0715/

1/2022
CHEM A/L
SOUTHWESTREGIONALMOCKEXAMI
NATI
ON
GENERALEDUCATI
ON

TheTeachers’ResourceUni
t(TRU)incol
laborati
onwiththeRegi
onal Subj
ectCode PaperNumber
Pedagogi
cInspector
ateofPedagogyforScienceEducati
onandSouth 0715 1
WestChemi str
yTeacher
s’Associati
on(SOWECTA)

CANDI
DATENAME…………………………………………………..
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ectTi
tl
e
CANDI
DATENUMBER
…………………………….
………………………………..
………….
. CHEMI
STRY
CENTRENUMBER…………………………………………………………………………..

DATE
ADVANCEDLEVEL
29/
03/
2022(Mor
ning)

Ti
meAl
l
owed:
Onehourt
hir
tymi
nut
es

I
NSTRUCTI
ONSTOCANDI
DATES:
1. USEASOFTHBPENCI
LTHROUGHOUTTHI
SEXAMI
NATI
ON.
2. DONOTOPENTHI
SBOOKLETUNTI
LYOUARETOLDTODOSO.
Bef
oret
heExami
nat
ionbegi
ns:
3. Checkt
hatt
hisquest
ionbookl
eti
sheaded“
Adv
ancedLev
el–07I
5Chemi
str
y,Paper1”
.
4. I
nser
tthei
nfor
mat
ionr
equi
redi
nthespacespr
ovi
dedabov
e.
5. Wi
thoutopeni
ngt
hebookl
et,pul
loutt
heanswersheetcar
eful
l
yfr
om i
nsi
det
hef
rontcov
eroft
hisbookl
et.
Takecar
ethaty
oudonotcr
easeorf
oldt
heanswersheetormakeanymar
ksoni
tot
hert
hant
hoseaskedf
or
i
nthesei
nst
ruct
ions.
6. I
nser
tthei
nfor
mat
ionr
equi
redi
nthespacespr
ovi
dedont
heanswersheetusi
ngy
ourHBpenci
l
:
Candi
dat
eName,
Cent
reNumber
,Candi
dat
eNumber
,Subj
ectCodeNumberandPaperNumber
.
Howt
oanswerquest
ionsi
nthi
sexami
nat
ion:
7. AnswerALLt
he50quest
ionsi
nthi
sexami
nat
ion.Al
lquest
ionscar
ryequal
mar
ks.
8. Non-
progr
ammabl
ecal
cul
ator
sar
eal
l
owed.
9. Foreachquest
iont
her
ear
efoursuggest
edanswer
s,A,B,C,andD.Deci
dewhi
chansweri
scor
rect
.Fi
ndt
he
numberoft
hequest
ionont
heAnswersheetanddr
aw ahor
izont
all
i
neacr
osst
hel
ett
ert
ojoi
nthesquar
e
br
acket
sfort
heanswery
ouhav
echosen.Forexampl
e,i
fCi
syourcor
rectanswer
,mar
kCasshownbel
ow:

A B C D

10.Mar
konl
yoneanswerf
oreachquest
ion.I
fyoumar
kmor
ethanoneanswer
,youwi
l
lscor
ezer
ofort
hat
quest
ion.I
fyouchangey
ourmi
ndaboutananswer
,er
aset
hef
ir
stmar
kcar
eful
l
y,andt
henmar
kyournew
answer
.
11.Av
oidspendi
ngmucht
imeonanyquest
ion.I
fyouf
indaquest
iondi
ff
icul
t,mov
etot
henextquest
ion.Youcan
comebackt
othi
squest
ionl
ater
.
12.Doal
lroughwor
kint
hisbookl
etusi
ng,
wher
enecessar
y,t
hebl
ankspacesi
nthequest
ionbookl
et.
13.Mobi
l
ephonesar
eNOTALLOWEDi
ntheexami
nat
ionr
oom.
14.Youmustnott
aket
hisbookl
etandanswersheetoutoft
heexami
nat
ionr
oom.Al
lquest
ionbookl
etsand
answersheet
swi
l
lbecol
l
ect
edatt
heendoft
heexami
nat
ion
©TRU/
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Questions1–37( Thirt
y-sevenquestions)
.
Direct
ions:Eachofthequestionsorincomplet
e
statementsinthi
ssecti
oni sfoll
owedbyf our
suggestedanswers.Selectthebestanswerin 6.Ident
ifyt
hecompoundt
hatcanexhi
bit
eachcase. stereoi
someri
sm?
A.CH3CH2CHO
1.Amolarsolut
ionis: B.CH3CH(CH3)2
A.Asolut
ionof1mol ofsol
utedi
ssol
vein1 C.CH3CH2COCH3
dm3ofsolvent. D.CH3CH2CH(OH)CH3
B.Asolut
ionof1mol ofsol
utedi
ssol
vein1kg
ofsol
vent. 7.Whati
sthecoor
dinat
ionnumberofI
roni
nthe
C.Asolut
ionof1mol ofsol
utedi
ssol
vein1 compl
excompoundK2[Fe(CN)
6]
?
dm3ofsoluti
on. A. 3
D.Asolut
ionof1gr am ofsol
utedi
ssol
vein1 B. 4
dm3ofsoluti
on. C. 6
D. 8
2.I
denti
fyt
hehybri
dizat
ionofcar
boni
nthe
fol
l
owingmolecul
e. 8.Thegener
al out
erelect
roni
cconf
igur
ati
onof
thegr
oupVel ementis?
A.np5
B.ns2np3
C.nsnp4
D.ns2np5
1 2 3 4

