Chemistry - Periodic Classification & Chemical Bonding DPP Challenge - MARKS App

Periodic
Classification & Chemical Bonding DPP #99PercentileChallenge

Questions MARKS App
Q1
In a period, the ionisation energy
(1) increases from left to right.
(2) decreases from left to right.
(3) first increases then decreases.
(4) remains the same.
Q2
Types of bonds present in K 4 [Fe(CN)6 ] molecule are
(1) covalent and electrovalent bonds.
(2) covalent and coordinate covalent bonds.

(3) electrovalent, covalent and dative bonds.
(4) electrovalent bond and dative bonds.
Q3
Chloride ion and potassium ion are isoelectronic. Then:
(1) Their sizes are same.

(2) Cl ion is bigger than K ion.
− +
(3) K ion is relatively bigger.

+
(4) Their sizes depend on other cation and anion.
Q4
The first (Δ H
i 1) and the second (Δ H i 2) ionization enthalpies (in kJ mol −1
) and the Δe gH electron gain
enthalpy (in kJ mol −1

) of a few elements are given below:
Elements ΔH1 ΔH2 ΔegH
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Periodic
Questions MARKS App
Elements ΔH1 ΔH2 ΔegH
I 520 7300 -60
II 419 3051 -48
III 1681 3374 -328
IV 1008 1846 - 295
V 2372 5251 + 48
VI 738 1451 -40
Which of the above is likely to be the most reactive non-metal?
(1) Element (III)

(2) Element (II)
(3) Element (I)

(4) Element (IV)
Q5
The valence bond theory is unable to explain the_____
(1) delocalization of electrons over the two nuclei of bonding atoms

(2) shieldihg effect of electrons
(3) concept of resonance
(4) bonding in electron deficient molecules
Q6
Which one of the following is a correct set?
(1) H 2 O, sp
3
, angular
(2) H 2 O, sp
2
, linear
(3) NH +
4
, dsp ,
2
square planar

Periodic
Questions MARKS App
(4) CH 4,
2
dsp , tetrahedral
Q7
The electronegativities, χ for four elements are given in the table.

P
Element H C O Cl
χP 2. 2 2. 6 3. 4 3. 2
Which bond is the most polar?
(1) C − H
(2) O − H
(3) H − Cl
(4) C − O
Q8
The correct decreasing order of electropositive character among the following elements is
(1) Fe > Sc > Rb > Br > Te > F > Ca

(2) Ca > Rb > Sc > Fe > Te > F > Br
(3) Rb > Ca > Sc > Fe > Br > Te > F

(4) Rb > Ca > Sc > Fe > Te > Br > F
Q9
Which of the following species does not exist?
(1) He +
(2) H +
(3) Be 2
(4) Be +

Periodic
Questions MARKS App
Q10
Which of the following statements regarding modern periodic law is incorrect?
(1) Henry Moseley observed regularities in the characteristics X-ray spectra of elements

(2) A plot of frequency of X-rays emitted against atomic number (Z) give a straight line
(3) The atomic number of an element is equal to the number of neutron(s) in a neutral atom
(4) Electronic configuration of an atom determine the physical and chemical properties
Q11
Lithium hydride reacts with aluminium chloride to form a complex. The geometry of the complex and the
ligand present in the complex is
(1) Octahedral, chloride
(2) Tetrahedral, hydride

(3) Octahedral, bridging chloride
(4) Tetrahedral, Chloride and hydride
Q12
As per molecular orbital theory, bond order of Li is x and that of Li is y . The value of (x − y) is
2
−
Q13
Which of the following molecule does not consist of intramolecular hydrogen bonding?
(1)
Chloral
(2) Chloral hydrate

(3) Ortho hydroxybenzaldehyde
(4) Ortho chlorophenol

Periodic
Questions MARKS App
Q14
Value of shielding constant σ for Ne is 4. 15. Find the effective nuclear charge on Na and F , respectively.
+ −
(1) 4. 85, 6. 85

(2) 5. 85, 6. 85
(3) 6. 85, 4. 85

(4) 4. 85, 4. 85
Q15
For NaCl, lattice energy = −186 kcal/mol, the solvation energy of Na and Cl are −97 and
+ −
−85kcal/mole , respectively.Therefore, for NaCl(s)
(1) enthalpy of solution is exothermic and magnitude equal 4 kcal/mol.
(2) enthalpy of solution is exothermic and magnitude equal to 368kcal/mol.

