Actual 29 Juli

Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 42 T/h
Capacity 345.616630283515 TPD VCM 41930.15 Kg/h
41,457.48 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
418.94 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 423.71234551683 kmol

Molecular Weight VCM MWVCM 62.499 cracking 230.414773492052 230.414773 230.4148 kmol
Molecular Weight HCl MWHCl 36.461 remain 193.297572024778 230.414773 230.4148 kmol
1.95330967395364 345.61663
CONVECTION 1 3.68669536 6.319486
192.3289 oC
EDC Temp in T1,in
465.4789 K
401.2332 oC 460.829547
EDC Temp out T1,out
674.3832 K
EDC Heat Capacity Cp1,in 5,550.41 kcal/kmol
Heat Duty Convection 1 Q1 2,325,266.11 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.69 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,615.02 kg/hr 4,360.00 2,460.99 321,224.75
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 533,786.88 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 1
 Actual 29 Juli
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

401.2332 oC
Temp in Tr,in
674.3832 K 33678.1 kJ/kmol
491.5199 oC 1871.006 kJ/kg
Temp out Tr,out
764.6699 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,819,400.24 kcal/hr

HEAT OUTLET
EDC Outlet
188.52 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
18,655.87 kg/hr
Entalpy of EDC outlet 2,225,499.10 kcal/hr

VCM Outlet
230.41 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
14,400.69 kg/hr
Entalpy of VCM outlet 1,938,382.21 kcal/hr

HCl Outlet
230.41 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,401.15 kg/hr
Entalpy of HCl outlet 756,044.13 kcal/hr
668370
Total Entalpy Product HOUT 4,919,925.43 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,864,682.83 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,965,208.02 kcal/hr

Page 2
 Actual 29 Juli
7,824,261.01 kcal/hr
Total Heat Absorbed QF
31.05 MMBTU
mmBTU
mH2 306.5121 kg/hr 1.0375 836.807224628572 589
mNG 76.15 kg/hr 1.522 77.5969502857143 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 9,601,243.84 kcal/hr

Efisiensi ղ 81.49 % 745.179543220351

1.03

0.035959595959596

12

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
07/29/2019 08:00:00 2.769368 41.93015 314.0962 2.686355 76.14654 401.2332 192.3289 491.5199 491.5301 1.429208 2.5

Page 3
 Actual 29 Juli
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 4
 Actual 29 Juli
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 5
 Actual 29 Juli

imit PDR 21153

1.472435

Page 6
 Actual 24 Juli
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 42 T/h
Capacity 349.424911330055 TPD VCM 42392.17 Kg/h
41,914.29 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
423.55 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 428.381147748057 kmol

Molecular Weight VCM MWVCM 62.499 cracking 232.953668145394 232.953668 232.9537 kmol
Molecular Weight HCl MWHCl 36.461 remain 195.427479602664 232.953668 232.9537 kmol
1.97483280553223 349.424911
CONVECTION 1 3.72731833 6.389119
192.499 oC
EDC Temp in T1,in
465.649 K
422.3528 oC 465.907336
EDC Temp out T1,out
695.5028 K
EDC Heat Capacity Cp1,in 6,161.57 kcal/kmol
Heat Duty Convection 1 Q1 2,609,747.27 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 1.76 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 1,717.79 kg/hr 4,360.00 2,460.99 211,010.79
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 350,641.70 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 7
 Actual 24 Juli
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

422.3528 oC
Temp in Tr,in
695.5028 K 33678.1 kJ/kmol
487.6748 oC 1871.006 kJ/kg
Temp out Tr,out
760.8248 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,122,068.24 kcal/hr

HEAT OUTLET
EDC Outlet
190.60 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
18,861.43 kg/hr
Entalpy of EDC outlet 2,227,636.25 kcal/hr

VCM Outlet
232.95 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
14,559.37 kg/hr
Entalpy of VCM outlet 1,940,141.87 kcal/hr

HCl Outlet
232.95 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,493.72 kg/hr
Entalpy of HCl outlet 757,898.01 kcal/hr
668370
Total Entalpy Product HOUT 4,925,676.12 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,907,267.00 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,710,874.89 kcal/hr

Page 8
 Actual 24 Juli
7,671,263.85 kcal/hr
Total Heat Absorbed QF
30.44 MMBTU
mmBTU
mH2 221.8678 kg/hr 1.0375 605.720224266667 589
mNG 635.13 kg/hr 1.522 647.228427619048 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 13,155,960.84 kcal/hr

Efisiensi ղ 58.31 % 730.608154339576

1.01

0.035959595959596

12

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
07/24/2019 08:00:00 6.294335 42.39217 221.8678 1.764652 635.1307 422.3528 192.499 487.6748 487.6744 1.611524 2.5

Page 9
 Actual 24 Juli
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 10
 Actual 24 Juli
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 11
 Actual 24 Juli

imit PDR 21153

1.513215

Page 12
 Actual 12 Juli
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 42 T/h
Capacity 343.6076429248 TPD VCM 41686.42 Kg/h
41,216.50 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
416.50 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 421.249406319789 kmol

Molecular Weight VCM MWVCM 62.499 cracking 229.075427156701 229.075427 229.0754 kmol
Molecular Weight HCl MWHCl 36.461 remain 192.173979163088 229.075427 229.0754 kmol
1.94195554889487 343.607643
CONVECTION 1 3.66526548 6.282752
192.4183 oC
EDC Temp in T1,in
465.5683 K
408.7957 oC 458.150854
EDC Temp out T1,out
681.9457 K
EDC Heat Capacity Cp1,in 5,767.57 kcal/kmol
Heat Duty Convection 1 Q1 2,402,198.40 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 1.96 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 1,910.24 kg/hr 4,360.00 2,460.99 234,651.41
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 389,925.88 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 13
 Actual 12 Juli
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

408.7957 oC
Temp in Tr,in
681.9457 K 33678.1 kJ/kmol
493.1352 oC 1871.006 kJ/kg
Temp out Tr,out
766.2852 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,888,538.07 kcal/hr

HEAT OUTLET
EDC Outlet
187.43 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
18,547.43 kg/hr
Entalpy of EDC outlet 2,221,824.02 kcal/hr

VCM Outlet
229.08 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
14,316.99 kg/hr
Entalpy of VCM outlet 1,935,223.41 kcal/hr

HCl Outlet
229.08 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,352.32 kg/hr
Entalpy of HCl outlet 754,326.22 kcal/hr
668370
Total Entalpy Product HOUT 4,911,373.65 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,842,218.34 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,865,053.93 kcal/hr

Page 14
 Actual 12 Juli
7,657,178.21 kcal/hr
Total Heat Absorbed QF
30.39 MMBTU
mmBTU
mH2 313.0649 kg/hr 1.0375 854.696992704762 589
mNG 92.92 kg/hr 1.522 94.6880500952381 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 9,968,542.95 kcal/hr

Efisiensi ղ 76.81 % 729.266643328369

1.01

0.035959595959596

12

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
07/12/2019 08:00:00 4.523676 41.68642 313.0649 1.962355 92.91818 408.7957 192.4183 493.1352 493.1216 1.545314 2.5

Page 15
 Actual 12 Juli
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 16
 Actual 12 Juli
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 17
 Actual 12 Juli

imit PDR 21153

1.434295

Page 18
 Actual 9 Juli
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 44 T/h
Capacity 360.828076232473 TPD VCM 43775.6 Kg/h
43,282.13 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
437.37 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 442.360977778676 kmol

Molecular Weight VCM MWVCM 62.499 cracking 240.555899716044 240.5559 240.5559 kmol
Molecular Weight HCl MWHCl 36.461 remain 201.805078062632 240.5559 240.5559 kmol
2.03927968211716 360.828076
CONVECTION 1 3.84895598 6.597622
192.1971 oC
EDC Temp in T1,in
465.3471 K
400.073 oC 481.111799
EDC Temp out T1,out
673.223 K
EDC Heat Capacity Cp1,in 5,520.02 kcal/kmol
Heat Duty Convection 1 Q1 2,414,314.18 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.77 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,699.17 kg/hr 4,360.00 2,460.99 331,561.89
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 550,964.36 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 19
 Actual 9 Juli
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

400.073 oC
Temp in Tr,in
673.223 K 33678.1 kJ/kmol
493.5495 oC 1871.006 kJ/kg
Temp out Tr,out
766.6995 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,972,830.27 kcal/hr

HEAT OUTLET
EDC Outlet
196.82 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
19,476.96 kg/hr
Entalpy of EDC outlet 2,335,670.00 kcal/hr

VCM Outlet
240.56 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
15,034.50 kg/hr
Entalpy of VCM outlet 2,034,395.32 kcal/hr

HCl Outlet
240.56 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,770.91 kg/hr
Entalpy of HCl outlet 792,851.55 kcal/hr
668370
Total Entalpy Product HOUT 5,162,916.86 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,034,777.11 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 5,224,863.70 kcal/hr

Page 20
 Actual 9 Juli
8,190,142.24 kcal/hr
Total Heat Absorbed QF
32.50 MMBTU
mmBTU
mH2 314.6518 kg/hr 1.0375 859.029380838095 589
mNG 98.14 kg/hr 1.522 100.004574380952 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,069,856.53 kcal/hr

Efisiensi ղ 81.33 % 780.025928073468

1.08

0.035959595959596

12

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
07/09/2019 08:00:00 2.319197 43.7756 314.6518 2.772803 98.13533 400.073 192.1971 493.5495 493.5573 1.750873 2.5

Page 21
 Actual 9 Juli
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 22
 Actual 9 Juli
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 23
 Actual 9 Juli

imit PDR 21153

1.630774

Page 24
 Actual 4 Juli
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 40 T/h
Capacity 333.366530448557 TPD VCM 40443.97 Kg/h
39,988.06 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
404.09 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 408.69420669166 kmol

Molecular Weight VCM MWVCM 62.499 cracking 222.247909598925 222.24791 222.2479 kmol
Molecular Weight HCl MWHCl 36.461 remain 186.446297092735 222.24791 222.2479 kmol
1.88407620421321 333.36653
CONVECTION 1 3.55602345 6.095497
191.3316 oC
EDC Temp in T1,in
464.4816 K
402.7734 oC 444.495819
EDC Temp out T1,out
675.9234 K
EDC Heat Capacity Cp1,in 5,618.82 kcal/kmol
Heat Duty Convection 1 Q1 2,270,492.45 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.01 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 1,961.20 kg/hr 4,360.00 2,460.99 240,911.24
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 400,327.99 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 1
 Actual 4 Juli
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

402.7734 oC
Temp in Tr,in
675.9234 K 33678.1 kJ/kmol
492.6463 oC 1871.006 kJ/kg
Temp out Tr,out
765.7963 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,702,035.62 kcal/hr

HEAT OUTLET
EDC Outlet
181.84 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
17,994.63 kg/hr
Entalpy of EDC outlet 2,152,882.92 kcal/hr

VCM Outlet
222.25 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
13,890.27 kg/hr
Entalpy of VCM outlet 1,875,162.92 kcal/hr

