,

p-Block Elements (Halogen & Noble Gases),,__ _ _ _ _ _ _ _ _ _ __ _ __ _ __

=====~P~A~R~T~-~.~, O;:N;::L
=Y:::::O_
N_E_O_P_T_IO--N-:.-::
C::.:O;;R-;;R~
ErcTTTTYYPPEE- ---...___
---~~~~~~~~~-=-=-~---~ ==

Section (A) : Elements : Occurance and laolatlon

A-1 . Which of the following gaseous molecules Is mOl'loatomlc 7
(D) nitrogen
(A) chlor1ne (BJ helium (Cl o,cygen

A-2. W hich one or the following noble gases Is not round In etmosphero 7 l17JC 12003')
(O)Ar
(A)Rn (B)Kr (CJ Ne
The inert gas abundantly found In atmosphere Is :
(O) Xe
(A)Ar (8) Kr (C) He

Electrolysis of aqueous solution or Brina (NaCl) will give: (17 JC120o4oi

(D) all of these
(A)CI, (B)H2 (C)NaOH
A-4. The catalyst used In the Deacon's process for the manulacLure of chlorine Is :
(A)Cu (B)Analloyofcopper (C)CuCI, (D)CuS

Section (B) : Based on Periodic Trends

B-1. Which one of the following configuration represents a noble gas?
(A) 1s' 2s2 p•. 3s1 (8 ) 1s1 2s' p•, 3s' (C) 1s' 2s1 p• (D) 152 2s' p•. Js>p• . 4s'

B-2. Aslaline Is the element b'9low iodine In the group VIIA of the periodic table. Which of the following statem"1tl
Is not true for astatine? (17JC120041)
(A) It ls less electronegative than iodine.
(8) It wil exhlbil only-1 oxidation state.
(C) lntennolecular forces between the astatine molecules wUI be larger than lhat between iodine molecules.
(D) None of these.

~ Which is wrong statement ?

. ~Basic nature of x· is in oroer F· > Cl·> Br> 1· )
-,, ( 8)'£fectron F
gain enthalpy in order > Cl> Br> I.
(C) The ionic character of M-X bond decreases in the order M-F > M- C I > M-Br > M-1
(O)Among F·, Cr, Br and 1·, F· has the highest enthalpy of hydralion.

Section (C) : Based on Chemical Bonding

C-1._ Whi~ of the following structure is correct for BrF,?

F F
l _,F F I
C>Br,
(8)
OF (C)
0~
"-Br<) (0) none or these

c.a. Among the following molecules, (I) XeO, (ii) XeOF. (iii) XeFG (17JC1200'2I
those having same number of lone pairs on Xe are :
(A) (I) and (li}~ly (8) (I) and (ill) only (C) (ii) and (lii) only (D) (I). (ii) and (iii)

c.-3. Select the Incorrect match.

(Al XeF, : Linear (8 ) XeF, : square planar
(C) XeF• : distorted octahedral (D) Xeo, : Trigonal planar

C-6. Which of the following hydrogen halide is most 110latile. [17JC12004ll

(A) HCI (B) HF (C) HI (O) HBr
Wnldl al the following haS maximum bond strength :
(A>HI (B)HCI (C)HF (D)HBf

..., -~ , , . . d·•Diiritiih\Hi;Mi:i❖JdWi◄3P#f:IHi:flf.
 p-~B~lo~c~lc~E~le~m~e='.:n~ts~('!_ff.~ai!:_ & Noble Gases )
l0~g~en~:.:.:,::.:----
r - - - ---
0

27. (II)

(Xe OF,)
Sq uar e pyram idal

I It Is 1>eeause sulphUt ro,ms sing

le
(b) ( l 0- 0 bond beC 8Ul 8 there~ s whereas o11ygen fom1s
Is more repulsion betw
sll"Onger !hen double bond
size tha n sulpllUr. een electrons ~
bee•,..
(ll) It is ICI 15 more pclar and ~s less eff_ . 01
(iii) II is due lo higher standa
~ bon d due repulsion among
ectiv e overtapp,ng tha n
rd reducliOn ~ol enhal of Fz whi 1
ch is due lo ~w
ox ~ ' '-•
i \~ ~:
10 small s,ze F atoms, high etectro
n . boll
~ - gain enlha1..d dis, ,
28. (s) (i) Due to small size of nuorine
'"Y
ir. cl ,~1
atom, there are strong interelectro
orbitals of 11uo,tne and lhuS, the nic repufslo Ii
Incoming electron does not exp
(H) unlike NH PH moleCUles are erie nce m h ns '" the r~
not associated through hyd rog
boili
Ilg p0l·nt ~ PH
JI
·slo we r tha n NH
,.
en bondiuc . attrilt1ion. • 11,
ng 111 liquid s1a1e 1\....
• " "!~I

(b) (i) F F,'"'"-.·O/ F

(iii) 1/i◊e'\.
F ... • :\F
.:
F

OR
(a) (i) A mix tur e of helium and
oxygen does not cau se pain due
compared to nitrogen. to very low solubihly of heUwnntic
(i) The fluorine atom has no d-o
rbital8 In its valence shell and the
mo st electronegative, it exh ref( )(e cannot expand its odlt. a.
ibits only-1 oxidation state.
(iii) The single 0- 0 bond Is weake
r than the single S-S bond becaus
non-bonding electrons, owing to e of high intereleciroocr~
the small bond length. As a res
oxygen. ult the catenation tendencyls ..

... 1-a o ·o
(b) (i) Q . -1~ ~ (ii)
II
~
O OH O- OH O
II
~ o
F
I. (I) P. + H20 ➔ No reaction

(iij
r ~
e,ef"ents ( Hatoger, cl N.ob/ea

r
0 _ _ _ _ _ __ _ _ __ . :_ _
. ~~),

~ ,. ~r 9)
I
(ll)A
... - / p ('"
~
1•l (I)
OJ I' 9Jt
-- J> ,..... <?)
I/\
0) C?.I

cyciotnmetaphosphorlc acid
(Ill (I) 3HgCl 2 + 2PH, - - . (:PO,),
1
~
ii) so a + H aso,-Hso Ga + 8HCI
.
(
tilil.sxaF. + , 2H,o __: ;x•' + 2Xeo,
. ♦ 2◄HF ♦ 301 7

_... ............_......,................... ...................

~l 11 fluu,
1s_~~...- t~

" " ' - ol 5d -

h~her
k)l'l

(ii) II iS t)eCaU&e Xe is noble gas ~nd

• . , . ~ , , . -"'"" -
-
lattice energy of oxides aa campsed to ftuondel as Oltide ton la i,i,,egat!Ye -'* •
IS mononegative

.,,.., ... -
-
·' ..............- .

