KOTA STUDY CIRCLE Where We Shape The Career Time … MIN

Sol.TEST – No.7(IIT-JEE) XI

1.
Date : …..

(c)
RCLE
Stress = Y α∆θ ; hence it is independent of length.
No. MCQ …
Melting point of ice decreases with rise of temp but that
of wax etc increases with increase in temperature.
Similarly ice starts forming from top downwards
2. (d) 10 /° whereas wax starts its formation from bottom.

3. (d) 11. (a) Let m gm of steam get condensed into water (By heat
loss). This happens in following two steps.
4. (a) If m gm ice melts then
100°C 100°C
Heat lost = Heat gain
Steam (H1 = m × 540) Water
80 × 1 × (30 − 0 ) = m × 80  m = 30 gm

[H2 = m × 1 × (100 – 90)]

5. (b) When water is cooled at 0°C to form ice then 80
calorie/gm (latent heat) energy is released. Because potential 90°C
energy of the molecules decreases. Mass will remain constant Water
in the process of freezing of water.
Heat gained by water (20°C) to raise it’s temperature
upto 90° = 22 × 1 × (90 − 20 )
6. (d) Temperature of mixture
Hence, in equilibrium heat lost = Heat gain
.  m × 540 + m × 1 × (100 − 90 ) = 22 × 1 × (90 − 20 )
 m = 2.8 gm
7. (a) When water falls from a height, loss of potential energy The net mass of the water present in the mixture
causes rise in temperature. = 22 + 2.8 = 24 .8 gm.

8. (a) Freezing point of water decreases when pressure 12. (a) Initially, on heating temperature rises from –10°C to
increases, because water expands on solidification while 0°C. Then ice melts and temperature does not rise. After the
“except water” for other liquid freezing point increases with whole ice has melted, temperature begins to rise until it
increase in pressure. reaches 100°C. Then it becomes constant, as at the boiling
Since the liquid in question is water. Hence, it expands point will not rise.
on freezing.

13. (c)
9. (b) Loss of weight at 27ºC is
= 46 – 30 = 16 = V1 × 1.24 ρl × g …(i) 14. (c) Substances having more specific heat take longer time
Loss of weight at 42ºC is to get heated to a higher temperature and longer time to get
T A
= 46 – 30.5 = 15.5 = V2 × 1.2 ρ l × g …(ii) cooled.
B
16 V 1 . 24
Now dividing (i) by (ii), we get = 1 × C
15 .5 V2 1 .2

V2 15 .5 × 1 .24
But = 1 + 3α (t2 – t1) = = 1.001042 tA tB tC
t
V1 16 × 1.2

 3α (42º – 27º) = 0.001042  α = 2.316 × 10–5/ºC.

If we draw a line parallel to the time axis then it cuts the
10. (b) Substances are classified into two categories given graphs at three different points. Corresponding
points on the times axis shows that
(i) water like substances which expand on
solidification. ! " # " $  ! " # " $

(ii) CO2 like (Wax, Ghee etc.) which contract on

solidification. 15. (c) From given curve,
Their behaviour regarding solidification is opposite. Melting point for A = 60 °C
and melting point for B = 20 °C

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 Time taken by A for fusion = (6 − 2) = 4 minute 5 L M B B
27. (a) M ; < 1
Time taken by B for fusion = (6 . 5 − 4 ) = 2 . 5 minute 5 L B

HA 6 × 4 × 60 8
Then = = . 5
H B 6 × 2 . 5 × 60 5 28. (c) Energy radiated per sec N OPQ B
6
N R B
4 2000 B
N∝R B
⇒ . U V 1
16. (a) Fire is extinguished by the vaporization do water which N R B 1 4000
lowers the temperature of the burning body. Further, the water
vapor envelops the body, keeping oxygen away. Hot water
evaporates more than cold water as 29. (a)