(3) enthalpy of solution is endothermic and magnitude equal to 4kcal/mol.
(4) enthalpy of solution is endothermic and magnitude equal to 368kcal/mol.
Q16
Which one of the following ions will be the smallest in size?
(1) Na +
(2) Mg 2+
(3) F −
(4) O −
Q17
In which molecule is the Van der Waals force likely to be the most important in determining m.pt. and b.pt.?
(1) ICl
(2) Br 2
(3) H 2S

Periodic
Questions MARKS App
(4) CO
Q18
H2O is dipolar, whereas BeF2 is not. It is because
(1) The electronegativity of F is greater than that of O

(2) H2O involves hydrogen bonding whereas BeF2 is a discrete molecule
(3) H2O is linear and BeF2 is angular
(4) H2O is angular and BeF2 is linear
Q19
Periodic classification of elements based on atomic volume curve was given by
(1) Newland
(2) Lother Mayer

(3) Dobereiner
(4) Mendeleev
Q20
Choose the incorrect statement among the following:
(1) All the actinoid elements are radioactive.

(2) Alkali and alkaline earth metals are s-block elements.
(3) Chalcogens and halogens are p-block elements.
(4) The first member of the lanthanoid series is lanthanum.
Q21
The I st
IEs of four consecutive elements present in the second period of periodic table are 8. 3, 11. 3, 14. 5
and 13. 6 eV respectively. Which of these is the IE of Nitrogen?

Periodic
Questions MARKS App
(1) 13. 6
(2) 8. 3
(3) 14. 5
(4) 11. 3
Q22
A hybrid orbital formed from s and p-orbital can form_____
(1) σ bond only

(2) either σ or π bond
(3) π bond only

(4) none of these
Q23
The bond angle and dipole moment of water, respectively, are
(1) 109 .5 ° and 1 .84 D.
(2) 107 .5 ° and 1 .56 D.

(3) 104.5° and 1 .84 D.
(4) 102 .5 ° and 1 .56 D.
Q24
Paramagnetism of oxygen is explained on the basis of its electronic configuration of
(1) π ∗ 1
2px , π 2pz
∗ 1
(2) π ∗ 1
2px , π 2py
∗ 1
(3) σ ∗ 1
2s , π2py
1
(4) σ ∗ 1 ∗
2s , π 2py
2
Q25

Periodic
Questions MARKS App
The group number of an element in periodic table indicates
(1) valency with respect to hydrogen

(2) the atomicity
(3) the number of electrons in the outermost shell
(4) none of the above.

Periodic
Questions MARKS App
Answer Key
Q1 (1) Q2 (3) Q3 (2) Q4 (1)
Q5 (4) Q6 (1) Q7 (2) Q8 (4)
Q9 (3) Q10 (3) Q11 (2) Q12 (0.5)
Q13 (1) Q14 (3) Q15 (3) Q16 (2)
Q17 (2) Q18 (4) Q19 (2) Q20 (4)
Q21 (3) Q22 (1) Q23 (3) Q24 (2)
Q25 (3)

Periodic
Hints & Solutions MARKS App
Q1
Ionization energy is simple terms can be described as a measure of the difficulty in removing an electron from
an atom or ion or the tendency of an atom or ion to surrender an electron. The loss of electron usually happens
in the ground state of the chemical species.
IP ↑
L −−
−→ R
Q2
The electrovalent or ionic bond is formed between ions due to the complete transfer of electrons.
4−
In the given compound, four K ions are bonded to the [Fe (CN)
+
6
] anion by ionic bonds.
A coordinate bond is a type of covalent bond in which both the electrons are contributed by the
same atom. In this compound, Fe is bonded to six CN ligands by dative bonds where the
2+ −
electrons of cyanide ligands occupy the hybrid orbitals of ferrous ion. In CN , a triple bond is −
present between the carbon and nitrogen atom, which is a covalent bond.
Q3
[
Z
e
]
−
< [
Z
e
]
+
for isoelectronic species as [ Z
e
] increases ionic size decreases.
CI K
Q4
Ionization Energy:
Energy required to remove an electron from atoms or ions.
Electron Affinity:
If an electron is added to a neutral atom in gaseous state, energy is given off. We call this energy as "electron
affinity".
The most reactive non-metal is element (III) because it has high Δ H (first ionization enthalpy) and a very
i 1
high negative electron gain enthalpy Δe gH .
The given values for element III match with F.