(1) (i) p• + 10S02Cl2 ➔ 4PCI +1080

(ii) XeF• + 3H,O ➔ XeOa 6HF a !
.
--~-r -0.
.. -~Xe
..
•
(Iii) - • ;-~
(ii)
(b) F
F xeF,
(linear)
CIF,
T-shiped

OR
(a) (I) 6Na OH + 3Cl 2 ➔
NaCIO, + 5NaCI + 3~0
(Hot and cono,)
2
(ii) XeF4 +0 F2 ➔ XeF, +01 0

(b) (I) /l,

HO' H H
(11)
r-: t /elfle" ts (Halo gen & Noble G ases) ~ - -- - - - - -

(il
3CI, + 6Na0 H - SNaC I + NeC to, + 3H ,O
-- - - - - - -- - - - -

,.1-4, P 0 > ,,_. • 3 HPO

, •+Pl- \
ii' (i ) ptF • • xe -+ Xe"(P tF ;I
~ of F _,.
,,, 10 small slz.e the electr on..1ec1ron ....,ull lone In the ,w4a4lvelY ()(lfflp ecll ~,~~ ~
~?8,a dvely large and henc. the Incom ing •lactro n la nol tern . . . . . te lhe c.ese
ec:cep ted with the ume •, ,n.uc,,, of F ( g ) frotf'
~ If"" ,.,ai;-, e1yblg oef 3p aubeh e1 of Cl ■lam . c _ _ , .nUy.
-
l ;s little lnS than lhat of the forma Uon of Cl·(g) !Tom Cl(g) r•••••••
•-u , dunnG 0#
f"~~g ) + e· - F · (g ) ; A.. • - 333 kJ mot-• and Cl (g ) + _. _ . Ct(g) kJ mol '
; A.. • - 3,4g
-n,us, ,-egati ve eluctU n oaln en1ha lpy of Fla 1 - , lhen IMI of Cl .

FK .. --
~1
,~~IC--,--.- -""' u i- F
Sq...,..,._, F
Bon l-T-

The oleCtr<>d• poten tlal of F, and Cl, a.-e :

F, • 2o· - 2F· ; E" • + 2.87 V and Cl + 2r -
Since E' fOf F / F· al• cboda la hig'- r than lhat of 2Ct- ; e- " 1 •36 V ed than
ci)er
c 1,. 1n Olher words , F, Isa •tronQ eroxid lsinga genl lhan
oleetr ode, u--ef ore. F • Is more .asilY rec~ bt.rt
C•
ci_. For exam ple, F,oxi dllles Cr Ions 10 2
does no\ oxide F· Ions to F • .,
1
F1 + 2Ct - - • 2F· + Cl ; C l, + 2F-- ~ 2Cr + F,
1
Except radon which Is radioa ctive, Xe haa tho lowea t Ioniza
tion entha lpy amon g noble gase s and henc e can
be easily oxldlz ed by strong oxidis lng agen, s like
0 1 and F •· Thal ls why major ity of noble gas comp
aro tho6e of xenon . ound s

1l firstly. He does not conta in d-ort>i\als in the valenc e shell

and hence eledr ons cann ot be prom o-..d to highe
energy levels like lhat In Xe to focm bonds . There fore, r
1-ium does not form ci-t\i cal comp ound s. Seoo nd\y,
lonlzal lon entha lpy of He Is suffic iently highe r than those
of F 2 and 0 2 •
,1. In lhe forma lion ct XeF molec ule. Xa undel g0es sp> o-hyb
2 ridiza lion. Two of the five sp> d-orb itals over1 ap
with one p-ort>ital o f each of the two F-atom s to form two
X.-F bond s while tne remain ing three conta in lone
pair of electr ons. To reduc e bood1 )alr --lone pair repuls
ions X-F bond s, 00CUPY axial positi ons while the thr-
lone pan occup y equat orial posillo ns (for S11Udure,
refer to Fig. 7 .34, page 71101 ) . Aa a result . XeF mole
has linear but not bani a!Nct ure. 2 cule
II,
The reaso na - ;
(i) F being a mailer canno t eccom moda le larger sized
other halog en atom s arour> d It.
(li)Ou eto the absen ceol d-orbltala, F does not show
positive 01<1dalionata!es of +3, +5 or +7 need ed for
formation of polya tomic lnlefh alogen compow>ds . the

"· (a)

~) 6NaO H- + 3CI.,., - - + SNeC l + NaCIO , + 3H O

2
...... CIDl'C.I
( i) X
eF "''' + 3H,o ,~ ➔ XeO, + 6HF

le
L,; r9 '
 p-~B~loc~k~E.~'J1~m~1~n~t5~('!;_lli~'al~o~gt & iVoblt· G,ue.f) ~ -- -- - -
1~n~.: ;:: ..: :.: ..- -~
(b) _, , ,..i
(I) The nepllYe eleeu"' •.,.. n enlf181pios are lar ge IOf ele m
i eecause of this, lhe eIec1
oxygen II quli. sma . te<:lro ron ec1roen11 01 llt«>up
n Is not accopled as ea1-e1 lly In o._" repu111ooa 111
Hence , the tooom~y~or ,ur
pt,ur In . ~ \
tllclrca, QelRen ,,_ ...r t Is ... 11 higher 11111n thol of OXY'Qt1
n
_ to )'Qen •• ll 1
1 in ?t1 ~ ..'..."-,
nstat,/llly ot ,.v ., uu v the we ak NC I·- ~ Th . 11111>11
..
(I) Th e . 11()111S, on the olher ha "'" ""· 111 Is d v, -,... Ir '\
nitrogen and;:r or :,dlng nd . ato ms of both n ue lo lhe 1 ~ , ..._,
in NF, 1s qui te strong an d It 0 11 ',"
11 1111 9 ._ ~' oen (7s ~
; ~ ; ~ involYIS 8
spldhyt,ridltatlon of the ce 0 ow i., , \
ntral atoo,~~~le to o, ~' le l , ~~"',
I\
3$
Jp
Ell ldl onl c stn1cture of Cl
(ground slalo) [ID [JfltlfJ
Bll dro nlc st,vclUre of Cl
(ex cite d state) [ID
[j~~.' 1] ~
sp d h}'bridlsahon

20.
---
Thul , CF , halle lrigonal blp
T....._• .....,

Tiwr ale bo.liG configurallon

~ element known.Fthe
Is 1s
yramidal geometries with

of 1
two posili

2s1 2p,2 2p/ 2p 1• It has on

1
ons OCCUPied

e unpa1ree1 ele
by 2 lo ne ~
·~
more elecb.:oegative than Its refore , the possibi Hy of s.haring its unpa ire d~· ~
elf does not arise and henc f ,._
does not have d-otbitafs in Its e ii cannot show an Oltloat
ect
sh ow higher positive oxida
oxJda1ion states.
valence shell. TherefOf'e, it ca
tion states of +3, +5 and
nnot expand its valence
+7. Thus, In nutshell, F can
ron

OQI~~~
witi- ~
01 •l "'"-::'ate
21 . (I) XeF, haa two bonded ~~
pa irs an d three lone pairs
110 minimize repwsion . There of electrones, which are pla
fore XeF is linear without ced at eq uil or ia\ ~
(ii) II is beca11ee F ha s 2 a bent.
2 higher standard redt.lction po '1
h)<dratln energy of F· Ion. ten tial due to lower bond dissociallonensg
y111 ~
22 . Structure of XeF :
2
F

