Professional Documents
Culture Documents
Laboratory Manual
Faculty of Applied Medical Sciences
Department of Basic Medical Sciences
Instructor
Dr. Amal Abu-Almakarem
1444H
1
Contents
Safety In the General Chemistry Laboratory
General Chemistry Laboratory Glassware
Experiment 1: Densities of Some liquids& Solids
Experiment 2: Physical Methods for Separation mixture
Experiment 3: Identification of Solutions (acidic, basic, neutral)
Experiment 4: Types of Chemical Reactions
Experiment 5: Identification of Metal ions and Inorganic
Compounds by their Chemical Reaction
Experiment 6: Identification of Common Chemicals
Experiment 7: Determination of Molecular Weight of a Volatile
Liquid
Experiment 8: Determination of Acid Content in
Vinegar
تعال إلى املختبر وأنت.ربما تكون أفضل قاعدة لسالمة املختبر يمكن أن نقدمها لك هي التفكير والتفكير في املستقبل
مستعد واعرف بالضبط ما تريد القيام به ؛ قم بإعداد مخطط تفصيلي للعمل املخبري الخاص بك حتى تعرف ما هو
الوقت اإلضافي املستثمر في العمل بعناية وبوتيرة. ال تحاول تسريع األمور في املختبر. اعمل ببطء وحذر.التالي
. وستكون نتائجك بال شك أفضل، محسوبة يتم تعويضه أكثر من خالل الكفاءة الناتجة عن التخطيط املسبق الدقيق
2
اللهم ال سهل اال ما جعلته سهال و أنت تجعل الحزن إذا شئت سهال
Perhaps the best rule for laboratory safety we can give you is to think,
and to think ahead. Come to the laboratory prepared and know exactly what
you want to do; prepare an outline of your lab work so you know what’s
next. Work slowly and carefully. Don’t try to rush things in the laboratory.
The extra time invested in working carefully and at a measured pace is
more than compensated by the efficiency resulting from careful prior
planning, and your results will undoubtedly be better.
Lab Coats or Aprons: The Chemistry Laboratory requires that students
wear laboratory coats or aprons when working in an instructional
laboratory.. يتطلب مختبر الكيمياء أن يرتدي الطالب معاطف أو مآزر املختبر عند العمل في مختبر تعليمي:🥼 معاطف أو مآزر املختبر 7
Shose must be worn in the labratory at all times these must be covered-top.
No sandals, no clothes you love more than life, no contact lenses, and long
pants are preferable to shorts or short skirts. Tie long hair back. Wear safety
وال مالبس تحبينها أكثر من، ال صنادل.يجب ارتداء األحذية في املختبر في جميع األوقات التي يجب أن تكون مغطاة
goggles and a lab coat. وال، الحياةِ ارتد نظارات. اربطي الشعر الطويل للخلف. والسراويل الطويلة أفضل من السراويل القصيرة أو التنانير القصيرة، عدسات الصقة
.واقية ومعطفًا للمختبر
Safety Equipment: Walk through the laboratory and learn the locations of
all the safety equipment well enough so that you can indicate their locations
on a map of the laboratory. You should know the place of :
II • Exit Doors • أبواب الخروج تجول في املختبر وتعرف على مواقع جميع معدات السالمة:معدات السالمة
example, hydrochloric acid and sodium hydroxide will give you salt and
water, but the reaction could break your glassware or splash the reactants
onto you if you aren't careful!
. بالتأكيد لن يتم التسامح مع أي خداع أو لعب عبث في املختبر:التسكع بالجوار
Don't Taste or Sniff Chemicals: For many chemicals, if you can smell
them then you are exposing yourself to a dose that can harm you! If the
