Ch.

26
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1
non-rigdrotorinitialstate.finalstate.hn
ergyleveb
"

I-Io.lltx.IS/0E
E-42.exlx4.mx 4ns
2
-2
八

ǘj Ě
T tint -_-
E
11 ⼼ )
⼀
⼆点 _ i
t.xli-fB-J.lJtD-D.int/itransFliOndipole
-1

āntrīfugaldīsturationconstant

spectrumi Jsjtl
3
LĀ 1 到 古 > wn ĚITĒU)
了
2⽉ (列 -45 (列
( 电 荷 位置) dīpdeoperator
4
⼆

iǎqixǜ ✗

increasejspacingdecreasesabsorptionintensityn.hr
úbratīonalspectrum

ECRX
5
harmonicappoximationinitialstatepopulation-kerrf.tk
Bdtzmann factor

Deizfe prob
!
Deidīssocīationenergy

Poispectroscopīc dīssocīationenergy
Do-De.tt wo

i-thstatecpopulationfifo~e-BE0.jxe-Eiz.EE#selection
EF Eet Eivt Eirt Es
rulei
6
é
Z-filnttu_nnufn-ll-e-gxe.tn
úbratinal ⼆

出 ⽣活
"
Emuyw 4。 出
7
。
⼆ ⼀

Ǜ fn ÈǗE
xiii
"
-
Etti
⼆

=
e
⼆ Èxethhw 。

low T s S》 求
8
@ hīght B-) 0
-

" "
allstates pupulated

ouygroundstateppulatedx-rotationaliEJ-B.J.nl/g-2Jtl
9
f-1-gxe-E -ixlZJtlj.es 157 (列

dīatomīc molecule : 10

omnzimr.I /VuclearHamiltonia Fln=gtHiotHvib 11

Àrot
點 approxīmatin
啞
12
under

Hwteǚ
Ioīs

aconstan tlrot.YJE J.Y ErlJK-JUtDJ-al.2a in

wavenumber
13

㬫
⾾上 長 了 (列 ⼆⽉ 孔列 ✗

14
⼆

nrǖalterm rāatinalconstantccmt)

termvalue selectionrul i-4e-4r.hn 出⼼ 州

Eǎhhihi
ieanlüli 15
Mai
Miegnitfibnxduxdndtr

define permanentdīpole 16
ijfiüühdtedu
Mzljygúcǔhidtr
ix. Ē
17
nrcos unxSYJ.co 㷋 soc dtr

coso
戀 焜 嚷叫 "
焜
18
⼀
.

-
SYY.la Yǐhta 焖 ) 。
、 dtr

EG.fi/J'-lSM 'tCzT.J't1 SM, rota ionalsel ctionruleforMl2tO 19

20
Dpermanetdīpde h-tolGrossselec.hn rue )

lspecifīdi △ III ,
△ M -0

* absorption occurs from Js Jtl īntensītgxfg 21

XCZJty.e-BEJabsorbsEIJtD-FLD-BUtDUtD-B.J.nl ) ⼆ 2⽉ 汀⼗ 1)

22
a b s . s p e c t r u p ru fl e o. / p o p u I a t i o n F t fi i Y i l i
*

eqaalg spaced

-
23

24

25
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