••

F
(a) (I) HCI Is stronger acid
tha n HF. The acid str• ength
(i) Element of this group for of hydrogen halide is HF < HCI < H13<< HI.
m both ionic and covalent co r,e1t,11,'
covalent character decreases mpounds in +3 oxldalioO a1a 1
in lhe order : is. n
Due to inert pair effect N > P > As > Sb > Bl.
(b) (I) P, +.10 S0 Cl ➔
2 2 4PCl5 + 10 S0
1
Phosphorus penlachlotide
(ii) 2)(eF + H 0 ➔ 2Xe
2 2 + 4H F + 0
(I ) 1, + 10 HNO, ➔ 2HI0 + 2
1 10
(oonc.)
 & Noble Gose!)/""_ _ _ _ _ _ _ _ __ __ __ ~
p-B/ocJ. F/i-men/5 (f/o/ogtll PART• 111 ----
, ''"' inremalOQfln (X - X'J19 weaker lhan x-x
and bond
This 15 i:,acause the DOnd ,ri pp,ng 1,ei-en or blI.Ills ol dlu imllar alum■ lhan ~ ~ ~
x· x·
1. I
IS due 10 ,.., eflecilve 0 ~ ene,vyol F- F bond, FI II men f'MC!lwi than .. Inlet!'
H0WfYIII'. (k,e lO IOWoond
""""'~"
.alo\,er ,~~•,
• __ d--Ofbllal■ and hence can •how an o•klatlon ., le .--.._
Cl 1189 .,_..1 Id ti .,, ol •3 but
2. Rea.;on5 are (I) cat'"°' thOW positive ox • on IIIIH. Further, ■Inca F a.n •how , i._
d-ort>1talS. 111en1rore. II only CIF and nol FCI, . on1y . , 0( ~
srare. 111eretore ,1can:c, oanaccommodata lhrN sm.u F atom, around ii wtllle F being
(•Jaecause of i,,gge, • • sized cr atom• around H ""--c....
accommodale rhraa bigg8' -..,
ol Xe hi.,. paired eleclrons. The promotion or one, two Of lhraa '-cit
3. (I) All 1t1e tiled o,t,ltals d vacant (l(bltals will give rise lo two, four and 1h1 hall-filled o,blr:
Sp-filled ort,itals IOtt,a 5 • t,ol 1101 odd number of F atom,. Hence, ii cannot form X.F .,.; ~
°"' ' °""-,
~
Xe can tnn1>iM ~ - - : ' ,adk)eC!iYe, Xe 1\81 least lonlucion enthalpy among ,_..
gases •·
(•J Excepl radon ~compounds particularly with O, and F,. enc,~.
readily torms cl'Mlm .....
cok)Ured matenll by ollidalioo : Cl, + H,O - 2HCI + [OJ
Cl, blUCheS Cok)Ured matenal + (OJ _ _ . CAllour1ess

and llenOe blead1ing is pennanenL

other hand. SO bleache• coloured material by reduction and hence bleaching ia lempora,y
~ thett1e bleached col~rless material is exposed lo air, 11 gets oxld!zed end the colour 1s rearored lir'Ce
en so, +2 H,O --+ 2 H,SO, + 2{HJ ·
AarW
Coloured ma1erial • [HJ --+ Colourless material oaldallOn Coloured material.

5. Smee PrF, OXJdlSeS o, loo,·. Bartlett ttioughl that PtF, should also oxldlle Xe loXa· becauaelha IOnllallor,

6. (i) Ca(OCI), + 4 HCl --+ CaCl1 + 2 H,O + 2C~

(Ii) 2 NaCIO, (aq ) • so, (g) __. 2 CIO, (g) + Na,so,
Chlorine dioxide
7. Noble gases are chemicallyinett because oflhe following reasons.
(i) Ttiey have completely fllled ns> np' 1,lecb 01ilc conr19urallon1 in their valence &hellI.
(u) They have high Ionization enthalpfas .
(di) Elecuon gain enthalpies of noble gases art positive.

8. Due to smaller' size, the lone pairs of eledr 001 of the F-atoms repel Iha bond pair ol lhe F-F
bond. In
contrast, because ot comparallvefy larger size of Cl atoms, the lone pairs on the Cl atoms do not repel lht
bond pairot Cl-Cl bond.As a result, F-F bond energy is lower than lhal of Cl-Cl bond energy.
9. Banum chloride. Bae~ and barium chlorate, Ba(CIOJ, are formed as follows :
6 Ba(OH), (oonc.) + 6 c~ Ho! 5 B.C~ + Ba(CIO,)J + 6 H,O
.
10. (I) The outerelectronlccoofigurallonof group 13 elementt 11 nslnp'.On mOWIQdown the group,duelOIM1
pair effect. there Is a dl!Cf81te In the tendency of s electrons of the valence shell to parUcipale In bond
formation. This is due to the paorshieldlng of the nr electrons of the valence shell bylhe inil,wningd
°'
I electrons. So, only the p eltdrons can partlclpete In bonding. Hence, lhe oxldallon Ital&I t ~
to + 1 only. .

(if) Fluorine is more electronegative than chlorine. rti.efora, HF undergoes stronge( H-bonding
thin HCt
Hence, HF is much less volatJlt than HCI.
(Iii) Halogens are very eledtonegaUve, so they act as strong oxidising agents. In ini.halog
en oo,njlOlllCK ,
X - X' bond ls very weak and can be easily broken. As a result, interhalogen compounds allO ICI 11
strong oxidising agents.

• I . '. ..., , • >t t- ','I: l J ' : •-' -

I,~
1~ '
1

6
"·-
7.
-
12.
-
32
2
2 9
P~ T - 11
3.
- a 4 4\
---
5. 1
,,.. 17.
0
9 e 10 !>
6 - 4 13,
14
14 3 11 13
22.
""JI,; 3
- 6
11,

ll.
10
IQ r, 20 2
27.
8 - 15 2
2.4 :1 JS 7
~ 28
- 81
29. ~ 30 15
(ABC) 2.
(BC)
PART· Ill
(BCD) 7. 3
(AC) (AB)
4 lABCO) 5._ (ABC O)
• (ABCD) 12.
8.
(A.BO )
fl, - (ACO) 9.
- (BC) 10.
- (H5)
13._ (A.CO)
(ABC) 17. (BO) 14.- (AB) 15. ~
~ 18. (CO)
- )
(AB) 22.- (ABO) 19.
- (AC) 20._ (ABC D )
~·, 23._
~
(BC) 27. (ABCD)
(A.BCD) ~-- (BC) 25.
- (ABOD)
28._ (BCD)
JI.,
(AB) 32.
- (BCD)
33. (BCD)
29.
- (ABO ) 30. (AC)

34. (ABC O)

PART - IV
,. (0) 2. (D)
3. (C) 4.- 5.
- (A)
~- (C) 7.
- (A)
8.
- (B) 9.-
(C)

(DJ 10._ (C)

EXERCISE - 3
PART -l
2Kl(aq.) + c~---. 2KCl(aq.) + 12
In the reac tion Cl2 oxid ises iodide ion (-1 oxida
tion stale) lo 1-i(0 oXl<ialion state). C~ ~as higher
potential than 12 and thus oxidises iodide to iodine oxidation
getting itself reduced to chloride Ion. Simllar1y,
21- (aq.) --+ 12 (s) + 2e· .
Cl, (g) + 2e --. 2Ct- (aq).

21 (aq) + Cl (g) -1 (s) + 2c1- (aq).