safety information says that a chemical should only be used inside a fume
hood, then don't use it anywhere else. This is not cooking class - don't taste
your experiments!
Waste: Use the proper container to dispose of all waste generated in the
laboratory. . استخدم الحاوية املناسبة للتخلص من جميع النفايات املتولدة في املختبر:النفايات
إذا كان، بالنسبة للعديد من املواد الكيميائية:ال تتذوق أو تشم املواد الكيميائية
فأنت تعرض نفسك لجرعة يمكن أن تؤذيك! إذا كانت معلومات، بإمكانك شمها
فال، السالمة تنص على أنه يجب استخدام مادة كيميائية داخل غطاء دخان فقط
! ال تتذوق تجاربك- هذه ليست صف طبخ.تستخدمه في أي مكان آخر
4
زجاجيات مختبر الكيمياء العامة
I 2 3 4
Erlenmeyer Flask
Beaker (Conical Flask) Test Tube Measuring
Cylinder
5 6 7 8
a
i
Buchner am Tripod
Digital Balance
Funnel Thermometer Na
13 14 15 16
w
250
Round
Bottom Volumetric flask
Test tube Bunsen Burner Flask
holder
5
تجارب
Experiments
6
1
volume for a liquid is milliliters (mL), and the unit of volume for a solid is اﻟﻤﺎدة ووﺣﺪة ﺣﺠﻢ، (mL)
اﻟﺼﻠﺒﺔ ھﻲ ﺳﻨﺘﯿﻤﺘﺮ ﻣﻜﻌﺐ
a cubic centimeter (cm3). Therefore, the density of a liquid is usually اﻟﺘﻌﺒﯿﺮﻟﻜﻞﻋﻦ ﯾﺘﻢ، ﻟﺬﻟﻚ.(cm3)
ﻛﺜﺎﻓﺔ اﻟﺴﺎﺋﻞ ﻋﺎدةً ﺑﺎﻟﺠﺮام
expressed as grams per milliliter (g/mL), and the density of asolid is ﺑﺎﻟﺠﺮام وﯾﺘﻢ اﻟﺘﻌﺒﯿﺮ، ( ﻣﻞ/ ﻣﻠﯿﻠﺘﺮ )ﺟﻢ
ﻋﻦ ﻛﺜﺎﻓﺔ اﻟﻤﺎدة اﻟﺼﻠﺒﺔ
expressed as grams per cubic centimeter (g/cm3). [Note: 1 mL =1 cm3] [3 ﺳﻢﺳﻢ/1)ﺟﻢ ﻟﻜﻞ ﺳﻨﺘﯿﻤﺘﺮ ﻣﻜﻌﺐ
= ﻣﻞ1 : ]ﻣﻼﺣﻈﺔ.(3
Procedure
Part A: Determining the Density of Water
1. Record the mass of a clean and dry 10.00 mL graduated cylinder to
0.001g. ﺟﻢ0.001 ﻣﻞ ﺣﺘﻰ10.00 ﺳﺠﻞ ﻛﺘﻠﺔ أﺳﻄﻮاﻧﺔ ﻣﺪرﺟﺔ ﻧﻈﯿﻔﺔ وﺟﺎﻓﺔ-1
2. Fill this 10 mL graduated cylinder approximately halfway with
distilled water. Record the mass of your graduated cylinder with
this volume of water in it. ﺑﺎﻟﻤﺎء.ﺑﺪاﺧﻠﮭﺎ ﻣﻞ ﻓﻲ ﻣﻨﺘﺼﻒ اﻟﻄﺮﯾﻖ ﺗﻘﺮﯾﺒًﺎ10 اﻣﻸ ھﺬه اﻷﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ ﺳﻌﺔ-2
ﺳﺠﻞ ﻛﺘﻠﺔ اﻷﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ ﺑﮭﺬا اﻟﺤﺠﻢ ﻣﻦ اﻟﻤﺎء.اﻟﻤﻘﻄﺮ
3. Calculate the mass of the water.. اﺣﺴﺐ ﻛﺘﻠﺔ اﻟﻤﺎء-3
4. Read the volume of water using the bottom of the meniscus as
demonstrated by your instructor. Record your volume to the
hundredth decimal place value (i.e. 4.23 mL). ﺳﺠﻞ.ﻣﻌﻠﻤﻚ اﻗﺮأ ﺣﺠﻢ اﻟﻤﺎء ﺑﺎﺳﺘﺨﺪام ﻗﺎع اﻟﻐﻀﺮوف اﻟﻤﻔﺼﻠﻲ ﻛﻤﺎ أوﺿﺢ-4
.( ﻣﻞ4.23 اﻟﺤﺠﻢ اﻟﺨﺎص ﺑﻚ إﻟﻰ اﻟﻘﯿﻤﺔ اﻟﻌﺸﺮﯾﺔ اﻟﻤﺎﺋﺔ )أي
5. Calculate the density of the water. (Remember: density =
mass/volume). .( اﻟﺤﺠﻢ/ اﻟﻜﺜﺎﻓﺔ = اﻟﻜﺘﻠﺔ: اﺣﺴﺐ ﻛﺜﺎﻓﺔ اﻟﻤﺎء )ﺗﺬﻛﺮ-5
. ﺗﺤﺪﯾﺪ ﻛﺜﺎﻓﺔ اﻟﺤﻞ:اﻟﺠﺰء ب
ﯾﺘﻢ وﺻﻒ ﺗﺮﻛﯿﺰ اﻟﻤﺤﻠﻮل أﺣﯿﺎﻧًﺎ ﻣﻦ ﺣﯿﺚ ﺗﻜﻮﯾﻦ اﻟﻨﺴﺒﺔ اﻟﻤﺌﻮﯾﺔ ﻟﻠﻤﺤﻠﻮل ﻋﻠﻰ:ﻣﻼﺣﻈﺔ
Part B: Determining the Density of a Solution. ﺟﻢ ﻣﻦ ﻛﻠﻮرﯾﺪ5 ( ﻋﻠﻰNaCl) ٪5 ﯾﺤﺘﻮي ﻣﺤﻠﻮل ﻣﻠﺢ، ﻋﻠﻰ ﺳﺒﯿﻞ اﻟﻤﺜﺎل.أﺳﺎس اﻟﻮزن
. ﺟﻢ ﻣﻦ اﻟﻤﺎء95 ﺟﻢ ﻣﻦ اﻟﻤﻠﺢ ﻟﻜﻞ5 وھﻮ ﻣﺎ ﯾﻌﺎدل، ﺟﻢ ﻣﻦ اﻟﻤﺤﻠﻮل100 اﻟﺼﻮدﯾﻮم ﻟﻜﻞ
NOTE: The concentration of a solution is sometimes described in terms of
the solution's percentage composition on a weight basis. For example,a
5% salt (NaCl) solution contains 5 g of NaCl per 100 g of solution, which
corresponds to 5 g of salt per 95 g of water.
1. Use the clean and dry (the same 10 mL) graduated cylinder. Fill the
graduated cylinder halfway with the 5% NaCl solution. Record the
mass of the graduated cylinder and salt solution.
