DAB

ji
ar
H2O
HCl F Htt ci
H2O

NaOH

Htt Ott
D
Nat t Ott
ti
H2
up
Tr

Ciii Neutralization salt hydrolysis acid base strength also

explain by this theory
r.
D

V ca NH 3 Marco are bases but donot contain OH

CO2 so 2 so 3 are acids but donot contain Ht
Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 1


Molecular
Bronsted Hci Htt CT

cationic µcµz Pt Htt AllHzolglott

Acids Anionic

Hco5 Htt co

ji

t
Molecular by Ht pyH

ar

Bronsted
cationic ask.olgcotdjdt
tet CAICHzbc.tt

Bases
Anionic

tecoj c Ht 4 03

Conjugate Acid Base Pairs

D
ti

up

consider a reaction oneprotonetitgoingtote oneprotonitilgoingtoei

x
1
Tr

HCl t 420 1130 t Ci

ut H
r.

HCl Ci and 1430 1 H2O

conjugate acid Base pair

Acid 2 Bases
Acids Base

HCl t H2O argot Cl j

conjugate

Acid Base pair

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 2



ji

3 3

ar

D
ti

up

Tr

d
r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 3



Acids Basez Acidz Bases

stronger

ji

ar

Weakenacid Weaken

strongeracid stronger base a

base

ti

up

Ott CT
HCl 1 H2O a Hz

Tr

Weaken acid Weakenbases strongeracid stronger

r.

base

got
D

1430T t CH z COO

CH3COOH t H2O e

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 4



7 1430 1 973 COO ka 1.8 10

CH 3COOH t 1420

Kae 4 ox to

ji

HCN t H2O 1430T t CN

ar

D
ti

Stronger weaacikden
Weaken
stronger e base
up

acid base

1720 t C2450 a CzHs OH 1 OH

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 5



ji

ar

D
ti

up

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 6



I­numbenn oI.o

E 4 to c o i.oi.eci gii
oxidant

t1 3 5 y

ji

change delocalisation increasing

Acidity increasing Basicity decreasing

ar

D
ti

up

H O H H O O H

Hy P H
P

P P O H
O4
O H O H
O
Tr

1431302 1431303 1431004

Protonated monobasic dibasic tribasic

0 atoms 1 2 3

Unprotonated 1
r.

o atom
I 1

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 7



ji

ar

D
ti

Ht
up

1 120 t MHz NH4t t OH

Ht
Tr

H2O 1 CO a Hcoj Oli

r.

Proton
D

Hz Ott CT

1 120 t HCl

Weaken stangndgetfstrongen

Weaken base
acid base

H2O t H2O Hzott Ott

14

Kix 1 10

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 8



ji

ar

D
ti

up

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 9



ji

ar

D
ti

up

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 10



ji

ar

D
ti

up

Tr

r.

electron pain

Ite NHI NHI

Ht MHz a

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 11



ji

ar

D
ti

up

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 12



Ammonation Agt 24MHz rag

IH3 NH3

MHz 2T

cult 4 iNH3 MHz Cut

A
NH3

ji

NH3
Hydration

ar

3T

H2O b
0112

cost GC 0142 7 H2O d

404T 042

D H2O OHz
1
ti

Alcoholation t
H H
up

Li t O Lik O

kHz CH3
Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 13



OH

St d

ii Ceo H C

Lewis acid Lewis Q

base

fly

i is E t H E

ji

ar

bisulphate ion

D
ti

Lewis acid t Lewis base Adduct

up

5032 t O s Os

505.75024­5032
Tr

O Isa Sos
t 52025

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 14



ji

ar

D
ti

up

Tr

r.

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 15



ji

ar

D ex
ti

up

Tr

r.

ERGOT

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 16

 ji
ar
D
ti
up
Tr
r.
D

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 17

 ji
ar
D
ti
up
Tr
r.
D

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 18

 ji
ar
D
ti
up
Tr
r.
D

Dr. Trupti Darji (V.P. & R.P.T.P. Science College) 19