A sp3 sp2 sp2 sp2 9.Whichofthef ol

l
owingdblockmetal
ions
formscolour
lesscomplexi
onsandcompounds:
B sp2 sp2 sp2 sp A.Mn4+
3+
B.Cr
C sp3 sp sp2 sp C.Fe2+
D.Cu+
D sp sp2 sp sp2
10.Whichpr opert
iesaccountforthediagonal
rel
ati
onshipbetweenelementsint heper iodic
3.Whenasolutionofpot assium i
odidei str
eat
ed tabl
e?
wi
thsil
verni
tr
ate( v)sol
ution,AgNO3i tforms A. Simil
aroxidati
onstateandioni zat
ionener gy
A.Ay ell
owpr ecipi
tateinsolubl
einaqueous B.Similarmelti
ngpointandboi l
ingpoi nt
NH3 C. Simil
arelectr
onegati
vit
yandat omicsi ze
B.Acr eam precipi
tateinsolubl
einaqueous D.Abili
tytocatenateandhy bri
dize.
NH3
C.Awhi teprecipit
atesolubleinaqueousNH3 11.Whichst at
ementdescr ibesbondi ngi
n
D.Apal e-
yell
owpr ecipi
tatesolubl
ei naqueous hydr
ocyanicaci d,
HCN?
NH3 A. El ectrostati
cattract
ionbetweenH+andCN-
i
ons
4.Whichoft hefol
l
owingchl
ori
desnei
theri
oni
zes B. VanderWaal sforceandhy drogenbond.
norhydrolyzesi
nwater C. VanderWaal sforceonly
A. SiCl4 D. El ect
rostaticattr
acti
onbet weenshared
B. NaCl elect
ronpai randposi t
ivenuclei
C. CCl4
D. CuCl 2 12.Whichoft hefoll
owingisapr
oper
tyuni
quet
o
groupI
Vel ement s?
5.Thecor r
ectf
ormulaofanOXOaci
dofchl
ori
ne A.Var i
ableOxidation
whichhasanoxidat
ionstat
eof+3and+7ar
e B.Diagonal Relat
ionshi
p
respecti
vel
y, C.Hy bri
dizati
on
+3 +7 D.Cat enati
on
A.HCl
O3 HCl
O4 13.Whichoft hefol
lowingel
ementshast
he
B.HCl
O2 HCl
O4 l
argestsecondi oni
zat
ionenergy
?
C.HCl
O HCl
O3 A. Sodi um
D.HCl
O3 HCl
O B. Pot assium
C. Magnesi um
D. Cal ci
um
©TRU/
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 20.Predi
ctt
hemaj
orpr
oductoft
hef
oll
owi
ng
14.Whichofthef
ollowi
ngisanaci
dicoxi
deof
react
ion.
thet
hir
dperiodoftheperi
odi
ctabl
e?
A. Na2O
B. NO2
C. CO
D. Si
O2
A.m-chlor ophenol
15.Brominecanbepr
oducedf
rom t
hef
oll
owi
ng B.o-
chlorophenol andp-
chlor
ophenol
react
ion;
C.o-
hydr oxy t
olueneandp-hydroxy
tol
uene
D.m-hydr oxytoluene
-
5Br( O-(
aq)+Br aq)+6H+(
aq) 3Br
2(l
)+3H2O(
l)
21.Whyar
escandi
um andzi
ncconsi
der
edasd-
Whi
chtwomet hodsthatcouldbeusedt o bl
ockel
ement
sbutnotastransi
ti
onal met
als?
moni
tortherateofthereaction? A. Theydonotf orm col
ouredcompound
A. Conductivi
tyanddilatometry B. Theydonotf ormionsorcompounds
B. Colori
met r
yanddilatomet r
y wit
hpart
ial
l
yf i
l
ledd-orbi
tals
C. ConductimetryandCol ouri
metr
y C. Theyarenotparamagnet i
c
D. Tit
rimetryanddil
atomet ry D. Theydonotf orm complexes