2. Calculate the mass of the salt solution. (You determined the mass
اﻣﻸ اﻻﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ ﺣﺘﻰ.( ﻣﻞ10 اﺳﺘﺨﺪم اﻷﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ اﻟﻨﻈﯿﻔﺔ واﻟﺠﺎﻓﺔ )ﻧﻔﺲ.1
7 . ﺳﺠﻞ ﻛﺘﻠﺔ اﻻﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ وﻣﺤﻠﻮل اﻟﻤﻠﺢ.٪5 اﻟﻤﻨﺘﺼﻒ ﺑﻤﺤﻠﻮل ﻛﻠﻮرﯾﺪ اﻟﺼﻮدﯾﻮم ﺑﻨﺴﺒﺔ
)ﻟﻘﺪ ﺣﺪدت ﻛﺘﻠﺔ اﻷﺳﻄﻮاﻧﺔ اﻟﻔﺎرﻏﺔ اﻟﻤﺘﺪرﺟﺔ ﻓﻲ اﻟﺠﺰء أ )ﺗﺨﻠﺺ ﻣﻦ. اﺣﺴﺐ ﻛﺘﻠﺔ ﻣﺤﻠﻮل اﻟﻤﻠﺢ.2
.(اﻟﻤﺤﻠﻮل ﻓﻲ اﻟﺤﻮض ؛ ﻻ ﺗﻌﻮد إﻟﻰ زﺟﺎﺟﺔ اﻟﻜﺎﺷﻒ
. ﺳﺠﻞ ﺣﺠﻢ اﻟﺤﻞ.3
.٪5 اﺣﺴﺐ ﻛﺜﺎﻓﺔ ﻣﺤﻠﻮل ﻛﻠﻮرﯾﺪ اﻟﺼﻮدﯾﻮم ﺑﻨﺴﺒﺔ.4
. ﻛﻠﻮرﯾﺪ اﻟﺼﻮدﯾﻮم٪20 و٪15 و٪10 ﻣﻊ ﺣﻠﻮل4 إﻟﻰ1 ﻛﺮر اﻟﺨﻄﻮات ﻣﻦ.5
. ﻟﻠﺤﻞ ﻏﯿﺮ اﻟﻤﻌﺮوف4 إﻟﻰ1 ﻛﺮر اﻟﺨﻄﻮات ﻣﻦ. اﻟﺤﺼﻮل ﻋﻠﻰ ﺣﻞ ﻏﯿﺮ ﻣﻌﺮوف.6
POSTLAB QUESTIONS:
1. Compare a 50 mL beaker and a 50 mL graduated cylinder. :POSTLAB أﺳﺌﻠﺔ
Which is more precise? Why? .ﻣﻞ 50 ﺳﻌﺔ ﻣﺪرﺟﺔ واﺳﻄﻮاﻧﺔ ﻣﻞ 50 ﺳﻌﺔ ﻗﺎرن ﺑﯿﻦ دورق.1
اﺷﺮح اﻟﻜﺜﺎﻓﺔ ﺑﺄﺳﻠﻮﺑﻚ اﻟﺨﺎص.3 أﯾﮭﻤﺎ أﻛﺜﺮ دﻗﺔ؟ ﻟﻤﺎذا؟
3. Explain density in your own words
ﺳﺠﻞ ﺣﺠﻢ. ﻣﻞ ﻣﺘﺪرﺟﺔ50.0 ﻣﻞ )ﻟﯿﺲ ﻣﻦ اﻟﻀﺮوري أن ﺗﻜﻮن دﻗﯿﻘﺔ( ﻣﻦ اﻟﻤﺎء اﻟﻤﻘﻄﺮ ﻓﻲ اﺳﻄﻮاﻧﺔ ﻧﻈﯿﻔﺔ وﺟﺎﻓﺔ30 ﺻﺐ ﺣﻮاﻟﻲ.1
. ﻣﻞ( ﻣﻦ ﺧﻼل ﻗﺮاءة اﻟﺠﺰء اﻟﺴﻔﻠﻲ ﻣﻦ اﻟﻐﻀﺮوف اﻟﻤﻔﺼﻠﻲ31.2 اﻟﻤﺎء إﻟﻰ اﻟﻘﯿﻤﺔ اﻟﻌﺎﺷﺮة )أي
condenser. ﺗﻨﺘﻘﻞ اﻷﺻﺒﺎغ ﻷﻋﻠﻰ ﻓﻲ ورﻗﺔ اﻟﻜﺮوﻣﺎﺗﻮﻏﺮاﻓﯿﺎ ﻋﻠﻰ ﻣﺴﺎﻓﺎت ﻣﺨﺘﻠﻔﺔ ﻗﺒﻞ أن ﺗﺘﻤﻜﻦ ﻣﻦ اﻟﺒﻘﺎء ﻓﻲ. ﻟﻔﺼﻞ اﻷﺻﺒﺎغ اﻟﻤﻠﻮﻧﺔ اﻟﻤﺨﺘﻠﻔﺔ- اﻟﻠﻮﻧﻲ-٥
. وﺑﺎﻟﺘﺎﻟﻲ ﺗﻨﻔﺼﻞ ﻋﻦ ﺑﻌﻀﮭﺎ اﻟﺒﻌﺾ، ﺗﺘﺤﺮك اﻷﺻﺒﺎغ اﻷﻛﺜﺮ ﻗﺎﺑﻠﯿﺔ ﻟﻠﺬوﺑﺎن إﻟﻰ أﻋﻠﻰ ﻣﻦ اﻷﺻﺒﺎغ اﻷﻗﻞ ﻗﺎﺑﻠﯿﺔ ﻟﻠﺬوﺑﺎن.اﻟﻤﺤﻠﻮل
• Chromatography - To separate different coloured dyes. The dyes
travel upthe chromatography paper at different distances before they
cannot remain in solution. The more soluble dyes move further up
than the less soluble ones, hence separating from each other.
• Adsorption/desorption – This is used to separate liquid or gaseous
mixtures that contain at least one component that adsorbs.
