1.

Perbandingan volume air dan volime dioksan

Rumus : δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
Diketahui :
 Volume total = 5 mL
 δ air = 23,5
 δ dioksan = 10,0
 Volume air =x
 Volume dioksan = 5-x
Perhitungan :
a. δ total = 10,0
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
10,0 . 5 = ( x . 23,5) + ( (5-x) . 10,0)
50 = 23,5x + 50-10x
23,5x – 10x = 50-50
13,5x =0
0
x =
13,5
x=0
Maka :
V air = 0
V dioksan =5–x
=5–0
= 5 mL
b. δ total = 12,0
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
12,0 . 5 = ( x . 23,5 ) + ( (5 – x ) . 10,0)
60 = 23,5x + 50 – 10x
23,5x – 10 x = 60 – 50
13,5x = 10
10
x =
13,5
x = 0,74
Maka:
V air = 0,74 mL
 V dioksan =5–x
= 5 – 0,74
= 4,26 mL
c. δ total = 14,0
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
14,0 . 5 = ( x . 23,5) + ( (5 -x) . 10,0)
70 = 23,5x + 50 – 10x
23,5x – 10x = 70 – 50
13,5x = 20
20
x =
13,5
x = 1,48
Maka:
V air = 1,48 mL
V dioksan =5–x
= 5 – 1,48
= 3,52 mL
d. δ total = 17,0
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
17,0 . 5 = ( x . 23,5) + ( (5 -x) . 10,0)
85 = 23,5x + 50 – 10x
23,5x – 10x = 85 – 50
13,5x = 35
35
x =
13,5
x = 2,59
Maka:
V air = 2,59 mL
V dioksan =5–x
= 5 – 2,59
= 2,41 mL
e. δ total = 20,0
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
20,0 . 5 = ( x . 23,5) + ( (5 -x) . 10,0)
 100 = 23,5x + 50 – 10x
23,5x – 10x = 100 – 50
13,5x = 50
50
x =
13,5
x = 3,70
Maka:
V air = 3,70 mL
V dioksan =5–x
= 5 – 3,70
= 1,3 mL
f. δ total = 23,5
δ total . V total = (Vair . δ air) + (V dioksan . δ dioksan)
23,5 . 5 = ( x . 23,5) + ( (5 -x) . 10,0)
117,5 = 23,5x + 50 – 10x
23,5x – 10x = 117,5 – 50
13,5x = 67,5
67,5
x =
13,5
x =5
Maka:
V air = 5 mL
V dioksan =5–x
=5–5
= 0 mL
b
2. Penentuan kadar kafein (% )
v
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Rumus: Kadar % = x
v vol larutan x 1000
100%
Diketahui :
 Volume titran blanko : 8 mL
 Na titran : 0,1 N
 BE : 194,19 g/mol
Perhitungan :

a. δ total = 10,0
V titran = 2,3 mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−2,3 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
5,7 mL x 19,419
= x 100 %
5000
110,688
= x 100 %
5000
= 2,2137 mg%
b. δ total = 12,0
V titran = 3,4 mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−3,4 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
4,6 mL x 19,419
= x 100 %
5000
89,3274
= x 100 %
5000
= 1,7865 mg%
c. δ total = 14,0
V titran = 7,6mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−7,6 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
0,4 mL x 19,419
= x 100 %
5000
7,7676
= x 100 %
5000
 = 0,1553 mg%
d. δ total = 17,0
V titran = 5,0 mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−5,0 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
3 mL x 19,419
= x 100 %
5000
58,257
= x 100 %
5000
= 1,1651 mg%
e. δ total = 20,0
V titran = 4,5 mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−4,5 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
3,5 mL x 19,419
= x 100 %
5000
67,9665
= x 100 %
5000
= 1,3593 mg%
f. δ total = 23,5
V titran = 3,0 mL
b ( Vol. blanko ( mL )−Vol . titran ( mL ) ) x N titran x BE
Kadar % = x
v vol larutan x 1000
100%
( 8 mL−3,0 mL ) x 0,1 x 194,19
= x 100 %
5 mL x 1000
5 mL x 19,419
= x 100 %
5000
97,095
= x 100 %
5000
 = 1,9419 mg%