16.Analy
sisof2.
20gofacompoundof 22.ThepHofa0.
01M sol
uti
onofNaOHi
s?
phosphorusandsulphurshowedthatitcont
ained A. 14
1.24gofphosphorus.Theempiri
calformulaof B. 12
thecompoundis? C. 11
(RAM:P=31, S=32) . D. 13
A. P2S
B. P4S3 23.I
dent
if
ytheelementwi
tht
hehi
ghestmel
ti
ng
C. P3S4 poi
nt.
D. P2S3 A. Boron
B. Carbon
17.I
dentif
ytheparti
cleXinthenucl
earr
eact
ion C. Aluminum
4 14 1
2
Ηe+ 7
Ν→ 1
Η+Χ bygivi
ngit
s massnumber D. Sili
con
andatomicnumber .
A. 17and8r especti
vel
y 24.Themostsui
tabl
er eagentf
ort
heconv
ersi
on
B. 19and2r especti
vely ofCH3CONH2toCH3NH2i s?
C. 19and8r especti
vel
y A. Li
AlH4/dryether
D. 17and10r especti
vel
y B. NaNO2/HCl,
temp<5℃
C. RedP4/Zn/Heat
18.Whatvolumeof12.
0M HCli
srequi
redt
o D. Br2/KOH
prepar
e75.0mLof3.50M HCl
?
A. 21.9mL 25.Whi
choft hefoll
owi
ngnit
rat
eswi
ll
B. 0.560mL decomposetogivetheni
tr
it
eandoxy
gen?
C. 257mL A. NaNO3
D. 75.0Ml B. LiNO3
C. Mg( NO3)2

19.Whi
choft hefol
lowi
ngwill
changet
hev
alue D. Ca(NO3)2

ofKc?
A.Concentrati
onchanges 26.Thereacti
onCH4+Cl 2→ CH3Cl +HCl
isan
B.Pressurechanges exampleof:
C.Temper atur
echange A. Af reeradicalsubst
it
ution
D.Empl oyi
ngacataly
st B. Anel ectr
ophili
csubstit
ut i
on
C. Anucl eophili
csubsti
tution.
D. Anucl eophili
caddit
ion.

27.Whi
choft hef
oll
owi
ngspeci
eisaLewi
sbase?
A. Al
Cl3
B. BF3
C. OH-
©TRU/
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 D. H+ D.I
nfr
a-r
edspect
roscopy

