Professional Documents
Culture Documents
• DESCRIPTION • MATERIALS
Crush soda pop bottles using only temperature o Empty 2-liter soda pop bottle
changes. o Sink with hot water
o Refrigerator, freezer, or large container filled with
• OBJECTIVE ice water
This lesson demonstrates the relationships between
temperature, volume, and pressure. Students use water Always remember to use the appropriate safety
with different temperatures to physically change a equipment when conducting your experiment.
plastic bottle. The lesson can be extended to address Refer to the Safety First section in the Resource Guide
energy and energy transfer. on pages 391–393 for more detailed information about
safety in the classroom.
• CONTENT TOPICS
Scientific inquiry; measurement; states of matter; Jump ahead to page 285 to view the
properties of matter (gas laws); energy Experimental Procedure.
(energy transfer); force (pressure)
Matter exists primarily as a solid, liquid, or gas on the Gases are defined by a set of laws known as the gas
earth. Solids have a definite volume and a definite shape. laws, which describe the relationships between volume,
Examples of solids are chairs, glasses, and trees. Liquids temperature, and pressure. One of those laws, Charles’
have a definite volume but no definite shape. Examples Law, explains the relationship between temperature and
of liquids are water and oil. Gases have no definite shape volume. Charles’ Law states that the volume and
and no definite volume. The volume and shape of a gas temperature of a gas are directly proportional. As the
are determined by the vessel that contains it. Examples temperature of a gas increases, the volume of the gas
of gases include oxygen, nitrogen, and argon, which increases at a proportional rate. (Proportional means that
along with other gases, make up the air around you. they change at a constant rate. For example, ½ is
proportional to 2/4 and 3/6.)
Chemist®Activity
You Be TheLESSON Activity
1: Goofy Guide
Guides
Putty| page 282 282
LESSON 22: Crushing Bottles
Gay Lussac’s Law states that the pressure exerted on a Pressure is the amount of force exerted on an area.
container by a gas is directly proportional to the This relationship is described by the following equation:
temperature of the gas. When the temperature of the gas p = F/A
is increased, the pressure exerted on the container also
increases. Charles’ Law: The volume and temperature of a gas are
directly proportional. Therefore, the proportion of
The particles that make up a gas, such as the air, move volume to temperature of a gas equals a constant.
around freely. When air is trapped within a certain space V/T = K
or container, the particles bounce around and collide Likewise, because the formula is equal to a constant, it is
with one another, creating pressure on the container. possible to solve for a change in volume or temperature
Pressure is the amount of force exerted on an area. using the following proportion:
Air pressure, or atmospheric pressure, is the force V1 /T1 = V2 /T2
exerted on a surface by the weight of the air above that
surface. The average air pressure at sea level is about Gay Lussac’s Law: The pressure exerted on a container by
14.7 pounds per square inch (101.325 kPa). That’s a gas is directly proportional to the temperature of the gas.
almost 15 pounds of air pushing on every inch of our P/T = K
bodies! Fortunately, we’re so used to this pressure that Again, Gay Lussac’s Law can be used to calculate changes
we don’t even notice it. in pressure or temperature using the following proportion:
In this experiment, empty soda pop bottles are used to P1 /T1 = P2 /T2
illustrate the changes in volume and pressure as the
temperature of the air is changed. As the temperature
of a gas increases, the volume of the gas increases. CONNECT TO THE YOU BE THE
Therefore, as the air inside the bottle is heated, the CHEMIST CHALLENGE
increased volume increases the pressure. The pressure
For additional background information, please
the gas exerts on the inside of the bottle is greater than
review CEF’s Challenge study materials online at
the pressure exerted on the bottle by the outside air.
When the hot air is cooled, the gas particles slow down http://www.chemed.org/ybtc/challenge/study.aspx.
and the volume of the gas decreases. The pressure the • Additional information on mass, volume,
gas exerts on the inside of the bottle is also decreased. temperature, and pressure can be found in the
The air pressure outside of the bottle is now greater than Measurement section of CEF’s Passport to
the pressure inside the bottle. As a result, the bottle is Science Exploration: The Core of Chemistry.
crushed inward. When the crushed bottle is placed under
hot water, the air inside the bottle expands, pushing the • Additional information on states and properties of
sides of the bottle out. matter can be found in the Classification of Matter
section of CEF’s Passport to Science Exploration:
FORMULAS & EQUATIONS The Core of Chemistry.
Air is a mixture of gases. A mixture is made of two or
more substances that are combined physically. The air
around us is made up mainly of nitrogen (N2) and
oxygen (O2) gas. Approximately 78% of the air is N2,
and about 21% is O2. The remaining 1% is made up of HYPOTHESIS
trace gases such as argon (Ar), carbon dioxide (CO2),
water vapor (H2O), and other gases. uWhen a plastic bottle is heated and then
cooled, the bottle will crush inward as a
Volume is measured in a number of different ways. The result of the relationships between temperature,
simplest equation is finding the volume of a rectangular volume, and pressure.
solid. The volume of a rectangular solid can be found by
using the following equation:
V=l×w×h
NOTES
Fun Fact
Jacques Alexandre César Charles,
who developed Charles’ Law, launched
the world’s first manned hydrogen-filled
balloon in December 1783. He and his
co-pilot, Nicolas-Louis Robert,
ascended to a height of about
1,800 feet.