HCl Outlet
222.25 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,103.38 kg/hr
Entalpy of HCl outlet 731,057.67 kcal/hr
668370
Total Entalpy Product HOUT 4,759,103.50 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,727,702.29 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,784,770.17 kcal/hr

Page 2
 Actual 4 Juli
7,455,590.61 kcal/hr
Total Heat Absorbed QF
29.59 MMBTU
mmBTU
mH2 303.2572 kg/hr 1.0375 827.921037638095 589
mNG 0.00 kg/hr 1.522 4.42777107619E-17 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 8,693,170.90 kcal/hr

Efisiensi ղ 85.76 % 710.067519167213

0.98

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
07/04/2019 08:00:00 2.508861 40.44397 303.2572 2.014705 4.35E-17 402.7734 191.3316 492.6463 492.6431 1.497942 2.5

Page 3
 Actual 4 Juli
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 4
 Actual 4 Juli
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 5
 Actual 4 Juli

imit PDR 21153

1.359113

Page 6
 Actual 24 Juni
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 45 T/h
Capacity 373.290837101587 TPD VCM 45287.58 Kg/h
44,777.07 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
452.48 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 457.63983063693 kmol

Molecular Weight VCM MWVCM 62.499 cracking 248.864539900363 248.86454 248.8645 kmol
Molecular Weight HCl MWHCl 36.461 remain 208.775290736568 248.86454 248.8645 kmol
2.10971504094188 373.290837
CONVECTION 1 3.98189635 6.8255
193.5719 oC
EDC Temp in T1,in
466.7219 K
423.3121 oC 497.72908
EDC Temp out T1,out
696.4621 K
EDC Heat Capacity Cp1,in 6,164.04 kcal/kmol
Heat Duty Convection 1 Q1 2,789,111.49 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.76 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,690.74 kg/hr 4,360.00 2,460.99 330,526.12
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 549,243.19 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 7
 Actual 24 Juni
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

423.3121 oC
Temp in Tr,in
696.4621 K 33678.1 kJ/kmol
486.8364 oC 1871.006 kJ/kg
Temp out Tr,out
759.9864 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,416,345.33 kcal/hr

HEAT OUTLET
EDC Outlet
203.62 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
20,149.68 kg/hr
Entalpy of EDC outlet 2,374,577.55 kcal/hr

VCM Outlet
248.86 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
15,553.78 kg/hr
Entalpy of VCM outlet 2,068,095.31 kcal/hr

HCl Outlet
248.86 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
9,073.85 kg/hr
Entalpy of HCl outlet 808,154.79 kcal/hr
668370
Total Entalpy Product HOUT 5,250,827.65 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,174,135.62 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 5,008,617.93 kcal/hr

Page 8
 Actual 24 Juni
8,346,972.62 kcal/hr
Total Heat Absorbed QF
33.12 MMBTU
mmBTU
mH2 324.2428 kg/hr 1.0375 885.213724266666 589
mNG 126.84 kg/hr 1.522 129.259872380952 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,651,972.76 kcal/hr

Efisiensi ղ 78.36 % 794.962391747363

1.10

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
06/24/2019 08:00:00 7.728527 45.28758 324.2428 2.764141 126.8438 423.3121 193.5719 486.8364 488.8869 1.843761 2.5

Page 9
 Actual 24 Juni
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 10
 Actual 24 Juni
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 11
 Actual 24 Juni

imit PDR 21153

1.712892

Page 12
 Actual 19 Juni
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 45 T/h
Capacity 371.052950637503 TPD VCM 45016.08 Kg/h
44,508.63 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
449.77 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 454.896270172496 kmol

Molecular Weight VCM MWVCM 62.499 cracking 247.372591719803 247.372592 247.3726 kmol
Molecular Weight HCl MWHCl 36.461 remain 207.523678452692 247.372592 247.3726 kmol
2.09706725464781 371.052951
CONVECTION 1 3.9580248 6.784581
192.8427 oC
EDC Temp in T1,in
465.9927 K
432.0573 oC 494.745183
EDC Temp out T1,out
705.2073 K
EDC Heat Capacity Cp1,in 6,438.93 kcal/kmol
Heat Duty Convection 1 Q1 2,896,026.57 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.24 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,181.29 kg/hr 4,360.00 2,460.99 267,945.91
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 445,252.16 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 13
 Actual 19 Juni
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

432.0573 oC
Temp in Tr,in
705.2073 K 33678.1 kJ/kmol
484.0341 oC 1871.006 kJ/kg
Temp out Tr,out
757.1841 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,505,652.97 kcal/hr

HEAT OUTLET
EDC Outlet
202.40 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
20,028.88 kg/hr
Entalpy of EDC outlet 2,343,057.86 kcal/hr

VCM Outlet
247.37 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
15,460.54 kg/hr
Entalpy of VCM outlet 2,040,564.33 kcal/hr

HCl Outlet
247.37 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
9,019.45 kg/hr
Entalpy of HCl outlet 798,300.93 kcal/hr
668370
Total Entalpy Product HOUT 5,181,923.11 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,149,111.59 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,825,381.73 kcal/hr

Page 14
 Actual 19 Juni
8,166,660.46 kcal/hr
Total Heat Absorbed QF
32.41 MMBTU
mmBTU
mH2 334.3307 kg/hr 1.0375 912.754652019047 589
mNG 133.29 kg/hr 1.522 135.826615238095 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 11,010,103.31 kcal/hr

Efisiensi ղ 74.17 % 777.78953233763

1.08

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
06/19/2019 08:00:00 4.762517 45.01608 334.3307 2.240792 133.2878 432.0573 192.8427 484.0341 485.9379 1.854031 2.5

Page 15
 Actual 19 Juni
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 16
 Actual 19 Juni
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 17
 Actual 19 Juni

imit PDR 21153

Page 18
 Actual 8 Juni
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 45 T/h
Capacity 370.13059522192 TPD VCM 44904.18 Kg/h
44,397.99 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
448.65 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 453.765498842955 kmol

Molecular Weight VCM MWVCM 62.499 cracking 246.757678270799 246.757678 246.7577 kmol
Molecular Weight HCl MWHCl 36.461 remain 207.007820572156 246.757678 246.7577 kmol
2.09185441013102 370.130595
CONVECTION 1 3.94818602 6.767716
192.6395 oC
EDC Temp in T1,in
465.7895 K
431.7527 oC 493.515357
EDC Temp out T1,out
704.9027 K
EDC Heat Capacity Cp1,in 6,434.80 kcal/kmol
Heat Duty Convection 1 Q1 2,886,975.45 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 4.15 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 4,035.03 kg/hr 4,360.00 2,460.99 495,656.15
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 823,643.73 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 19
 Actual 8 Juni
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

431.7527 oC
Temp in Tr,in
704.9027 K 33678.1 kJ/kmol
483.1798 oC 1871.006 kJ/kg
Temp out Tr,out
756.3298 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,490,419.24 kcal/hr

HEAT OUTLET
EDC Outlet
201.89 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
19,979.09 kg/hr
Entalpy of EDC outlet 2,331,982.84 kcal/hr

VCM Outlet
246.76 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
15,422.11 kg/hr
Entalpy of VCM outlet 2,030,894.81 kcal/hr

HCl Outlet
246.76 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,997.03 kg/hr
Entalpy of HCl outlet 794,793.78 kcal/hr
668370
Total Entalpy Product HOUT 5,157,671.43 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,138,797.82 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,806,050.01 kcal/hr

Page 20
 Actual 8 Juni
8,516,669.19 kcal/hr
Total Heat Absorbed QF
33.80 MMBTU
mmBTU
mH2 314.9049 kg/hr 1.0375 859.720367942857 589
mNG 127.75 kg/hr 1.522 130.183435238095 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,393,989.93 kcal/hr

Efisiensi ղ 81.94 % 811.124226775898

1.12

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
06/08/2019 08:00:00 10.271 44.90418 314.9049 4.145099 127.7501 431.7527 192.6395 483.1798 486.3911 1.784499 2.5

Page 21
 Actual 8 Juni
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 22
 Actual 8 Juni
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 23
 Actual 8 Juni

imit PDR 21153

1.603179

Page 24
 Actual 31 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 37 T/h
Capacity 304.539090867355 TPD VCM 36946.63 Kg/h
36,530.14 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
369.14 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 373.352903727806 kmol

Molecular Weight VCM MWVCM 62.499 cracking 203.029309047181 203.029309 203.0293 kmol
Molecular Weight HCl MWHCl 36.461 remain 170.323594680625 203.029309 203.0293 kmol
1.7211531511093 304.539091
CONVECTION 1 3.24852092 5.568397
188.0904 oC
EDC Temp in T1,in
461.2404 K
429.1068 oC 406.058618
EDC Temp out T1,out
702.2568 K
EDC Heat Capacity Cp1,in 6,465.32 kcal/kmol
Heat Duty Convection 1 Q1 2,386,635.87 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.71 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,634.13 kg/hr 4,360.00 2,460.99 323,572.27
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 537,687.82 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 25
 Actual 31 mei
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

429.1068 oC
Temp in Tr,in
702.2568 K 33678.1 kJ/kmol
485.9038 oC 1871.006 kJ/kg
Temp out Tr,out
759.0538 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,665,861.93 kcal/hr

HEAT OUTLET
EDC Outlet
166.11 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
16,438.56 kg/hr
Entalpy of EDC outlet 1,932,510.51 kcal/hr

VCM Outlet
203.03 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
12,689.13 kg/hr
Entalpy of VCM outlet 1,683,063.30 kcal/hr

HCl Outlet
203.03 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
7,402.65 kg/hr
Entalpy of HCl outlet 657,942.55 kcal/hr
668370
Total Entalpy Product HOUT 4,273,516.36 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,405,354.06 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,013,008.49 kcal/hr

Page 26
 Actual 31 mei
6,937,332.17 kcal/hr
Total Heat Absorbed QF
27.53 MMBTU
mmBTU
mH2 231.8 kg/hr 1.0375 632.836076190476 589
mNG 344.22 kg/hr 1.522 350.774125714286 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,327,907.12 kcal/hr

Efisiensi ղ 67.17 % 660.708789523833

0.92

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
05/31/2019 08:00:00 10.27047 36.94663 231.8 2.705987 344.2176 429.1068 188.0904 485.9038 486.146 1.151932 2.5

Page 27
 Actual 31 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 28
 Actual 31 mei
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 29
 Actual 31 mei

imit PDR 21153

0.9949474

Page 30
 Actual 29 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 47 T/h
Capacity 385.800416368918 TPD VCM 46805.24 Kg/h
46,277.62 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
467.64 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 472.976081003244