28.Giventhef ol
lowingstandar denthalpy
changesinKJ/ mol :∆Hoc(
C6H6)=- 3267. 6;
o o
∆H f(H2O)=-285. 9;∆H f(CO2)=- 393.5.The 35.Whatistheoxidat
ionstat
eofsul
phuri
n
standardenthalpyofformationofbenzenei s? potassi
um per
sulphat
e,K2S2O8?
6C(s)+3H2O( l)→ C6H6( l
) A. +6
A.+48. 9 B. +4
B.+2016. 4 C. - 2
C. -679.4 D. +7
D. -2874.1
29.Anor ganiccompoundgi v esoutwhi tefumes 36.Whichoft hefoll
owingi sanenv ironment al
withPCl5andr eactswithami xt
ureofNaOHand eff
ectofNi t
rogen?
I2togivetr
ii
odomet hane.Thecompoundcoul dbe? A. It’soxidescauseaci dr ai
n.
A.CH3CH2CH2OH B. Itsammoni um saltsar eusedasf er
ti
lizer
.
B.CH3COCH3 C. It’satmospher i
cfixationtonour ishthe
C.CH3CH2OH soi
l
D. CH3-O-CH3 D. Itsnitri
deisusedi nt hemanuf actur
eof
rechargeabl
elit
hium bat ter
ies.
30.Thestrongestoxi
dizi
ngagentamongt
he
hal
ogensis? 37.Whatist
hemajorpr
oductoft
hef
oll
owi
ng
A. F2 react
ion?
B. Cl2 CH3CH=CH2+HBr /
CCl4→
C. Br2 A. CH3CH2CH2Br
D. I
2 B. CH3CHBrCH3
C. CH2BrCH=CH2
31.Fort hereacti
onR→ P: Whatist
heorderof D. CH3CH=CHBr
ther eact
ionwithrespecttoR,i
ftherat
e
i
ncreases9t i
meswhent heconcent
rat
ionofRis
tri
pled? Questi
ons38–45( Eightquesti
ons).
A. Fi rstor
der Dir
ecti
ons:Foreachoft hequesti
onsbel owONE
B. Thi rdorder orMOREoft heresponsesi s(ar
e)correct.Deci
de
C. Zer oorder whichofther esponsesi s(are)corr
ectthen
D. Secondor der choose;
AIf1,2,and3ar eallcorrect.
32.Amixt
urethatboil
swithoutchangein BIf1and2onl yarecor r
ect.
composi
ti
onis? CIf2and3onl yar ecor r
ect.
A. Aminimum boil
ingpointmixtur
e DIf3onlyiscor rect.
B. Amaximum boili
ngpointmixture SUMMARI SEDDI RECTIONS
C. Aconstantboi
li
ngpointmixture
D. Amixturewit
houtamaxi mum or A B C D
minimum point
1,
2and3 1and2 2and3 3Only
Al
lCor
rect Onl
y Onl
y Cor
rect
33.Thel
atti
ceenergyforrubi
dium chl
ori
deis
-1 -
1 Cor
rect Cor
rect
-657Kj
mol andit
sheatofsol ut
ioni
s+9Kj mol.
Thehydrat
ionenergyofrubi
dium chl
ori
deis?
-
1
A. -
648Kj mol 38.Fort
hereact
ion:
-
1 N2(g)+3H2(g)⇌ 2NH3(
g)∆H<0
B. +648Kj
mol
-
1 1. Increasi
ngt hepressure,i
ncreasesthe
C. -
676Kj
mol
val
ueoft he equil
ibri
um constantKp.
-
1 2. Liqui
fyi
ngtheammoni aonceformed
D. +676Kj
mol
i
ncreases theyield.
34.Whi
choneoft hefoll
owingt echni
queswoul
d 3. Theoptimum condi t
ionsfort
hebesty iel
d
bemostappropri
ateinidenti
fyi
ngt heposi
ti
onof areapressureof200at m,atemper at
ureof
hydr
ogenatomsinanor ganiccompound? ≈700Kandt heuseoff i
nel
ydividedIr
on
A.Massspect r
omet r
y catal
yst
B.Nucl earmagneticresonance
39.Whi
chcondi
ti
onsar
erequi
redt
ogi
veagood
C.X-raydiff
racti
on
©TRU/
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MOCK2022 4
yi
eldofet
hanoicacidwhenet
hanol i
soxi
dized
usi
ngpotassi
um dichr
omate,
K2Cr2O7?

1.Addsul phuricaci
d. 43.Whichofthef oll
owingistr
ueaboutcar bonyl
2.Heatther eacti
onmi x
tureunderr
efl
ux compounds?
3.Dist
il
lthepr oductastheoxidi
zi
ngagenti
s 1.BothAl dehydesandKet onesreactwi t
h
added. Toll
en’sreagenttoform asil
vermirror.
2.AllAldehydesandKet oneshav eantisept
ic
40.Whi
choft
hef
oll
owi
ngi
s/ar
eacy
lat
ingagent
s? smell.
3.Theani onformedaf t
erthelossoft heα-
1.RCO2R hydrogenat om i
sresonancestabil
ized
2.(RCO)
2O
3.RCOCl 44.CompoundAwaspr epar
edbyoxi
dationof
compoundBwi thal
kalineKMnO4.CompoundA
41.Whatwi
lhappenwhen1cm3of0.
l 001M HCl onreducti
onwithLi
AlH4get sconv
ert
edbackto
i
saddedtoabuffersol
uti
onof0.
1M H2CO3and compoundB.WhencompoundAi sheatedwit
h
0.
04M NaHCO3? compoundBi nthepresenceofH2SO4,i
t
producesfr
uit
ysmellofCompoundC.
1.ThepHoft hebuf f
erwi
llr
educe.
2.ThepHoft hebuf f
erwi
lli
ncrease. 1.CompoundAi
sanal
cohol
.
+
3. TheH ionsfr
om HCl wil
lbepickedupby 2.CompoundBi
sacar
boxyl
icaci
d.
-
theexcessHCO3suppliedfr
om NaHCO3 3.CompoundCi
sanEst
er.