%& %& 30. (c) Q ∝ T4

17. (b) As we know ( *
&' % )&'
5° 31. (d) KH + H 2 O → KOH + H 2 ↑

18. (b) When length of the liquid column remains constant, 32. (c) Order of adsorption of H 2 (occlusion) is
then the level of liquid moves down with respect to the Colloidal Palladium > Palladium > Platinum > Gold >
container, thus γ must be less than 3α. Nickel
Now we can write V = V0(1 + γ ∆T)
Since V = Al0 = [A0 (1 + 2α∆T)]l0 = V0 (1 + 2α∆T) 33. (c) Occlusion is the phenomenon of adsorption of hydrogen
Hence V0(1 + γ ∆T) = V0(1 + 2α∆T)  γ = 2α. by metal.

01 4'
34. (c) These allotropic forms have similar chemical properties.
/ 2
19. (c) mix
3
10°
35. (a) F2 has maximum tendency to react with hydrogen. the
decreasing order of reactivity is F2 > Cl 2 > Br2 > I2 .
20. (c) Ice (0°C) converts into water (100°C) in following two
steps.
36. (c) H → H + + e −
ice H + e− → H −
0°C (Q1 = mLi) (Q2 = mcW∆θ)
Water at 0°C Water at 100°C 37. (c) IE of H is 1312 kJ/mole.
IE of Cl is 1255 kJ/mole.
Total heat required
Q = Q1 + Q2 = 1 × 80 + 1 × 1 × (100 − 0) = 180 cal
38. (c) Actually these exist in the ratio.
Protium : Deuterium : Tritium
5 7$% 5 $ :
21. (d) 6 8
 6
∝ 8
∝ 8
(d = Diameter of rod) 1 : 1.56 × 10 - 2 : 1 × 10 −17

5/6 : 8
 5/6
;: < 8
; < ; < = 39. (b) 13 H → 32 He + −01e

7$ 6 40. (c) Ca (OH )2 is used for the softening of temporary hard

22. (a) > 8
; in both the cases , A, l and @
7 6
water.
are same so Kt = constant  = 1.5. Ca (OH )2 (aq ) + CO 2 (g ) → CaCO 3 (s)+ H 2 O(l)
7 6
cloudiness

23. (a) For a black body emissivity = absorptive power.

41. (d) Hydrogen is the lightest gas.

24. (b) 42. (c) An atom of tritium contains 1 proton, 1 electron and 2
neutrons.
25. (a) At low temperature short wavelength radiation is
emitted. As the temperature rise colour of emitted radiation 43. (d) Hydrogen is a non-metal while all other members of group
are in the following order 1 (alkali metals) are metals.
Red→Yellow→Blue→White (at highest temperature)
44. (c) Hydrogen is the lightest gas. It is insoluble in water.
A B A B
26. (c) A
; <  ; < =16  C 320 GHIJ/K min.
45. (c) K 2 SO 4 . Al 2 (SO 4 ) 3 .24 H 2 O
Potash alum is generally used for purifying water.
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46. (c) Water molecule associate due to inter molecular hydrogen 62. (a) (x + 1)2 = 4 a(y + 2)
bonding. 1
Passes through (3, 6)  16 = 4 a.8  a =
2
47. (b) H 2 O 2 + Cl 2 → 2 HCl + O 2  (x + 1)2 = 2(y + 2)  x 2 + 2 x − 2 y − 3 = 0 .

48. (c) 63. (b) Always eccentricity of parabola is e = 1 .

49. (a) In the following reaction H 2 O 2 acts as a reducing agent. 64. (a) Tangents at ' t1 ' , ' t 2 ' meet at (at1 t 2 , a(t1 + t 2 )) .
PbO 2 (s) + H 2 O 2 (aq) → PbO (s) + H 2 O(l) + O 2 (g)