Some of the example mixtures that can be separated using the above
ﯾﺴﺘﺨﺪم ھﺬا ﻟﻔﺼﻞ اﻟﻤﺨﺎﻟﯿﻂ اﻟﺴﺎﺋﻠﺔ أو اﻟﻐﺎزﯾﺔ اﻟﺘﻲ ﺗﺤﺘﻮي ﻋﻠﻰ- ازاﻟﮫ اﻻﻣﺘﺰاز/ (آﻟﯿﮫ اﻻﻣﺘﺰاز)اﻻدﻣﺼﺎص
mentioned techniques: : وﻣﻦ أﻣﺜﻠﺔ اﻟﻤﺨﺎﻟﯿﻂ اﻟﺘﻲ ﯾﻤﻜﻦ ﻓﺼﻠﮭﺎ ﺑﺎﺳﺘﺨﺪام اﻟﺘﻘﻨﯿﺎت اﻟﻤﺬﻛﻮرة أﻋﻼه، ﻣﻜﻮن واﺣﺪ ﻋﻠﻰ اﻷﻗﻞ ﯾﻤﺘﺺ
(1) separating dyes in inks, or chlorophyll in plants (ethanol as
solvent) - chromatography;
(2) separating sand from water - filtration; ( ﻓﺼﻞ اﻷﺻﺒﺎغ ﻓﻲ اﻷﺣﺒﺎر أو اﻟﻜﻠﻮروﻓﯿﻞ ﻓﻲ اﻟﻨﺒﺎﺗﺎت )ﻣﺴﺎﻋﺪ1
اﻹﯾﺜﺎﻧﻮل( ﻛﺮوﻣﺎﺗﻮﻏﺮاﻓﯿﺎ ؛
(3) separating ethanol and water - fractional distillation; اﻟﺘﺮﺷﯿﺢ ؛- ( ﻓﺼﻞ اﻟﺮﻣﻞ ﻋﻦ اﻟﻤﺎء2)
(4) separating water from ink - simple distillation; ( ﻓﺼﻞ اﻹﯾﺜﺎﻧﻮل واﻟﺘﻘﻄﯿﺮ اﻟﺠﺰﺋﻲ ﺑﺎﻟﻤﺎء ؛3)
ﺗﻘﻄﯿﺮ ﺑﺴﯿﻂ ؛- ( ﻓﺼﻞ اﻟﻤﺎء ﻋﻦ اﻟﺤﺒﺮ4)
(5) separating salt from water – evaporation اﻟﺘﺒﺨﺮ- ( ﻓﺼﻞ اﻟﻤﻠﺢ ﻋﻦ اﻟﻤﺎء5)
9
( ﺑﺎﺳﺘﺨﺪام اﻟﻤﻐﻨﺎطﯿﺲ )اﻟﻤﻐﻨﺎطﯿﺲ ﯾﻠﺘﺼﻖ ﺑﺎﻟﺤﺪﯾﺪ وﻟﯿﺲ اﻟﺮﻣﻞ- ( ﻓﺼﻞ اﻟﺤﺪﯾﺪ ﻋﻦ اﻟﺮﻣﻞ6
(6) separating iron from sand – using magnet ( The magnet sticks
the iron but not the sand)
Diagrams below show suggested experiment setting for the various separation
techniques. .ﺗﻮﺿﺢ اﻟﺮﺳﻮم اﻟﺒﯿﺎﻧﯿﺔ أدﻧﺎه إﻋﺪاد اﻟﺘﺠﺮﺑﺔ اﻟﻤﻘﺘﺮح ﻟﺘﻘﻨﯿﺎت اﻟﻔﺼﻞ اﻟﻤﺨﺘﻠﻔﺔ
Filtration Evaporation
10
اﻟﻤﻔﮭﻮم اﻟﻜﺎﻣﻦ وراء. وﻏﺎﻟﺒًﺎ ﻣﺎ ﺗﻜﻮن أﻗﻞ ﻣﻦ ﻗﻄﺮة، ھﻨﺎك ﺣﺎﺟﺔ إﻟﻰ ﻛﻤﯿﺔ ﺻﻐﯿﺮة ﻓﻘﻂ ﻣﻦ ﻋﯿﻨﺎت اﻟﺨﻠﯿﻂ، ﻓﻲ ﺗﻘﻨﯿﺔ اﻟﻜﺮوﻣﺎﺗﻮﻏﺮاﻓﯿﺎ
ﻓﺈن اﻟﻤﻜﻮن اﻷﻗﻞ، ﻋﻨﺪﻣﺎ ﯾﺘﺤﺮك اﻟﻤﺬﯾﺐ ﻷﻋﻠﻰ ﻋﻠﻰ اﻟﻮرق.ھﺬه اﻟﺘﻘﻨﯿﺎت ھﻮ أن اﻟﻤﻜﻮﻧﺎت اﻟﻤﺨﺘﻠﻔﺔ ﻓﻲ اﻟﺨﻠﯿﻂ ﻟﮭﺎ ﻗﺎﺑﻠﯿﺔ ذوﺑﺎن ﻣﺨﺘﻠﻔﺔ
وﻣﻦ ﺛﻢ ﺳﯿﻨﻔﺼﻞ اﻟﺨﻠﯿﻂ ﻓﻲ اﻟﻨﮭﺎﯾﺔ إﻟﻰ.ﻗﺎﺑﻠﯿﺔ ﻟﻠﺬوﺑﺎن ﺳﻮف ﯾﻨﺘﻘﻞ ﺑﻤﻌﺪل أﺑﻄﺄ ﻣﻦ ﺗﻠﻚ اﻟﻤﻮﺟﻮدة ﻓﻲ اﻟﻤﻜﻮﻧﺎت اﻷﻛﺜﺮ ﻗﺎﺑﻠﯿﺔ ﻟﻠﺬوﺑﺎن
ﻣﺜﻞ اﻷﻟﻮاح اﻟﺒﻼﺳﺘﯿﻜﯿﺔ اﻟﺮﻗﯿﻘﺔ، ﯾﺘﻢ اﺳﺘﺨﺪام وﺳﯿﻂ أﻛﺜﺮ ﺗﻌﻘﯿﺪًا، ﻓﻲ ﺑﻌﺾ اﻷﺣﯿﺎن.ﺑﻘﻊ ﻣﻠﻮﻧﺔ ﻣﺨﺘﻠﻔﺔ ﺣﯿﺚ ﯾﺘﺤﺮك اﻟﻤﺬﯾﺐ إﻟﻰ اﻷﻋﻠﻰ
.اﻟﻤﻄﻠﯿﺔ ﺑﺄﻛﺴﯿﺪ اﻷﻟﻮﻣﻨﯿﻮم اﻟﻨﻘﻲ اﻟﻨﺎﻋﻢ ﺟﺪًا
In chromatography technique, only a small amount of
mixture samples are required, often as little as a drop.