Periodic
Q5
With the help of the valence bond theory, the delocalisation of the electrons over the two nuclei of
the bonding atoms, shielding effect of the electrons, concept of resonance can be explained

because, in these cases, the octet is complete, while bonding in the electron deficient molecules
cannot be explained due to the incomplete octet.
Q6
H2 O molecule is having two bond pairs and two lone pairs. Hence, H 2O has sp -hybridisation and is angular.
3
NH4
+
and CH4 molecule are having all four bond pairs, hence, they have sp -hybridisation and are
3
tetrahedral.
Q7
The greater the electronegativity difference between the two atoms, the more polar will be the
bond.
ΔχP
C − H 0. 4
O − H 1. 2
H − Cl 1. 0
C − O 0. 8

Periodic
From the above table, it is clear that O − H bond is most polar.
Q8
Metallic character(electropositive) is inversely proportional to ionization energy.
Alkali and alkaline earth metals are most electropositive. Alkali metals are more electropositive than alkaline
earth metals.
In d-block elements , the elements near the alkaline earth metals are more electropositive than rest of the
members. Metalloids are less electropositive than metals. Halogens (nonmetals) are least electropositive. In
halogen group electropositive character increases down the group.
Q9
Be2 - 8 electrons
2 * 2
σ1s σ 1s σ2s σ 2s
2 * 2
, bond order is 0.
So it doesn't exist.
Q10
The atomic number of an element is equal to the number of protons present in a neutral atom. The
protons are positively charged and electrons are negatively charged. The total number of protons
is equal to the total number of electrons in a neutral atom.
Q11
4 LiH + AlCl3 → Li[AlH4 ] + 3 LiCl
Tetrahedral and Hydride ligand
Q12

Periodic
2
Li2 ⇒ σ1s σ 1s σ2s
∗ 2 2

Nb −Na
Bond order= 2

4−2
= = 1
2
∴ x = 1
Li
−
2
2 ∗
⇒ σ1s σ 1s σ2s σ 2s
2 2 ∗ 1

4−3
Bond order =
1
= = 0. 5
2 2
∴ y = 0. 5
∴ (x − y) = (1 − 0. 5) = 0. 5
Q13
Intramolecular hydrogen bonds are those bond which occur within one single molecule.
For the formation of hydrogen bond, molecules must have Oxygen (O), Nitrogen (N) and
Fluorine (F), Chlorine (Cl) atoms in functional group and Hydrogen (H) atom in molecules.
Chloral structure does not have hydrogen atom to form hydrogen bond with aldehyde oxygen
atom in structure.
Other three molecules has intramolecular hydrogen.

Periodic
Q14
Ne, Na
+
, Fe
−
are all isoelectronic species..
Electronic configuration of each species is given as
2 2 6
10
Ne : 1s , 2s 2p
+ 2 2 6
Na : 1s , 2s 2p
11
− 2 2 6
F : 1s , 2s 2p
9
All have shielding constant.
Also, Z ef f
= Z − σ
∴ Z eff
( Na
+
) = 11 − 4. 15 = 6. 85
and Z eff
(F
−
)= 9 − 4. 15 = 4. 85

Periodic
Q15
ΔHsol. = −97 − 85 = −182kcal/mol
−LE = + 186kcal/mol
ΔH (solution)= ΔHhydration + LE = 186 − 182 = 4 kcal / mol Enthalpy change is positive,
so, process is endothermic.
Q16
Greater is the positive charge on atom, large is effective nuclear charge. Hence smaller is the size.
Q17
Br2 . Each of the other molecules has a dipole in addition to Van der Waals forces. Only in Br are
2
the Van der Waals forces the only intermolecular forces. It is a heavy halogen having
many electrons in the valence shell, which makes Van der Waals forces stronger, slightly
increasing the boiling and the melting point. It is non-polar because of no electronegativity
difference and only a weak Van der Waals force is holding it together.
In a non-polar molecule, the Van der Waals force is the most important in determining the melting
point and the boiling point.
ICl → Polar Br2 → non polar
H2 S → Polar CO → Slight polar
Q18
The overall value of the dipole moment of a polar molecule depends on its geometry and shape i.e. vectorial
addition of dipole moment of the constituent bonds. Water has angular structure with bond angle 105o as it
has dipole moment. However BeF2 is a linear molecule since dipole moment summation of all the bonds
present in the molecule cancel each other.

