CQ on Chap-3 (Chemistry 1st paper)

1.
a) What is electronegativity?
b) “Electron affinity of chlorine is higher than
fluorine”-explain.
c) Explain the changing of atomic radius with atomic
number in the above graph.
d) Explain the above mentioned graph.

2.
Elements of 3rd Na Mg Al Si P S Cl Ar
period→
Ionization 495.8 737.7 577.6 786.55 1011.8 999.6 1251.1 1520.5
energy (kJ/mol)
a) What is pi bond?
b) First electron affinity is exothermic process but second electron affinity is endothermic process-explain.
c) Discuss the acid-base properties of oxides of the elements given in stem.
d) Explain the variation of ionization from left to right in the given period of stem.
3.
Gr. 13 Gr. 14 Gr. 15 Gr.16 Gr. 17

Period→ 2 M W R Z X

Period→ 3 Y

a) What is second ionization potential?

b) In between 12Mg2+ and 10Ne, which one is smaller in size? Explain.
c) Explain the term ‘shielding effect’ on ionization energy with the help of period-2 elements.
d) Compare the electron affinity in between ‘X’ and ‘Y’.
4.
Element electronic configuration of period
outer shell
A (n-1) d10 ns2 4
1 2
B (n-1) d ns 4
6 2
C (n-1) d ns 4
a) What is shielding effect?
b) Phosphorous (P4) is more reactive then nitrogen (N2) - explain.
c) In between ‘B’ and ‘C’ which one is transitional element? Explain.
d) Which one can form colored complex ion among A2+, B3+ and C2+? Analyze with your logic.
5. ‘X’ is a transitional element, electron configuration is (n-1)d6 ns2;where, n=4
a) What is transitional element?
b) Normally CO2 is gaseous but SiO2 is solid –explain.
c) The element ‘X’ of the stem shows variable valency-explain why?
d) The compounds formed by the element, ‘X’ in stem are colored- analyze with proper logic.
6. Valance Bond Theory can explain the bond formation of PCl3, CH4, C2H4 and C2H2. But this theory can’t
explain bond angle and bond length. The phenomenon of orbital hybridization can do the job.
a) What is electronegativity?
b) Compound PCl5 is possible but as a compound NCl5 is not possible-explain.
c) Describe the bond formation process of the last compound of the stem by orbital hybridization.
d) What type of hybridization of Phosphorous will occur compound formed by the addition of one Cl2 with the
1st compound of the stem?
7.

a) Define transition metal.

b) Aluminium chloride exists as dimer-explain why?
c) Discuss the mentioned graph.
d) If a hydrogen ion is added to the 2nd period compound in graph what will be the changes of shape of the
molecule-analyse.
8. The electronic configuration of the outer most shell of the elements A, B, C, D are (n-1)s1, ns2np2, ns2np3
and ns2np4 respectively. Where n=2.
a) What is quantum number?
b) Why the electronic configuration of Cr is exceptional from general rule?
c) Explain the physical state of compound A2Oin normal temperature.
d) Which one’s bond angel value is greater between the hydride of ‘B’ and ‘C’ in the mentioned stem? Explain
with orbital hybridization.
9. HCHO, NH3 and H2O are some covalent compound
a) What is diamagnetic ion?
b) Boiling point of acetic acid is more than other two carbon containing organic compound-explain.
c) Explain hybridization of carbon in 1st compound mentioned in stem.
d) Analyze the shapes of mentioned last two compounds by VSEPR theory.
10.

S.N. Compound Shape Bond Angle

i NH3 Pyramidal 107
ii NF3 Pyramidal 102
iii BH4- Tetrahedral 109.28′

a) Define hydrogen bond.

b) Why sodium is kept under kerosene-explain why?
c) Explain the hybridization process of (iii) mentioned in the stem with orbital figure.
d) Why the bond angle of compound (i) and (ii) are different from each other-analyze.
11.
Group 15 16
Period
2rd X Y

a) What is electronegativity?
b) Which one is more ionic in between CuCl and KCl?
c) Carbon and silicon both form stable compounds with Y but the physical states of the compounds are
different-explain.
d) Discuss the causes of different angles of the hydrides of elements X and Y.
6. Atomic number of an element 26.
a) What is ionization potential?
b) 1st electron affinity is exothermic process but 2nd electron affinity is endothermic process- explain with
taking an example.
c) The element of the stem shows variable valency-explain why?
d) ‘The compounds formed by the element in stem are colored’- analyze this statement.
7.
S.N. Compound Shape Bond Angle
i H2O Angular 104
ii H2S Bent 92
-
iii BF4 Tetrahedral 109.28′
a) What is shielding effect?
b) Ice floats on water-explain why?
c) Explain the shape of the molecule (iii) mentioned in the stem.
d) Why the bond angle of compound (i) and (ii) are different from each other-analyze.
8.
a) Define Hydrogen bond?
b) Why ethanol is dissolve in water-explain?
c) Explain the changing of atomic radius with atomic number in the above graph.
d) Why the ionization energy of Boron and oxygen deviate from regular tend in graph?