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Lesson
Describing Gases
1
There are three states of matter, namely solids, liquids, and
gases. All states of matter differ in their properties based on the
arrangement of their particles. Solid particles are tightly packed,
usually in a regular pattern, liquid particles are close together with no
regular arrangement, while gas particles are well separated with no
regular arrangement.
What’s
In
What’s
New
Activity 2: How does gas behave?
(Adapted from: SCIENCE LINKS 10 Worktext for Scientific and
Technology Literacy, Revised Edition)
Directions: Perform the activity below and write your observations
and answers to the guide questions in your notebook/on a separate
sheet of paper
Guide Questions:
1. How big does the balloon in the soda bottle get?
2. How big does the balloon outside the soda bottle get?
3. Explain the difference.
What is
It
Properties of Gases
Gas is the state of matter that has particles that are freely
moving and are far from each other, which makes them highly
compressible.
Gases have important fundamental properties that are
measurable such as volume, pressure, temperature, and the amount
of the gas or the number of moles.
Volume
Volume, which is one of the measurable properties of gas, is
denoted by the symbol V. It is the amount of space occupied by a gas
sample. Its SI unit is in liters (L). It can also be expressed in millilitres
(mL), cubic centimeter (cm3), cubic meter (m3), and cubic decimeter
(dm3).
Pressure
Pressure is the next important measurable property of the gas,
which is denoted by the symbol P. Pressure of the gas is the force
exerted by the gas per unit area. In equation:
Pressure (P) = force (F) / area (A)
The SI unit used for pressure is pascal (Pa), named after Blaise
Pascal. This unit is equivalent to force of 1 newton, acting on 1 square
meter.
1 Pa = 1 N / 1 m2
Other units of pressure are atmosphere (atm), millimetre of
mercury (mmHg). Torr, bar, kilopascal (kPa), and pounds per square
inch (psi).
Temperature
In symbols, n = m /M
Lesson
Gas Laws
2
The four measurable properties of gases such as pressure,
volume, temperature, and number of moles are related to each other.
If one of these variables is changed, there is a corresponding change in
other variables depending on its relationship. Gas law equations can
be derived whenever one of these variables is altered.
There are four main gas laws. These are Boyle’s Law, Charles’
Law, GayLussac’s Law, and Avogadro’s Law. The combination of
Boyle’s Law and Charles’ Law is known as the Combined Gas Law
while the relationship between variables used by the four main gas
laws is explained by the Ideal Gas Law.
What’s
In
Activity 6: Match Me
Directions: Identify the given pictures below by choosing the
appropriate answers found inside the word pool. Write your answers
in your notebook/on a separate sheet of paper.
Gas and volume Gas and temperature Gas and Pressure Gas and
amount of gas
A. C.
https://
images.app.goo.gl/
2TytLmjm35Fpm1gkg https://images.app.goo.gl/hk5NeRb8wRLrNoBNA
B. D.
https://images.app.goo.gl/4SM7dRx2XoKvlSEw5
https://images.app.goo.gl/iZ9QfodQAjBd3T1P8
What’s
New
Activity 7:
Directions: Match Column A with Column B. Write the letter of your
answer in your notebook/on a separate sheet of paper.
COLUMN A COLUMN B
1. Combined Gas Law A. Volume is inversely proportional to pressure.
2. Avogadro’s law B. Volume is directly proportional to temperature.
3. Boyle’s Law C. Pressure is directly proportional to
temperature.
4. Ideal Gas Law D. Pressure and volume are inversely proportional
to each other, but are both directly
proportional to the temperature.
5. Gay Lussac’s Law E. Volume is directly related to the number of
moles.
6. Charles’ Law F. Pressure is directly related to mass.
G. Volume is directly proportional to the number
of moles and temperature and inversely
proportional to pressure.
What is
It
Boyle’s Law
Robert Boyle, an English chemist was the first to investigate the
relationship between the pressure of a gas and its volume at a
constant temperature. Based on his experiment made wherein he
trapped a fixed amount of air in a J-tube and changed the pressure at
a constant temperature, he found out that as the pressure increases,
the volume decreases. He then concluded that the volume occupied by
the fixed amount of gas is inversely proportional to its pressure at a
constant temperature.