2a 2a / m  a 
65. (c) y− =− x − 2 
50. (e) H 2 O 2 acts as an oxidising agent in acidic and alkaline m 2a  m 
medium. 2 a −1  a 
 y− = x − 2 
m m  m 
51. (c,d) Mg + 2 H 2 O → Mg(OH )2 + H 2 ↑  m 3 y + m 2 x − 2am 2 − a = 0 .
LiH + H 2 O → LiOH + H 2 ↑
66. (a) Normal to parabola will be, y = mx − 2 am − am 3
52. (b) Reaction of NaBH 4 with cold water is very slow. All For three values of m. Three normal can be drawn on
other statements except (b) are correct. parabola y 2 = 4 ax . So three feet of normals can be
obtained, hence centroid of triangle lies on axis of
53. (c,d) Ice is a poor conductor of heat (a good thermal insulator) parabola.
and its density is less than water.
67. (c) Checking from options point (±2, 2) is nearest. Hence
54. (d) MnO 2 , PbO 2 and BaO will not give H 2O2 with option (c) is correct.
HCl .MnO 2 and PbO 2 will give Cl 2 and BaO will react with
HCl to give BaCl 2 and water. 2a 1
68. (c) According to the condition, = 6 ae  e = .
e 3

55. (d) H 2 O absorbs neutrons more than D2 O and this decreases

x2 y2
the number of neutrons for the fission process. 69. (b) + =1
(48 / 3) (48 / 4 )
b2 1
56. Your Self a 2 = 16 , b 2 = 12  e = 1 − =
a2 2
COONa 1
∆
57. (b) 2 HCOONa (s) → H 2 (g ) ↑ + | (s) Distance is 2ae = 2 ⋅ 4 ⋅ =4.
Sod. formate 2
COONa
Sod. oxalate

a 1 8e 8 . 4 16
70. (d) − ae = 8 . Also e =  a = = =
58. (b) Presence of CO 32 − and SO 42 − ions in water reduced the e 2 (1 − e 2 ) 2(3) 3
tendency of dissolution of Pb in water as Pb(OH )2 . 16  1  16 3 8 3
∴b = 1 −  = =
3  4 3 2 3
59. (d) Water obtained from organic ion-exchange resins is free 16 3
from all ionic impurities. Hence the length of minor axis is .
3

60. (d) 2 AgNO 3 (aq) + 2 NaOH (aq) → 71. (b) Vertex (0,7), directrix y = 12 , ∴ b = 7
Ag 2 O (s)+ H 2 O (l) + 2 NaNO 3 (aq ) b 7 95
Brown ppt. Also = 12  e = ,a=7
e 12 144
Ag 2 O(s) + H 2 O 2 (aq ) → H 2 O(l) + O 2 (g ) + 2 Ag (s)
Black ppt. Hence equation of ellipse is 144 x 2 + 95 y 2 = 4655 .
The finely divided Ag is black in colour.
72. (a) Let point P (x 1 , y1 )
y 2 9
61. (d) Here = t and x − 2 = t 2 So, ( x 1 + 2)2 + y 12 =  x1 + 
2 3 2
2
y 2
 (x − 2) =    y 2 = 4 ( x − 2) . 4 9
2  (x 1 + 2)2 + y 12 =  x1 + 
9 2

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  81  Foci (±6, 0) ≡ (±ae, 0)  e =
6 3
= .
 9[ x 12 + y12 + 4 x 1 + 4 ] = 4  x 12 + + 9 x1 
 4  4 2

x 12 y 12
 5 x 12 + 9 y12 = 45  + =1,
9 5 x2 y2
84. (c) Given equation of hyperbola, − =1 ,
4 (16 / 9 )
x2 y2
Locus of ( x 1 , y1 ) is + = 1 , which is equation of an 4
9 5 ∴ a = 2, b = . As we know, b 2 = a 2 (e 2 − 1)
3
ellipse.
16 13 13
 = 4 (e 2 − 1)  e 2 = , ∴e = .
73. (b) SP + S ' P = 2a = 2 . 6 = 12 . 9 9 3

74. (c) It is obvious. 85. (a) Foci are (6,4) and (–4,4), e = 2 and centre is
6 −4 
 ,4  = (1,4 )
(x + 1)2 (y + 2)2  2 
75. (a) + =1
225 225 5 5
 6 = 1 + ae  ae = 5  a = and b = ( 3 )
25 9 2 2
225 15 225 15 9 4 ( x − 1)2 (y − 4 )2
a= = ,b = =  e = 1− = Hence the required equation is − =1
25 5 9 3 25 5 (25 / 4 ) (75 / 4 )