Molecular Weight VCM MWVCM 62.499 cracking 257.204392849564 257.204392849564 257.204392849564
Molecular Weight HCl MWHCl 36.461 remain 215.77168815368 257.204392849564 257.204392849564
2.18041500170454 385.800416368918
CONVECTION 1 4.11533613097112 7.05423309425315
192.7458 C o
EDC Temp in T1,in
465.8958 K
425.7966 oC 514.408785699128
EDC Temp out T1,out
698.9466 K
EDC Heat Capacity Cp1,in 6,256.81 kcal/kmol
Heat Duty Convection 1 Q1 2,925,960.16 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.61 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893850638799
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,539.54 kg/hr 4,360.00 2,460.99 311,953.15
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A
490.36 K 468.15 490.36 92.053
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1
C2
Heat Duty Convection 2 & 3 Q3 518,380.04 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3
C4

Page 31
 Actual 29 mei
RADIANT C5
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

425.7966 oC
Temp in Tr,in
698.9466 K 33678.101785965
488.3405 oC 1871.00565477583
Temp out Tr,out
761.4905 K 8043.8798991706
25 oC 446.882216620589
Temp Reff
298.15 K
HEAT INLET
EDC Inlet
Entalpy of EDC inlet HIN 4,598,476.64 kcal/hr

HEAT OUTLET
EDC Outlet
210.44 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
20,824.93 kg/hr
Entalpy of EDC outlet 2,463,810.77 kcal/hr

VCM Outlet
257.20 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
16,075.02 kg/hr
Entalpy of VCM outlet 2,145,855.79 kcal/hr

HCl Outlet
257.20 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
9,377.93 kg/hr
Entalpy of HCl outlet 838,033.73 kcal/hr

Total Entalpy Product HOUT 5,447,700.29 kcal/hr

HEAT REACTION
70,224.00 kJ/kmole
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,314,017.65 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 5,163,241.30 kcal/hr

Page 32
 Actual 29 mei
8,607,581.50 kcal/hr
Total Heat Absorbed QF
34.16 MMBTU
mmBTU
mH2 345.0692 kg/hr 1.0375 942.071779733333 589
mNG 109.13 kg/hr 1.522 111.203571428571 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 11,059,391.19 kcal/hr

Efisiensi ղ 77.83 % 819.78267894908

1.14

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF 211 HCL COL. REF DRUM VC 311 BOTTOM VC711
05/29/2019 08:00:00 8.202901 46.80524 345.0692 2.608818 109.125 425.7966 192.7458 488.3405 488.352

Page 33
 Actual 29 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

kmol
kmol EDC VP 214
kmol
CONVECTION 1

RADIANT

VH-221B VH-221A
B C D
-3.9953E-02 -2.1103E-04 ###

21 barg
73.649 22.01325 barA
-7258.2 16511.346348
-7.3037 20000 mmHg
4.17E-06 16511.346348

Page 34
 Actual 29 mei
2 217.20593706 C

Antoine Constants for Water

Water Temperature A B C
kJ/kmol 1 to 100 degrees Celsius 8.07131 1730.63 233.426
kJ/kg 99 to 374 degrees Celsius 8.14019 1810.94 244.485
kcal/kmol
Notes,

1868.1 kJ/kg 1. The equation is valid from 1 to 374 degrees Celsius.

446.188213 kcal/kg 2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

668370
223347

445023
445.023

Page 35
 Actual 29 mei

PDR21153 Limit PDR 21153

1.900202 2.5

Page 36
 Actual 25 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 45 T/h
Capacity 369.970440032244 TPD VCM 44884.75 Kg/h
44,378.78 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
448.46 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 453.569154902535 kmol

Molecular Weight VCM MWVCM 62.499 cracking 246.650906435999 246.650906 246.6509 kmol
Molecular Weight HCl MWHCl 36.461 remain 206.918248466537 246.650906 246.6509 kmol
2.09094926652994 369.97044
CONVECTION 1 3.94647765 6.764787
192.2917 oC
EDC Temp in T1,in
465.4417 K
427.9831 oC 493.301813
EDC Temp out T1,out
701.1331 K
EDC Heat Capacity Cp1,in 6,332.00 kcal/kmol
Heat Duty Convection 1 Q1 2,839,624.60 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.87 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,790.81 kg/hr 4,360.00 2,460.99 342,818.58
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 569,669.86 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 37
 Actual 25 mei
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

427.9831 oC
Temp in Tr,in
701.1331 K 33678.1 kJ/kmol
489.2747 oC 1871.006 kJ/kg
Temp out Tr,out
762.4247 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,438,643.62 kcal/hr

HEAT OUTLET
EDC Outlet
201.81 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
19,970.45 kg/hr
Entalpy of EDC outlet 2,368,472.82 kcal/hr

VCM Outlet
246.65 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
15,415.44 kg/hr
Entalpy of VCM outlet 2,062,847.59 kcal/hr

HCl Outlet
246.65 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,993.14 kg/hr
Entalpy of HCl outlet 805,313.83 kcal/hr
668370
Total Entalpy Product HOUT 5,236,634.25 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 4,137,006.96 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,934,997.59 kcal/hr

Page 38
 Actual 25 mei
8,344,292.05 kcal/hr
Total Heat Absorbed QF
33.11 MMBTU
mmBTU
mH2 335.6606 kg/hr 1.0375 916.385405676191 589
mNG 117.33 kg/hr 1.522 119.560679047619 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,877,433.89 kcal/hr

Efisiensi ղ 76.71 % 794.707095350806

1.10

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
05/25/2019 08:00:00 2.337142 44.88475 335.6606 2.866941 117.3259 427.9831 192.2917 489.2747 489.2677 1.703894 2.5

Page 39
 Actual 25 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 40
 Actual 25 mei
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 41
 Actual 25 mei

imit PDR 21153

1.539537

Page 42
 Actual 19 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 38 T/h
Capacity 310.230081480235 TPD VCM 37637.06 Kg/h
37,212.79 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
376.04 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 380.329833567437 kmol

Molecular Weight VCM MWVCM 62.499 cracking 206.823363493972 206.823363 206.8234 kmol
Molecular Weight HCl MWHCl 36.461 remain 173.506470073465 206.823363 206.8234 kmol
1.75331672787179 310.230081
CONVECTION 1 3.30922676 5.672454
187.8455 oC
EDC Temp in T1,in
460.9955 K
421.2166 oC 413.646727
EDC Temp out T1,out
694.3666 K
EDC Heat Capacity Cp1,in 6,239.26 kcal/kmol
Heat Duty Convection 1 Q1 2,346,228.44 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 2.30 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 2,236.77 kg/hr 4,360.00 2,460.99 274,761.29
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 456,577.44 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 43
 Actual 19 mei
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

421.2166 oC
Temp in Tr,in
694.3666 K 33678.1 kJ/kmol
487.6774 oC 1871.006 kJ/kg
Temp out Tr,out
760.8274 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,647,168.60 kcal/hr

HEAT OUTLET
EDC Outlet
169.22 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
16,745.75 kg/hr
Entalpy of EDC outlet 1,977,776.75 kcal/hr

VCM Outlet
206.82 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
12,926.25 kg/hr
Entalpy of VCM outlet 1,722,528.81 kcal/hr

HCl Outlet
206.82 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
7,540.99 kg/hr
Entalpy of HCl outlet 672,888.83 kcal/hr
668370
Total Entalpy Product HOUT 4,373,194.39 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,468,990.68 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,195,016.47 kcal/hr

Page 44
 Actual 19 mei
6,997,822.35 kcal/hr
Total Heat Absorbed QF
27.77 MMBTU
mmBTU
mH2 100.2939 kg/hr 1.0375 273.8118988 589
mNG 717.46 kg/hr 1.522 731.122643809524 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 10,551,812.70 kcal/hr

Efisiensi ղ 66.32 % 666.469850234552

0.92

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
05/19/2019 08:00:00 2.1125 37.63706 100.2939 2.297788 717.4568 421.2166 187.8455 487.6774 487.6757 1.1805 2.5

Page 45
 Actual 19 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 46
 Actual 19 mei
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 47
 Actual 19 mei

imit PDR 21153

1.023481

Page 48
 Actual 15 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 39 T/h
Capacity 323.602668897803 TPD VCM 39259.42 Kg/h
38,816.86 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
392.25 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 396.724097858709 kmol

Molecular Weight VCM MWVCM 62.499 cracking 215.738564415566 215.738564 215.7386 kmol
Molecular Weight HCl MWHCl 36.461 remain 180.985533443143 215.738564 215.7386 kmol
1.82889412224399 323.602669
CONVECTION 1 3.45187226 5.916968
189.5972 oC
EDC Temp in T1,in
462.7472 K
424.1536 oC 431.477129
EDC Temp out T1,out
697.3036 K
EDC Heat Capacity Cp1,in 6,283.73 kcal/kmol
Heat Duty Convection 1 Q1 2,464,803.82 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 0.00 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 0.34 kg/hr 4,360.00 2,460.99 42.25
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 70.22 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 49
 Actual 15 mei
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

424.1536 oC
Temp in Tr,in
697.3036 K 33678.1 kJ/kmol
487.2648 oC 1871.006 kJ/kg
Temp out Tr,out
760.4148 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 3,838,184.12 kcal/hr

HEAT OUTLET
EDC Outlet
176.51 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
17,467.59 kg/hr
Entalpy of EDC outlet 2,060,807.66 kcal/hr

VCM Outlet
215.74 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
13,483.44 kg/hr
Entalpy of VCM outlet 1,794,833.71 kcal/hr

HCl Outlet
215.74 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
7,866.04 kg/hr
Entalpy of HCl outlet 701,250.55 kcal/hr
668370
Total Entalpy Product HOUT 4,556,891.93 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,618,522.86 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,337,230.66 kcal/hr

Page 50
 Actual 15 mei
6,802,104.70 kcal/hr
Total Heat Absorbed QF
26.99 MMBTU
mmBTU
mH2 243.2813 kg/hr 1.0375 664.181118647619 589
mNG 99.12 kg/hr 1.522 101.010659714286 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 8,034,513.67 kcal/hr

Efisiensi ղ 84.66 % 647.829777931088

0.90

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
05/15/2019 08:00:00 3.025124 39.25942 243.2813 0.0003534 99.12261 424.1536 189.5972 487.2648 487.2507 1.243679 2.5

Page 51
 Actual 15 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 52
 Actual 15 mei
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 53
 Actual 15 mei

imit PDR 21153

1.088373

Page 54
 Actual 01 mei
Heat Balance of EDC Cracking Furnace

Data :
Total EDC Feed FEEDSUM 40 T/h
Capacity 333.196071914202 TPD VCM 40423.29 Kg/h
39,967.61 kg/hr Cracking Conversion Xc 54.38%
EDC flowrate mEDC
403.88 kmole/hr
Molecular Weight EDC MWEDC 98.959 C2H4Cl2 C2H3Cl + Hcl

Molecular Weight H2O MWH2O 18.015 feed 408.485231257389 kmol

Molecular Weight VCM MWVCM 62.499 cracking 222.134268757768 222.134269 222.1343 kmol
Molecular Weight HCl MWHCl 36.461 remain 186.350962499621 222.134269 222.1343 kmol
1.88311282955184 333.196072
CONVECTION 1 3.55420517 6.09238
189.2107 oC
EDC Temp in T1,in
462.3607 K
428.8621 oC 444.268538
EDC Temp out T1,out
702.0121 K
EDC Heat Capacity Cp1,in 6,431.44 kcal/kmol
Heat Duty Convection 1 Q1 2,597,531.46 kcal/hr