Boyle’s Law can be expressed by the following equation:
1
V at constant T and n
P
Where:
V = volume, P = pressure, T = temperature, n = amount of gas
To change the proportionality, sign to an equal sign, the
proportionality constant k, is introduced
1
V =k or PV = k
P
For a given sample of gas under two different conditions at a constant
temperature, the product of pressure and volume is constant, and it is
written as follows:
P1V1 = P2V2
Where P1 and V1 are the initial pressure and volume; P2 and V2 are the
final pressure and volume at constant temperature and the same
amount of gas.
In Boyle’s law, the following formulas are to be used when three
variables are given and one is unknown:
(https://images.app.goo.gl/
gVhLsvtnwPpmDeC6A] Schematic illustration of
Boyle’s Law
Example:
A sample of nitrogen gas (N2) has a volume of 12.0 L and a pressure of
760.0 mm Hg. When the gas is released, it gives 32.0 L of nitrogen. If
the temperature is the same, what is the new pressure of nitrogen?
Given:
P1 = 760.0 mm Hg V1 = 12.0 L
V2 = 32.0 L
Find: P2
Solution:
P1V1
P2 =
V2
Then, substitute the given values to the equation
760.0 mm Hg x 12.0 L
P2 =
32.0 L
P2 = 285 mm Hg
V T at constant P and n
Where:
V = volume, P = pressure, T = temperature, n = amount of gas
V
V =kT
or k =
T
For a given sample of gas under two different conditions, you will
arrive at the following equations:
V1 V2
= k and = k
T1 T2
V1 V2
=
T1 T2
Where V1 and T1 are the initial volume and temperature; V2 and T2 are
the final volume and temperature at constant pressure and the same
amount of gas
In Charles’ law, the following formulas are to be used when
three variables are given and one is unknown:
Given:
V1 = 484.0 mL T1 = -10.0oC
T2 = 37.0oC
Find: V2
Solution:
V1T2
V2 =
T1
Then, substitute the given values to the equation
484.0 mL x 310 K
V2 =
263 K
V2 = 570.49 mL ≈ 570 mL
Kinetic Molecular Theory and Charles’ Law
From the kinetic molecular theory, the average kinetic energy of gas
particles is directly proportional to the temperature of a gas. The
particle’s average kinetic energy is related to its speed. When the
temperature of the gas is increased, the particles move at higher
speed. This results in frequent collision of the particles with the walls
of the container, so the gas particles exert a greater force on the walls.
Gay-Lussac’s Law
The person who is credited with the determination of the
temperaturepressure relationship in gases at constant volume is
Joseph Louis Gay-Lussac. He deduced that the pressure of the gas is
directly proportional to its temperature.
Gay-Lussac’s Law states that, at constant volume, the pressure
of a fixed amount of gas is directly proportional to the absolute
temperature.
P T at constant V and n
Where:
P1 P2
= k and = k
T1 T2
P1 P2
=
T1 T2
https://images.app.goo.gl/
DYk4mMvrsiZ9vuqm6 Schematic diagram
of Gay Lussac’s Law
Example:
What will happen to a can of paint spray containing only the
propellant at a pressure of 750.0 torr at 30.0 oC if it is thrown into a
heap of garbage burning at 165.0oC?
Given:
Find: P2
Solution:
P1T2
P2 =
T1
Then, substitute the given values to the equation
750.0 torr x 438 K
P2 = = 1,084 torr
303 K
Combined Gas Law
Boyle’s Law and Charles’ Law can be combined and treated as a
single law, called the combined gas law, which describes the pressure-
volume-temperature relationship of a constant amount of gas.
The pressure and volume of a gas are inversely proportional to
each other, but are both directly proportional to the temperature of
that gas.
