜) )=Δ𝑇_𝑐𝑜𝑛𝑡𝑟^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜−Δ𝑇_𝑐𝑜𝑛𝑡𝑟^ℎ𝑜𝑡

𝑟𝑣𝐹𝑟í𝑜=Δ𝑇_(𝑚𝑖𝑛,(𝑠𝑒𝑟𝑣𝑖𝑐𝑖𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜) )+Δ𝑇_𝑐𝑜𝑛𝑡𝑟^ℎ𝑜𝑡

𝑣𝐹𝑟í𝑜=𝑇_𝑟𝑒𝑎𝑙^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜+Δ𝑇_𝑐𝑜𝑛𝑡𝑟^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜=𝑇_𝑟𝑒𝑎𝑙^𝑆𝑒𝑟𝑣𝐹𝑟í𝑜+(Δ𝑇_(𝑚𝑖𝑛,(𝑠𝑒𝑟𝑣𝑖𝑐𝑖𝑜−𝑝𝑟𝑜𝑐𝑒𝑠𝑜) )+Δ𝑇_𝑐𝑜𝑛𝑡𝑟^ℎ𝑜𝑡 )

𝐹𝑟í𝑜=252°𝐶+(10°𝐶+(−(117°𝐶)/2))=203.5°𝐶

Línea auxiliar
Q Tdespl
(MW) (ºC)
7.93818182 250
7.93818182 100
 H1 H2 H3
Tent (ºC)= 377 376 180
Tsal (ºC)= 375 180 70
-1
CP (MW K )= 3.5 0.01836735 0.02181818 CP (MW K-1)=
Q (MW)= 7 3.6 2.4
DTcontr (ºC)= -58.5 -58.5 -58.5 117
Tent,despl (ºC)= 318.5 317.5 121.5
Tsal,despl (ºC)= 316.5 121.5 11.5

N.O. Tdespl Thot, real CP CP CP DHhot,intervalo Hhot,graf-CC

(ºC) (ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW)
1 318.5 377
2 318.5 377 0 0 0 0 13
3 317.5 376 3.5 0 0 3.5 9.5
4 316.5 375 3.5 0.01836735 0 3.51836735 5.98163265
5 218.5 277 0 0.01836735 0 1.8 4.18163265
6 218.5 277 0 0.01836735 0 0 4.18163265
7 188.5 247 0 0.01836735 0 0.55102041 3.63061224
8 121.5 180 0 0.01836735 0 1.23061224 2.4
9 121.5 180 0 0.01836735 0 0 2.4
10 118.5 177 0 0 0.02181818 0.06545455 2.33454545
11 78.5 137 0 0 0.02181818 0.87272727 1.46181818
12 11.5 70 0 0 0.02181818 1.46181818 0
 C1 C2 C3
Tsal (ºC)= 160 130 260
Tent (ºC)= 60 20 160 Calientes
-1
CP (MW K )= 0.024 0.00181818 0.002 (kW)
Q (MW)= 2.4 0.2 0.2 C. Proceso = 13
DTcontr (ºC)= 58.5 58.5 58.5 Servicios = 0
Tsal,despl (ºC)= 218.5 188.5 318.5 Balance = 13
Tent,despl (ºC)= 118.5 78.5 218.5

Tcold, real CP CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO

(ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW) (MW) (MW)
260 0
260 0 0 0 0 13 0 0
259 0 0 0.002 0.002 12.998 -3.498 3.498
258 0 0 0.002 0.002 12.996 -3.51636735 7.01436735
160 0 0 0.002 0.196 12.8 -1.604 8.61836735
160 0 0 0.002 0 12.8 0 8.61836735
130 0.024 0 0 0.72 12.08 0.16897959 8.44938776
63 0.024 0.00181818 0 1.72981818 10.3501818 0.49920594 7.95018182
63 0.024 0.00181818 0 0 10.3501818 0 7.95018182
60 0.024 0.00181818 0 0.07745455 10.2727273 0.012 7.93818182
20 0 0.00181818 0 0.07272727 10.2 -0.8 8.73818182
-47 0 0 0 0 -1.46181818 10.2
 Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl
Frías (MW) (ºC) (ºC) (MW) (ºC)
(kW) 0 185 190 0 301.5
2.8 0 185 190 1.48320652 203.5
10.2 7.93818182 203.5
13
Tdesplazada (ºC)