CONVECTION 2 & 3 conv 3 conv 2&3

Volumetric Flowrate BFW mCond 1.74 m3/hr 4.50 2.52
Pressure BFW in P3,in 24 barG 24 24
100 C o
115 90 4.47893851
Temp BFW in T3,in
373.15 K 388.15 363.15
Density 973.44 kg/m3 968.56 976.58
mass Flowrate BFW mCond 1,698.17 kg/hr 4,360.00 2,460.99 208,600.61
Pressure Steam Generated 21.00 barg 21.00
Water Boiling Point 217.21 C o
195.00 217.21 A B C
490.36 K 468.15 490.36 92.053 -3.9953E-02 -2.1103E-04
Sensible Heat Cpcond 2,212.93 kcal/kmol 1,499.60 2,393.08
122.84 kcal/kg 83.24 132.84
374.2 C o 374.2
Temp critical water Tc
647.35 K 647.35
Temp reduction TR 0.76 0.76
Heat of Vaporization ΔHv 81.29 kcal/kg 446.88 kcal/kg C1 73.649
C2 -7258.2
Heat Duty Convection 2 & 3 Q3 346,636.64 kcal/hr 362,934.76 1,426,684.17 1,789,618.92 C3 -7.3037
C4 4.17E-06

Page 55
 Actual 01 mei
RADIANT C5 2
Heat = Heat Output - Heat Input + Heat Reaction

EDC Conversion to VCM 55 %

428.8621 oC
Temp in Tr,in
702.0121 K 33678.1 kJ/kmol
482.2994 oC 1871.006 kJ/kg
Temp out Tr,out
755.4494 K 8043.88 kcal/kmol
25 oC 446.8822
Temp Reff
298.15 K
HEAT INLET 1868.1 kJ/kg
EDC Inlet 446.188213 kcal/kg
Entalpy of EDC inlet HIN 4,007,906.11 kcal/hr

HEAT OUTLET
EDC Outlet
181.75 kmole/hr
Mass Flowrate EDC Outlet mout,EDC
17,985.42 kg/hr
Entalpy of EDC outlet 2,094,410.60 kcal/hr

VCM Outlet
222.13 kmole/hr
Mass Flowrate VCM Outlet mout,VCM
13,883.17 kg/hr
Entalpy of VCM outlet 1,823,973.51 kcal/hr

HCl Outlet
222.13 kmole/hr
Mass Flowrate HCl Outlet mout,HCl
8,099.24 kg/hr
Entalpy of HCl outlet 714,070.56 kcal/hr
668370
Total Entalpy Product HOUT 4,632,454.68 kcal/hr 223347

HEAT REACTION 445023

70,224.00 kJ/kmole 445.023
Entalpy of Reaction ΔHRo
16,772.72 kcal/kmole
Heat of Reaction QRxn 3,725,796.23 kcal/hr

Heat absorbed Radiant Section

Heat absorbed Radiant Section QRadiant 4,350,344.80 kcal/hr

Page 56
 Actual 01 mei
7,294,512.89 kcal/hr
Total Heat Absorbed QF
28.95 MMBTU
mmBTU
mH2 59.65188 kg/hr 1.0375 162.855313531429 589
mNG 970.00 kg/hr 1.522 988.476190476191 133
Total Heat Supply LHV H2 28,666.00 kcal/kg 722
LHV NG 10,700.00 kcal/kg
Qs 12,088,980.79 kcal/hr

Efisiensi ղ 60.34 % 694.726541194239

0.96

0.035959595959596

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142PDR21153 Limit PDR 21153
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF HCL COL. RE BOTTOM VC711
05/01/2019 08:00:00 2.983381 40.42329 59.65188 1.744496 970 428.8621 189.2107 482.2994 484.429 1.106301 2.5

Page 57
 Actual 01 mei
STEAM

VB 214
CONVECTION 3
BFW

CONVECTION 2

EDC VP 214

CONVECTION 1

RADIANT

VH-221B VH-221A
D
###

21 barg
22.01325 barA
16511.346348
20000 mmHg
16511.346348

Page 58
 Actual 01 mei
217.20593706 C

Antoine Constants for Water

Water Temperature A B C
1 to 100 degrees Celsius 8.07131 1730.63 233.426
99 to 374 degrees Celsius 8.14019 1810.94 244.485

Notes,

1. The equation is valid from 1 to 374 degrees Celsius.

2. There is an over lap between 99 and 100 degrees Celsius where both sets of constants can be used.
3. The calculated pressure is the point in which water will boil at the entered temperature.
4. The equation uses Celsius for temperature and pressure is in mmHg.

Page 59
 Actual 01 mei

imit PDR 21153

Page 60
 24h

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142 TRCA21142
REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF 211 HCL COL. REF DRUM VC 311 BOTTOM VC711
05/01/2019 08:00:00 2.983381 40.42329 59.65188 1.744496 970 428.8621 189.2107 482.2994 484.429
05/02/2019 08:00:00 10.25977 0 4.02E-17 597.7258 403.3255 181.1772 444.953 446.786
05/03/2019 08:00:00 9.520034 0 1.57E-16 550.1113 387.2542 178.4511 444.1348 443.8977
05/04/2019 08:00:00 3.725872 37.32145 99.01741 7.97E-17 773.699 435.5571 187.6435 486.4203 487.8272
05/05/2019 08:00:00 3.427248 38.91383 107.0919 1.833141 727.1701 432.7313 188.4838 486.594 487.3231
05/06/2019 08:00:00 3.413175 38.41553 103.5836 1.451102 708.6379 428.0573 188.5735 483.7407 484.2539
05/07/2019 08:00:00 3.728111 39.13054 113.7151 2.147801 698.3179 428.4317 189.1011 483.7388 483.9139
05/08/2019 08:00:00 2.462812 39.09152 118.9659 1.806383 664.1862 425.8214 188.3969 483.6728 484.648
05/09/2019 08:00:00 2.752841 39.22791 242.2874 2.634531 134.4901 427.7986 189.15 485.9886 485.9834
05/10/2019 08:00:00 4.130353 38.81194 3.77E-17 2.208313 970 444.8579 189.1904 486.7422 486.7414
05/11/2019 08:00:00 3.546733 39.06602 241.4037 1.906383 108.1496 420.8373 188.3433 480.267 480.2625
05/12/2019 08:00:00 3.331468 38.96492 250.2274 2.510704 99.77861 422.931 187.9712 484.0362 484.0398
05/13/2019 08:00:00 10.27023 4.38E-17 1.66E-16 479.4016 402.4723 174.3466 463.5474 463.6243
05/14/2019 08:00:00 10.27053 4.38E-17 8.01E-17 391.252 373.0738 177.1426 418.7969 418.7997
05/15/2019 08:00:00 3.025124 39.25942 243.2813 0.0003533717 99.12261 424.1536 189.5972 487.2648 487.2507
05/16/2019 08:00:00 3.093551 39.05041 242.9102 1.505962 95.53643 420.7253 188.7288 484.5966 484.593
05/17/2019 08:00:00 3.097429 39.19486 252.3423 2.008933 70.54169 421.102 189.4417 484.2052 484.2093
05/18/2019 08:00:00 3.164213 39.63992 252.5512 1.59E-16 62.65343 420.7077 189.4436 483.7988 483.6721
05/19/2019 08:00:00 2.1125 37.63706 100.2939 2.297788 717.4568 421.2166 187.8455 487.6774 487.6757
05/20/2019 08:00:00 2.825139 39.39489 255.2488 2.866281 49.14198 419.1244 189.2281 484.5505 484.5518
05/21/2019 08:00:00 2.844544 39.02403 251.7333 1.65E-16 50.52628 417.4672 189.0497 483.0767 483.0694
05/22/2019 08:00:00 2.602871 40.7552 291.7595 8.24E-17 78.6731 417.291 190.3901 485.7203 485.7056
05/23/2019 08:00:00 3.153715 42.27163 303.4834 2.998542 108.9633 428.367 191.0726 485.5753 485.578
05/24/2019 08:00:00 3.000202 42.79868 305.2898 1.624089 95.9761 427.1515 191.033 486.9185 486.9172
05/25/2019 08:00:00 2.337142 44.88475 335.6606 2.866941 117.3259 427.9831 192.2917 489.2747 489.2677
05/26/2019 08:00:00 1.862249 46.85833 340.3381 2.06647 166.5553 427.3541 193.4223 487.7534 487.7466
05/27/2019 08:00:00 2.007029 45.88813 324.9927 3.96E-17 116.17 424.2981 193.0196 485.3056 485.3039
05/28/2019 08:00:00 1.937006 46.11903 347.2684 1.769749 88.23419 424.9805 192.7953 486.4948 486.501
05/29/2019 08:00:00 8.202901 46.80524 345.0692 2.608818 109.125 425.7966 192.7458 488.3405 488.352
05/30/2019 08:00:00 10.27047 0 1.95E-16 1.46E-16 174.3486 53.71945 169.1461 169.1511
05/31/2019 08:00:00 10.27047 36.94663 231.8 2.705987 344.2176 429.1068 188.0904 485.9038 486.146
06/01/2019 08:00:00 5.327547 37.57845 310.1138 1.738465 97.75318 433.1051 189.4459 494.0263 494.1196
06/02/2019 08:00:00 2.948426 42.34583 311.8636 3.18692 88.23761 429.4357 189.5975 489.8828 491.1691
06/03/2019 08:00:00 3.163187 44.3875 313.02 1.751461 132.9137 425.426 191.0603 485.824 487.5049
06/04/2019 08:00:00 2.975347 44.61673 330.6626 2.350279 120.1642 428.9427 191.7154 488.356 490.0562
06/05/2019 08:00:00 4.492743 43.8749 316.4413 1.58E-16 108.2766 425.8546 191.6316 486.7889 489.2605
06/06/2019 08:00:00 10.2705 44.42598 322.1443 3.859873 108.6388 427.8963 192.6967 488.7762 491.8328
06/07/2019 08:00:00 10.27106 43.77436 324.9845 4.536586 96.92673 426.7454 192.1107 485.9618 489.4865
06/08/2019 08:00:00 10.271 44.90418 314.9049 4.145099 127.7501 431.7527 192.6395 483.1798 486.3911