The concept behind this techniques is that different
constituentin a mixture have different solubility. As the
solvent moves up the paper the less soluble constituent
will travel at a slower rate than those of more soluble
constituents. Hence the mixture will eventually separate
into different colored spots as the solvent moves to the
top. Sometimes, more sophisticated medium is used,
such as thin plastic sheets coated with very fine pure
aluminium oxide.
ﯾﻜﻮن، ﺑﺎﻟﻨﺴﺒﺔ ﻟﻠﺘﻘﻄﯿﺮ اﻟﻌﺎدي.ﯾﻮﺿﺢ اﻟﺮﺳﻢ اﻟﺒﯿﺎﻧﻲ اﻟﻤﻮﺟﻮد ﻋﻠﻰ اﻟﯿﺴﺎر إﻋﺪاد اﻟﻤﻌﺪات ﻟﻠﺘﻘﻄﯿﺮ اﻟﺘﺠﺰﯾﺌﻲ
اﻟﮭﯿﻜﻞ اﻟﻤﻨﺤﻨﻲ ﻟﻌﻤﻮد اﻟﺘﺠﺰﺋﺔ ھﻮ زﯾﺎدة ﻣﺴﺎﺣﺔ اﻟﺴﻄﺢ. ﻓﯿﻤﺎ ﻋﺪا أﻧﮫ ﺗﺘﻢ إزاﻟﺔ ﻋﻤﻮد اﻟﺘﺠﺰﺋﺔ، اﻹﻋﺪاد ﻣﺸﺎﺑ ًﮭﺎ
. ﯾﺘﻜﻮن اﻟﻌﻤﻮد أﺣﯿﺎﻧًﺎ ﻣﻦ أﻧﺒﻮب ﻣﻌﺒﺄ ﺑﺈﺣﻜﺎم ﺑﺎﻟﺨﺮز اﻟﺰﺟﺎﺟﻲ.وﺗﺸﺠﯿﻊ ﺗﻜﺜﯿﻒ اﻟﺴﻮاﺋﻞ ﺑﻨﻘﺎط ﻏﻠﯿﺎن أﻋﻠﻰ
Diagram on the left shows
equipment set-up for fractional
distillation. For normal
distillation, the set-up is similar,
except that the fractionating
column is being removed. The
curving structure of the
fractionating column is to increase
the surface area and encourage
condensation of liquids with
higher boiling points.
Sometimes the column consists of
a tube tightly packed with glass
beads.
11
أ( ﻓﺼﻞ اﻟﺮﻣﻞ ﻋﻦ اﻟﻤﻠﺢ
ﻣﻮﺿﺤﯿﻦ اﻟﻮﺳﺎﺋﻞ، ﻣﺰﯾﺠﺎ ﻣﻦ اﻟﺮﻣﻞ واﻟﻤﻠﺢً ﯾﻔﺼﻞ اﻟﻄﻼب، ﻓﻲ ھﺬه اﻟﺘﺠﺮﺑﺔ
A) Separating sand and salt .اﻷﺳﺎﺳﯿﺔ ﻟﻔﺼﻞ ﺧﻠﯿﻂ ﻣﻦ ﻣﺎدة ﻏﯿﺮ ﻗﺎﺑﻠﺔ ﻟﻠﺬوﺑﺎن ﻋﻦ ﺧﻠﯿﻂ ﻣﻦ ﻣﺎدة ﻗﺎﺑﻠﺔ ﻟﻠﺬوﺑﺎن
In this experiment students separate a mixture of sand and salt,
illustrating the fundamental means of separating a mixture of an
insoluble material from one which is soluble.
اﻷﺟﮭﺰة واﻟﻤﻮاد اﻟﻜﯿﻤﯿﺎﺋﯿﺔ
دورق، ورق ﺗﺮﺷﯿﺢ، ﻗﻤﻊ ﻓﻠﺘﺮ، ﻗﻀﯿﺐ ﺗﺤﺮﯾﻚ زﺟﺎﺟﻲ، (3 ﺳﻢ250) دورق
Apparatus and chemicals . ﺧﻠﯿﻂ ﻣﻦ اﻟﺮﻣﻞ واﻟﻤﻠﺢ، ﻣﻮﻗﺪ ﺑﻨﺴﻦ، ﺣﻮض ﺗﺒﺨﯿﺮ، (3 ﺳﻢ250) ﻣﺨﺮوطﻲ
Beaker (250 cm3), Glass stirring rod, Filter funnel, Filter paper,
Conical flask (250 cm3), Evaporating basin, Bunsen burner, Mixture
of sand and salt.
Procedure
a) Pour the sand-salt mixture into the beaker so that it just covers
thebase.
b) Add about 50 cm3 of water or add water until the beaker is about
a) ﺻﺐ ﺧﻠﯿﻂ اﻟﻤﻠﺢ واﻟﺮﻣﻞ ﻓﻲ اﻟﺪورق ﺑﺤﯿﺚ ﯾﻐﻄﻲ اﻟﻘﺎﻋﺪة.
one- fifth full. b) ﻣﻦ اﻟﻤﺎء أو أﺿﻒ اﻟﻤﺎء ﺣﺘﻰ ﯾﻤﺘﻠﺊ اﻟﺪورق ﺑﺤﻮاﻟﻲ اﻟﺨﻤﺲ3 ﺳﻢ50 أﺿﻒ ﺣﻮاﻟﻲ.
c) Stir the mixture gently for a few minutes. c) ﻗﻠﺐ اﻟﺨﻠﯿﻂ ﺑﻠﻄﻒ ﻟﺒﻀﻊ دﻗﺎﺋﻖ.