CQSÍ 350

(MW) 300

0 =Serv. Calor 250

0 =Pinch 200
3.498
150
7.01436735
100
8.61836735
50
8.61836735
8.44938776 0
0 2 4 6 8 10 12 14
7.95018182 H (MW)
7.95018182
Tdesplazada (ºC)

7.93818182
350
8.73818182
10.2 =Serv. Frío 300

250

200

150

100

50

0
0 2 4 6 8 10 12
Q (MW)
 Treal ṁagua DHvap Cp vapor
(ºC) (kg s-1) (kJ kg-1) (kJ kg-1 K-1)
350 3.78369009 1706 4
252
252 𝑄 ̇=𝑚 ̇ (Δ𝐻_𝑣𝑎𝑝+𝐶_𝑝^𝑣𝑎𝑝 (350−252)°𝐶)

Corte del servicio con la GCC

Q Tdespl Treal
(MW) (ºC) (ºC)
7.93818182 203.5 252

Línea auxiliar
Q Tdespl
(MW) (ºC)
7.93818182 250
7.93818182 100
 H1 H2 H3
Tent (ºC)= 377 376 180
Tsal (ºC)= 375 180 70
-1
CP (MW K )= 3.5 0.01836735 0.02181818 CP (MW K-1)=
Q (MW)= 7 3.6 2.4
DTcontr (ºC)= -58.5 -58.5 -58.5 117
Tent,despl (ºC)= 318.5 317.5 121.5
Tsal,despl (ºC)= 316.5 121.5 11.5

N.O. Tdespl Thot, real CP CP CP DHhot,intervalo Hhot,graf-CC

(ºC) (ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW)
1 318.5 377
2 318.5 377 0 0 0 0 13
3 317.5 376 3.5 0 0 3.5 9.5
4 316.5 375 3.5 0.01836735 0 3.51836735 5.98163265
5 218.5 277 0 0.01836735 0 1.8 4.18163265
6 218.5 277 0 0.01836735 0 0 4.18163265
7 188.5 247 0 0.01836735 0 0.55102041 3.63061224
8 121.5 180 0 0.01836735 0 1.23061224 2.4
9 121.5 180 0 0.01836735 0 0 2.4
10 118.5 177 0 0 0.02181818 0.06545455 2.33454545
11 78.5 137 0 0 0.02181818 0.87272727 1.46181818
12 11.5 70 0 0 0.02181818 1.46181818 0
 C1 C2 C3
Tsal (ºC)= 160 130 260
Tent (ºC)= 60 20 160 Calientes
-1
CP (MW K )= 0.024 0.00181818 0.002 (kW)
Q (MW)= 2.4 0.2 0.2 C. Proceso = 13
DTcontr (ºC)= 58.5 58.5 58.5 Servicios = 0
Tsal,despl (ºC)= 218.5 188.5 318.5 Balance = 13
Tent,despl (ºC)= 118.5 78.5 218.5

Tcold, real CP CP CP DHcold,intervalo Hcold,graf-CC DHintervalo CQNO

(ºC) (MW K-1) (MW K-1) (MW K-1) (MW) (MW) (MW) (MW)
260 0
260 0 0 0 0 13 0 0
259 0 0 0.002 0.002 12.998 -3.498 3.498
258 0 0 0.002 0.002 12.996 -3.51636735 7.01436735
160 0 0 0.002 0.196 12.8 -1.604 8.61836735
160 0 0 0.002 0 12.8 0 8.61836735
130 0.024 0 0 0.72 12.08 0.16897959 8.44938776
63 0.024 0.00181818 0 1.72981818 10.3501818 0.49920594 7.95018182
63 0.024 0.00181818 0 0 10.3501818 0 7.95018182
60 0.024 0.00181818 0 0.07745455 10.2727273 0.012 7.93818182
20 0 0.00181818 0 0.07272727 10.2 -0.8 8.73818182
-47 0 0 0 0 -1.46181818 10.2
 Servicio de Calor Servicio de Frío
Q Tdespl Treal Q Tdespl
Frías (MW) (ºC) (ºC) (MW) (ºC)
(kW) 0 185 190 0 301.5
2.8 0 185 190 1.26752231 203.5
10.2 6.78383114 203.5
13 7.93818182 118.5
Tdesplazada (ºC) 8.84808176 51.5

