SMJK CHUNG LING PULAU PINANG

Peperiksaan Percubaan Kimia Tingkatan 5

Kertas 2 (2 hours 30 min)

Name: ___________________________ Class: 5S ____ Sch no: _____

Answer all the questions on the space provided.

Section A (60 marks)
1. The secret to crystal clear skin is using SKII facial treatment essence constantly. The
essence contains over 90% Pitera and sorbic acid. Diagram 1 shows that the structural
formula of sorbic acid.

Diagram 1

(a) What is mean by molecular formula? [1m]

____________________________________________________________________
____________________________________________________________________
____________________________________________________________________

(b) Write the molecular formula and empirical formula of sorbic acid in the SKII. [2 m]
Molecular formula: ________________
Empirical formula: _________________

(c) State the functional group of sorbic acid. [1m]

(d) State the type of bond present in sorbic acid. [1m]

_____________________________________________________________________

1
2. Table 1 shows the information of two acids, X and Y.
Name of acid Basicity of acid Ionisation in water
X Diprotic Completely ionised
Y Monoprotic Partially ionised
Table 1

(a) Name the acid. [2m]

Acid X: ____________________________

Acid Y: ____________________________

(b) Both acid have the same concentration which is 1.0 mol dm-3.
Explain the pH value of acid X and acid Y. [3m]

_____________________________________________________________________

_____________________________________________________________________

_____________________________________________________________________

(c) Diagram 2 shows a magnesium ribbon is added to acid X.

Diagram 2
(i) Write the chemical equation for the reaction.
[1m]
__________________________________________________________________

(ii) Calculate the volume of gas produced at room condition when 0.4 mol of
magnesium ribbon used. [3m]
[Molar volume of gas at room condition = 24 dm3 mol-1]

(iii) Describe a chemical test to identify the gas produced. [2m]

__________________________________________________________________

2
 __________________________________________________________________
3. (a) Diagram 3 shows a limestone cave where the major chemical substance is called
calcium carbonate salt.

Diagram 3

(i) State the type of solubility of salt in terms of solubility. [1m]

______________________________________________________________________

(ii) Name the reaction to prepare the salt.

Suggest two chemical subtances that can be used to prepare the salt. [3m]
______________________________________________________________________
______________________________________________________________________

(iii) By using the suggested chemical subtances in 3(a)(ii), write a balanced chemical
equation for the reaction. [2m]
______________________________________________________________________

(b) Diagram 4 shows the series of reactions that involve salt X.

Salt A → Metal oxide B + CO2

Diagram 4

Metal oxide B is yellow when it is hot but turns white when it is cold. [1m]

(i) State the name of metal oxide B. [1m]

_____________________________________________________________________

(ii) State the anion present in the aqueous solution of A. [1m]

_____________________________________________________________________

(iii) Describe a chemical test to verify anion mentioned in 3(b)(ii). [3m]

_____________________________________________________________________

_____________________________________________________________________

3
 _____________________________________________________________________
4. An experiment was conducted to study the effect of temperature on the rate of reaction
between 50 cm3 of 0.2 mol dm-3 sodium thiosulphate solution and 5 cm3 of 0.1 mol dm-3
sulphuric acid. Time taken for fixed amount of Sulphur formed is recorded. The
experiment was repeated five times using different temperature of sodium thiosulphate
solution.
Table 2 shows the temperature and time taken for mark ‘X’ sign to disappear from view.

Experiment 1 2 3 4 5

Temperature of sodium 30.0 40.0 60.0 80.0 92.0

thiosulphate (℃ ¿

Time taken for fixed amount 38 31 19 14 12

of sulphur (s)

1
(s-1)
Time

Table 2
(a) Write the ionic equation for the reaction between sodium thiosulphate and sulphuric
acid. [1m]
_____________________________________________________________________

(b) Complete Table 2 for 1/time. [1m]

(c) What is the colour of the solid sulphur formed? [1m]

_____________________________________________________________________

(d) State the relationship between the temperature of sodium thiosulphate and rate of
reaction. [1m]

_____________________________________________________________________

_____________________________________________________________________

(e) Explain your answer in (c) using collision theory. [3m]

_____________________________________________________________________

_____________________________________________________________________

_____________________________________________________________________

_____________________________________________________________________

_____________________________________________________________________

4
 (f) When Joy travelling to Russia Siberia, she found that frozen woolly mammoth was
still with fur intact after 39 000 years. Explain why. [1m]

5. Diagram 5 shows several reactions involving compound M.

A B
Ethene Compound M Ethanoic acid

Diagram 5

(a) Ethene is produced from compound S through the process of A.