2 2

2. (A) 3. (C) 4. (C) s. (/\) &. (C)

l. (A) 8. (A- p, s) : (8 - p, q, r, I): (C-p, q) . (D;>) 9. (A)

ti. (A) 11. (C)

PAR T-II
1. (1) 2. (4) 3. (1) 4. (2) s. (3)
l (1) 7. (2) 8. (4) 9. (4) 10. (2)

11 (4) 12. (4) 13. (2)

 (ii) Ca(OH)2 + c,2 - - + Ca(OL;IJVI • 1
· ~...,

PART-II
A-1. (B) A-2. (A) A-3. (A) A-'. (D) A-5. (C)
B-1. (C) S-2. (B) B-3._ (B) C-1._ (C) C-2. (0)
C.J. (D) (A) C-6. (C) c~. (A) C-7. (A)
D-1._ (A) (D) D-3. (C) D-4._ (C) 0-5. (B)
E-1. (D, E-2. (C) E-3. (B) E-4. (A) E-6. (B)
e,~. (A) F-1. (D) F-2. (B) F-3. (B) F-4. (A) 2Kll
F-6 (B) F~. (D) F-7._ (C) F,..a. (A) F,-9. (C) 1,
In ti
F,-10. (A) G-1._ (B) G-2. (8) G-3._ (A) G-4. lA) pot
G-6._ (D) H-1._ (D) H-2. (B) H-3._ (A) H-4. (C)
PART-Ill
1. (A- p , q) ; (B - p, r) ; (C - q , s) ; ([) - p, q, r, s)
2. (A - q, s) ; (B - s) ; (C - p) ; (D - r)
3. (A- p, q, r, s) ; (8 - p, q, r, s, t); (C - p, q, r, s) ; (D - q, s, t) i

EXERCISE - 2 1.

PART-I ,o.
1._ (D) 2. (A) 3. (B) ..._ (0) 5. (A)
8. (D) 7._ (A) ·a. (C) 9._ (A) 10. {A)
t
11. (8) 12._ (A) 13. (0) 14._ (D) 15. (C)
16. (8) 17._ (8) 18._ (0) 19. (0) 20. (C) 6.
21. (0) 22._ (A) 23._ (D) 24. (B) 25. (B)
28._ (C) 27. (8) 28. (C) 29._ (C) 30. (A)

31._ (C)

:s:a.t.iil.hiSJ.«IIJii!!l.♦.il.S:J~PJIIU.,-95.lfoSJll.i.4.il.S:t,iW!f.i:t■ •
'l ) Hc10
:10
o , ) Hc, ,o
•) 11c 0 1 > Hc,o, > HCI()
~en c o roa olJ wllh NHJ ?
(C) N t,
c, (D) NH4CI
Nt) J

c it with KOH
7
(C;~it,o, fl e (DJ KCIO
IOi •
. d C,o- 1n,,..
)H1o1 lro
IJ n, ,, produa,1 Cl In -~,.
, H· ns
"· in d F - Jo ,,
. prop0(tlon reac,io
or dis
," ''• la '>'Pe
8
98 electrons

C/OJ - CIOl- ♦ '

(8) CI02 O ♦
H" - 0
+ Na 0 - - - + NaCI02 + 2
(D) CI02 1 1
i1
cid and OX}'aC
hydra
M/xted satt of (P) at are ~
lements. Then wh

'
1 alpy among all e
th
(0)+5
(C)+3
:
,!are possible (D)BIF5
(C)FC~
en s:
Ing intematog

KOducts.
st u n ,.

(DJ NC-
(C) (oqNh
rope,t-.
that have halogen lilce p
, Of more al
om
m.

ol 7
d(s) with quin
ra te compou (D)Neon
(C)Kryploo (1~-
? nduc;tivily.
has very high thermal co
(8) It w viscosity.
e ry lo
(D) JI h e s v
gases.
Jarding noble

1ses fr
om He to Xe
 '/{Plogat cf Noble Gas

,r
•, ,ti ow lhe variaUon
of
'~ gies of noble ga M •
(,r ,I 1o11111t1on ener

{I)

~ N•
Af Kr Xe
.....,;,,,n• •
\:
H1
~ ~ Kr ,ce Rn
1t111trU8.,,,.....- · lnt
~ 1~ th e vavariariatiotionnofor the fi r s t~
boifm g PO
,,., Gi-" 11 shOWS lhe
: ~ :. I st,own ll'le
variation of the
Is comllaria
Int~::::
on
while graph II sh ow n

ficult lo rlfflO
th

Ye e·
e variation of bOlllnQ

from he
.
lium in
II helium m «e dif
pCI easier ID bO lo Xlnon while it "
pl ~ risOO 10 xenon.
~ 11',8 jnc0ff8CI or de
r. oiling point ).
an ce in air) (I ) H e< Ne < Ar < Kr < Xe - (b
- (abund F bor¥i leng1h).
(AJ Ht >Al > Kr > N e> Xe ). !tl )XeFe < XeF• <X eF r( X e-
- (melting point
(CJ Xeft >X ef , >XeFz
~ the folloWing
reactions

. x,• F2 ~ A
2:1
x ,+ F 2 - B
I : 20
x ,+ F 2 - C
1 : 5
ents : •
s,11e1 inc008Ct statem m oi .:.
JA.Ban d C al l are noo-p0Car an d pl an nw
(A
of electrons
(8) s has no lone pair B
nd length IIA> C >
(Cl The order ol Xe-F bo
as lewis ba se.
(O) A. Band Care act
e correct statements ?
Which of lhe following ar al.
IA) He can be absorb
ed by coconut charco
compound.
(Bl XeO, Is are eJCploslve ka i to fo rm pe rx nt e (XeO,~) and 0 2 llnall
y.
reacts with aqueous
al
(C)x.o, 10 M nO,-in acid medium becaul
e
will oxidise M n2 "
(0) Ptrxenate solution
E• R P( x. ot ) =2 .1 V.
E'Mn04 /Mnl•=1.51 V,

oduc t (s) of X efI it ll tt :

Thwmal decomposition p, (C)XeF•
(B)XeF2
IA)Xe
lments(s) Is /are true
b ' XeF,?
Wt-=n ol lhe folc>wil,g stat
f e l XeOF4•
IA)b P11111f ~ g i ' ,
give& XeOF4
18)lta f98dion wi1t1 silica f2
(C) ll • Pf1l)lted by th e
reedion of x .f• end O
, "'"'IS ( ,v ~ c ,. u t "OD~ G
pe n u
ethod G.re,J
ing m
n/(;'1 of the follow ."c,be
do <l's p ro c e sa : Mooi+• c ◄ H "'-a
'- -- . ~
"" w e1
(AJ
's p roc e s s : ◄ f- fC 1 +O
(8 } Reacan
a, : ~~
._,
(C) NitrOSyf chlo
ride P"Oee
c1Crn01tt,,, ~
W l'l 's process : 2Na
~
101 po
e follow in g W I l10t dltpi
Wt,ieh of·t h
r Uletfit11' "'111..11:
,.,s, 2
added to N a l (B J B
~lddecf lo
'-<:i
I'
,odine reacts wffl'I
h )1 )0 to g,-,.. :
( B ) ~)
I· (A) Na l
➔ A.., B
C'2 + NH3'excess} -Is a lt o obtained
duct
(A} one o t lh e p
ro bydaq,
,.,
r In one o f the Pf'Oduct la 3
(8) eond o rd e
(C} Both prodUct
co nlaina chlonne.
Instead o f~ . one
orPrOd
(OJ It e,2 1s u s e d
I
~~
ll o w in g
/fl wti/Ch Of th e fo I
er - ➔ ~
~ (A} F1 ♦ Hof wat
aOH - - . ~
(CJ c i: + Hot end cone. N
ction 2 8 r ♦ Xa ~ e,2 +2X- X21
In the rea '
(B) F2
ta.. (A} C li
in g state mentera correct
In which fo llo w llid ltQrd
rou s h yd ro g en ffuroide 11 • lq
Ii_ (/}Anhyd
o e s n o t form a
ny~
ead ace ta te d d~
(II} L m ix tureofMnO,an
te d w it h a
(lll}H F Is h e a
~vedgases. agent bl
Is not oxidised strong oxlciN)g
(IV) HF (B) II, Ill • IV
(A) I, II
g dried by e
t s m e lli n g g a s X a ft e r bekl I
11_ A pung e n
. T h e g a 8 's o g/',te . _lWliltA
acidic solution e for X ?
hi ch o f th e fo llo w in g are tru
W
(A)X is HCI ·
(S )X is C!z !M e am o n g lhe h )l d ri d ll "
a t Y O la
(C} X is th e mo ate rc an libefalB CO, Atm
l
n o f X in w
(0 ) SokJlio
A(gas at room i.tf¥'.) ♦ B(
HCI + 0 2 cue; •
11_ C
az S aO , - ➔ C + HO
A(gas) + N ment ,..,-clinQ
A. 8 end
u t co rre ct st a te
rind o ll~
ln g d n g o f gas A In c;ampo
n stata « aulplU
(A )8 'u c :h