Perhitungan Kadar (g/5ml)

a. δ total = 10,0
Kadar kafein = 2,21 mg%
2,21 100 ml
=
x 5 ml
100x = 11,05
11,05
x =
100
x = 0,1105g/5ml
b. δ total = 12,0
Kadar kafein = 1,78 mg%
1,78 100 ml
=
x 5 ml
100x = 8,9
8,9
x =
100
x = 0,089g/5ml
c. δ total = 14,0
Kadar kafein = 0,15 mg%
0,15 100 ml
=
x 5 ml
100x = 0,75
0,75
x =
100
x = 0,0075g/5ml
d. δ total = 17,0
Kadar kafein = 1,16 mg%
1,16 100 ml
=
x 5 ml
100x = 5,8
5,8
x =
100
x = 0,058g/5ml
 e. δ total = 20,0
Kadar kafein = 1,36 mg%
1,36 100 ml
=
x 5 ml
100x = 6,75
6,75
x =
100
x = 0,0675g/5ml
f. δ total = 23,5
Kadar kafein = 1,94 mg%
1,94 100 ml
=
x 5 ml
100x = 9,7
9,7
x =
100
x = 0,097g/5ml
3. Perhitungan Fraksi mol kafein
mol sampel
Rumus : Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
Diketahui :
 BM Kafein = 194,19 g/mol
 BM air = 18 g/mol
 BM Dioksan = 88,119 g/mol
 V total = 5 ml

Perhitungan :

a. δ total = 10,0
Kadar kafein = 110,5 x 10-3 g/5ml
Bobot Kafein = 110,5 x 10-3 g
g 110,5 x 10−3
mol Kafein = = = 5,69 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – 110,5 x 10-3 g = 4,8895 g
Perbandingan Dioksan dan air = 5 : 0
 5
Bobot dioksan = x 4,8895 g = 4,8895 g
5
0
Bobot air = x 4,8895 g = 0 g
5
4,8895 g
Mol dioksan = = 0,055 mol
88,119 g/mol
0g
Mol air = = 0 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
5,69 x 10−4
=
0+0,055+5,69 x 10−4
= 101,6 x 10-4
b. δ total = 12,0
Kadar kafein = 89 x 10-3 g/5ml
Bobot Kafein = 89 x 10-3 g
g 89 x 10−3
mol Kafein = = = 4,5831 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – (89 x 10-3 g) = 4,911 g
Perbandingan Dioksan dan air = 4,26 : 0,74
4,26
Bobot dioksan = x 4,9911 g = 4,2524 g
5
0,74
Bobot air = x 4,9911 g = 0,7386 g
5
4,2524 g
Mol dioksan = = 0,0482 mol
88,119 g/mol
0,7386 g
Mol air = = 0,0410 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
4,5831 x 10−4
=
0,0410+0,0482+4,5831 x 10−4
= 51,11 x 10-4
c. δ total = 14,0
Kadar kafein = 7,5 x 10-3 g/5ml
Bobot Kafein = 7,5 x 10-3 g
 g 7,5 x 10−3
mol Kafein = = = 0,3862 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – 7,5 x 10-3 g = 4,9925 g
Perbandingan Dioksan dan air = 3,52 : 1,48
3,52
Bobot dioksan = x 4,9925 g = 3,5147 g
5
1,48
Bobot air = x 4,9925 g = 1,4777 g
5
3,5147 g
Mol dioksan = = 0,0398 mol
88,119 g/mol
1,4777 g
Mol air = = 0,0820 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
0,3862 x 10− 4
=
0,0820+0,0398+0,3862 x 10−4
= 3,169 x 10-4
d. δ total = 17,0
Kadar kafein = 58 x 10-3 g/5ml
Bobot Kafein = 58 x 10-3 g
g 58 x 10−3
mol Kafein = = = 2,9867 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – (58 x 10-3 g) = 4,942 g
Perbandingan Dioksan dan air = 2,41 : 2,59
2,41
Bobot dioksan = x 4,942 g = 2,3820 g
5
2,59
Bobot air = x 4,942 g = 2,5599 g
5
2,3820 g
Mol dioksan = = 0,0270 mol
88,119 g/mol
2,5599 g
Mol air = = 0,1422 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
 2,9867 x 10−4
=
0,1422+ 0,0270+2,9867 x 10−4
= 17,62 x 10-4
e. δ total = 20,0
Kadar kafein = 67,5 x 10-3 g/5ml
Bobot Kafein = 67,5 x 10-3 g
g 67,5 x 10−3
mol Kafein = = = 3,4759 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – (67,5 x 10-3 g) = 4,9325 g
Perbandingan Dioksan dan air = 1,3 : 3,7
1,3
Bobot dioksan = x 4,9325 g = 1,2824 g
5
3,7
Bobot air = x 4,9325 g = 3,650 g
5
1,2824 g
Mol dioksan = = 0,0145 mol
88,119 g/mol
3,650 g
Mol air = = 0,2027 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
3,4759 x 10−4
=
0,2027+0,0145+3,4759 x 10−4
= 15,97 x 10-4
f. δ total = 23,5
Kadar kafein = 97 x 10-3 g/5ml
Bobot Kafein = 97 x 10-3 g
g 97 x 10−3
mol Kafein = = = 4,9951 x 10-4 mol
BM 194,19
Bobot kafein + air + dioksan = 5 ml = 5g
Bobot air + Dioksan = 5g – (97 x 10-3 g) = 4,903 g
Perbandingan Dioksan dan air = 0 : 5
0
Bobot dioksan = x 4,903 g = 0 g
5
5
Bobot air = x 4,903 g = 4,903 g
5
 0g
Mol dioksan = = 0 mol
88,119 g/mol
4,903 g
Mol air = = 0,2723 mol
18 g / mol
mol sampel
Fraksi mol sampel =
mol air+ mol dioksan+mol sampel
4,9951 x 10−4
=
0,2723+0+ 4,9951 x 10−4
= 18,31 x 10-4
4. Perhitungan Fraksi mol teoritis
Rumus :
2
Δ Hf T o −T V 2 Φ1 2
−log X 2 = ( )+ ( ∂ −∂ )
Fraksi mol teoritis = 2 ,303 RT T o 2 , 303 RT 1 2