(i) Name the process of A. [1m]
____________________________________________________________________

(ii) Name compound M. [1m]

____________________________________________________________________

(iii) State the homologous series of compound M. [1m]

____________________________________________________________________

(iv) Write the chemical equation for the process of A. [1m]

____________________________________________________________________

(b) (i) Name the reagent used in the process of B. [1m]

___________________________________________________________________

(ii) State the change of colour of the reagent used in (b)(i). [1m]
__________________________________________________________________

(c) The pineapple jam contains butyl butanoate which gives pineapple flavor.

(i) Name the process to prepare butyl butanoate. [1m]

____________________________________________________________________

(ii) State 2 reactants used to produce butyl butanoate. [2m]

_____________________________________________________________________

(iii) Draw the structural formula of butyl butanoate. [1m]

5
6. An experiment was carried out to determine the empirical formula of lead oxide. A
sample of lead oxide was heated in the flow of dry hydrogen gas as shown in Diagram 6.

Diagram 6

After heating, the porcelain boat and its content are cooled in the flow of hydrogen and its
mass is recorded. The heating, cooling and weighing processes are repeated until the mass
of the porcelain boat and its contents is constant. The data recorded from the experiment
are as follows:

Mass of porcelain boat = 25.30 g

Mass of porcelain boat and lead oxide before heating = 36.45 g
Mass of porcelain boat and lead after heating = 35.65 g

(a) Write one chemical equation that can produce hydrogen gas. [1m]
_____________________________________________________________________

(b) State one observation that can be made from experiment. [1m]
_____________________________________________________________________

(c) Why is it necessary to cool the porcelain boat and its contents in the flow of hydrogen
gas? [1m]
_____________________________________________________________________

(d) Based on the data, determine the empirical formula of lead oxide. [3m]
[Relative atomic mass: Pb,207; O,16]

6
 (e) Why is the process of heating, cooling and weighing processes are repeated until a
constant mass is obtained? [1m]
_____________________________________________________________________

(f) State one precautionary step to be taken while conducting this experiment. [1m]
_____________________________________________________________________
7. Diagram 7 shows the apparatus set up of a Daniell cell.

Diagr
am 7

(a) (i) State the direction of the electron flow of the cell. [1m]

__________________________________________________________________

(ii) Explain your answer in (a)(i). [1m]

__________________________________________________________________

(b) Why is the porous pot used in the cell. [1m]

_____________________________________________________________________

_____________________________________________________________________

(c) Write the half equation at the copper electrode. [1m]

_____________________________________________________________________

(d) State one observation for the reaction occurs in Diagram 7. [1m]

_____________________________________________________________________

(e) The voltage of the cell is 1.1v. How will the voltage change if zinc is replaced with
magnesium and the zinc sulphate is replaced with magnesium sulphate solution? [1m]

_____________________________________________________________________

7
 Section B (40 marks)

8 (a) The chemical equations below represent chemical equations.

Reaction I : CuSO4 + Mg → Cu + MgSO4

Reaction II: CuSO4 + Pb(NO3)2 → PbSO4 + Cu(NO3)2

Based on the chemical equations above, determine whether the reactions are redox
reactions. Explain your answer in terms of change in oxidation number. [4m]

(b) Diagram 8 shows two sets of experiments. Set A shows the apparatus set up to change
Fe3+ to Fe2+ and set B shows the apparatus set up to change Fe2+ to Fe3+.

Diagram 8
(i) Predict the observations in Set A and Set B. [2m]

(ii) Suggest substance L.Hence,write the half equations for Set A. [3m]

(iii) Suggest substance M. State the color change of substance M after react with iron(II)
sulphate solution[2m]

(d) Diagram 9 shows a drop of water on a piece of iron metal. After some time, there are
some brown solid on a surface of iron.

Diagram 9

Explain how the rusting of iron occurs. In your explanation,include the chemical
equation involved. [7m]

(e) H2O2 + Fe2+ → Fe3+ + H2O

8
 Write the oxidation, reduction half equations and includes the overall ionic equation.
[3m]

9 (a) When latex is exposed to air for a period of time, it turns to white lump. Explain how
the latex changes to white lump. [5m]

(b) Name the monomer of natural rubber. Write the chemical equation to show the
formation of natural rubber. [2m]

(d) Natural rubber is soft and less elastic. What is the process used to make the natural
rubber harder and more elastic? Explain it. [5m]

(e) Purification of metals is one of the uses of electrolysis in industries. With the help of a
labelled diagram,describe an experiment to purify an impure copper strip by
electrolysis in the laboratory. In your description, give the half equations and
observations that can be made from the process. [8m]

Prepared by: Lee Mee Ling

Checked by: Chee Ai Sim
Verified by: Sim Jiuan Nee

9
10