MODIFICATIONS/EXTENSIONS
Modifications and extensions provide alternate methods
for performing the lesson or similar lessons. They also
introduce ways to expand on the content topics presented
and think beyond those topics. Use the following
examples or have a discussion to generate other ideas
as a class.
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
3. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an
image of the example.
Matter
Mass
Volume
Solid
Liquid
Gas
Temperature
Pressure
Air pressure
4. Consider how an empty soda pop bottle will react when the temperature of the air inside changes and why.
______________________________________________________________________________________
______________________________________________________________________________________
1. Take the cap off an empty soda pop bottle. Then, run the bottle under hot water for one minute.
2. Put the cap on quickly. Place the bottle in a freezer, fridge, or ice bath.
4. With the cap on, run the bottle under hot water again. Observe.
1. Does the bottle seem to change when you first run it under hot water? Do you think a change is taking place? Why or
why not? __________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
2. What does the bottle look like after you take it out of the freezer, refrigerator, or ice bath? Why? ________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
3. What happens to the cooled bottle after you run it under hot water again? Why? ______________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
Volume
Pressure
5. Which gas law describes the relationship between temperature and volume? What does it state? ________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
6. Which gas law describes the relationship between temperature and pressure? What does it state? ________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
7. What will happen if the air in the bottle is cold, and then you place the cap on and heated the gas in the bottle? Why?
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
8. Is your hypothesis valid? Why or why not? If not, what would be your next steps? ____________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
1. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an
image of the example.
Energy
Thermal energy
Heat
Conduction
Convection
Radiation
2. Can you deflate a balloon using only changes in temperature? Explain. ______________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
______________________________________________________________________________________________________
bath may be used to reduce the temperature of a substance. Hot water may be used to increase the temperature of a substance.
______________________________________________________________________________________________________
These materials may be used to test the effects of temperature on the volume and pressure of the air inside the empty soda pop bottles.
3. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an
image of the example.
4. Consider how an empty soda pop bottle will react when the temperature of the air inside changes and why.
______________________________________________________________________________________
of the relationship between temperature and volume. As the temperature decreases, the volume of the gas decreases.
______________________________________________________________________________________
1. Take the cap off an empty soda pop bottle. Then, run the bottle under hot water for one minute.
2. Put the cap on quickly. Place the bottle in a freezer, fridge, or ice bath.
4. With the cap on, run the bottle under hot water again. Observe.
1. Does the bottle seem to change when you first run it under hot water? Do you think a change is taking place? Why or
why not? __________________________________________________________________________________________
The bottle does not seem to change when you first run it under hot water. However, a change is taking place. The energy of
______________________________________________________________________________________________________
the gas particles is increasing, which increases the volume of the gas inside the bottle. The increase in volume increases the pressure
______________________________________________________________________________________________________
that the gases exert on the inside of the bottle.
2. What does the bottle look like after you take it out of the freezer, refrigerator, or ice bath? Why? ________________
After you take the
______________________________________________________________________________________________________
bottle out of the freezer, it looks crushed. This change occurs because the colder temperature decreases the volume and the pressure of the
______________________________________________________________________________________________________
air inside the bottle. The air pressure on the outside of the bottle is greater than the pressure inside of the bottle, which causes the outside air
______________________________________________________________________________________________________
pressure to crush the bottle.
3. What happens to the cooled bottle after you run it under hot water again? Why? ______________________________
After running the bottle under hot water
______________________________________________________________________________________________________
again, the volume of the gas inside the bottle increases. This increase in volume causes the pressure inside the bottle to increase as well.
______________________________________________________________________________________________________
The increased pressure inside pushes the bottle back out.
4. In the table below, record whether the volume and pressure increased or decreased in the bottle.
5. Which gas law describes the relationship between temperature and volume? What does it state? ________________
Charles’ Law describes
______________________________________________________________________________________________________
the relationship between temperature and volume. It states that the volume and temperature of a gas are directly proportional. Therefore, the
______________________________________________________________________________________________________
proportion of volume to temperature of a gas equals a constant.
6. Which gas law describes the relationship between temperature and pressure? What does it state? ________________
Gay-Lussac’s Law
______________________________________________________________________________________________________
describes the relationship between temperature and pressure. It states that the pressure exerted on a container by a gas is directly
______________________________________________________________________________________________________
proportional to the temperature of the gas.
7. What will happen if the air in the bottle is cold, and then you place the cap on and heated the gas in the bottle? Why?
______________________________________________________________________________________________________
If you heat a capped bottle filled with cold air, the volume of the gas inside will expand. The bottle may not be large enough to hold the
______________________________________________________________________________________________________
increased volume and pressure. The bottle would then be stretched out or would burst.
______________________________________________________________________________________________________
8. Is your hypothesis valid? Why or why not? If not, what would be your next steps? ____________________________
______________________________________________________________________________________________________
Answer 1: Valid because the data support my hypothesis.
______________________________________________________________________________________________________
Answer 2: Invalid because the data do not support my hypothesis. I would reject my hypothesis and could form a new one, such as …
1. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an
image of the example.
2. Can you deflate a balloon using only changes in temperature? Explain. ______________________________________
Yes. If there is a gas inside the balloon,
______________________________________________________________________________________________________
decreasing the temperature of the gas will decrease the volume and deflate the balloon slightly. However, the same amount of gas will
______________________________________________________________________________________________________
still be inside the balloon. If the gas in the balloon becomes warmer, its size will increase again.