Periodic
Q19
Lother Meyer gave periodic classification of elements based on atomic volume curve.
Q20
Lanthanoids are 58Ce −71 Lu (14 elements ).
Electronic configuration of 57 La
2
=[Xe]6s 5d
1
and it is a d-block element.
Q21
Generally, across a period, IE increases but Nitrogen due to the presence of half-filled p-subshell (stable
configuration) has higher IE as compared to its consecutive elements. Thus, the IE of Nitrogen is 14. 5.
Q22
When atomic orbitals combine to each other then new orbitals are formed those are equal to
atomic orbitals. All the hybrid orbitals have same energy and these hybrid orbital forms only σ
bond only while π bond is formed by atomic orbitals.
Q23
In water molecule, the H − O − H bond angle is 104.5° and the dipole moment is 1. 84 D.

Periodic
The bond angle of H 2O is lower than 109. 28° due to the presence of two lone pairs of electrons on the
oxygen atom.
Q24
The molecular orbital electronic configuration of O is 2
O2 = 16e
− 2 ∗ 2 2 ∗ 2 2 2 2 ∗
= (σ1s) , (σ 1s) (σ2s) , ( σ 2s) , (σ2pz ) , (π2px = π2py ) , (π 2px = π 2py )
1 ∗ 1

Molecules having unpaired electrons are paramagnetic. Thus in O 2 ⇒ π

∗ 1 ∗
2px & π 2py
1
are half filled ,
therefore O shows paramagnetism
2
Q25
The number of electrons in the valence shell of the atom indicates the group to which element
belongs. For examples, the alkali metal sodium which belongs to group 1 of the periodic table has
one electron in its outermost shell.


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Periodic

Classification & Chemical Bonding DPP #99PercentileChallenge

In a period, the ionisation energy

(1) increases from left to right.

(2) decreases from left to right.

(3) first increases then decreases.

(4) remains the same.

Types of bonds present in K 4 [Fe(CN)6 ] molecule are

(1) covalent and electrovalent bonds.

(2) covalent and coordinate covalent bonds.

(4) electrovalent bond and dative bonds.

Chloride ion and potassium ion are isoelectronic. Then:

(1) Their sizes are same.

(3) K ion is relatively bigger.

(4) Their sizes depend on other cation and anion.

enthalpy (in kJ mol −1

Elements ΔH1 ΔH2 ΔegH

MARKS - IIT JEE & NEET Prep App

Elements ΔH1 ΔH2 ΔegH

I 520 7300 -60

II 419 3051 -48

III 1681 3374 -328

IV 1008 1846 - 295

VI 738 1451 -40

Which of the above is likely to be the most reactive non-metal?

(1) Element (III)

(3) Element (I)

The valence bond theory is unable to explain the_____

(1) delocalization of electrons over the two nuclei of bonding atoms

Which one of the following is a correct set?

MARKS - IIT JEE & NEET Prep App

The electronegativities, χ for four elements are given in the table.

Which bond is the most polar?

(1) Fe > Sc > Rb > Br > Te > F > Ca

(3) Rb > Ca > Sc > Fe > Br > Te > F

Which of the following species does not exist?

MARKS - IIT JEE & NEET Prep App

Which of the following statements regarding modern periodic law is incorrect?

(1) Henry Moseley observed regularities in the characteristics X-ray spectra of elements

(1) Octahedral, chloride

(2) Tetrahedral, hydride

(4) Tetrahedral, Chloride and hydride

Which of the following molecule does not consist of intramolecular hydrogen bonding?

(2) Chloral hydrate

(4) Ortho chlorophenol

MARKS - IIT JEE & NEET Prep App

(1) 4. 85, 6. 85

(3) 6. 85, 4. 85

−85kcal/mole , respectively.Therefore, for NaCl(s)

(1) enthalpy of solution is exothermic and magnitude equal 4 kcal/mol.

(2) enthalpy of solution is exothermic and magnitude equal to 368kcal/mol.

(4) enthalpy of solution is endothermic and magnitude equal to 368kcal/mol.

Which one of the following ions will be the smallest in size?

MARKS - IIT JEE & NEET Prep App

H2O is dipolar, whereas BeF2 is not. It is because

(1) The electronegativity of F is greater than that of O

(3) H2O is linear and BeF2 is angular

(4) H2O is angular and BeF2 is linear

Periodic classification of elements based on atomic volume curve was given by

(2) Lother Mayer

Choose the incorrect statement among the following:

(1) All the actinoid elements are radioactive.

(4) The first member of the lanthanoid series is lanthanum.

MARKS - IIT JEE & NEET Prep App

Chemistry - Periodic Classification & Chemical Bonding DPP Challenge - MARKS App

Chemistry - Periodic Classification & Chemical Bonding DPP Challenge - MARKS App