d) ﻗﻢ ﺑﺘﺼﻔﯿﺔ اﻟﺨﻠﯿﻂ ﻓﻲ دورق ﻣﺨﺮوطﻲ اﻟﺸﻜﻞ.
d) Filter the mixture into a conical flask. e) ﺻﺐ اﻟﻤﺮﺷﺢ ﻓﻲ ﺣﻮض اﻟﺘﺒﺨﯿﺮ.
f) ﻻ ﺗﻘﺘﺮب ﻛﺜﯿﺮا: رﻋﺎﯾﮫ.("ﻗﻢ ﺑﺘﺴﺨﯿﻦ ﻣﺤﻠﻮل اﻟﻤﻠﺢ ﺑﺮﻓﻖ ﺣﺘﻰ ﯾﺒﺪأ ﻓﻲ ﺗﻘﻮﯾﺾ "اﻟﺒﺼﻖ.
e) Pour the filtrate into an evaporating basin. g) أﻏﻠﻖ ﻣﻮﻗﺪ ﺑﻨﺴﻦ واﺗﺮك اﻟﻤﻠﺢ اﻟﺮطﺐ ﯾﺠﻒ ﻓﻲ اﻟﻄﺒﻖ.
f) Heat the salt solution gently until it starts to decrepitate “spit”). CARE:
do not get too close.
g) Turn off the Bunsen burner and let the damp salt dry in the dish.
.ب( ﻓﺼﻞ اﻟﻤﺎء ﻋﻦ اﻟﻤﻠﺢ ﺑﺎﻟﺘﻘﻄﯿﺮ اﻟﺒﺴﯿﻂ
B) separation of water from a salt by simple distillation. :أھﺪاف
.• اﻟﺘﻌﺮف ﻋﻠﻰ ﺗﻘﻨﯿﺎت اﻟﺘﺮﺷﯿﺢ ﻟﻔﺼﻞ اﻟﻤﻮاد اﻟﺼﻠﺒﺔ ﻋﻦ اﻟﺴﻮاﺋﻞ
Objectives: .• اﻟﺘﻌﺮف ﻋﻠﻰ ﺗﻘﻨﯿﺎت اﻟﺘﻘﻄﯿﺮ ﻟﻔﺼﻞ اﻟﻤﺎدة اﻟﻤﺬاﺑﺔ ﻋﻦ اﻟﻤﺎدة اﻟﻤﺬاﺑﺔ
• To learn about filtration techniques for the separation of solids
fromliquids.
• To learn about distillation techniques for the separation of a
dissolvedsubstance from the dissolving substance.
Background:
Distillation consists of heating a liquid until it vaporizes, and then
condensing the vapor and collecting it in a separate container. Distillation
is used to purify liquids, or to separate mixtures of liquids that have
different boiling points. There are many types of distillation, each of which
has a distinct purpose. For this experiment you will do a simple distillation :ﺧﻠﻔﯿﺔ
. ﺛﻢ ﺗﻜﺜﯿﻒ اﻟﺒﺨﺎر وﺗﺠﻤﯿﻌﮫ ﻓﻲ وﻋﺎء ﻣﻨﻔﺼﻞ، ﯾﺘﻜﻮن اﻟﺘﻘﻄﯿﺮ ﻣﻦ ﺗﺴﺨﯿﻦ ﺳﺎﺋﻞ ﺣﺘﻰ ﯾﺘﺒﺨﺮ
in order to obtain pure water from salt water. ھﻨﺎك. أو ﻟﻔﺼﻞ ﻣﺨﺎﻟﯿﻂ اﻟﺴﻮاﺋﻞ اﻟﺘﻲ ﻟﮭﺎ ﻧﻘﺎط ﻏﻠﯿﺎن ﻣﺨﺘﻠﻔﺔ، ﯾﺴﺘﺨﺪم اﻟﺘﻘﻄﯿﺮ ﻟﺘﻨﻘﯿﺔ اﻟﺴﻮاﺋﻞ
Materials: ﻓﻲ ھﺬه اﻟﺘﺠﺮﺑﺔ ﺳﻮف ﺗﻘﻮم ﺑﻌﻤﻞ ﺗﻘﻄﯿﺮ. وﻟﻜﻞ ﻣﻨﮭﺎ ﻏﺮض ﻣﻤﯿﺰ، اﻟﻌﺪﯾﺪ ﻣﻦ أﻧﻮاع اﻟﺘﻘﻄﯿﺮ
.ﺑﺴﯿﻂ ﻣﻦ أﺟﻞ اﻟﺤﺼﻮل ﻋﻠﻰ ﻣﺎء ﻧﻘﻲ ﻣﻦ اﻟﻤﺎء اﻟﻤﺎﻟﺢ
100 mL round-bottom flask, water condenser, distillation head,
thermometer adapter, vacuum adapter, thermometer, heating mantle,
power supply, 50 mL graduated cylinder, 2 beakers, 3 test tubes, small
clamps for organic, blue glassware clamps, boiling chips, salt water, silver :ﻣﻮاد
nitrate. ﺣﺮارة ﻣﻘﯿﺎس ، ﻓﺮاغ ﻣﺤﻮل ، ﺣﺮارة ﻣﻘﯿﺎس ﻣﺤﻮل ، ﺗﻘﻄﯿﺮ رأس ، ﻣﺎء ﻣﻜﺜﻒ ، ﻣﻞ 100 داﺋﺮي
ﻣﺸﺎﺑﻚ، أﻧﺎﺑﯿﺐ اﺧﺘﺒﺎر3 ، أﻛﻮاب2 ، ﻣﻞ ﻣﺘﺪرﺟﺔ50 أﺳﻄﻮاﻧﺔ، ﻣﺼﺪر طﺎﻗﺔ، ﻋﺒﺎءة ﺗﺴﺨﯿﻦ،
دورق
Safety Precautions: . رﻗﺎﺋﻖ اﻟﻐﻠﯿﺎن واﻟﻤﺎء اﻟﻤﺎﻟﺢ وﻧﺘﺮات اﻟﻔﻀﺔ، ﻣﺸﺎﺑﻚ اﻷواﻧﻲ اﻟﺰﺟﺎﺟﯿﺔ اﻟﺰرﻗﺎء، ﺻﻐﯿﺮة ﻟﻠﻌﻀﻮﯾﺔ
Remember not to touch the glassware when it is very hot. Let it cool down
before you disassemble it. :اﺣﺘﯿﺎطﺎت اﻟﺴﻼﻣﺔ
12 اﺗﺮﻛﮫ ﯾﺒﺮد ﻗﺒﻞ أن ﺗﻘﻮم ﺑﺘﻔﻜﯿﻜﮫ.ﺗﺬﻛﺮ أﻻ ﺗﻠﻤﺲ اﻷواﻧﻲ اﻟﺰﺟﺎﺟﯿﺔ ﻋﻨﺪﻣﺎ ﺗﻜﻮن ﺷﺪﯾﺪة اﻟﺴﺨﻮﻧﺔ
Procedures:
1. Set the 100 ml round-bottom flask in the heating mantle and clamp it to
a ring stand. Place two boiling chips in the flask, measure out 50 ml of the
salt-water solution, and transfer it to the flask.