Focus =  − 1,−2 ±
15 4  or 12 x 2 − 4 y 2 − 24 x + 32 y − 127 = 0 .
.  = (−1,−2 ± 4 ) =(–1,2); (–1,–6) .
 3 5

86. (a) Given equation of hyperbola is,

x (y − 3)2 2
9 x 2 − 16 y 2 + 72 x − 32 y − 16 = 0
76. (b) 9 x 2 + ( 5 y − 3 5 )2 = 45 or + =0
5 9
 9 (x 2 + 8 x ) − 16 (y 2 + 2 y ) − 16 = 0
2
 a 2 = 5, b 2 = 9 . Therefore e = .
3  9 ( x + 4 )2 − 16 (y + 1)2 = 144
(x + 4 )2 (y + 1)2
 − =1
77. (c) 3 x − 12 x + 4 y − 8 y = −4  3( x − 2) + 4 (y − 1) = 12
2 2 2 2 16 9
(x − 2)2 (y − 1)2 X2 Y 2 2b 2 9 9
 + =1  + =1 Therefore, latus rectum = = 2× = .
4 3 4 3 a 4 2
3 1  1 
∴ e = 1− = . ∴ Foci are  X = ±2 × , Y = 0 
4 2  2  87. (a) y = x tan θ will be equation of chord. The points of
i.e., (x − 2 = ±1, y − 1 = 0 ) = (3, 1) and (1, 1) . intersection of chord and parabola are
 4a 4a 
(0, 0),  , 
 tan θ tan θ 
2

78. (a) The tangent will be y − 3 = m ( x − 2)  y − mx = 3 − 2m .

2
But it is tangent to the given ellipse, therefore m = 0, − 1  1  1
Hence length of chord = 4 a   +
 tan 2
θ  tan 2
θ
. Hence tangents are y = 3 and x + y = 5 .
4a 1 + tan 2 θ
= = 4 a cosec 2θ cos θ .
79. (b) The tangent at (a cos θ , b sin θ ) to the ellipse is tan θ tan 2 θ
(a cos θ )x (b sin θ )y x y
+ = 1 or + =1
a2 b2 (a / cos θ ) (b / sin θ ) 88. (a) Any normal to the hyperbola is
ax by
a b a2 b 2 + = a2 + b 2 .....(i)
∴ Intercepts are, h = ,k=  2 + 2 =1. sec θ tan θ
cos θ sin θ h k
But it is given by lx + my − n = 0 .....(ii)

80. (c) Here, a = 3, b = 2 . ∴ By formula, c 2 = b 2 + a 2 m 2 Comparing (i) and (ii), we get

a  −n  b  −n 
∴ c 2 = 4 + 9m 2 ; ∴ c = ± 9m 2 + 4 . sec θ =   and tan θ =  2 
l  a2 + b 2  m  a + b2 

a2 b 2 (a 2 + b 2 )2
81. (b) It is obvious. Hence eliminating θ , we get 2
− 2 = .
l m n2

x2 y2
82. (b) − = 1 . Therefore PS 1 ~ PS 2 = 2(3) = 6 . x2 y2 1
32 4 2 89. (c) Hyperbola is − =
144 81 25

83. (c) Vertices (±4 , 0 ) ≡ (±a, 0 )  a = 4 144 81 81 225 15 5

a= ,b= , e1 = 1 + = = =
25 25 144 144 12 4

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 Therefore, foci = (ae1 ,0) = 
12 5 
. ,0  = (3, 0)
 5 4 
Therefore, focus of ellipse = (4 e ,0) i.e. (3, 0)
3  9 
 e= . Hence b 2 = 16  1 −  = 7 .
4  16 

90. (b) Eccentricity of rectangular hyperbola is 2 .

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