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22 Sigma bond – overlapping of orbitals in head on fashion/ pi bond-overlapping of orbitals in side wise fashion
23 2sigma and 2 pi bonds
24
39 a)SiO2 b)AlBr3
40 Heisenberg’s uncertainty principle states that for particles exhibiting both particle and wave nature, it will
not be possible to accurately determine both the position and velocity at the same time.
If ∆x is the error in position measurement and ∆p is the error in the measurement of momentum, then
ΔX×Δp≥h4π
Since momentum, p = mv, Heisenberg’s uncertainty principle formula can be alternatively written as-
ΔX×Δmv≥h4π
or
ΔX×Δm×Δv≥h4π
Where, ∆V is the error in the measurement of velocity and assuming mass remaining constant during the
h is planck’s constant
41 m=mass/molarmassxmass of the solven in kg==> 1.26/126x1=0.01m
42
B.O=Nb-Na/2= 0/2=0 Because bond order is zero, Helium molecule never exist.
43 Any 3 differences
44
Hybridization-Intermixing up of hybrid orbitals of approximately
same energies .
45 a)any two points b)Cr+3 1s2 2s2 2p6 3s23p63d3b)O-2 1s32s22p6c) Electronic configuration of N2 is (σ1s2
σ∗1s2 σ2s2 σ∗2s2 π2px2 π2py2 σ2pz2) diagram B.O=Nb-Na/2=10-4/2=3
46 a) IE –The energy required to remove the electron present in outer shell in gaseous state b)EN-The
tendency of an atom to attract the electron towards itself in the molecule c)AR-It is the distance
between centre of the nucleus to the outermost shell
Graphs