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College of Science
Department of Chemistry
CHEM- 115 General Chemistry Lab
Fall-2021
Title of the experiment
Heat of neutralization
1
ABSTRACT:
In chemical reactions between acids and basis, the energy changed is observed, in
the form of heat at constant pressure.
It is defined as enthalpy change (∆H). The amount of heat is measured
experimentally by using calorimeter. In this experiment the system acts as a closed
system where only heat is allowed to flow between system and surrounding.
INTRODUCTION:
In this experiment, the amount of heat neutralization is measured when acids and bases react to
form salt and water. The temperature change of calorimeter and its contents is measured before
and after reaction.
The heat capacity of calorimeter was calculated by using hot and cold water
qcal
Heat capacity C cal=
T f −T i
qcal, can be found using:
q cal =heat lost by hot water−heat gained by cold water
We experimented 2 reactions between strong acid and strong base and in other procedure
between weak acid and strong base, in those two reactions heat was released, ∆H outcome is
negative.
2
EXPERIMENTAL:
Materials& Reagents:
1 M HCl, 1 M NaOH, 1 M acetic acid
Equipment:
– Hot plate
– Styrofoam cups (2)
– Cardboard Square with hole in the center,
– 400 mL beaker, thermometer (2)
– 50 mL graduated cylinder
– 250 mL baker
Procedure:
Part A: Heat Capacity of the Calorimeter
7. Allow the water to stand for a minute and quickly measure its temperature using a
thermometer – 2 to the nearest 0.1 °C and record in the data sheet.
8. Immediately pour the hot water to the calorimeter completely .
9. Place the cap with the thermometer – 1 and carefully stir the water with the thermometer.
10. Observe the temperature for the next 3 min and record the temp. every 15 s on Temp Vs
Time data sheet
3
Part B: Heat of Neutralization of HCl & NaOH
4. Measure exactly 50.0 mL 1 M HCl in to a dry beaker, and allow to stand for few mints.
5. Measure the temperature of the acid, rise the thermometer with water and dry.
6. Insert the thermometer into the calorimeter and measure the temperature of the NaOH
solution and record in the data sheet.
8. Lift the lid carefully and add the 1 M HCl solution all at once
9. avoid splashing, and immediately cap the calorimeter with the thermometer -1 and stir
gently
4
RESULTS & CALCULATION:
Add your data table and show all the calculations here
You must attach the data sheet at the end of your report
DISCUSSIONS:
On the other hand the enthalpy of neutralization of weak acid /strong base was
lower because weak acid slightly ionized in aqueous solution, both reactions
produced 0.05 mol of H2O.
CONCLUSIONS:
The main purpose of this experiment was achieved, we have learned how to
preform neutralization reaction in order to calculate to calculate change of enthalpy
using calorimeter.
The neutralization reaction between strong acid HCl and a strong base of NaOH
releases heat energy and has a greater negative enthalpy change; as a strong
acid/strong base dissociates completely in water.
REFERENCES:
1. General chemistry lab for college of science
2. Enthalpy Change of Neutralization. (2020, August 16). Truro School in Cornwall.
https://chem.libretexts.org/@go/page/3812