2. Assemble the rest of the distillation apparatus .
connecting the pieces with the clips provided. Make sure the entire
thermometer bulb is below the sidearm of the distillation head. Water
should go in on the lower side of the condenser and exit on the upper side.
Clamp the loose hose end over the sink so it doesn’t spray the lab. Place a
beaker below the end of the condenser to receive the condensed liquid.
3. Heat the flask with the heating mantle so that the liquid boils gently. The
very first liquid collected might be contaminated with organic material or
salt from the glassware, so you will throw out the first ml of distillate. To
do this, switch to a fresh beaker after about 1 ml has been collected. Record
the temperature at this point as the beginning of the collection phase.
Throw out the liquid in the first beaker, but keep the beaker at you work
area because you will use it again.
4. Continue collecting liquid until about half of the original mixture has
been distilled (it is never safe to distill to dryness). Record the temperature
as the end of the collection phase, turn off the heating mantle. Liquid will
continue to collect for a while. Switch the beakers again, putting the
original beaker in place to catch the last of the liquid – this is just so it
doesn’t end up on the counter. Remove the heating mantle. Let the
apparatus cool before taking it apart.
5. Prepare three test tubes for chloride ion testing, one 2 mL sample
(approx.) of each of the following: deionized water from the lab, the
original mixture, and the distillate.
6. Add 5 drops of silver nitrate solution to each test tube. The presence of
chloride ion in solution is indicated by formation of the white precipitate