- ..-
a ge oxi d a tio
(B)AIIW
n act•• liQ&
CC) Uqwct scaecgo in dlaPru,)Ollk»•ti
#d. --.,wlf!Hr
(D) Gas 'A 'u lld
.
" ~ /n ! 1 u s -
 - - - - - - - -- - - ~
P-lllock El«ments (~al ogen & Noble Gases)
22..- How many of the followlngproperttes of not,11 g,se. Wo lJd
___,.,,.In let:
t
lncreaae from Hallum to Radon 1
; •ai1a r force t, Atomic votumo, ~
Bolll 01
in ng P0int. First loniaation enfhllpy, ~ s .,
•lmoePhent, Density el STP. vaienc:e · tftlcal lemper11ure.
QIS Ion,, '+
23._ In Which
how many comp ound are cok>Url.., OF ·
X•F2 • XeF ,, XeF, , xe0•. XeO,F, ,xeO,Fr' "'' ◄
a..,_ How man y of the fallowing hes spltt1 h)t )rl~·
XeF2. XeF, . XeF, . XeOi . XeO,F1 ,xeOF, 'x,o.'
XeO,F7 . 1x,o,,....
g foffowing ts:
-- The number ol compoundsJelemenlS o,cldtted by XeF2 amon
HF, ,HBr. HCI. HI, NHi, Crf 1, Pt. S.
21
·-
:n._ ::_ 11
The Oxldation state of xenon in perxenate loll +n. Give
Xo • OF, ---.
lhe value of ·n·.

1
B+C +Xe
ounds A, 8 and C is.
'The 5'.ffirnation of total no. of lone pairs and a bonds in comp
follow ing table regarding the compounds ol xeno
n
28._ Cons ider the
Fonnu1a Oxidation No.. of bond No. ofonlone Hybridisation
Xe
state of Xe oairs on Xe pair&
XeF2 x, y, z, spm•cl"•
X.F• X2 Y2 z, ap""rf'a
XeF8 X3 YJ z, s pm, cl"•
z• spm.cf,
Xe02F2
.X.OF•
•• Y◄
Zs ap""d"•
X5 Ys
5

Find the value of L(x, + Y1+Z; + m1 +n1) .

,_,
21._ How man y ol the given oompounde can produe1 Xe03
XeF,, XeF ,' Xe02F2 ' H,xe 0•. XeOF,
d palra in XeO, and Xe04 are :
30._ The total number of lone pairs of Xe, a-bood pairs and ff-bon
CORRECT TYPE
PART - Ill : ON E OR MO RE THAN ONE OPTIONS
1. Bec trol ~ of aqueous aolutlon of Brine (NaCl) ghles :
(C)NaOH (O)N one
(A) ~ (B)H2
on treatment with cone . H1SO4 ?
2. Whic h of the following salts wiill evolve ~log en
(C)NaBr (D)n oneo flhase
(A)N aO (8 ) KI
[1SJC1205lfl
3. Which starementa are corre ct abou t halog en ?
(A) They are all diatomic and fOffll univalent iooa
ctive periods
(B) Halogen have the smaHest atomic radii In there respe
(C) The y.,. all diatomic and fOffll diato mic ions
(0) They are aM reducing agents
Which al the following reactions are comtel ?
CA) N110, +&N a+ 6Hz5()4 ~ 6NaHS04 3H 20 +
12
(8) 2tC8r + MnO, + 3HzS() --+ 2KHS04 + MnSO, + 2~0 + Br2 i
4

CC) ",P P,+ 14HO _.. . 2 KO+ 2QQ, + 1ffi0 + 3C'2

ma 2K.•2 ~. +..w, --+ 4KSbF, • ~ F,
 pe,,1erl1S I 11uw ~ttn di: Nobl e G -
•..,c,ngs lhe following how men r•Q.re.,)
,.... 11
(
,-) ,.._2SIO, ♦ HF - - .,,llction, acUon
c;CI ♦ HF - '-clo• re
(Cl • (8 ) c eSI0 1 ♦ HF - •

<=)SiF.+HF -
('- (0) 510 1 ► HF - .

l'fOW many comp ound s Will liber: (Fl c■F 1 • H,S04 - ,

•
1
~02, KMnO ., Pb02, Pb.a4 O•~ Cia(Q) t
N9C1o ~ ~ld■tlon of hydrochl01l c acid
1,,, ' a, (DRN211Je}
HOW many of the fotlowing rea ' ''!Ct 0
~ (a) cH. + C'2 -+ ction , ~Ille! I ,
♦ Cl2 ♦ H 20 ---♦
(C) I ' HCI II on• of th• PfOdu cla?
(b) FeSO, t- H,5O 4 + Ct - ,
~ Q + so2 + Cl '
(d) a ♦ H O - .
(e) 2 a--.
rot~· 2 2
Elecl (f} SO, + Cl 1 - ,
(9) NaCl(aq) ___;;;=.::::z.=~
(i) Cl2 + NaOH(oonc.)-- . (h) Cl 2O 1 + H 2O--+

HOW many reactions are correct In fot

(1) Cl20, + HF - + HCIO, + c 1olowl"9
(2) c~o + HCI --+ Cl2 ♦ H2O
~.,
(3) HCI + F2 --+ HF ♦ Cl2
2F

(5).AQNO, + HI - + Agl + HNO (4) CuSO , + HI --+ Cu212 + 2HaSQ, + 12

en ~o . + HI - - . K 2so. + H(6l HI + 0 2 --+ H2o + 12

l""t cts 'th 2S03 ♦ la (8) HgClz + HI - - Hglz + HCI
When "'2 rea WI HgO at 300oc th
fl., . . ' en haw rnany Cl-0 bonds are presenl in product?
IS- Ari oxyacid of chlorine Which fonns most weak conjugate base upon disprop011ionation.
' 5ame oxyacid on tree Ung with stro d Stable anion or a very
fo'.ms a comp aund *P'. The numb er of oxygen to
c;hlorine bonds in compound p Is. (:v:.hyor.ang age_nt
The number of mixed anhydride among the bond& including sigma and Pl bonds)
fl_ f0lowi g are
Cl2O : CI02 : C'2Os ; Cl2O 7 ; N 2O 5 ; NO2 ; NaO n

'~- Br2 + F2 (excess) --- . A i,,ira:pta • 8 + C

The summation of atomicities of compound A, 8 and C Is :
Ion in ls resemblance to Cr. Br, i- : {16JC120580l
tl_ Nt.mberof ~ which are true forCN- l)&8UdOhalide
(I) It forms an acid HCN
(i) tt can be olCidlsed to (CN) i molecule.
•
(tii) It forms Insoluble salts with Ag•, Pb2+ and Hg/•
lexes a.9. {Cu(CN)JZ-, {CO(CN).?"
(iv) ltforms large number of complexes similar lo halide comp
(v) AgCN Is insoluble in water but soluble In ammonia Uke AgCI.
(vi) HCN Is oxidised llk.e HCI.