Page 61
 24h
06/09/2019 08:00:00 10.27094 43.74641 317.9945 3.377401 132.9953 429.3332 192.6917 482.0057 484.6519
06/10/2019 08:00:00 10.27085 44.10651 323.3453 2.618562 165.61 432.4382 192.2963 485.8863 488.9828
06/11/2019 08:00:00 10.27097 44.17539 332.5884 2.625041 162.1804 432.7868 193.4195 485.8864 488.7444
06/12/2019 08:00:00 10.27108 45.28963 324.4568 2.364021 140.0166 427.2354 194.1544 480.4225 483.1432
06/13/2019 08:00:00 10.27096 45.05333 324.134 3.468743 133.749 433.6801 192.9427 483.6013 485.2112
06/14/2019 08:00:00 10.27079 44.55746 324.2813 2.378844 130.4405 431.4594 193.0148 482.0014 484.5613
06/15/2019 08:00:00 10.27064 44.75396 326.9545 1.67515 127.6285 427.6275 193.3388 479.7773 482.0739
06/16/2019 08:00:00 10.27079 45.3194 326.0197 1.949778 130.5716 430.0654 193.8314 482.2603 485.3646
06/17/2019 08:00:00 10.27081 45.29622 319.7674 3.213188 133.5208 431.9965 193.5609 482.73 484.1698
06/18/2019 08:00:00 10.27061 44.58736 328.932 2.161719 135.6407 431.7859 192.6319 484.974 486.4787
06/19/2019 08:00:00 4.762517 45.01608 334.3307 2.240792 133.2878 432.0573 192.8427 484.0341 485.9379
06/20/2019 08:00:00 8.616709 45.45583 331.2251 3.057286 122.3012 430.1052 193.4743 482.7753 484.7596
06/21/2019 08:00:00 3.501372 44.86591 200.688 3.189998 968.9734 432.8611 193.8111 486.4648 486.4012
06/22/2019 08:00:00 6.277689 45.1199 186.1351 2.354236 970 434.2044 193.4949 485.2795 485.2846
06/23/2019 08:00:00 6.360668 45.03632 324.405 1.922633 94.43671 418.744 193.7175 483.8784 484.8812
06/24/2019 08:00:00 7.728527 45.28758 324.2428 2.764141 126.8438 423.3121 193.5719 486.8364 488.8869
06/25/2019 08:00:00 6.493812 44.76516 333.2219 3.391791 63.86897 425.5179 193.2997 489.382 489.3994
06/26/2019 08:00:00 10.27046 41.04709 310.9261 3.851992 54.44903 430.6298 192.1257 485.2211 485.2232
06/27/2019 08:00:00 3.648737 41.25792 313.7135 2.862612 67.1749 429.446 192.338 483.3823 484.7133
06/28/2019 08:00:00 4.323923 40.21812 161.5738 2.641063 896.6588 431.6487 189.99 481.575 481.6063
06/29/2019 08:00:00 3.651902 40.34492 301.8221 2.329479 79.18868 425.6018 191.8405 482.8826 485.0009
06/30/2019 08:00:00 3.522488 41.03275 288.5235 1.9618 86.28295 424.559 192.0768 484.3857 486.0106
07/01/2019 08:00:00 3.923339 40.75467 297.4248 2.186338 79.30718 424.0842 191.937 483.531 485.2283
07/02/2019 08:00:00 10.27057 40.73182 305.4559 2.185688 79.51367 426.0471 192.1479 486.3706 489.2793
07/03/2019 08:00:00 10.27067 40.56203 295.1754 2.25 54.39308 425.9171 192.0473 485.7558 487.886
07/04/2019 08:00:00 2.508861 40.44397 303.2572 2.014705 4.35E-17 402.7734 191.3316 492.6463 492.6431
07/05/2019 08:00:00 0.3128555 43.09813 298.7349 3.94E-17 114.901 401.867 192.2709 493.2958 493.2896
07/06/2019 08:00:00 0.1662835 9.35E-17 1.746525 582.6605 376.1977 183.0314 417.7242 417.7265
07/07/2019 08:00:00 10.27078 4.36E-17 8.02E-17 761.548 397.4353 177.3261 445.5499 445.5479
07/08/2019 08:00:00 0 41.2253 307.2173 1.94805 64.96902 405.5939 191.7006 491.4153 491.4104
07/09/2019 08:00:00 2.319197 43.7756 314.6518 2.772803 98.13533 400.073 192.1971 493.5495 493.5573
07/10/2019 08:00:00 2.867255 40.90599 306.4901 1.687876 48.38352 401.3944 191.482 492.2534 492.3105
07/11/2019 08:00:00 3.140121 40.48872 295.7018 1.765898 18.65295 399.2832 191.5211 488.92 488.9166
07/12/2019 08:00:00 4.523676 41.68642 313.0649 1.962355 92.91818 408.7957 192.4183 493.1352 493.1216
07/13/2019 08:00:00 4.305832 41.48981 312.4899 2.34312 87.74435 404.6627 192.2331 491.9185 491.9031
07/14/2019 08:00:00 5.492769 41.85371 292.4988 2.306848 87.33546 403.502 192.4648 491.8103 491.8075
07/15/2019 08:00:00 5.682961 41.43006 309.5308 7.94E-17 97.11487 405.2551 191.9237 490.4451 490.4478
07/16/2019 08:00:00 4.434237 41.7007 292.3879 2.405273 108.5576 404.9993 192.3304 490.346 490.3487
07/17/2019 08:00:00 3.746332 41.88127 303.7205 2.488217 95.7439 402.7569 192.2444 490.6469 490.6826
07/18/2019 08:00:00 5.751856 42.29816 290.1653 2.209574 87.41698 403.3553 192.3255 489.9246 489.9265
07/19/2019 08:00:00 2.678237 41.32146 304.0006 2.318438 81.20287 401.1919 191.985 489.851 489.845
07/20/2019 08:00:00 3.271808 41.98082 300.2943 2.071894 88.31502 400.9389 192.3994 488.5478 488.5536
07/21/2019 08:00:00 4.798777 43.10394 298.0561 2.278479 103.4712 398.8178 192.976 494.267 494.2665
07/22/2019 08:00:00 4.049023 43.05738 306.2131 2.510874 108.4737 396.4396 192.8278 491.4543 491.459
07/23/2019 08:00:00 4.882963 42.51516 41.69765 3.152178 970 426.058 192.7083 490.8497 490.8203
07/24/2019 08:00:00 6.294335 42.39217 221.8678 1.764652 635.1307 422.3528 192.499 487.6748 487.6744

Page 62
 24h
07/25/2019 08:00:00 2.946302 42.7053 308.6611 3.053446 123.3384 410.1236 192.8685 487.8104 487.814
07/26/2019 08:00:00 3.32486 42.39781 294.0358 2.926674 127.3683 414.6294 192.4737 490.5554 490.5507
07/27/2019 08:00:00 3.835262 42.93912 306.5121 3.033493 65.14397 404.6187 192.5682 491.1824 491.1858
07/28/2019 08:00:00 3.282557 42.777 314.0962 3.244071 77.84375 403.8434 192.879 490.8431 490.8962
07/29/2019 08:00:00 2.769368 41.93015 322.6797 2.686355 76.14654 401.2332 192.3289 491.5199 491.5301

Page 63
 24h

PDR21153 Limit PDR PDR21143 PROD

OXYCHLORIN. REATPD
1.106301 2.5 0.9640198 333
2.5 0
2.5 0
1.046903 2.5 0.8964224 308
1.129481 2.5 0.9890995 321
1.107537 2.5 0.9588518 317
1.143927 2.5 0.9970598 323
1.183067 2.5 1.048621 322
1.211474 2.5 1.059918 323
1.195236 2.5 1.038343 320
1.234636 2.5 1.088481 322
1.20385908333333 1.05736584166667 330 TPD
1.254028 2.5 1.120251 321
2.5 0
2.5 0
1.243679 2.5 1.088373 324
1.244041 2.5 1.091024 322
1.227877 2.5 1.089984 323
1.271326 2.5 1.118384 327
1.1805 2.5 1.023481 310
1.275523 2.5 1.134601 325
1.252802 2.5 1.096921 322
1.357088 2.5 1.206249 336
1.534524 2.5 1.3818 348
1.559542 2.5 1.405669 353
1.703894 2.5 1.539537 370
1.832294 2.5 1.67556 386
1.63877538888889 1.47017118888889 360 TPD
1.781596 2.5 1.628682 378
1.848228 2.5 1.690863 380
1.900202 2.5 1.737099 386
1.70818303571429 2.5 0 1.55427462142857 370 TPD
1.151932 2.5 0.9949474 305
1.202555 2.5 1.022707 310
1.47933 0.144972101851852 2.5 1.292075 349 0.137601782407407
1.572302 0.069407646825397 2.5 1.399857 366 0.084103432539682
1.617963 2.5 1.437217 368
1.625195 0.107189874338624 2.5 1.446949 362 0.110852607473545 Increasing / 10 ton
1.681123 2.5 1.480992 366
1.661818 2.5 1.461422 361
1.784499 2.5 1.603179 370

Page 64
 24h
1.654229 2.5 1.501375 361
1.733264 2.5 1.579171 364
1.707991 2.5 1.56578 364
1.731007 2.5 1.625498 373
1.787883 2.5 1.648939 371
1.672404 2.5 1.600486 367
1.766297 2.5 1.606684 369
1.846801 2.5 1.664721 374
1.83142 2.5 1.677155 373
1.774309 2.5 1.660551 368
1.854031 2.5 1.704733 371
1.868053 2.5 1.705202 375
1.850853 2.5 1.702492 370
1.784278 2.5 1.700263 372
1.815801 2.5 1.667758 371
1.843761 2.5 1.712892 373
1.819752 2.5 1.680535 369
1.492769 2.5 1.385427 338
1.583237 2.5 1.440438 340
1.432235 2.5 1.403746 332
1.565917 2.5 1.398038 333
1.597398 2.5 1.43925 338
1.547945 2.5 1.416395 336 /increasing per day
-0.081464 0.000866
1.466481 2.5 1.417261 336
1.51706 2.5 1.394957 334
1.497942 2.5 1.359113 333
1.64241 2.5 1.577866 355
2.5 0
2.5 0
1.550817 2.5 1.387166 340
1.750873 2.5 1.630774 361
1.50454 2.5 1.380053 337
1.379941 2.5 1.332312 334
1.545314 2.5 1.434295 344
1.449862 2.5 1.424713 342
1.477968 2.5 1.437327 345
1.576228 2.5 1.413459 341
1.495681 2.5 1.440099 344 /increasing per day
0.021857 0.008234
1.517538 2.5 1.448333 345
1.396808 2.5 1.461469 349
1.425364 2.5 1.413052 341
1.547763 2.5 1.432567 346
1.539385 2.5 1.535066 355 /increasing per day
-0.261158 0.003074
1.278227 2.5 1.53814 355
1.45902 2.5 1.502393 350
1.611524 2.5 1.513215 349

Page 65
 24h
1.390031 -0.09553575 2.5 1.522188 352 0.00406375 /increasing per day
1.519794 2.5 1.486959 349
1.506441 2.5 1.518316 354 /increasing per day
-0.061378 0.004081
1.445063 2.5 1.522397 353
1.429208 2.5 1.472435 346

Start 1.69414021494709
199.304468791861 days
6.64348229306204 bulan

Page 66
 Sheet2

12

10

6
AR21115

0
03/26/2019 00:00:0005/15/2019 00:00:0007/04/2019 00:00:0008/23/2019 00:00:00

50

45

40

35

30

25
FEEDSUM
20

15

10

400

350

300

250

200
FI21185

150
Page 67
100

50
 300

250

200
FI21185 Sheet2
150

100

50

0
03/26/2019 00:00:00 05/15/2019 00:00:00 07/04/2019 00:00:00 08/23/2019 00:00:00

