GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

SKEMA KIMIA KERTAS 2 SET 2

Question Answer Mark

Number
1 (a)(i) Contact process 1
(a)(ii) Catalyst : Vanadium(V) oxide 1
Temperature : 450 oC 1
(a)(iii) 1. The reaction is too exothermic 1
2. Produce acidic vapor instead of liquid
(b)(i) ammonia 1
(b)(ii) 1:3 2
(c)(i) Ammonium sulphate 1
(c)(ii) firtilizer 1

Total 9

2 (a) Proton, electron and neutron 1

(b) (i) Isotopes are atoms of the same element with the same 1
number of proton but different number of neutrons

(ii) R and S 1

(iii) Cobalt-60 1

(c) (i) 2.8.1 1

(ii) 1 1

(d) 24
S 1
11

(e) (i)

T 1

(ii) Group 2 , Period 3 1

TOTAL 9

No 3 Mark scheme Mark ∑Mark

3 (a) Able to state the meaning of end point correctly
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
Answer:
The volume of an acid which exactly neutralizes the fixed volume 1 1
of an alkali
(b) Able to name the indicator correctly
Answer:
Phenolphthalein 1 1
Reject : methyl orange
(c) Able to state colour change of phenolphthalein at end point
Answer:
Pink to colourless 1 1
(d) Able to name reaction correctly
Answer:
Neutralization 1 1
(e) Able to write a balanced equation correctly

Correct formulae of reactants 1

Correct formulae of products 1 2
Answer:
HCOOH + NaOHHCOONa + H2O
(f) Able to state the volume of methanoic acid correctly
Answer:
48.60 cm3 1 1
(g) Able to calculate the concentration of methanoic acid correctly
Answer:
Mol ratio of HCOOH and NaOH =1:1
M ( 48.60 ) =1 1
0.493 X 40.551

/ concentration = 0.411mol dm-3 1 2

(h) Able to give two reasons for using ammonia gas instead of
ammonia solution
Sample answer
1. Ammonia gas does not have water in it // So latex is not 1
diluted // Latex added with ammonia gas is lighter
compared to latex added with ammonia solution .
2. It is easier to transport from estate to factory // Save 1 2
transportation cost.
11
Total

Question Answer Mark

Number
4 (a)(i) CnH 2n+1 OH 1
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
(a)(ii) Hydroxyl 1

(b)(i) propena 1
(b)(ii) 1
H H H
| | |
H- C = C -C–H
|
H

(c) (i) Potassium manganate(VII) // potassium dichromate(VI) 1

(ii) Purple to colourless // orange to green 1
(d)(i) 2C3H6 + 9O2 6CO2 + 6H2O 1+1
11.2 = 0.2667
(d)(ii) 42 1

2mol C3H6 : 6mol CO2 1

0.2667 mol C3H6 : 0.8 mol CO2
Bil molekul CO2 = 4.824 x 1023

Total 10

Question Answer Mark

Number
5 (a) Acidified Potassium manganate(VII) 1
(b) +7 1
(c) reduction 1
(d)(i) Colourless solution turn brown 1
(ii) 2I- → I2 + 2e 2
(iii) Iodide ion release electron 1
(e) To allow the flow of ion from both electrolytes 1
(f) Functional diagram of simple cell 1
Label 1
Total 10

Number Answer / sample answer Marks

6 (a) CaCO3 + 2HCl CaCl2 + CO2 + H2O
1. Correct formula reactants and products 1
2. Balanced equation 1 2
(b) (i)  correct label of axes and units for both axes – X and – Y and
correct uniform scale 1
 correct transfer of data 1
1 3
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

 smooth curve
(ii)  tangent on the curve 1
 answer : 0.14 ± 0.05 cm3s-1 1 2
3
(c) (i) Volume of gas / cm

b(i)
c(i)

Time /s

(ii) (Refer to (b) (i)

1. The smaller the size of reactants, the larger the total surface
area // 1
2. frequency of collision between particles increases 1
3. frequency of effective collision increases 1 4
( vice versa for (c) (i) )
11

NO JAWAPAN MARKAH
7 (a) Blue precipitate formed 1
Copper(II)hydroxide salt that insoluble in water form 1
Cu2+ + 2OH-  Cu(OH)2 1
(b) Observation :Blue precipitate formed and dissolve in excess 1
ammonia solution 1
Explanation : Cu(OH)2 dissolve in excess ammonium solution
(c) (i) Solid J – copper(II)oxide 1
Gas K – oxygen 1
Gas L – nitrogen dioxide 1
(ii) 2Cu(NO3)2  2CuO + O2 + NO2 1+1
(d) (i) *anion : probably is nitrate 1
Salt Q is dissolved in water 1
Iron(II)sulphate and concentrated sulphuric acid are added 1
slowly
A brown ring is formed 1
(ii) *cation : probably are aluminium & lead(II) 1
Potassium iodide is added to solution Q 1
Yellow/white precipitate is formed 1
Yellow/white precipitate shows the presence of lead(II) ion 1
No precipitate formed
No precipitate indicates the presence of aluminium ion
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
8 a Aluminium ion : 2.8 1
Oxide ion : 2.8.8 1

b (i)