42.Thedecayof75%63
o5
Cut 9
Ni
hasahal
f-
li
feof 45.Considertheel
ectrodesy
stems;
29 28 EoMg2+(aq)/
Mg( s)=-2.36Vand
0.
01year
s. EoZn2+(
aq)/Zn(s)=-0.
76V
Whent hetwoelectr
odesarecoupl
edtogi
vea
1.Thedecayi
sanalphadecayfol
l
owedbya spontaneousreact
ion:
bet
adecay.
-1
2.Thedecayconst
anti
s69.3year 1.Thecel
lpotenti
alforthecoupleis+1.60V.
3.Thedecayi
sanalphadecay. 2.Thecel
ldi
agr am f
orthepr ocessis
Mg(s)
/Mg2+(aq)/
/Zn2+(aq)
/Zn(s)
3.Thecoupl
ef ormsanel ectr
olyt
iccel
l.

Quest
ions46–50(
Fiv
equest
ions)
.

Directi
ons:Eachoft hequestionsconsistsofast at ementi
ntheleft
-handcol umnfoll
owedbyasecond
statementint heri
ght-
handcol umn.Deci dewhethert hefir
stst
atementi sTrueorFalse.Decidewhethert
he
secondst atementisTrueorFal se.Thenchoose:
AI fbothstatementsareTrueandt hesecondstat ementisacor r
ectexplanationofthefi
rststat
ement.
BI fbothstatementsareTrueandt hesecondstat ementisNOTacor rectexplanat
ionofthefir
stst
atement.
CI fthefi
rststatementi
sTr ueandt hesecondstat ementisFal
se.
DI fthefi
rststatementi
sFal sebutt hesecondstat ementisTrue.

DI
RECTI
ONSSUMMARI
SED

Opt
ion Fi
rstSt
atement Second Comment
Stat
ement

A TRUE TRUE Secondstat

ementi
saCORRECTexpl
anat
ionoft
he
fi
rstst
atement
.

B TRUE TRUE Secondstatementi

sNOTaCORRECTexpl
anat
ion
ofthefi
rststat
ement.

©TRU/
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MOCK2022 5
 C TRUE FALSE

D FALSE TRUE

FI
RSTSTATEMENT SECONDSTATEMENT

onnumberofNa+andCl
-
4 Thecoor
dinati NaClcry
stal
lat
ti
ceadopt
saf
acecent
eredcubi
c
6 i
oninNaCl cr
ystal
lat
ti
cear
eeach6. (
fcc)uni
tcel
l.

4 Thehal
ogensshowachangeinphy
sical DowngroupVI
Ivanderwaal
sfor
cesi
ncreasesi
n
7 stat
efr
om gasi
nF2andCl2,
thr
ough st
rengt
hwithi
ncr
easeinat
omicnumber
.
l
iqui
dinBr
2tosoli
dinI
2andAt2

4 CH3CH2OHandCS2f or
msami sci
ble Onmi xi
nget
hanolandcarbondi
sul
phide,st
rongH-
8 l
iqui
dmixturet
hatdevi
ateposi
ti
vel
y bondsinet
hanolar
ebrokenbyint
eracti
onwithCS2
fr
om Raoult
’sl
aw molecul
es.

4 Ammoni acoordi
nateswithbor
on Ammoniai
nit
sreact
ionwithbor
ont
ri
fl
uor
ide
9 tr
if
luor
idetoform H3NBF3 behav
esasanArr
heniusbase

Mg2+, 3+ 2-
5 Al O andN3-ar
, eisoel
ect
roni
c Theioni
cradi
usofthei
onsi
ncr
easesi
ntheor
der
:
2+ 3+ 2- 3-
0 i
ons. Mg <Al<O <N

END

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