4.5

3.5

2.5
FI21407
2

1.5

0.5

0
03/26/2019 00:00:00 05/15/2019 00:00:00 07/04/2019 00:00:00 08/23/2019 00:00:00

1200

1000

800

600
FIC21145

400

200

0
03/26/2019 00:00:0005/15/2019 00:00:0007/04/2019 00:00:0008/23/2019 00:00:00

500

450
Page 68
400

350

300
 Sheet2
500

450

400

350

300

250
TR21121B
200

150

100

50

250

200

150

TR21137
100

50

0
03/26/2019 00:00:0005/15/2019 00:00:0007/04/2019 00:00:0008/23/2019 00:00:00

600

500

400

300
TRA21142

200

100
Page 69
0
300
TRA21142

200
Sheet2
100

600

500

400

300
TRCA21142

200

100

1.8

1.6

1.4

1.2

1
PDR21153
0.8

0.6

0.4

0.2

50
2

1.8
45

1.6
40 Page 70
1.4
35

1.2
30

25
1 PDR21153
50
2 Sheet2
1.8
45

1.6
40

1.4
35

1.2
30

25
1 PDR21153
FEEDSUM
0.8
20

0.6
15

0.4
10

0.2
5

Page 71
 Sheet3

PDR 21153 and FEEDSUM Vs. Time

2.5
2.45
2.4
49
2.35
2.3
2.25 Productivity 370 TPD
2.2
47
2.15
2.1
2.05
45
2
1.95
1.9
1.85
1.8
43
1.75
1.7 PDR21153
Pressure (bar)

Pressure (bar)
1.65 Limit PDR
1.6
41 Column L
1.55 FEEDSUM
1.5
1.45
1.4
39
1.35
1.3
1.25
1.2
37
1.15
1.1
1.05
35
1
0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00
:0 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
: 00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00
0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 00
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
0 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20
/2 / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
/ 15 /17 /20 /22 /25 /27 /30 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29
05 05 0 5 05 05 05 05 06 06 06 06 06 06 06 06 06 06 06 06 07 07 07 07 07 07 07 07 07 07 07 07

Time

Productivity (TPD) dP Highest dP Lowest Total Increasing dP Total days Increasing dP/day
360 1.875 1.65 0.225 22 0.0102272727273
07/29/19 330 1.75 1.375 0.375 33 0.0113636363636

Page 72
 Sheet3
0.0107954545455

137.2229102 hari

PDR 21153 and FEEDSUM Vs. Time

2.5
2.45
2.4
49
2.35
2.3
2.25
2.2
47
2.15
2.1
2.05
45
2
1.95
1.9
1.85
1.8
43
1.75 PDR21153
1.7 Moving average (PDR21153)
Pressure (bar)

Pressure (bar)
1.65
Column L
1.6
41
FEEDSUM
1.55
Moving average (FEEDSUM)
1.5
1.45
1.4
39
1.35
1.3
1.25
1.2
37
1.15
1.1
1.05
35
1
0 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00
:0 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
: 00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00
0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 0 0 1 2 00
19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
0 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20
/2 / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
/ 15 /17 /20 /22 /25 /27 /30 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29
05 05 0 5 05 05 05 05 06 06 06 06 06 06 06 06 06 06 06 06 07 07 07 07 07 07 07 07 07 07 07 07

Time

Page 73
 Sheet3

PDR 21153 and FEEDSUM Vs. Time

2.5
2.45
2.4
49
2.35
2.3
2.25
2.2
47
2.15
2.1
2.05
45
2
1.95
1.9
1.85
1.8
43
1.75 Limit PDR
1.7 Moving average (Limit PDR )
Pressure (bar)

Pressure (bar)
1.65
Column L
1.6
41
FEEDSUM
1.55
Moving average (FEEDSUM)
1.5
1.45
1.4
39
1.35
1.3
1.25
1.2
37
1.15
1.1
1.05
35
1
00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00
00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00: 00:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00 12 00
9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9
01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01
5/2 7/2 0/2 2/2 5/2 7/2 0/2 1/2 4/2 6/2 9/2 1/2 4/2 6/2 9/2 1/2 4/2 6/2 9/2 1/2 4/2 6/2 9/2 1/2 4/2 6/2 9/2 1/2 4/2 6/2 9/2
/1 /1 /2 /2 /2 /2 /3 /0 /0 /0 /0 /1 /1 /1 /1 /2 /2 /2 /2 /0 /0 /0 /0 /1 /1 /1 /1 /2 /2 /2 /2
05 05 05 05 05 05 05 06 06 06 06 06 06 06 06 06 06 06 06 07 07 07 07 07 07 07 07 07 07 07 07

Time

Page 74
 Sheet10

Trend and Forecast VF 211

2.5
48

2.4
47
2.3
46
2.2
45
2.1

2
44
1.9
43
1.8
42
1.7

1.6
41

Feedsum (T/H)
DP (barg)

1.5
40
1.4
39
1.3

1.2
38
1.1
37
1
36
0.9

0.8
35
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
:0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0 :0
: 00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00 :00
08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08 16 00 08
019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019 019
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
0/ 2/ 5/ 7/ 9/ 2/ 4/ 6/ 9/ 1/ 3/ 6/ 8/ 0/ 2/ 4/ 6/ 9/ 1/ 3/ 6/ 8/ 0/ 3/ 5/ 7/ 0/ 2/ 4/ 7/ 9/ 1/ 4/ 6/ 8/ 1/ 3/ 5/ 8/ 0/
4/3 5/0 5/0 5/0 5/0 5/1 5/1 5/1 5/1 5/2 5/2 5/2 5/2 5/3 6/0 6/0 6/0 6/0 6/1 6/1 6/1 6/1 6/2 6/2 6/2 6/2 6/3 7/0 7/0 7/0 7/0 7/1 7/1 7/1 7/1 7/2 7/2 7/2 7/2 7/3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Date

PDR21143 Moving Average PDR FEEDSUM Moving Average Feedsum (T/H)

Page 75
 Sheet10

Increasing dP by
Parameter Productivity ( /10 Latest dP (29 July If 360 TPD For Next
(dP) tons) Increasing dP by day 2019) → 330 TPD Productivity (dP Start on) n (days until limitation 2.5 bar) Decoking

PDR 21143 0.1109 0.0041 1.4724 1.8050 172.03 Friday, January 17, 2020
Monday, July 29, 2019

PDR 21153 0.1072 -0.0955 Decrease dP → impossible (PDR Error)

Page 76
 Sheet10

x f(x)
PDR21153 5 29.11003991

PDR21143 1

15 mei
19
25
31
8 juni
24
4 juli
9
12

Page 77
 Sheet10
24
29

Page 78
 Sheet19

% Efficiency D % efficiency decrease FEEDSUM TPD PDR21153 dp increase dp

1 05/01/19 60.3402 40.4233 126 1.1063
15 05/15/19 84.6611 24.3209 1.6214 39.2594 285 1.2437 0.1374 0.0092
19 05/19/19 66.3187 5.9785 0.3147 37.6371 339 1.1805 0.0742 0.0039
25 05/25/19 76.7120 16.3718 0.6549 44.8848 370 1.7039 0.5976 0.0239
29 05/29/19 77.8305 17.4903 0.6031 46.8052 48 1.9002 0.7939 0.0274
31 05/31/19 67.1707 6.8306 0.2203 36.9466 296 1.1519 0.0456 0.0015
39 06/08/19 81.9384 21.5982 0.5538 44.9042 1.7845 0.6782 0.0174
50 06/19/19 74.1742 13.8341 0.2767 45.0161 1.8540 0.7477 0.0150
55 06/24/19 78.3608 18.0206 0.3276 45.2876 1.8438 0.7375 0.0134
65 07/04/19 85.7638 25.4236 0.3911 40.4440 1.4979 0.3916 0.0060
69 07/09/19 81.3333 20.9931 0.3042 43.7756 1.7509 0.6446 0.0093
73 07/12/19 76.8134 16.4732 0.2257 41.6864 1.5453 0.4390 0.0060
85 07/24/19 58.3102 -2.0300 -0.0239 42.3922 1.6115 0.5052 0.0059
90 07/29/19 81.4922 21.1520 0.2350 41.9302 1.4292 0.3229 0.0036
90 days 15.8813 0.4388 0.4704 0.0110

PDR21153 date decocking

sampai (days) hari lagi
187.6997 97.6997 November 3, 2019 38.6194 2.5000 90
127.1620 37.1620 September 4, 2019 4.5387 2.5000 1
PDR21143
sampai (days) hari lagi
184.6001 94.6001 October 31, 2019 2.5000 90
141.4060 51.4060 September 18, 2019 2.5000 1

PDR 21153 and FEEDSUM Vs. Time

100.0000
364
353
342 Page 79
90.0000
331
320
309
298
80.0000
287
276
 PDR 21153 and FEEDSUM Vs. Time

100.0000 Sheet19
364
353
342
90.0000
331
320
309
298
80.0000
287
276
265
70.0000
254
243
232
60.0000
221
210
199
188
50.0000
Pressure (bar)

Pressure (bar)
177 TPD
166 Limit P
155
40.0000 FEED
144
133 % Effi
122
30.0000
111
100
89
78
20.0000
67
56
45
10.0000
34
23
12
0.0000
1
9 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19
/1 / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
/ 15 /17 /20 /22 /25 /27 /30 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29 /01 /04 /06 /09 /11 /14 /16 /19 /21 /24 /26 /29
05 05 05 05 05 05 05 06 06 06 06 06 06 06 06 06 06 06 06 07 07 07 07 07 07 07 07 07 07 07 07

Time

Page 80
 Sheet19

Limit PDR 21153 PDR21143 dp increase dp

2.5000 0.9640
2.5000 1.0884 0.1244 0.0083
2.5000 1.0235 0.0595 0.0031
2.5000 1.5395 0.5755 0.0230
2.5000 1.7371 0.7731 0.0267
2.5000 0.9949 0.0309 0.0010
2.5000 1.6032 0.6392 0.0164
2.5000 1.7047 0.7407 0.0148
2.5000 1.7129 0.7489 0.0136
2.5000 1.3591 0.3951 0.0061
2.5000 1.6308 0.6668 0.0097
2.5000 1.4343 0.4703 0.0064
2.5000 1.5132 0.5492 0.0065
2.5000 1.4724 0.5084 0.0056
0.0056 0.0056 0.0109

Page 81
 Pressure (bar) Sheet19

TPD
Limit PDR 21153
FEEDSUM
% Efficiency

a b x f(x)
PDR21153 0.004909813 -212.864485 43864.08974 2.5
PDR21143 0.006139947 -26.6465672 1 -26.6404272