17._ How many ion in following behave like psaud2 ohallde

CN-, SCN- , 11-, o-2, N3-, CNO- , ¾03- , ezo.-2
1l_ Among the following number of pseuohallde lonS is :
; SeCN- : TeCN-; N3-; SCSN3-
J-. IC'2-: 1c1.-; IBrCt" ; ,. ; CN- ; NC-; OCN': 0NC- ; SCN-; Ncs-
It._ ln followings, how many acid anionS behave Nke Pseudohalide? , • HCI, HBr, HI, HCIO4 ' H8rO 3' HI03.
HCN , HNCS, HNCO, HCNO, HN, • ~co, ' H2SO, . H2SO3,
H3PO

H,PO,, HCI02• HCIO

CIFJ is :
The number of lone pairs of electrons present in central atom of 3 2
atom hybridization sp d
Which of the foflowing interhalogenS exist at room temp erature and have central
(b)CIF (c)BrCl3 (d)IF3
(a) CIF (h)IC I,

{I).:
(e)IF l (f)B tf 5 (g)IF,
(i)Bff: (k)CIBr5
& &
,,,,- v, ts (Halog.en & Nobl e
Gases)
-
pP" pa■sed ho ug h ■odlurr, d .._ .. .
In
rdl oll lde ga ■ la
of lh • folk>Wing PfOdu
ct Is fom i
8d '
~~ i,cldic so lut ion ?(B ) CIO2 '4.itpt,"
f sr;i;c,o. (Cl N• 1s O,
10 1so, r1l0fl
1.A) wilt! CIO -rorm. ca n be ob lalne d by di ■9( ..- ,0,
follow,ng ■talemants wt,
0 0 m ~ )( ~ Q a 5 Y. X wh ich
~ Z by so diu l
m hYtJroicfd e (hot 8 at lc l~ g the
ic:t1 are
11011 pe> Und 1ld ~ a te d ). Th en om oo
f., de ¢"
low er ox ida tio n Sia
y> p,18C)Jtid8tiOn sta te Of le ~ 11pen of Z Is • 3.
(.A: X ls stable lha n Z
(Ill y' iS 12 .
~) zIs ai.able al ro om tempera1ure am on g
p an d
With ho t nd a. St ab le an ion
on tre ati ng
. _.. ..in hy po t\a lite 1· • ..._ llfld COnc,
Na OH for ms an ion s Pa
tai ne d by neu 1ra
.AOS'_... ob IZJt\g " " COnJugale es llm atl on of a tolUC
ga s
f, 0 c;a,i be a eo n, ~ ~ -is for me d, wnlch is us ed In lng statem en la
=~re of the fol low
iJpO'l t, ea ti~ O = h for ~ i n thl JI' djo xy go n. Th en wh ich
a .. u, 7
~ I\IIV8 S
,,_ tfU 8.
(.Al Xis HI .
(Bl y Is Cl 10 s al no. of bonds 5
Cl Fin al pr od uc t Y. ha s tot in lire ex bn gulsh er.
th tox ic ga s PfOduces a ~ IW\ich Is us ed
lo) yo n rea ctl ng wi
d:
ne d by the interaCllon of chlorine an Ca(OH).,
Bleaching ~ Is ob tai ......,.,.,_,trated solution of
(A)dil&M solution c:J Ca (O H) i (B l._ .,. ~ ..
II id (D I dr y sla ke d lim e
calcl
(C) dry um ox e W hic h on treating
id x a gre en ish ye llo w ga s Y is for me d.
8 so lut ion of ml ne ra18C: ge s into
Wt-,ell F 2 is pa ss ed int o us Is in co nta ct wi th z, it ch an
kep;
i. ~t h sla ke d lim e for ms
W ·z: .
he n Re d litm
(Bl No ch an ge in co lou r
(A) Blue ~ r (D) No ne of these
(C) W hite rn oo lou r
is :
nie 1soe1ect1onic pa ir (C) lf2• , 1,-
(B ) lC12-, C' °2
(Al ~O. 1~ -
rid e Is incorrect.
Whlch &t ate me ot re ga rd ing Iod ine lric hlo
I
II.. (A) It for ms dim8' n ga se ou s state . bo nd s.
dge bo nd s are longe r than the ter mi na l
(BJ In dimer 12Cl1 , the bri
as pla na r mo lec ule.
(C) Ill solid state, it ex ist s acid an d hYtJrochloric
ac id.
es a mi xtu re of iodou
(0) On hy dro lys is, it giv
no ble ga se s in water Is
ll_ The or de r of so lub ilit y c:J {B ) He > Ne >A t> Kr
> Xe
Ne > Xe
(A) He > Ar > Kr > (D l Xe > Kr > Ar > Ne
> He
Xe > Ar > Kr > He > Ne
(C)
jM of lhe noble ga se s.
ll Consider fol low l,,g pr op en lDuliess.
mp ou nd s wh ich are co
I: They re ad ily for m co s.
II : They gene,aUy do
not form ionic compound
in compounds.
oxidation ata18s its
111 : Xenon has variable ounds.
do not form cla thnll8 comp
IV : lhe smaller He and Ne
Select COi i ec t i>ropertles. (B) 11 , 111, IV
(C) I, Ill, IV (O)AII
(A) I, 11.111
s us ed is :
s o1 the pro du cli on of draniUm. the ine n ga
In K/'0IM an d I.C J pr oc es (C )K r
(O )X e
{B )A r
(A )N e (1 6J C1 2u 5l1 J
helium are. (0 ) Metallic
l. Tlla be .a of Cl0hNiun in liquid (B) Ionic (C ) Van da rw aal's
~ Co:sh t
-.. . mol8 d Xe 03 an d two mole of Xe F1 is :
• Tlla ~ al . . ,. . b : bi t 11 n (C)X eO ,f2 {O)X.e04
(B)x .o f•
~X ao ;,
. - -•41HWihtikifi;@Mi3=11:9
Hl;tMfW
l0trt, Ilion
of •enon nuonaes Ttue la '

lil1,
"· lg
~:I
llo
qu1111on.
:it)(, ~ found 1h11 • CIYllllline lolid (O
1~
81m011 idtnllcel to lhlt of o'
the nret com po un d~
1,
.JilPIF, ~
11~
," S ~~
~""' IOI.
(C) Ionisation en.g y (D) ~
~a..' I

