The document discusses the history of theories and discoveries related to the nature and composition of matter from ancient Greek philosophers to modern atomic theory. Early thinkers such as Thales, Leucippus, Democritus, and Empedocles proposed that all matter is composed of fundamental elements like earth, air, water, and fire. Aristotle rejected the idea of fundamental particles. Dalton proposed atoms as the fundamental units of matter. Later scientists such as Lavoisier, Proust, Gay-Lussac, and Avogadro established laws of chemistry. Rutherford, Bohr, Schrodinger, and others contributed models of atomic structure and discovered subatomic particles like electrons, protons, and neutrons that make up atoms.
The document discusses the history of theories and discoveries related to the nature and composition of matter from ancient Greek philosophers to modern atomic theory. Early thinkers such as Thales, Leucippus, Democritus, and Empedocles proposed that all matter is composed of fundamental elements like earth, air, water, and fire. Aristotle rejected the idea of fundamental particles. Dalton proposed atoms as the fundamental units of matter. Later scientists such as Lavoisier, Proust, Gay-Lussac, and Avogadro established laws of chemistry. Rutherford, Bohr, Schrodinger, and others contributed models of atomic structure and discovered subatomic particles like electrons, protons, and neutrons that make up atoms.
The document discusses the history of theories and discoveries related to the nature and composition of matter from ancient Greek philosophers to modern atomic theory. Early thinkers such as Thales, Leucippus, Democritus, and Empedocles proposed that all matter is composed of fundamental elements like earth, air, water, and fire. Aristotle rejected the idea of fundamental particles. Dalton proposed atoms as the fundamental units of matter. Later scientists such as Lavoisier, Proust, Gay-Lussac, and Avogadro established laws of chemistry. Rutherford, Bohr, Schrodinger, and others contributed models of atomic structure and discovered subatomic particles like electrons, protons, and neutrons that make up atoms.
There must ultimately be tiny particles of water that could not be subdivided Democritus 470 – 370 B.C. - expanded Leucippus’ idea - world made up of empty space and tiny particles “atomos” “indivisible” - All forms of matter were divisible into invisible particles called “atoms”
Empedocles (440 B.C.)
All matter was composed of four elements: Earth, air, water and fire Aristotle (384 - 322 B.C.) Endorsed and advanced the Empedoclean theory. Believed that matter was continuous and was not made up of smaller particles “hyle” Heat, cold, moisture and dryness ex: fire = hot and dry water = cold and moist air = hot and moist earth = cold and dry JOHN DALTON
He offered logical hypothesis about the
existence of atoms by studying certain experimental observations made by other scientists concerning chemical reactions •Antoine Laurent Lavoisier When a chemical change occurred in a closed system, the mass of the products after a chemical change equals the mass of the reactants before the change. In all tests, the mass remained constant.
LAW OF CONSERVATION OF MASS OR MATTER
“In ordinary chemical reactions, matter is neither created nor destroyed.” Joseph Proust LAW OF DEFINITE PROPORTIONS “Specific substances always contain elements in the same ratio by mass” LAW OF MULTIPLE PROPORTIONS The ratio of masses of one element that combine with a constant mass of another element can be expressed in the ratio of small whole numbers
Amadeo Avogadro (1811)
AVOGADRO’S LAW OF MOLAR VOLUMES Joseph Louis Gay-Lussac (1778-1823) LAW OF COMBINING VOLUMES DALTON’S ATOMIC THEORY MODERN MODIFICATIONS OF DALTON’S ATOMIC THEORY 1. All matter is composed of extremely small particles called 1. Discovery of the sub-atomic atoms. particles of atoms. 2. Atoms of a given element are alike in size, mass and other properties; 2. Discovery of radio-isotopes. atoms of different elements differ 3. Nuclear reactions. in size, mass and other properties. 4. Unmodified. 3. Atoms cannot be subdivided, 5. Unmodified for simple created, or destroyed. 4. Chemical compounds are formed chemical reactions. when atoms of different elements combine in simple, whole number ratios. 5. In chemical reactions, atoms are combined, separated or rearranged. An atom is the smallest particle of an element that can exist either alone or in combination with other atoms.
“Plum Pudding” Model
“Raisin Bread” Model Sir J.J. Thompson Composed of a positively charged cloud with the electrons distributed / suspended Ernest Rutherford – British physicist Miniature Solar System with electrons moving around like planets around the nucleus
Neils Bohr – Danish physicist
Postulated further that electrons
could only move in certain orbits and has certain energies Erwin Schrodinger – Austrian physicist
Electrons are described not by the paths
they take but by the regions of space where they are most likely to be found Negative electrical charge (-1) Mass 9.110 x 10-24 g ; Mass in amu = 5.486 x 10 -4 amu Discovered by Sir Joseph John Thompson in 1897
Positive electrical charge (+1)
Mass 1.673 x 10-24 g ; Mass in amu = 1.0073 amu Discovered by Eugene Goldstein (German physicist) in 1886 Bears no electrical charge; neutral no Mass 1.675 x 10-24 g ; Mass in amu = 1.0087 amu Existence was first predicted by Rutherford; First evidence of the particle was obtained by Walter Bothe in 1930 and was finally discovered by James Chadwick