CQSÍ 350

(MW) 300

0 =Serv. Calor 250

0 =Pinch 200
3.498
150
7.01436735
100
8.61836735
50
8.61836735
8.44938776 0
0 2 4 6 8 10 12 14
7.95018182 H (MW)
7.95018182
Tdesplazada (ºC)

7.93818182
350
8.73818182
10.2 =Serv. Frío 300

250

200

150

100

50

0
0 2 4 6 8 10 12
Q (MW)
 Treal ṁagua DHvap Cp vapor Cp líquido
(ºC) (kg s-1) (kJ kg-1) (kJ kg-1 K-1) (kJ kg-1 K-1)
350 3.23347528 1706 4 4.2
252
252 𝑄 ̇=𝑚 ̇ (𝐶_𝑝^𝑣𝑎𝑝 (350−252)°𝐶+Δ𝐻_𝑣𝑎𝑝+𝐶_𝑝^𝑙𝑖𝑞 (252−167)°𝐶)
167
100
Corte del servicio con la GCC
Q Tdespl Treal
(MW) (ºC) (ºC)
7.93818182 118.5 167

Línea auxiliar
Q Tdespl
(MW) (ºC)
7.93818182 250
7.93818182 100
 Tdesplazada (ºC)
Tdespl CQSÍ Servicio de Frío
(ºC) (MW) 600 Q
495 3.6 500 (MW)
455 9.2 0
400
415 10.8 12
305 4.2 300 16.1721854
285 0 200
215 16.8
100
195 17.6
185 16.6 0
0 5 10 15 20 25
125 16.6 Q (MW)
95 21.1
85 18.1
ervicio de Frío
Tdespl Treal ṁagua DHvap Cp líquido Cp vapor
(ºC) (ºC) (kg s-1) (kJ kg-1) (kJ kg-1 K-1) (kJ kg-1 K-1)
235 230 6.62251656 1812 4.2
235 230
85 80 𝑄 ̇=𝑚 ̇ Δ𝐻_𝑣𝑎𝑝

Corte del servicio con la GCC

Q Tdespl Treal
(MW) (ºC) (ºC)
12 235 230
 Tdesplazada (ºC)
Tdespl CQSÍ Servicio de Frío
(ºC) (MW) 600 Q
495 3.6 500 (MW)
455 9.2 0
400
415 10.8 1.0430839
305 4.2 300 12
285 0 200 15.8095238
215 16.8
100
195 17.6
185 16.6 0
0 5 10 15 20 25
125 16.6 Q (MW)
95 21.1
85 18.1
ervicio de Frío
Tdespl Treal ṁagua DHvap Cp líquido Cp vapor
(ºC) (ºC) (kg s-1) (kJ kg-1) (kJ kg-1 K-1) (kJ kg-1 K-1)
285 280 6.04686319 1812 4.2 3.45
235 230
235 230 𝑄 ̇=𝑚 ̇ (Δ𝐻_𝑣𝑎𝑝+𝐶_𝑝^𝑣𝑎𝑝 (280−230)°𝐶)
85 80

Corte del servicio con la GCC

Q Tdespl Treal
(MW) (ºC) (ºC)
12 235 230
 𝐻_2/(𝐶_7 𝐻_8 )=5 𝑚𝑜𝑙/

M Tb DHvap a Tb Cp liquido Cp vapor

(g mol-1) (ºC) (J mol-1) (J mol-1 K-1) (J mol-1 K-1)
H2 = 2 29.3 H2 =
CH4 = 16 53 CH4 =
C6H6 = 78 80.1 30765 140.9 157.9 C6H6 =
C7H8 = 92 110.6 33470 168.7 191.9 C7H8 =