1 are :
(C)Xeo3 & Xe (D )~ . & Xe

(C) IXeFJ• [PfzF,,J- (D) IXti♦ [F\FJ-

-
~BLE VALUE INTEGER TY PE '
st orbit of halogens ? ---......

tN of Astatatine {.At) are :

•increases with Increase in atomic number.
:>rnicity (c) Melallic nature
1iling point& (f}Atomic radii
1ns1ty (I) inolaation enalhalpies
1activity (I) Solubility In waf8f
:idising nattl'e.
,)"Sis of brine. The gas P when treated wiUl excess«lfl
- y) where x & y are the molar mass of Panda.
(11JC 1~

Jtabilily)

KJred precipitate la tonned :

, (B) Pb(NOJ, + HCI ---+
(D)AIJNO, + HBr __ .
(F)AfiNO, + HI-- -+
(H) HgCI, +HI __.
 p-Block. Elements ( Halogen & Noble Gases)
5 1 r.4rt02?
. w(Ah) ':' Of the following la not oxldleed b)/ (C) B
F (B)CI" r (0) ,-
IS. Which of lhe ~ ~?
(A} F foltowlng ii weak•t (C) B
2 (B) Cla r2 (0)1,
7....
Fz + dil NaOH --+ A+ NaF + HP
F2•conc. Ne0H--. B+NaF•HaO
A and B reapecth,ely ere :
(A) OF2 end 0, (B) o2 and OF2 (C) Both 0 2 (0) Both OF2
,. When thloautphate Ion Is oxidised bY 1od•"'1 !tie new J>rOduct formed Is :
(A) s0,2-- (B) so.-r (C) s.0,2- (0) S20.2-
NH3(exceaa} + ~ --+ NH.Cl ♦ A(gaa}
··- NH, ♦ Clz(excess} - B ♦ HCI
Incorrect •tatement regarding Aand B. .
(A} A is highly reacliwi gaa II room tamperd"·
(B) eond order of gas 'A' 11 almllar to Ca-r, ·
(C) Compound 'B' is exploeive. '
(0) Bond angle of compound B ii hlgh« lhlfl bond angle of NF3 •

10. Which amongst the follOwing ructiOnS cannot be used'°'

the respective preparation ?
(A} 2KBr + H2S04 (cone.} - - ~S04 + 2H8r (B} NaCl + H2S04 (cone.} - NaHSO, + HCI
(C) NaHS04 + NaCl - NazSO• + HCI (0) CaF2 + HzS04 --♦ CaS04 + 2HF
11. In the prepa,ation of HSr 01 HI , NaX (X c er, I) la treated with H3P04 and not by concentrated HaSO.-.
(Al H:r504 makes the ruction revensible '
(8) HzSO• OXkfises HX to X:i (Br2 , 12}
(C} ~ . Is water soluble and Na3P04 is weter insoluble
(D} Na,P04 is water Insoluble and ~ 4 11 water soluble

12._ M-1,..,, , 1 •on (KJ/mol) are given for the h)'drtdll of halogens In the following graph.

~·- \ A

~s

The hydride HF w11 conespond lo

(A) P (B)Q (C)R (O)S
13. HBr and HI can reduce Ha504, HCI can reduce KMn04 and HF can reduce :
(A) KzCr2°' (B) KMn04 • (C) HaSQ. (D) none
Alkali mecal h,dlug.Nt tluoridN have a tonn._ M(HF~. They are found to contaii a linear symmetrielllllOI
having an overall F-H-F diatance of 2.26 AWhich may be compared with Iha H-F bond lenglh of 0.9'2Ail
the moment. Which rl the following ls false tor the anion ?
(A) Hydrogen bonding plays • significant role in the existence of the anion
(lt)Aw•-hiandlenU!h(l+-F) ii 1.13Ain._ ,nion HFf
(C) n. al I 41hU of . . H-# band In ....... 11 G.21 A
(DJH la•llbondadlDIIIOF da ••---MOTbondalnlheanion.
11. Thlrwt1at1, 3CK)-(aq.)--. c10a-t.q.)+2Ct(aq.) t15JC121111~
......... ot:
CAJ, rM II uwlon (B) Wdlan ,_. Ian (C) dilPf0p0rtlonal (D) decomp05lliOII ,_._.,
 P-B/ocJc E la ,, Noh/~ G as et )
F t!l rt. r ( H al og en & oa- lhrou(Bg)h ;
-3. H) 'd ro ge n
(A ) Qutc:I( ,::,,nlde is dr ie d by pa aslnQ til e •n h) 'd ro us ca lci um ch
CO) eo n. H1sO .
lo nd e
(C ) e pe11e1
P0 la $s ,u m h) 'd ro •ld prec,
F, ._ PIiate wfth Ag NO , ?
W h· acld do es no t ronn ltflY
(A ): one of th e hVdf (B ) HC I
(C ) 1-fBr (O )H I

