Chapter 3 ELECTROCHEMISTRY

Topic 3 Faraday’s law & Electrolytic cells

E = mc 2 E = hv PV = nRT m = ect

c  t  96500 c t 96500  m c m
E= E= E= E=
m m  96500 c t t  96500

1.6  10 −19 6.24 10−35 6.24 10−16 6.24 1012

Page | 1
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells

BrO3−

m
2

2+ +
Zn | Zn (1M) || Ag (1M) | Ag

I  t  60 I t  x I  t  60 I  t  x  60
96500  x 60  96500 96500  3x 96500  3

Page | 2
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells

PtSO 4 [Cu(H 2O) 4 ]SO4 H 2SO4 Cu 2SO4

Page | 3
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells
1
2W1 = W2 W1 = W2 W1 = 2W2 W1 = W2
3

Cr2O72−

MnO−4 MnO2

O2 , H 2 S2O82− , Na O2 , Na S2O82− , H2

12  10 46 96, 500 6.022 1023

Page | 4
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells

Na 2SO 4

Atomic weight  Valency Atomic weight  96,500

96,500 Valency
Atomic weight Valency  96,500
Valency  96,500 Valency  96,500
Ecell = 0.296 V,

1  1010 1 10 −10 2.96  10−2

Cl 2 H2 O2 H2 Cl 2 O2

Page | 5
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells

Page | 6
 Chapter 3 ELECTROCHEMISTRY
Topic 3 Faraday’s law & Electrolytic cells

Page | 7