Diketahui :
 𝛥𝐻f = 5044 kal/mol
 R = 1,987
 T0 = 512oK
 T = 30oC = 303oK
 V2 = 144 cm3/mol
 Φ1 =1
 δ2 = 14,1

Perhitungan :

a. δ total = 10,0
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT (
T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
5044 512−303 144 x 12
- log X2 =
2,303 x 1,987 x 303 (
512
+ )
2,303 x 1,987 x 303
( 10,0 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(16,81)

- log X2 = 3,6378 (0,4082) + 0,1038 (16,81)

- log X2 = 1,48 + 1,74
-log X2 = 3,22
 log X2 = -3,22
X2 = 6,02 x 10-4
b. δ total = 12,0
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT( T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
5044 512−303 144 x 12
- log X2 = (
2,303 x 1,987 x 303 512
+ )
2,303 x 1,987 x 303
( 12,0 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(4,41)

- log X2 = 3,6378 (0,4082) + 0,1038 (4,41)

- log X2 = 1,48 + 0,458
-log X2 = 1,938
log X2 = -1,938
X2 = 11 x 10-3
c. δ total = 14,0
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT( T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
5044 512−303 144 x 12
- log X2 = (
2,303 x 1,987 x 303 512
+ )
2,303 x 1,987 x 303
( 14,0 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(0,01)

- log X2 = 3,6378 (0,4082) + 0,1038 (0,01)

- log X2 = 1,48 + 0,001
-log X2 = 1,49
log X2 = -1,49
X2 = 32 x 10-3
d. δ total = 17,0
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT (T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
 5044 512−303 144 x 12
- log X2 = (
2,303 x 1,987 x 303 512
+ )
2,303 x 1,987 x 303
( 17,0 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(8,41)

- log X2 = 3,6378 (0,4082) + 0,1038 (8,41)

- log X2 = 1,48 + 0,872
-log X2 = 2,352
log X2 = -2,352
X2 = 4,44 x 10-3
e. δ total = 20,0
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT( T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
5044 512−303 144 x 12
- log X2 = (
2,303 x 1,987 x 303 512
+ )
2,303 x 1,987 x 303
( 20,0 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(34,81)

- log X2 = 3,6378 (0,4082) + 0,1038 (34,81)

- log X2 = 1,48 + 3,613
-log X2 = 5,093
log X2 = -5,093
X2 = 8,07 x 10-6
f. δ total = 23,5
ΔH f T 0−T V 2 Φ 21
Fraksi mol teoritis = - log X2 =
2,303 RT (T0
+ )
2,303 RT
(𝜕1 −

𝜕2)2
5044 512−303 144 x 12
- log X2 = (
2,303 x 1,987 x 303 512
+ )
2,303 x 1,987 x 303
( 23,5 – 14,1)2
5044 209 144
- log X2 = ( )
1386,54 512
+
1386,54
(88,36)

- log X2 = 3,6378 (0,4082) + 0,1038 (88,36)

- log X2 = 1,48 + 9,171
-log X2 = 10,651
log X2 = -10,65
X2 = 2,23 x 10-11