∑8_𝑖▒ 〖𝑛 _𝑖=100 𝑘𝑚𝑜𝑙 〗

Suma =
Calculos =
Masa (kg) =
Entalía (kJ) =
 Reactor Reactor Reactor Reactor Reactor Reactor Reactor

DHR
A A A (J mol-1) S S S
T (ºC) = 620 -41920 T (ºC) = 681.91931
Fase = GAS XL Fase = GAS
TRef (ºC) =
𝐻_2/(𝐶_7 𝐻_8 )=5 𝑚𝑜𝑙/𝑚𝑜𝑙 25 (mol mol-1) TRef (ºC) = 25
Fase Ref. = GAS 70% Fase Ref. = GAS
xi ni Hi ni xi ni Hi Balances
-1 -1
(mol mol ) (kmol) (kJ) coef. esteq. (mol mol ) (kmol) (kJ)
50 871675 -1 43 827652.639
0.4 40 1261400 1 47 1636386
0 0 0 1 7 726092.913
10 1141805 -1 3 378188.447

0.4 100 100

100
1660 1660 0
3274880 3568320 0

∑_𝑖𝑛▒∑_𝑖▒ 〖𝑛 _(𝑖,𝑖𝑛) 𝐶_(𝑝,𝑖) (𝑇_𝑖𝑛−𝑇_𝑟𝑒𝑓) 〗 +(𝑋_𝐿 ∑_𝑖𝑛▒𝑛_(𝐿,𝑖𝑛) )/|𝜈_𝐿 | (−Δ𝐻_𝑅 )− ∑_𝑜𝑢𝑡▒ 〖∑ _𝑖▒ 〖
 Te Te Te Te Te Te Te

S S S G G G F
T (ºC) = 681.91931 T (ºC) = 33
Fase = GAS Fase = LÍQUIDO
TRef (ºC) = 25 TRef (ºC) = 25
Fase Ref. = GAS Fase Ref. = GAS
xi ni Hi xi ni Hi xi
(mol mol-1) (kmol) (kJ) (mol mol-1) (kmol) (kJ) (mol mol-1)
H2 = 43 827652.639 0 0 0
CH4 = 47 1636386 0 0 0
C6H6 = 7 726092.913 0.7 1.82296965 -52321.2343
C7H8 = 3 378188.447 0.3 0.78127271 -23543.2468

𝑥_(𝐶_6 𝐻_6 )/𝑥_(𝐶_7 𝐻_8 ) =7/3

𝑥_(𝐶_6 𝐻_6 )+𝑥_(𝐶_7 𝐻_8 )=1

Suma = 100 2.60424236
Calculos = 2.60424236
Masa (kg) = 1660 214.068722
Entalía (kJ) = 3568320 -75864.4811

𝐻_𝑅 )− ∑_𝑜𝑢𝑡▒ 〖∑ _𝑖▒ 〖𝑛 _(𝑖,𝑜𝑢𝑡) 𝐶_(𝑝,𝑖) (𝑇_𝑜𝑢𝑡−𝑇_𝑟𝑒𝑓) 〗 =0 〗 𝐻_𝑆+𝐻_𝐺−𝐻_𝐹=0

Te Te Enfr.-Flash Enfr.-Flash Enfr.-Flash

F F F F F
T (ºC) = 620 T (ºC) = 620
Fase = GAS Fase = GAS
TRef (ºC) = 25 TRef (ºC) = 25
Fase Ref. = GAS Fase Ref. = GAS
ni Hi Balances xi ni Hi
(kmol) (kJ) (mol mol-1) (kmol) (kJ)
43 749640.5 H2 = 43 749640.5
47 1482145 CH4 = 47 1482145
8.82296965 828922.41 C6H6 = 8.82296965 828922.41
3.78127271 431747.608 C7H8 = 3.78127271 431747.608

102.604242 Suma = 102.604242

Calculos =
1874.06872 0 Masa (kg) = 1874.06872
3492455.52 -3.929E-10 Entalía (kJ) = 3492455.52
Enfr.-Flash Enfr.-Flash Enfr.-Flash Enfr.-Flash Enfr.-Flash Enfr.-Flash

