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GENERAL CHEMISTRY 1 having a likeness in both physical

and chemical properties


LESSON 7: PERIODIC TABLE: HISTORY
- Left a room for undiscovered
Periodic Table – systematic arrangement elements
of all the elements showing periodic - Made 8 major family
similarities and difference in their - Used the valence electron to
properties organize and keep the families in
the pattern
History:
- Flaws: not all elements are
Johann Dobereiner discovered that time that made
- Attempts to arrange the elements Meyer’s periodic table incomplete
based on similar properties and Dmitri Mendeleev
grouped them together in triads
- Father of periodic table
(group of 3) – LAW OF TRIADS
- Similar to Meyer’s
- Increasing order of atomic masses
- Published first in 1869
- Atomic mass of 2nd element is
- Took 63 elements and arranged it
(almost) equal to 1st and 3rd
by atomic mass and grouped by
element; making it halfway
physical and chemical properties
- Flaws: could be grouped into a set
- Left rooms for new elements and
of more than 3
predict some such as eke-silicon and
o Incorrect measurement
eka-boron (similar to Al and He)
John Newlands - Flaws: Noble gas were not found
- 8 elements per group due to being undiscovered
- Solved one of the discrepancies of
Johann Dobereiner (set larger than
3) GENERAL CHEMISTRY 1
- Elements that been known at the LESSON 8: PERIODIC TABLE:
time were put into relative atomic GENERAL FEATURES
mass
- Elements were similar to other  Group Number / Family
elements every 8th place - Vertical columns which
- Flaws: elements in the same row represent the similarities on
with different chemical properties their valence electrons and
as well as having two elements in
need for chemical bonding –
the same boxes.
there are 8 families (A; main
Lothar Meyer group and B; sub – group)
- He organized 28 elements into 6 - Indicated the number of
different families with the elements valence electron
reactivity
Group Name (A) Info
- Valence electron = 1
Alkali Metal (1A) - Electron
configuration: n s1 B; sub -group: Transition Metals
- Low ionization
energy and
electronegative
- Metallic; dense and lustrous, good
- Largest atomic size conductor of heat and electricity
and highly reactive
- Largest atomic
number, largest Inner Transition
atomic size and
level of reactivity Lanthanide Acetamide Series
- Valence electron = 2
Alkali-Earth Metal - Electron Series
(2A) configuration: n s2 - Rate-earth - Elements
-
- Less metallic
Soluble in water
- Metals after V are
- Reactive - Period 6 artificially
- Valence electron = 3
Boron Group (3A) - Electron
- 4f sublevel produced
configuration: - All
n s2 n p 1 radioactive
- All are metals
except Boron - 5f sublevel
- Metalloid - Period 7
- Valence electron = 4
Carbon Group (4A) - Electron
configuration:
2
ns np
2
 Period / Series – horizontal row of
- Metallic progression
- Has allotropes elements representing the number
elements of principal energy level in the
- “phictogens”
Nitrogen Group - Valence electron = 5 atoms of each elements
(5A) - Electron
configuration:
2 3
Classification:
ns np
- Metallic progression
-Has dangerous
Metals
allotropes
- Nitrogen-diatomic Properties:
molecule
Chalcogens (6A) - “Oxygen Group” Conductivity – ability to transfer
- Valence electron = 6
- electron configuration: heat and electricity
2 4
ns np
- allotropes of oxygen Luster – the mirror-like shine that
-one forming elements
- Valence electron = 7
reflects light well
Halogens (7A) - Electro
configuration: Malleability – ability to be
2 5
ns np hammered
- Some are diatomic
molecule
- Non-metals Ductility – ability to be drawn into
Noble Gas (8A) - Inner gases wire
- Valence electron=8
- Electron
configuration: Non – metals -opposite of Metals
2 6
ns np
- Except He(2) Metalliods / Semi – Metals
- Extremely stable
- Monoatomic gas  Blocks
- Colourless
- Little to no
S Block – electric configuration ends with s
sublevel (Group 1A and 2A including He)
GENERAL CHEMISTRY 1
P Block - electric configuration ends with p
LESSON 9: COVALENT COMPOUND
sublevel (Group 3A to 8A except He)
D Block - electric configuration ends with - Compounds whose atoms are
d sublevel (Group of Transition Metals) held together by covalent
bonds
F Block - electric configuration ends with f
sublevel (Lanthanide and Actinide Series) *composed of non-metals that
 Trends share electron aims to have
electronic configuration
Atomic Size
Period: increasing, Atomic Size: Octet Rule
increasing - Formulated by Gilbert Newton
Group: increasing, Atomic Size: Lewis
decreasing - States that atoms react in order
Metallic Property to acquire a fill set of 8 valence
electrons similar to the
Period: increasing, Metallic
Property: increasing electron configuration of the
noble gas
Group: increasing, Metallic
o Expanded Octet –
Property: decreasing
numbers of valence
Ionization Energy – energy required to
electron larger than 8
remove electron (cation)
after bonding (*only
Period: increasing, IE: decreasing visible in period 3 and
Group: increasing, IE: increasing below)
Electron Affinity – energy change that Structural Formula – a graphic
occurs when an atom gains electron representation of the molecular
(anion)
chamber and used to represent the
Period: increasing, EA: decreasing bonds
Group: increasing, EA: increasing Lewis Dot Structure –
Electronegativity – ability of an atom to represents the number of valence
attract an electron electron by means of dots
Period: increasing, EN: decreasing surrounding the symbol of the
elements.
Group: increasing, EN: increasing
*element sym. + dots + line bonds
*dots = valence electron = group # o Gives the composition of the
*single bond=1 pair (line), double bonds=2, triple bonds=3 molecule, in terms of the
STEPS IN DRAWING THE LEWIS DOT actual number of atom
STRUCTURE: present
 Empirical Formula – gives the
1. Identify the number of valence composition of the molecule, in
electrons and write the Lewis Structure of terms of the smallest ratio of the
the elements number of atom present.
2. Add the valence electrons of the  Structural Formula – use of line and
elements dots