- 2+
-
Cl Mg Cl

1. Correct number of shells and number of electron

2. Correct charge
[Description]
3. To achieve the stability of electron arrangement
4. Magnesium / Mg atom donates two electron to form
magnesium ion / Mg2+ and Chlorine / Cl atom accepts one
electron to form chloride ion / Cl-
5. [one] magnesium / Mg atom donate two electron to two
chlorine atoms
6. Magnesium ion / Mg2+ and chloride ion / Cl- are attracted
to one another by electrostatic forc
XX
XX
X
X X Cl XX
X X XX
XX X XX
b ii XX XX
X X XX
X X Cl X
X X XX X XX
C X X X Cl X X X
X
XX X
XX XX
XX XX
X
X X Cl XX
XX X X
X
XX
XX

1. Correct number of shell and electron

2. Correct number of atoms of carbon and chlorine
[Description]
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
3. To achieve the stability of electron arrangement
4. Carbon atom contribute four electron and chlorine atom
contribute one electron
5. One carbon atom share four electron with four chlorine
atoms.

c i 1. Compound (b)(i) / MgCl2 is an ionic compound 1

2. In molten state, MgCl2 has freely moving ions 1
3. Compound (b)(ii) / CCl4 is a covalent compound. 1
4. CCl4 has no freely moving ions// only consist of molecules. 1

ii 1. Ions in MgCl2 are held together by strong electrostatic force 1

2. A lot of heat energy is needed to overcome / break the 1
strong electrostatic force
3. Molecules in CCl4 are held together by weak intermolecular 1
forces / van der Waals
4. Less heat energy is needed to overcome the forces 1

9 a Water on the wet shirt evaporated 1

Evaporation absorbs heat energy from body 1
b 1. A and B are the reactants 1
2. C and D are the products 1
3. Heat energy is absorbed from surrounding //It is an endothermic reaction 1
4. Total energy content of C and D/ product is higher than total energy
content of A and B/ reactants 1

c 1
1. 1 mole of silver nitrate solution produces 1 mole of Ag+ ion 1
2. 1 mole of sodium chloride solution produces 1 mole of Cl- ion 1
3. One e mole of potassium chloride produces 1 mole of Cl- ion 1
4. The heat of precipitation of silver chloride is heat that released when 1 1
mole of AgCl is formed from Ag+ ion and Cl- ion
// Ag+ + Cl- AgCl
5. Number of mole of AgCl produced in bothe reactions are the same, heat
released are the same.

9(d) apparatus and material : 2 marks

- procedures : 5 marks
- Table : 1 mark
- Calculation : 2 marks

Sample answer:
1
Apparatus : Polystyrene cup, thermometer, measuring cylinder.
1
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
Materials : Copper (II) sulphate, CuSO4 solution, zinc powder.

Procedures :
1
1. Measure 25 cm3 of 0.2 mol dm-3 copper (II) sulphate, CuSO4 solution
and pour it into a polystyrene cup. 1
2. Put the thermometer in the polystyrene cup and record the initial
temperature of the solution. 1
3. Add half a spatula of zinc powder quickly and carefully into the 1
polystyrene cup.
1
4. Stir the reaction mixture with the thermometer to mix the reactants.
5. Record the highest temperature reached.

Tabulation of data:
1
Initial temperature of CuSO4 solution (oC) 1
Highest temperature of the reaction mixture (oC) 2
Temperature change (oC) 2 - 1

Calculation :
1
Number of mole of CuSO4
= MV/1000 = (0.2)(25)/1000 = 0.005 mol

Heat change = mc(2 - 1) = x J

1
-1
Heat of displacement = x / 0.005 kJ mol
= y kJ mol-1

10(a)(i) Electrodes Anode Cathode

Product Oxygen gas Hydrogen gas 1+1
Half- 4OH-→ O2+2H2O+4e 2H+ + 2e → H2
equation 1+1

(ii) 1
1. Concentration of hydrochloric acid increases 1
2. Cl- and OH- ions attracted to the anode
OH- ions selectively discharged – lower position in the electrochemical
series 1
3. H+ ions attracted to the anode
H+ ions are discharged – one type of ions only 1
4. Therefore only left with H+ and Cl- ions

(iii) 1
Anode: Position of ions the electrochemical series 1
Cathode: Position of ions in the electrochemical series
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

(b)
Procedure: 1
1. Clean a piece of iron ring with sand paper. 1
2. Pour 100cm3 of copper(II)nitrate solution , 0.1moldm-3 in a
beaker 1
3. Connect iron ring to the negative terminal and a copper plate to
the positive terminal. 1
4. Dip the both terminal into the copper(II)nitrate solution

 Rajah berfungsi 1 markah

 Label bahan kimia 1 markah

Electrode Anode/anod Cathode/katod

Half-equation Cu → Cu+2 + 2e Cu+2 + 2e → Cu 1+1
Copper becomes thinner Iron ring is coated with
Observation / decrease in size / mass shiny brown solid
1+1