9 9 19
/1 /
/ 26 /29
7 07

Page 82
 24h_2

Time AR21115 FEEDSUM FI21185 FI21407 FIC21145 TR21121B TR21137 TRA21142

REFLUX DRUM VB 132 H2 RANK TO DISRTRIBU. ON TOP OF VF 211 ON BOTTOM OF VF 211 HCL COL. REF DRUM VC 311
1 05/01/2019 08:00:00 2.983381 40.42329 59.65188 1.744496 970 428.8621 189.2107 482.2994
2 05/02/2019 08:00:00 10.25977 0 4.02E-17 597.7258 403.3255 181.1772 444.953
3 05/03/2019 08:00:00 9.520034 0 1.57E-16 550.1113 387.2542 178.4511 444.1348
4 05/04/2019 08:00:00 3.725872 37.32145 99.01741 7.97E-17 773.699 435.5571 187.6435 486.4203
5 05/05/2019 08:00:00 3.427248 38.91383 107.0919 1.833141 727.1701 432.7313 188.4838 486.594
6 05/06/2019 08:00:00 3.413175 38.41553 103.5836 1.451102 708.6379 428.0573 188.5735 483.7407
7 05/07/2019 08:00:00 3.728111 39.13054 113.7151 2.147801 698.3179 428.4317 189.1011 483.7388
8 05/08/2019 08:00:00 2.462812 39.09152 118.9659 1.806383 664.1862 425.8214 188.3969 483.6728
9 05/09/2019 08:00:00 2.752841 39.22791 242.2874 2.634531 134.4901 427.7986 189.15 485.9886
10 05/10/2019 08:00:00 4.130353 38.81194 3.77E-17 2.208313 970 444.8579 189.1904 486.7422
11 05/11/2019 08:00:00 3.546733 39.06602 241.4037 1.906383 108.1496 420.8373 188.3433 480.267
12 05/12/2019 08:00:00 3.331468 38.96492 250.2274 2.510704 99.77861 422.931 187.9712 484.0362
13 05/13/2019 08:00:00 10.27023 4.38E-17 1.66E-16 479.4016 402.4723 174.3466 463.5474
14 05/14/2019 08:00:00 10.27053 4.38E-17 8.01E-17 391.252 373.0738 177.1426 418.7969
15 05/15/2019 08:00:00 3.025124 39.25942 243.2813 0.0003533717 99.12261 424.1536 189.5972 487.2648
16 05/16/2019 08:00:00 3.093551 39.05041 242.9102 1.505962 95.53643 420.7253 188.7288 484.5966
17 05/17/2019 08:00:00 3.097429 39.19486 252.3423 2.008933 70.54169 421.102 189.4417 484.2052
18 05/18/2019 08:00:00 3.164213 39.63992 252.5512 1.59E-16 62.65343 420.7077 189.4436 483.7988
19 05/19/2019 08:00:00 2.1125 37.63706 100.2939 2.297788 717.4568 421.2166 187.8455 487.6774
20 05/20/2019 08:00:00 2.825139 39.39489 255.2488 2.866281 49.14198 419.1244 189.2281 484.5505
21 05/21/2019 08:00:00 2.844544 39.02403 251.7333 1.65E-16 50.52628 417.4672 189.0497 483.0767
22 05/22/2019 08:00:00 2.602871 40.7552 291.7595 8.24E-17 78.6731 417.291 190.3901 485.7203
23 05/23/2019 08:00:00 3.153715 42.27163 303.4834 2.998542 108.9633 428.367 191.0726 485.5753
24 05/24/2019 08:00:00 3.000202 42.79868 305.2898 1.624089 95.9761 427.1515 191.033 486.9185
25 05/25/2019 08:00:00 2.337142 44.88475 335.6606 2.866941 117.3259 427.9831 192.2917 489.2747
26 05/26/2019 08:00:00 1.862249 46.85833 340.3381 2.06647 166.5553 427.3541 193.4223 487.7534
27 05/27/2019 08:00:00 2.007029 45.88813 324.9927 3.96E-17 116.17 424.2981 193.0196 485.3056
28 05/28/2019 08:00:00 1.937006 46.11903 347.2684 1.769749 88.23419 424.9805 192.7953 486.4948
29 05/29/2019 08:00:00 8.202901 46.80524 345.0692 2.608818 109.125 425.7966 192.7458 488.3405
30 05/30/2019 08:00:00 10.27047 0 1.95E-16 1.46E-16 174.3486 53.71945 169.1461
31 05/31/2019 08:00:00 10.27047 36.94663 231.8 2.705987 344.2176 429.1068 188.0904 485.9038
32 06/01/2019 08:00:00 5.327547 37.57845 310.1138 1.738465 97.75318 433.1051 189.4459 494.0263
33 06/02/2019 08:00:00 2.948426 42.34583 311.8636 3.18692 88.23761 429.4357 189.5975 489.8828
34 06/03/2019 08:00:00 3.163187 44.3875 313.02 1.751461 132.9137 425.426 191.0603 485.824
35 06/04/2019 08:00:00 2.975347 44.61673 330.6626 2.350279 120.1642 428.9427 191.7154 488.356
36 06/05/2019 08:00:00 4.492743 43.8749 316.4413 1.58E-16 108.2766 425.8546 191.6316 486.7889
37 06/06/2019 08:00:00 10.2705 44.42598 322.1443 3.859873 108.6388 427.8963 192.6967 488.7762
38 06/07/2019 08:00:00 10.27106 43.77436 324.9845 4.536586 96.92673 426.7454 192.1107 485.9618
39 06/08/2019 08:00:00 10.271 44.90418 314.9049 4.145099 127.7501 431.7527 192.6395 483.1798

Page 83
 24h_2
40 06/09/2019 08:00:00 10.27094 43.74641 317.9945 3.377401 132.9953 429.3332 192.6917 482.0057
41 06/10/2019 08:00:00 10.27085 44.10651 323.3453 2.618562 165.61 432.4382 192.2963 485.8863
42 06/11/2019 08:00:00 10.27097 44.17539 332.5884 2.625041 162.1804 432.7868 193.4195 485.8864
43 06/12/2019 08:00:00 10.27108 45.28963 324.4568 2.364021 140.0166 427.2354 194.1544 480.4225
44 06/13/2019 08:00:00 10.27096 45.05333 324.134 3.468743 133.749 433.6801 192.9427 483.6013
45 06/14/2019 08:00:00 10.27079 44.55746 324.2813 2.378844 130.4405 431.4594 193.0148 482.0014
46 06/15/2019 08:00:00 10.27064 44.75396 326.9545 1.67515 127.6285 427.6275 193.3388 479.7773
47 06/16/2019 08:00:00 10.27079 45.3194 326.0197 1.949778 130.5716 430.0654 193.8314 482.2603
48 06/17/2019 08:00:00 10.27081 45.29622 319.7674 3.213188 133.5208 431.9965 193.5609 482.73
49 06/18/2019 08:00:00 10.27061 44.58736 328.932 2.161719 135.6407 431.7859 192.6319 484.974
50 06/19/2019 08:00:00 4.762517 45.01608 334.3307 2.240792 133.2878 432.0573 192.8427 484.0341
51 06/20/2019 08:00:00 8.616709 45.45583 331.2251 3.057286 122.3012 430.1052 193.4743 482.7753
52 06/21/2019 08:00:00 3.501372 44.86591 200.688 3.189998 968.9734 432.8611 193.8111 486.4648
53 06/22/2019 08:00:00 6.277689 45.1199 186.1351 2.354236 970 434.2044 193.4949 485.2795
54 06/23/2019 08:00:00 6.360668 45.03632 324.405 1.922633 94.43671 418.744 193.7175 483.8784
55 06/24/2019 08:00:00 7.728527 45.28758 324.2428 2.764141 126.8438 423.3121 193.5719 486.8364
56 06/25/2019 08:00:00 6.493812 44.76516 333.2219 3.391791 63.86897 425.5179 193.2997 489.382
57 06/26/2019 08:00:00 10.27046 41.04709 310.9261 3.851992 54.44903 430.6298 192.1257 485.2211
58 06/27/2019 08:00:00 3.648737 41.25792 313.7135 2.862612 67.1749 429.446 192.338 483.3823
59 06/28/2019 08:00:00 4.323923 40.21812 161.5738 2.641063 896.6588 431.6487 189.99 481.575
60 06/29/2019 08:00:00 3.651902 40.34492 301.8221 2.329479 79.18868 425.6018 191.8405 482.8826
61 06/30/2019 08:00:00 3.522488 41.03275 288.5235 1.9618 86.28295 424.559 192.0768 484.3857
62 07/01/2019 08:00:00 3.923339 40.75467 297.4248 2.186338 79.30718 424.0842 191.937 483.531
63 07/02/2019 08:00:00 10.27057 40.73182 305.4559 2.185688 79.51367 426.0471 192.1479 486.3706
64 07/03/2019 08:00:00 10.27067 40.56203 295.1754 2.25 54.39308 425.9171 192.0473 485.7558
65 07/04/2019 08:00:00 2.508861 40.44397 303.2572 2.014705 4.35E-17 402.7734 191.3316 492.6463
66 07/05/2019 08:00:00 0.3128555 43.09813 298.7349 3.94E-17 114.901 401.867 192.2709 493.2958
67 07/06/2019 08:00:00 0.1662835 9.35E-17 1.746525 582.6605 376.1977 183.0314 417.7242
68 07/07/2019 08:00:00 10.27078 4.36E-17 8.02E-17 761.548 397.4353 177.3261 445.5499
69 07/08/2019 08:00:00 0 41.2253 307.2173 1.94805 64.96902 405.5939 191.7006 491.4153
70 07/09/2019 08:00:00 2.319197 43.7756 314.6518 2.772803 98.13533 400.073 192.1971 493.5495
71 07/10/2019 08:00:00 2.867255 40.90599 306.4901 1.687876 48.38352 401.3944 191.482 492.2534
72 07/11/2019 08:00:00 3.140121 40.48872 295.7018 1.765898 18.65295 399.2832 191.5211 488.92
73 07/12/2019 08:00:00 4.523676 41.68642 313.0649 1.962355 92.91818 408.7957 192.4183 493.1352
74 07/13/2019 08:00:00 4.305832 41.48981 312.4899 2.34312 87.74435 404.6627 192.2331 491.9185
75 07/14/2019 08:00:00 5.492769 41.85371 292.4988 2.306848 87.33546 403.502 192.4648 491.8103
76 07/15/2019 08:00:00 5.682961 41.43006 309.5308 7.94E-17 97.11487 405.2551 191.9237 490.4451
77 07/16/2019 08:00:00 4.434237 41.7007 292.3879 2.405273 108.5576 404.9993 192.3304 490.346
78 07/17/2019 08:00:00 3.746332 41.88127 303.7205 2.488217 95.7439 402.7569 192.2444 490.6469
79 07/18/2019 08:00:00 5.751856 42.29816 290.1653 2.209574 87.41698 403.3553 192.3255 489.9246
80 07/19/2019 08:00:00 2.678237 41.32146 304.0006 2.318438 81.20287 401.1919 191.985 489.851
81 07/20/2019 08:00:00 3.271808 41.98082 300.2943 2.071894 88.31502 400.9389 192.3994 488.5478
82 07/21/2019 08:00:00 4.798777 43.10394 298.0561 2.278479 103.4712 398.8178 192.976 494.267
83 07/22/2019 08:00:00 4.049023 43.05738 306.2131 2.510874 108.4737 396.4396 192.8278 491.4543
84 07/23/2019 08:00:00 4.882963 42.51516 41.69765 3.152178 970 426.058 192.7083 490.8497
85 07/24/2019 08:00:00 6.294335 42.39217 221.8678 1.764652 635.1307 422.3528 192.499 487.6748