Translating it to mathematical equation:
1
V or PV T or PV = constant
P
PV
= k
T
P1V1 P2V2
=
T1 T2
Where P1, V1 and T1 are the initial pressure, volume and temperature;
P2, V2 and T2 are the final pressure, volume and temperature at
constant amount of gas
In Boyle’s law, the following formulas are to be used when five
variables are given and one is unknown:
P1 = P2V2T1/V1T2 V1 = P2V2T1/P1T2 T1 = P1V1T2/P2V2
P2 = P1V1T2/V2T1 V2 = P1V1T2/P2T1 T2 = P2V2T1/P1V1
Example:
A 20.0 mL bubble is released from a tank at a pressure of 4.0 atm
and a temperature of 10.0oC. What will be the volume of the bubble
when it reaches the water surface, where the pressure is 1.0 atm and
the temperature is 19.0oC??
Given:
P1 = 4.0 atm T1 = 10.0oC V1 = 20.0 mL P2 = 1.0 atm T2 =
19.0oC Find: V2
Solution:
Change the temperature to Kelvin when they are given in
Celsius.
T1 = 10.0oC + 273 = 283 K T 2 = 19.0oC +
273 = 292 K Derive the equation for the unknown from the combined
gas law
P1V1T2
V2 =
P2 T1
Substitute the values, then solve for the unknown
(4.0 atm)(20.0 mL)( 292 K)
V2 = = 82.5 mL (1.0 atm)(283 K)
Avogadro’s Law
When you inflate a balloon, its volume increases because you
add more air molecules. If the balloon has a small hole, the air leaks
out and causes the air volume to decrease. Amedeo Avogadro, an
Italian chemist and physicist, formulated the Avogadro’s Law, which
states that at constant temperature and pressure, the volume of a gas
is directly related to its number of moles.
This law is expressed as:
V n at constant P and T
V
V =kn or k =
n
V2
V1
=
n1 n2
Where V1 and n1 are the initial volume and amount of gas; V 2 and n2
are the final volume and amount of gas at constant pressure and
temperature.
In Avogadro’s law, the following formulas are to be used when
three variables are given and one is unknown:
Find: V2
Solution:
Derive the equation for V2 using Avogadro’s law.
Substitute the given values, the solve for the unknown.
1
Boyle’s law: V at constant T and n
P
P= 5.73 atm
1. The law which states that temperature and volume of gas are
directly related to each other.
2. The law which states that pressure is directly proportional to
temperature.
3. Absolute temperature
4. STP means ________ temperature and pressure
Set B: (Optional)
Directions: Analyze the problem and identify what formula will be
used. Write the answer in your notebook/on a separate sheet of paper.
1. Which of the six gas laws will be used if you are going to calculate
the pressure exerted by a 0.25 mole sulfur hexafluoride in a steel
vessel having a capacity of 1,250 ml at 70oC?
What I Have
Learned
Directions: Complete the summary below by filling in the blank
spaces with appropriate word/words. You may choose the words from
the textbox provided. Word/words can be used more than once. Write
your answers in your notebook/on a separate sheet of paper.
Gay-Lussac
increases
(1)____ is the state of matter which has particles that are freely
moving and are far from each other, which makes them highly
compressible. Gases have important fundamental properties that are
measurable such as (2)______, (3)________, (4)_____, and (5)_____. The
four measurable properties of gases are (6)_____ to each other. If one of
these variables is changed, there is a corresponding change in other
variables depending on its relationship. (7)_______ can be derived
whenever one of these variables is altered.
The gas laws are (8)_____, (9)_____, (10)_____ and (11)______. The
combination of Boyle’s Law and Charles’ Law is known as the
(12)_______ while the relationship between variables used by the four
main gas laws is explained by the (13)____. (14)_____, an English
chemist was the first to investigate the relationship between the
pressure of a gas and its volume at a constant temperature. French
physicist, (15)______ determined the volume-temperature relationship
in gases. The person who is credited with the determination of the
temperature-pressure relationship in gases at constant volume is
(16)_____. (17)_____, an Italian chemist and physicist, formulated the
law, which states that at constant temperature and pressure, the
volume of a gas is directly related to its number of moles.