3. Determine the central atom using the Writing Chemical Formula of Covalent
covalency (highest) or the Compound:
electronegativity (lowest) - Prefix used in the name of each
*central atom – atoms in between the element in a covalent compound
structural formula except Hydrogen indicates the number of atoms for
that elements and is shown in its
4. Put a pair of electrons on between
subscript
atom to form chemical bond
Step 1: Identify elements involved in the
5. Complete the octet (or check) on the
compound and their subscript
outside
Step 2: Identify the Greek prefixes in the
compound and its equivalent number
GENERAL CHEMISTRY 1 Step 3: Put together the elements’ symbol
LESSON 10: CHEMICAL FORMULA OF and the subscript coming from the Greek
COVALENT COMPOUND prefixes

Chemical Formula – tells the number of *if subscript is 1, no need to indicate


atoms of each element in a compound =invisible subscript

Ex: H 2 O - water Greek Prefixes

Subscript – number written tot eh 1 Mono


below and the right of the chemical 2 Di
symbol that indicates the number of 3 Tri
atoms are in the molecule 4 Tetra
5 Penta
KINDS OF CHEMICAL FORMULA 6 Hexa
 Chemical Formula (molecular 7 Hepta
formula) – numbers of atom are 8 Octa
indicated or the subscript can give 9 Nona
10 deca
accurate results
charge is written in
parentheses after the English
NAMING A COVALENT COMPOUND:
name of the metal
Step 1: identify the name of the element
For Non-Metals (anions)
nd
Step 2: Modifying the name of the 2
Monoatomic Anion
element using the suffix – ide.
 Name of the element is modified by
Step 3: Greek prefixes are used to indicate
suffix – ide
the number
Polyatomic Anion
Ex: oxygen = oxide
*need to be mindful about the number of
oxygen atom
GENERAL CHEMISTRY 1
 Suffix – ate (more oxygen atom) or –
LESSON 11: MONOATOMIC AND ite (less oxygen atom)
POLYATOMIC IONS  Prefix hypo – (fewest oxygen atom)
and per – (most oxygen atom)
Atoms – molecules made up of 2 or more
elements Polyatomic Ions – oxygen atom is
sometimes substituted with sulfur atom.
Molecule – 2 or more atoms combine
Prefix thio –
together or from a chemical bonding
Ions – atoms that losses or gains electron
When an atom and a molecule acquires a GENERAL CHEMISTRY 1
net charge, it became an ION. LESSON 12: WRITING AND NAMING
 Cations (+) – atom that losses BINARY AND TERIARY IONIC COMPOUND
electron (Metals) Ionic Compound – compounding 2 or
 Anions (-) – atom that gains more ions
electron (Non-Metals)
- Combination of cations (+) and
Naming Monoatomic and Polyatomic anion(-) or combining metal and
Cation and Anions non-metals
For Metals (monoatomic cations) - Aims to get neutral atoms which has
0 net charge – the sum of positive
 Use the name of the and negative charges must be equal
elements + term “ion” to zero
 Classic Method – latin name + - Use of Criss-Cross Method to set
suffix – ic (if it has highest net the net charge of 2 elements into 0
large) or – ous (if has lower
