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CHEMISTRY DPP # 4 (SOLID STATE)                                                  BATCH: ACME

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1. Schottky defect is observed in crystals when:- 7. NaCl shows Schottky defects and AgCl Frenkel
(1) some cations move from their lattice site defects. Their electrical conductivity is due to the :-
interstitial site (1) motion of ions and not the motion of electrons
(2) some impurity is present in the lattice (2) motion of electrons and not the motion of ions 
(3) some lattice sites are occupied by electrons (3) lower coordination number of NaCl
(4) equal number of cations and anions are (4) Higher coordination number of AgCl
missing from the lattice 8. Assertion : Frenkel defect is also called dislocation
2. Which of the following statement is NOT correct defect.
regarding schottky defects Reason : Frenkel defect is shown by ionic substances
(1) It is a stoichiometric defects in which cation and anion are of almost similar sizes.
(2) Schottky defect decreases the density of the (1) Assertion and Reason are True & the Reason
substance is a correct explanation of the Assertion.
(3) This effect is shown by ionic substance in (2) Assertion and Reason are True but Reason is
which there is a large difference in the size of not a correct explanation of the Assertion.
ions (3) Assertion is True but the Reason is False.
(4) In this effect, number of missing cations and (4) Both Assertion and Reason are False.
anions are equal. Which of the following is not correct consequences
9.
3. Which one of the following compounds shows of Frenkel defect ?
Frenkel defect? (1) Dielectric constant increases.
(1) ZnS (2) NaCl (3) KCI (4) CsCI (2) Density decreases.
4. Which of the following does not show Frenkel (3) Electrical conductivity increases.
defect?
(4) It results in interstitial defect.
(1) AgBr (2) AgCl  
10. NaCl is doped with 10 – 4 mol % SrCl2. The no. of
(3) KCl (4) Zns cation vacancies in one mole of NaCl is 
5. AgBr crystal shows :- (1) 6.02 × 1015
(1) Frenkel defect (2) Schottky (2) 6.02 × 1016

(3) Both (1) and (2) (4) None of these (3) 6.02 × 1017

6. In a solid lattice, the cation has  left a lattice site (4) 6.02 × 1014
and is located at interstitial position, the lattice
defect is : 11. Crystal structure of diamond is similar to :-
(1) interstitial defect (2) vacancy defect (1) NaCl(s) (2) Graphite(s)
(3) Frenkel defect (4) Schottky defect (3) ZnS(s) (4) Na2O(s)
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12. What is percentage of Fe+3 among cations in 18. F-centre is produced due to :-
Fe0.93O1.00 :- (1) Unpaired electron occupied anionic vacancies
(1) 7/93 × 100 (2) 14/93 × 100 (2) Monovalent ion is replaced by bivalent ion
(3) 79/93 × 100 (4) 93/93 × 100 (3) Ions present in cationic vacancies
13. In the crystal of CsCl; 8 : 8 coordination number, number
(4) Disslocation of ions
will be changed to 6 : 6 coordination number by :-
(1) Applying high pressure 19. Which is ferromagnetic-
(1) Ni (2) Co (3) CrO2 (4) All
(2) Increasing temperature
20. If a is the edge length of unit cell, then which one is
(3) By decreasing temperature
correct relationship -
(4) None of these
(1) For simple cubic lattice, Radius of metal atom =   a
14. A certain sample of cuprous sulphide is found to 2
have composition Cu1.8S, because of incorporation (2) √ 3a
of Cu2+ ions in the lattice. What is the mole % of For bcc lattice, Radius of metal atom = 
4
Cu2+ in total copper content in this crystal ? a
(3) For fcc lattice, Radius of metal atom = 
(1) 99.8% (2) 11.11% 2 √2
(3) 88.88% (4) None of these (4) All of these
15. The appearance of colour in solid alkali metal 21. Select the incorrect statement:
halides is generally due to :-
(1) Stoichiometry of crystal remains uneffected
(1) Frenkel defect (2) Interstitial positions due to schottky defect
(3) F-centres (4) Schottky defects (2) Frenkel defect is usually shown by ionic
16. At room temperature Zinc oxide is white in colour compounds having low coordination number
but on heating turns yellow. This is due to (3) F-centres generation is responisble factor for
(1) Metal excess defect (presence of extra cations imparting the colour to the crystal
at interstitial sites)
(4) Density of crystal always increases due to
(2) Metal excess defect (anionic vacancies) substitutional impurity defect
(3) Metal deficiency defect
22. Which of the following is incorrect :-
(4) Vacancy defect
(1) In ZnS co-ordination number is (4,4)
17. Analysis shows that nickel oxide has formula
(2) In NaCl solid , Radius ratio is 0.414 ⩽  rNa+ < 0.732
Ni0.98O. What percentage of nickel exist as Ni2+ rCl−
and Ni3+ ions respectively? (3) ZnS is crystallise in Body centered cubic unit lattice 
(1) 99%, 1% (2) 98%, 2% (4) In one unit cell of diamond there are 8
(3) 97%, 3% (4) 96%, 4% carbon present

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