W hi ch •lc hl ng ? (C)l-fNQ (O )S IF ,
(A) HI Oca n do glass )H F •
• (B
F- 6. llo wt ng reltciiOn,
Id en tif y A anc, 8 tn fo
A + B + H, O
H~SO. + HB r - -
,.5 (C ) Br O , • so , (D ) Br1 • SO ,
) Br
(A ) a, , · so .
(B
gla .
F- 7. _ ob ta in ed wh en go ld 15 treated With aq ua re
W hi ch ol th e folowtng (B )A uC I,
is (C )(A uC IJ - (D )(A uc r.r
'- - (A )A uQ ,
most v<>1a1,1e.
,drogen ha lid e is
F' -e. Which of th e fOllowing hy ) HF (C) Hf (O )HBr
I (B
(A ) HC e" 9l ti :
W hi ch of th e tolowin
g ha s m ax im um bond str (C ) HF (O ) HB r
F,-e. (B ) HCI
(A ) HI
ng is tn e st ro ng es t ac
id?
F, -10.. W hi ch of th e fo llo wi (C ) 1-i,.S (D)P H ,
(8) HF
(A ) H Br
:
es an d ox yh al id es
S ec ti u n (G ) : H al id on ce nt ra l atom ln Xe F2 , Xe F, an
d Xe F. ar e:
of lo ne pa irs (D ) 1, 3. 2
G- 1. _ The nu m be r (8) 3, 2, 1
(C ) 2, 2, 1
(A ) 1,2 ,3
e wh ich is ~ e o
on
,:
G--2. or th e foftowing sp ec ie s, (B )XeF,
(C )XeF. (D )X eF ,
(A )X eF • {1 7J C1 ~
hy dr ol ys ls gi ve s : (D)XeO,
G -3 ._ Xe F2 on co m pl et e (C )X e01F 1
(B )X e02
(A )X e
ec tiW ly :
d Ca CN2 giv es re sp
G -4 . Hy dr ol ys is of X eF , an
(B) Xe O, and Ca(OH),
(A) X eO , an d Ca CO, (D )X eO F, an d eaco,
(O H' 2 {1 7J C1 al l
(C )X eO F, an d Ga ne m ed iu m :
e un de f'g oe s hy dr oly sis in 5l ro ng alk ali
Xe no n he xa lu or id
G- 6._ +C
8 ~ 0 • 12 F' +A +B
2X eF .+ 16 0W -
then , eaction pr od uc t
m ay be: (O)A lloflh e above
(C)Xenon
(8 ) 0 2 lidll &
(A ) pe rx eo at e io n
ge ns , B le ac hi ng powder, P N ud o ha
te r ha lo
er co m po un ds (In
S ec ti o. 1 (H ) : O th
P o ly h al id es ): A8 /A B f0tm which is
co m po un ds of
co rre ct :
log en
In th e lrUe< ha k, ge rl (B ) 8 ls lar ge siz e ha
5
H- 1
(A )A is la rg e m a ha
k9 -n
·- (0 ) Bo fh (A ) & (C ) (J Ef 1. 7, fJ
h8 'o ge n
(C ) 8 Is amall size
ha lid e ? (O )N NN -
owing is no t a ps eu do
H..2. W hi ch on e of th e foM (C )O CN - {1TJC121J051l
(B ) RC OO -
(A )C N O - e P5 8U do ha lo ge n ~ ~
nd:
{D ) ,,-
. ·· ., __ .._ .,, .w,s lik
r b/e -
pd le. nJ S( Ha logen d: No
~ ~ - - - - - - 1 1 -
.~ -
--- the reactions liltped~Ill Col •, lttl~CH 1f~Hii=e:ic~onLU
~~ N- - - - -~
i ru
ii~M !..
um,...
coiumn • I <t, ~p roe :1uct(1) ll1 lod
In COiumn-ii
~ (~) ~ • FJ --- -+ (p ~ • II (X • Halogen
)
(S) NH, (excess.) + Cl2
--
..) -- + (q) ~
(C) NH ,+ Br, (e xc es (r)~
(0) NH, (aq .) + ~ -
, In COi (I ) ~ Iv e
t.4e lcll th e reaction1s lfalec um,..., With
Column - Ce ..~ pro<fu ct(1) llll ■d In COiumn-ii
.
J. r 1 o +H,o ➔ ,_:-"'Ill N
(A) ..,.,• c.) ➔ {p) tio " .
(8) NaCIO.(s) + HCl(c on (q) ~
(C ) KCK>,+ (C OO H) ,
➔
(r) C\o '
(D) Hg ()+ C1z 573K
(l ))iC!o
ted In co l n.1..,;..,. • . (s)/ type of reacllon(s) listed In column-II.
. 1c
"4atcll th• co mp au nd 1 fis um c"'"' ct, rac ter lst
-f 11
i colUffll1
" lJnoer-ff
!J>) goes hydrolysis with water.
""x .eF 2 ent.
(S) Xe f, (q )~ 85 oKidislng ag
rgo es ion rea ction.
(C)x. eF (r) lJncse ad dit
drons.
XI I)• (1) I-las lo08 pair(s ) of ele
with H,O or OH-
(D) ' "'-5 diSproportionatlon reac1ion
(t) G

l{EXarclse-2 f ~ 2
ONE
:..:OPTIO N C O R R EC T TY
..:.::...!~~ ~=-==-=:-_ PE
_:_-.:...:~=--- - -
_.-- - - - -- :- - P -
A R
-T
-en-erg-y=1.s minimwn n .
• I : O N LY

0
/ w~
X - X bond dis
The so
. ~~
ciation
~~
~ n F , with :
F2 11 fonned by reacting (C) KS bF,
(D) MnF5
1 (B) Mn Fl
(A) SbF5
:
solution When lreatadwllh
1
Iodine Is ll>erated fro m Kl (C Ni SO•
l
(D )Fe~ •
(8 ) Cu 504
(A) Zn S01
orrect 7
Which d the following gr ap h Is inc

4.0
13 Density
2.5 -a
2.0
Atomic rad ii
(B) lc!; 2.0
(A) 1.5
1.0
r
0.5 F
F Cl Br

:-"' 1800
I...
~ 1600
4.0 (0 ) i 1400
a.o ~ 1200
cc,z.o 1000
1.0
 ~ -- ts_(-;_H.,;::..,al;:o&~e:"-=cf::.;M:.::ob~/~:_ cG Clt
~ of the followltig la the ltrn...._~e.r)
'f (N~er (B)HF-'VWlt9cid?
(11 ~1... ..
1"' ,tr0ngest acid amon9,t the (C) Hr8
(D) PH,
(8) H c 1 ~ 11 :
,'· (f,J t'fCIO,
,riOl1 (0) : Propertlea of •'•"'hal-'toveao: (C) HC10, (D) HCIO

,. ~ order of boiling P01nt

of
(B) C~ > F > Ila
f' (A) f, < C~ <B r1< ~ J 8', :a. ,
la (C) FI> c~ > Br1 > I (D) c~< Fl < BrI < t I
wt',/dt of the following Statement
I
'
ha& abn orm al be ha vio ur ~ ?
~~
;, (Al t-te(ium
(S) Iodine Is readlly 10/uble In cs nd the lali olL. ·
Helium do not form any dat h.! .'
(C) M '"'8 -""'1111 Is purple In colour
(O) of these

r ~ ga s is dried over:
(B) NeOH
7' -
(A) Ce 0
F, reacts witl'I H2 0 as follows :
(C) conc, H,S O,

; Fa +H zo - . H· +F- +o
which of the following halogens ~ aame "IIC:llon bUt In opp osit e dn ctio n 1
(A) Br, (B) c~
(C) ~ v (D) Alt
,.. Chlorine acts as • ble ach !ng llge nl Only in
(B) moiature ✓Pl9ltnc. of : u~ t
,.
'/ (A) dry air (C )a (O) ptn OX )'ge n

~ (E) : Oxides, Hydroxide

a & Oxyaclda .
ent : •
~t seleCt the Incorrect statem
(A) Per chl ori c acid Is a strong
er acid ltwi aulPhlllc acid
ed by fluarine
(B) Only one oxyacid [HOF} is form
(C) The most atati,e ox y-a dd of
chlorine la pecd,blc of
(0) Nona of the u
it e1,o. reacts wllh water and alkafl to giw : (B) Only sod ium pe,chlo,ale
(A) Only sodium chlorate
(C) Solh sodium chlocallt and aod
lum pen::tllcnla (D)None oflh ase
[17JC120045l
~ On heating KOO, we gel : (C) l<C J+ 0 1 (0) KCI + 0 2 + 0 1
(A) KCI02 + 0 2 (B) KCI + 0 2
ton:lar.
en arranged In order cl de a n'"g add ltl• igl h. ldenllfy the con-ec:
M. Thi folowll ig acids have be (JE E1 -1 )
CIOH (I), BrO H (D), IOH (ID) (C) m> O> I {D) l >m >n
(A)J>ll>m (B )D >I> m
7
[1 JC12004IJ
!{ CIO>- Ion leads with ~ to
form : (0) ICI and OJ
(B) 10,- and Cl, (C) ICI and 02
(A) cio.- .
the ~ in : (C) HCIO (D) HOO
~( The llr'ollg&St acid am on gst HOO, 2
(A)HCIO, (B)

~Wli,,ida:oftt,..mWca.:l ldt aIll ~hi .l ug #' ~- - ,_."(C)""

HBr
••t conJUQata ban e 1
(O)HI
· (B)HCI ;(JEE 1111, 1) (17JC120047}
(A)HF .., . teflam Nl&f. blc llM It
J~

~ ..
fC'c C J Is at I HBr
·
ec.--.t._bl-ldlrt ~so. cauuot be uaed10 F- SF (B> 0::1:11 n ,- ,
(D)llaClallowtywlhNISr

·HkiiiSIF d ·E E