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 24h_2
86 07/25/2019 08:00:00 2.946302 42.7053 308.6611 3.053446 123.3384 410.1236 192.8685 487.8104
87 07/26/2019 08:00:00 3.32486 42.39781 294.0358 2.926674 127.3683 414.6294 192.4737 490.5554
88 07/27/2019 08:00:00 3.835262 42.93912 306.5121 3.033493 65.14397 404.6187 192.5682 491.1824
89 07/28/2019 08:00:00 3.282557 42.777 314.0962 3.244071 77.84375 403.8434 192.879 490.8431
90 07/29/2019 08:00:00 2.769368 41.93015 322.6797 2.686355 76.14654 401.2332 192.3289 491.5199

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TRCA21142 PDR21153 Limit PDR 21153 PDR21143

BOTTOM VC711 OXYCHLORIN. REACT. VR511
484.429 1.106301 2.5 0.9640198
446.786 2.5
443.8977 2.5
487.8272 1.046903 -0.059398 -0.0148495 2.5 0.8964224 -0.0675974 -0.01689935
487.3231 1.129481 0.02318 0.004636 2.5 0.9890995 0.0250797 0.00501594
484.2539 1.107537 0.001236 0.000206 2.5 0.9588518 -0.005168 -0.000861333333333
483.9139 1.143927 0.037626 0.005375142857143 2.5 0.9970598 0.03304 0.00472
484.648 1.183067 0.076766 0.00959575 2.5 1.048621 0.0846012 0.01057515
485.9834 1.211474 0.105173 0.011685888888889 2.5 1.059918 0.0958982 0.010655355555556
486.7414 1.195236 0.088935 0.0088935 2.5 1.038343 0.0743232 0.00743232
480.2625 1.234636 0.128335 0.011666818181818 2.5 1.088481 0.1244612 0.011314654545455
484.0398 1.254028 0.147727 0.012310583333333 2.5 1.120251 0.1562312 0.013019266666667
463.6243 2.5
418.7997 2.5
487.2507 1.243679 0.137378 0.009158533333333 2.5 1.088373 0.1243532 0.008290213333333
484.593 1.244041 0.13774 0.00860875 2.5 1.091024 0.1270042 0.0079377625
484.2093 1.227877 0.121576 0.007151529411765 2.5 1.089984 0.1259642 0.007409658823529
483.6721 1.271326 0.165025 0.009168055555556 2.5 1.118384 0.1543642 0.008575788888889
487.6757 1.1805 0.074199 0.003905210526316 2.5 1.023481 0.0594612 0.003129536842105
484.5518 1.275523 0.169222 0.0084611 2.5 1.134601 0.1705812 0.00852906
483.0694 1.252802 0.146501 0.006976238095238 2.5 1.096921 0.1329012 0.006328628571429
485.7056 1.357088 0.250787 0.011399409090909 2.5 1.206249 0.2422292 0.011010418181818
485.578 1.534524 0.428223 0.018618391304348 2.5 1.3818 0.4177802 0.018164356521739
486.9172 1.559542 0.453241 0.018885041666667 2.5 1.405669 0.4416492 0.01840205
489.2677 1.703894 0.597593 0.02390372 2.5 1.539537 0.5755172 0.023020688
487.7466 1.832294 0.725993 0.027922807692308 2.5 1.67556 0.7115402 0.027366930769231
485.3039 1.781596 0.675295 0.025010925925926 2.5 1.628682 0.6646622 0.024617118518519
486.501 1.848228 0.741927 0.026497392857143 2.5 1.690863 0.7268432 0.025958685714286
488.352 1.900202 0.793901 0.027375896551724 2.5 1.737099 0.7730792 0.026657903448276
169.1511 2.5
486.146 1.151932 0.045631 0.001471967741935 2.5 0.9949474 0.0309276 0.000997664516129
494.1196 1.202555 0.096254 0.0030079375 2.5 1.022707 0.0586872 0.001833975
491.1691 1.47933 0.373029 0.011303909090909 2.5 1.292075 0.3280552 0.009941066666667
487.5049 1.572302 0.466001 0.013705911764706 2.5 1.399857 0.4358372 0.012818741176471
490.0562 1.617963 0.511662 0.014618914285714 2.5 1.437217 0.4731972 0.01351992
489.2605 1.625195 0.518894 0.014413722222222 2.5 1.446949 0.4829292 0.0134147
491.8328 1.681123 0.574822 0.01553572972973 2.5 1.480992 0.5169722 0.013972221621622
489.4865 1.661818 0.555517 0.014618868421053 2.5 1.461422 0.4974022 0.013089531578947
486.3911 1.784499 0.678198 0.017389692307692 2.5 1.603179 0.6391592 0.016388697435898

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484.6519 1.654229 0.547928 0.0136982 2.5 1.501375 0.5373552 0.01343388
488.9828 1.733264 0.626963 0.015291780487805 2.5 1.579171 0.6151512 0.015003687804878
488.7444 1.707991 0.60169 0.014325952380952 2.5 1.56578 0.6017602 0.014327623809524
483.1432 1.731007 0.624706 0.014528046511628 2.5 1.625498 0.6614782 0.015383213953488
485.2112 1.787883 0.681582 0.0154905 2.5 1.648939 0.6849192 0.015566345454546
484.5613 1.672404 0.566103 0.012580066666667 2.5 1.600486 0.6364662 0.014143693333333
482.0739 1.766297 0.659996 0.014347739130435 2.5 1.606684 0.6426642 0.013970960869565
485.3646 1.846801 0.7405 0.015755319148936 2.5 1.664721 0.7007012 0.014908536170213
484.1698 1.83142 0.725119 0.015106645833333 2.5 1.677155 0.7131352 0.014856983333333
486.4787 1.774309 0.668008 0.013632816326531 2.5 1.660551 0.6965312 0.01421492244898
485.9379 1.854031 0.74773 0.0149546 2.5 1.704733 0.7407132 0.014814264
484.7596 1.868053 0.761752 0.01493631372549 2.5 1.705202 0.7411822 0.014532984313726
486.4012 1.850853 0.744552 0.014318307692308 2.5 1.702492 0.7384722 0.014201388461539
485.2846 1.784278 0.677977 0.012792018867925 2.5 1.700263 0.7362432 0.013891381132076
484.8812 1.815801 0.7095 0.013138888888889 2.5 1.667758 0.7037382 0.013032188888889
488.8869 1.843761 0.73746 0.013408363636364 2.5 1.712892 0.7488722 0.013615858181818
489.3994 1.819752 0.713451 0.012740196428572 2.5 1.680535 0.7165152 0.012794914285714
485.2232 1.492769 0.386468 0.006780140350877 2.5 1.385427 0.4214072 0.00739310877193
484.7133 1.583237 0.476936 0.008223034482759 2.5 1.440438 0.4764182 0.008214106896552
481.6063 1.432235 0.325934 0.005524305084746 2.5 1.403746 0.4397262 0.007452986440678
485.0009 1.565917 0.459616 0.007660266666667 2.5 1.398038 0.4340182 0.007233636666667
486.0106 1.597398 0.491097 0.008050770491803 2.5 1.43925 0.4752302 0.007790659016393
485.2283 1.547945 0.441644 0.007123290322581 2.5 1.416395 0.4523752 0.007296374193548
489.2793 1.466481 0.36018 0.005717142857143 2.5 1.417261 0.4532412 0.007194304761905
487.886 1.51706 0.410759 0.006418109375 2.5 1.394957 0.4309372 0.00673339375
492.6431 1.497942 0.391641 0.006025246153846 2.5 1.359113 0.3950932 0.006078356923077
493.2896 1.64241 0.536109 0.008122863636364 2.5 1.577866 0.6138462 0.0093007
417.7265 2.5
445.5479 2.5
491.4104 1.550817 0.444516 0.006442260869565 2.5 1.387166 0.4231462 0.006132553623188
493.5573 1.750873 0.644572 0.009208171428571 2.5 1.630774 0.6667542 0.00952506
492.3105 1.50454 0.398239 0.005609 2.5 1.380053 0.4160332 0.005859622535211
488.9166 1.379941 0.27364 0.003800555555556 2.5 1.332312 0.3682922 0.005115169444444
493.1216 1.545314 0.439013 0.006013876712329 2.5 1.434295 0.4702752 0.006442126027397
491.9031 1.449862 0.343561 0.004642716216216 2.5 1.424713 0.4606932 0.006225583783784
491.8075 1.477968 0.371667 0.00495556 2.5 1.437327 0.4733072 0.006310762666667
490.4478 1.576228 0.469927 0.00618325 2.5 1.413459 0.4494392 0.005913673684211
490.3487 1.495681 0.38938 0.005056883116883 2.5 1.440099 0.4760792 0.006182846753247
490.6826 1.517538 0.411237 0.005272269230769 2.5 1.448333 0.4843132 0.006209143589744
489.9265 1.396808 0.290507 0.003677303797468 2.5 1.461469 0.4974492 0.006296825316456
489.845 1.425364 0.319063 0.0039882875 2.5 1.413052 0.4490322 0.0056129025
488.5536 1.547763 0.441462 0.005450148148148 2.5 1.432567 0.4685472 0.005784533333333
494.2665 1.539385 0.433084 0.005281512195122 2.5 1.535066 0.5710462 0.00696397804878
491.459 1.278227 0.171926 0.002071397590361 2.5 1.53814 0.5741202 0.006917110843374
490.8203 1.45902 0.352719 0.004199035714286 2.5 1.502393 0.5383732 0.006409204761905
487.6744 1.611524 0.505223 0.0059438 2.5 1.513215 0.5491952 0.00646112

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487.814 1.390031 0.28373 0.003299186046512 2.5 1.522188 0.5581682 0.006490327906977
490.5507 1.519794 0.413493 0.004752793103448 2.5 1.486959 0.5229392 0.006010795402299
491.1858 1.506441 0.40014 0.004547045454545 2.5 1.518316 0.5542962 0.006298820454545
490.8962 1.445063 0.338762 0.003806314606742 2.5 1.522397 0.5583772 0.006273901123596
491.5301 1.429208 0.322907 0.003587855555556 2.5 1.472435 0.5084152 0.005649057777778
0.417833634146 0.009842804711294 0.447298174 0.010034303597348

2.5 108.7893168064 November 15, 2019 2.5 102.4052133 November 8, 2019

2.5 141.5957179767 September 19, 2019 2.5 153.0729248 October 1, 2019

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