11th

Structure of Atom
Quantum Numbers-3
LECTURE 13
Dr Monica Bedi
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QUANTUM NUMBERS Atomic Structure Lecture- 13
QUANTUM NUMBERS Atomic Structure Lecture- 13

THE PRINCIPAL QUANTUM NUMBER (n)

 QUANTUM NUMBERS Atomic Structure Lecture- 13

AZIMUTHAL QUANTUM NUMBER (l )

Value of l -------> 0 1 2 3 4 5 6

Designation of sub- s p d f g h i
shell -------->
QUANTUM NUMBERS Atomic Structure Lecture- 13

AZIMUTHAL QUANTUM NUMBER (l )

QUANTUM NUMBERS Atomic Structure Lecture- 13

THE MAGNETIC QUANTUM NUMBER (mI)

This quantum number which is denoted by mI refers to the different
orientations of electron cloud in a particular sub-shell.
These different orientations are called Orbitals.
QUANTUM NUMBERS Atomic Structure Lecture- 13

THE MAGNETIC QUANTUM NUMBER (mI)

QUANTUM NUMBERS Atomic Structure Lecture- 13

THE MAGNETIC QUANTUM NUMBER (mI)

 Atomic Structure Lecture- 11
Amazing things of Chemistry
QUANTUM NUMBERS Atomic Structure Lecture- 13
Orbitals Atomic Structure Lecture- 13
QUANTUM NUMBERS Atomic Structure Lecture- 13
QUANTUM NUMBERS Atomic Structure Lecture- 13

THE MAGNETIC QUANTUM NUMBER (mI)

QUANTUM NUMBERS Atomic Structure Lecture- 13

THE MAGNETIC QUANTUM NUMBER (mI)

Sub-shell s p d f g

Value of l 0 1 2 3 4

No. of orbitals (2I + 1) 1 3 5 7 9

 Crack it! Atomic Structure Lecture- 13

What is the total number of orbitals associated with the principal quantum
number, n = 3 ?
Crack it! Atomic Structure Lecture- 13

An electron is in a 4 f – orbital. What possible values for the quantum

number n, l can it have ?
 Atomic Structure Lecture- 13
Quantum Numbers

Which of the following set of quantum numbers are not possible and why
(a) n = 0 l=0 ml = 0 ms = + 1/2
(b) n = 1 l=0 ml = 0 ms = – 1/2
(c) n = 1 l=1 ml = – 0 ms = + 1/2
(d) n = 2 l=1 ml = 0 ms = – 1/2
(e) n = 3 l=3 ml = – 3 ms = + 1/2
(f) n = 3 l=2 ml = 0 ms = + 1/2
 Atomic Structure Lecture- 13
Quantum Numbers

Write n and l and m values for 3d2, 4px, 2pz, 2s

Crack it! Atomic Structure Lecture- 13

When azimuthal q. No. has value of 2, the number of orbitals possible

are :
(a) 3 (b) 0 (c) 7 (d) 5
 QUANTUM NUMBERS Atomic Structure Lecture- 13

THE SPIN QUANTUM NUMBER (ms)

This quantum number determines the orientation of spin.
The spin quantum number can have only two values which are + ½ and – ½.
The + ½ value indicates clockwise spin (generally represented by an arrow
pointing upwards, i.e.,) and the other indicates anti-clockwise spin (generally
represented by an arrow pointing downwards i.e., ).
Crack it! Atomic Structure Lecture- 13

The maximum number of electrons that can be accommodated is f-shell

is
(a) 2 (b) 8 (c) 18 (d) 14
Crack it! Atomic Structure Lecture- 13

How many electrons can fill into the orbitals that comprise the 3rd
quantum shell n = 3 ?
(a) 2 (b) 8 (c) 18 (d) 32
Race

How many orbitals and electrons are associated with n = 4 ?

(a) 32, 64 (b) 16, 32 (c) 4, 16 (d) 8, 16
 Atomic Structure Lecture- 13
Rules for filling Subshell

(1) Aufbau Principle

(2) (n + l) rule
(3) Hund’s maximum multiplicity principle
(4) Pauli’s exclusion principle
 Atomic Structure Lecture- 13
Aufbau Principle :

Aufbau is a German word and its meaning ‘Building up’

– Aufbau principle gives a sequence in which various subshell are
filled up depending on the relative order of the Energies of various
subshell.
– The sequence in which various subshell are filled are as follows.
 Atomic Structure Lecture- 13
Aufbau Principle :
 Atomic Structure Lecture- 13
Aufbau Principle :
 Atomic Structure Lecture- 13
Aufbau Principle :
 Atomic Structure Lecture- 13
Aufbau Principle :
 Atomic Structure Lecture- 13
Aufbau Principle :
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