L L L V V V
T (ºC) = 33 T (ºC) = 33
Fase = LÍQUIDA Fase = GAS
TRef (ºC) = 25 TRef (ºC) = 25
Fase Ref. = GAS Fase Ref. = GAS
xi ni Hi xi ni Hi Balances Qenfriador
(mol mol-1) (kmol) (kJ) (mol mol-1) (kmol) (kJ) (kJ)
0 0 0.47777778 43 10079.2
0 0 0.52222222 47 19928
8.82296965 -253228.934 0 0 0
3.78127271 -113946.687 0 0 0

12.6042424 90

1036.06872 838 0
-367175.621 30007.2 6.9121597E-11 -3829623.94
Para 10 t/h
Qenfriador (kW)= -11562.8742
 Mezcl.-CalenMezcl.-CalenMezcl.-Calent

R R R H H H
T (ºC) = 50 T (ºC) = 50
Fase = GAS Fase = GAS
TRef (ºC) = 25 TRef (ºC) = 25
Fase Ref. = GAS Fase Ref. = GAS
xi ni Hi xi ni Hi
(mol mol-1) (kmol) (kJ) (mol mol-1) (kmol) (kJ)
H2 = 0.47777778 35.9176471 26309.6765 0.95 14.0823529 10315.3235
CH4 = 0.52222222 39.2588235 52017.9412 0.05 0.74117647 982.058824
C6H6 = 0 0 0 0 0 0
C7H8 = 0 0 0 0 0 0

Suma = 75.1764706 14.8235294

Calculos = 75.1764706 14.8235294
Masa (kg) = 699.976471 40.0235294
Entalía (kJ) = 78327.6176 11297.3824

0.47777778 0.95 nR 50
0.52222222 0.05 nH 40
(■8(𝑥_(𝐻_2)^𝑅&𝑥_(𝐻_2)^𝐻@𝑥_(𝐶𝐻_4)^𝑅&𝑥_(𝐶𝐻_4)^𝐻 ))(■8(𝑛^𝑅@𝑛^𝐻 ))=(

-0.10588235 2.01176471 nR = 75.1764706

1.10588235 -1.01176471 nH = 14.8235294
 T T T A A A
T (ºC) = 50 T (ºC) = 620
Fase = LÍQUIDO Fase = GAS
TRef (ºC) = 25 TRef (ºC) = 25
Fase Ref. = GAS Fase Ref. = GAS
xi ni Hi xi ni Hi Qcalentador Balances
-1 -1
(mol mol ) (kmol) (kJ) (mol mol ) (kmol) (kJ) (kJ)
0 0 0 50 871675 0
0 0 0 40 1261400 0
0 0 0 0 0
1 10 -272665.8 10 1141805
0

10 100

920 1660
-272665.8 3274880 3457920.8 0
Para 10 t/h
Qcalentador (kW)= 10440.5821

)^𝐻 ))(■8(𝑛^𝑅@𝑛^𝐻 ))=(■8(𝑛_(𝐻_2)^𝐴@𝑛_(𝐶𝐻_4)^𝐴 ))

ptotal (bar(a)) 32 1,03bar/1atm

CP(J/MOLK) 168.7 29.3 53 191.9

TOTALES TOTALES TOTALES LÍQUIDO VAPOR VAPOR VAPOR
T H2 CH4 C7H8 C7H8 H2 CH4 C7H8
(ºc) (KMOL) (KMOL) (KMOL) (KMOL) (KMOL) (KMOL) (KMOL)
50 50 40 10 10 50 40 0
55 50 40 10 9.57227189 50 40 0.42772811
 c7h8
A 6.95805
B 1346.773
C 219.693

VAPOR VAPOR VAPOR VAPOR

TOTAL YH2 Y CH4 Y C7H8
(KMOL) SUMA pvaporTolueno
90 0.55555556 0.44444444 0 1 mmhg Y C7H8
90.4277281 0.55292775 0.4423422 0.00473005 1 2.0552203 113.55867 0.00473005
liquido vapor
H H