net charge Binary Compound – composed of
 Stock Method – place a monoatomic cation and monoatomic
roman numeral indication the anion
Ternary Compound – composed of Step 2: Using the chemical symbol of the
monoatomic cation and polyatomic anion element and the polyatomic ion, write
their ionic form
Step 3: Create electrically neutral
Naming Binary Compound
compound
- List first the cations (metals)
Naming Compounds of Metals with more
followed by the anion (non-metal)
than one Oxidation Number
Step 1: write the name of the cation
Step 1A: (Classic Method)
(metal)
 Name the metal with higher
Step 2: write the name of the anion (non-
oxidation – suffix – ic
metal) after the cation. Modified it using
 Name the metal with lower
the suffix – ide.
oxidation – suffix – ous
Step 3: Put together
Step 2A:
Writing Chemical Formula for Binary
 Name the non-metal with suffix –
Compound
ide
- Cation first then anion  Name the polyatomic anion with
Step 1: Write the chemical symbol of the suffix – ate or – ite
element involved Step 1B: (Stock Method)
Step 2: write the ionic form: cation and  Name the metal, followed by its
the anion that includes their net charge or oxidation number written in Roman
oxidation number numeral and enclosed in
Step 3: Create an electrically neutral parentheses
compound = 0 Step 2B:
Naming Ternary Ionic Compound  Name the non-metal which ends
- Cation first then polyatomic anion with – ide or by the name of the
polyatomic ion.
Step 1: Write the name of the cation
(metals)
Step 2: Write the name of the anion (non- GENERAL CHEMISTRY 1
metals) after the cation with the suffix – LESSON 13: WRITING AND NAMING
ate and – ite BINARY ACIDS AND OXYACIDS
Writing Chemical Formula for Ternary Binary Acids – composed of 2 elements
Compounds wherein the first elements are always
Step 1: Write the Chemical Symbol of the hydrogen while the second element is a
element and the polyatomic ion involved. nonmetal
Oxyacid – acids consisting of hydrogen,
oxygen and another central elements. In
other words, oxyacid are combinations of
hydrogen and a polyatomic ion
*Hydrogen – fixed element or atom

Writing Chemical Formula of Binary Acids


and Oxyacids
Step 1: Write the chemical symbol of given
compound
Step 2: Write the net charge of the given
compound
Step 3: Do the Criss-Cross Method
*for oxyacid, if the name ends with suffix
– ous then its ends with – ite with the net
charge will be _O3… if ends with the suffix
– ic then it ends with ide with the net
charge will be _O4
Naming Binary Acids and Oxyacids
Binary Acids – use the prefix hydro – and
and the suffix – ic attached to the name of
the acid-forming elements followed by te
word acid. Hydro + (non-metal)ic + acid
Oxyacids – drop the word hydro then the
– ite ending of the polyatomic ion is
changed to – ous and the – ate ending to –
ic finally add the word acid
*polyatomic anion – ite = - ous + acid
*polyatomic anion – ate = - ic + acid

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