PYQ 1

Previous Year Questions

Redox Reactions

Ashwani Tyagi
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 PYQ 1
Previous Year Questions

Redox Reactions

Ashwani Tyagi
From the following statements regarding H2O2 choose the incorrect
statement.
JEE Main 2015

A. It can act only as an oxidising agent

B. It decomposes on exposure to light

C. It has to be stored in plastic or wax linked glass bottles in dark

D. It has to kept away from dust

Consider a titration of potassium dichromate solution with acidified
Mohr’s salt solution using diphenylamine as indicator. The number of
moles of Mohr’s salt required per mole of dichromate is
IIT JEE 2007

A. 3

B. 4

C. 5

D. 6
In the standardisation of Na2S2O3 using K2Cr2O7 by iodometry, the
equivalent weight of K2Cr2O7 is
IIT JEE 2001

A. (molecular weight)/2

B. (molecular weight)/6

C. (molecular weight)/3

D. Same as molecular weight

An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL.
The volume of 0.1 N NaOH required to completely neutralise 10 mL of
this solution is
IIT JEE 2001

A. 40 mL

B. 20 mL

C. 10 mL

D. 4 mL
The number of moles of KMnO4 that will be needed to react with one
mole of sulphite ion in acidic solution is
IIT JEE 1997

A. 2/5

B. 3/5

C. 4/5

D. 1
Hydrogen peroxide solution (20 mL) reacts quantitatively with a
solution of KMnO4 (20 mL) acidified with dilute H2SO4. The same
volume of the KMnO4 solution is just decolourised by 10 mL of MnSO4
in neutral medium simultaneously forming a dark brown precipitate
of hydrated MnO2. The brown precipitate is dissolved in 10 mL of 0.2
M sodium oxalate under boiling condition in the presence of dilute
H2SO4. Write the balanced equations involved in the reactions and
calculate the molarity of H2O2.
IIT JEE 2001
An aqueous solution containing 0.10 g KIO3 (formula weight = 214.0)
was treated with an excess of KI solution. The solution was acidified
with HCl. The liberated I2 consumed 45.0 mL of thiosulphate solution
decolourise the blue starch-iodine complex. Calculate the molarity of
the sodium thiosulphate solution.
IIT JEE 1998
A 5.0 cm3 solution of H2O2 liberates 0.508 g of iodine from an
acidified KI solution. Calculate the strength of H2O2 solution in terms
of volume strength at STP.
IIT JEE Adv.
A 2.0 g sample of a mixture containing sodium carbonate, sodium
bicarbonate and sodium sulphate is gently heated till the evolution of
CO2 ceases. The volume of CO2 at 750 mm Hg pressure and 298 K is
measured to be 123.9 mL. A 1.5 g of the same sample requires 150 mL
of (M/10) HCl for complete neutralisation. Calculate the percentage
composition of the mixture.
IIT JEE Adv.
A sample of hydrazine sulphate (N2H6SO4) was dissolved in 100 mL of
water, 10 mL of this solution was reacted with excess of ferric
chloride solution and warmed to complete the reaction. Ferrous ion
formed was estimated and it, required 20 mL of M/50 potassium
permanganate solution. Estimate the amount of hydrazine sulphate in
one litre of the solution.
Reaction IIT JEE Adv.
4Fe + N2H4 → N2 + 4Fe + 4H+
3+ 2+

MnO4– + 5Fe2+ + 8H+ → Mn2+ + 5Fe3+ + 4H2O

5 mL of 8 N nitric acid, 4.8 mL of 5 N hydrochloric acid and a certain
volume of 17 M sulphuric acid are mixed together and made up to 2 L.
30 mL of this acid mixture exactly neutralise 42.9 mL of sodium
carbonate solution containing one gram of Na2CO3.10H2O in 100 mL of
water. Calculate the amount in gram of the sulphate ions in solution.

IIT JEE Adv.

4.08 g of a mixture of BaO and unknown carbonate MCO3 was heated
strongly. The residue weighed 3.64 g. This was dissolved in 100 mL of
1 N HCl. The excess acid required 16 mL of 2.5 N NaOH solution for
complete neutralisation. Identify the metal M.
IIT JEE Adv.
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