AgCl. Relative concentrations are indicated by the amount of precipitate
formed. Record your observations. Remove any tape from your test tubes,
pour the solutions into the waste beaker and rinse the tubes in the sink
before placing them in the dirty glassware bin.
. واﻧﻘﻠﮫ إﻟﻰ اﻟﺪورق، ﻣﻞ ﻣﻦ ﻣﺤﻠﻮل اﻟﻤﺎء اﻟﻤﺎﻟﺢ50 وﻗﻢ ﺑﻘﯿﺎس، ﺿﻊ ﺷﺮﯾﺤﺘﯿﻦ ﻣﻐﻠﯿﺘﯿﻦ ﻓﻲ اﻟﺪورق. ﻣﻞ ﻓﻲ ﻋﺒﺎءة اﻟﺘﺴﺨﯿﻦ وﺛﺒﺘﮭﺎ ﺑﺤﺎﻣﻞ داﺋﺮي100 ﺿﻊ اﻟﻘﺎرورة اﻟﻤﺴﺘﺪﯾﺮة ﺳﻌﺔ.1
ﯾﺠﺐ أن ﯾﺪﺧﻞ اﻟﻤﺎء ﻓﻲ اﻟﺠﺎﻧﺐ اﻟﺴﻔﻠﻲ ﻣﻦ. ﺗﺄﻛﺪ ﻣﻦ أن ﻟﻤﺒﺔ ﻣﻘﯿﺎس اﻟﺤﺮارة ﺑﺎﻟﻜﺎﻣﻞ أﺳﻔﻞ اﻟﺴﻼح اﻟﺠﺎﻧﺒﻲ ﻟﺮأس اﻟﺘﻘﻄﯿﺮ. رﺑﻂ اﻟﻘﻄﻊ ﻣﻊ اﻟﻤﺸﺎﺑﻚ اﻟﻤﻘﺪﻣﺔ. ﻗﻢ ﺑﺘﺠﻤﯿﻊ ﺑﺎﻗﻲ ﺟﮭﺎز اﻟﺘﻘﻄﯿﺮ.2
. ﺿﻊ ﻛﻮﺑًﺎ أﺳﻔﻞ ﻧﮭﺎﯾﺔ اﻟﻤﻜﺜﻒ ﻻﺳﺘﻘﺒﺎل اﻟﺴﺎﺋﻞ اﻟﻤﻜﺜﻒ. ﺛﺒﺖ طﺮف اﻟﺨﺮطﻮم اﻟﺴﺎﺋﺐ ﻓﻮق اﻟﺤﻮض ﺣﺘﻰ ﻻ ﯾﺮش اﻟﻤﺨﺘﺒﺮ.اﻟﻤﻜﺜﻒ وﯾﺨﺮج ﻣﻦ اﻟﺠﺎﻧﺐ اﻟﻌﻠﻮي
ﻟﺬﻟﻚ ﺳﻮف ﺗﺘﺨﻠﺺ ﻣﻦ اﻟﻤﻠﻠﯿﻠﺘﺮ اﻷول ﻣﻦ، ﻗﺪ ﯾﻜﻮن اﻟﺴﺎﺋﻞ اﻷول اﻟﺬي ﺗﻢ ﺟﻤﻌﮫ ﻣﻠﻮﺛًﺎ ﺑﻤﻮاد ﻋﻀﻮﯾﺔ أو ﻣﻠﺢ ﻣﻦ اﻷواﻧﻲ اﻟﺰﺟﺎﺟﯿﺔ. ﺳﺨﻦ اﻟﻘﺎرورة ﺑﻌﺒﺎءة اﻟﺘﺴﺨﯿﻦ ﺣﺘﻰ ﯾﻐﻠﻲ اﻟﺴﺎﺋﻞ ﺑﺮﻓﻖ.3
ﺳﺠﻞ درﺟﺔ اﻟﺤﺮارة ﻓﻲ ھﺬه اﻟﻤﺮﺣﻠﺔ. ﻣﻞ1 ﻗﻢ ﺑﺎﻟﺘﺒﺪﯾﻞ إﻟﻰ دورق طﺎزج ﺑﻌﺪ ﺟﻤﻊ ﺣﻮاﻟﻲ، ﻟﻠﻘﯿﺎم ﺑﺬﻟﻚ.ﻧﻮاﺗﺞ اﻟﺘﻘﻄﯿﺮ
. ﻟﻜﻦ اﺣﺘﻔﻆ ﺑﺎﻟﺪورق ﻓﻲ ﻣﻨﻄﻘﺔ ﻋﻤﻠﻚ ﻷﻧﻚ ﺳﺘﺴﺘﺨﺪﻣﮫ ﻣﺮة أﺧﺮى، ﺗﺨﻠﺺ ﻣﻦ اﻟﺴﺎﺋﻞ ﻓﻲ اﻟﺪورق اﻷول.ﻛﺒﺪاﯾﺔ ﻟﻤﺮﺣﻠﺔ اﻟﺘﺠﻤﯿﻊ
وأوﻗﻒ ﺗﺸﻐﯿﻞ ﻋﺒﺎءة، ﺳﺠﻞ درﺟﺔ اﻟﺤﺮارة ﻛﻨﮭﺎﯾﺔ ﻣﺮﺣﻠﺔ اﻟﺘﺠﻤﯿﻊ.( اﺳﺘﻤﺮ ﻓﻲ ﺟﻤﻊ اﻟﺴﺎﺋﻞ ﺣﺘﻰ ﯾﺘﻢ ﺗﻘﻄﯿﺮ ﺣﻮاﻟﻲ ﻧﺼﻒ اﻟﺨﻠﯿﻂ اﻷﺻﻠﻲ )ﻟﯿﺲ ﻣﻦ اﻵﻣﻦ أﺑﺪًا اﻟﺘﻘﻄﯿﺮ ﺣﺘﻰ اﻟﺠﻔﺎف.4
ﻗﻢ. وھﺬا ﻓﻘﻂ ﺣﺘﻰ ﻻ ﯾﻨﺘﮭﻲ ﺑﮫ اﻷﻣﺮ ﻋﻠﻰ اﻟﻤﻨﻀﺪة، ﺿﻊ اﻟﺪورق اﻷﺻﻠﻲ ﻓﻲ ﻣﻜﺎﻧﮫ ﻻﻟﺘﻘﺎط آﺧﺮ ﺳﺎﺋﻞ، ﻗﻢ ﺑﺘﺒﺪﯾﻞ اﻷﻛﻮاب ﻣﺮة أﺧﺮى. ﺳﯿﺴﺘﻤﺮ اﻟﺴﺎﺋﻞ ﻓﻲ اﻟﺘﺠﻤﻊ ﻟﻔﺘﺮة ﻣﻦ اﻟﻮﻗﺖ.اﻟﺘﺴﺨﯿﻦ
. دع اﻟﺠﮭﺎز ﯾﺒﺮد ﻗﺒﻞ ﺗﻔﻜﯿﻜﮫ.ﺑﺈزاﻟﺔ ﻋﺒﺎءة اﻟﺘﺪﻓﺌﺔ
. وﻧﻮاﺗﺞ اﻟﺘﻘﻄﯿﺮ، واﻟﺨﻠﯿﻂ اﻷﺻﻠﻲ، ﻣﺎء ﻣﻨﺰوع اﻷﯾﻮﻧﺎت ﻣﻦ اﻟﻤﺨﺘﺒﺮ: ﻣﻞ )ﺗﻘﺮﯾﺒًﺎ( ﻟﻜﻞ ﻣﻤﺎ ﯾﻠﻲ2 ﻋﯿﻨﺔ واﺣﺪة ﺳﻌﺔ، ﻗﻢ ﺑﺈﻋﺪاد ﺛﻼﺛﺔ أﻧﺎﺑﯿﺐ اﺧﺘﺒﺎر ﻻﺧﺘﺒﺎر أﯾﻮن اﻟﻜﻠﻮرﯾﺪ.5
ﺗﺘﻢ اﻹﺷﺎرة إﻟﻰ اﻟﺘﺮﻛﯿﺰات اﻟﻨﺴﺒﯿﺔ.AgCl ﯾﺸﺎر إﻟﻰ وﺟﻮد أﯾﻮن اﻟﻜﻠﻮرﯾﺪ ﻓﻲ اﻟﻤﺤﻠﻮل ﻋﻦ طﺮﯾﻖ ﺗﻜﻮﯾﻦ اﻟﺮاﺳﺐ اﻷﺑﯿﺾ. ﻗﻄﺮات ﻣﻦ ﻣﺤﻠﻮل ﻧﺘﺮات اﻟﻔﻀﺔ ﻟﻜﻞ أﻧﺒﻮب اﺧﺘﺒﺎر5 أﺿﻒ.6
وﺻﺐ اﻟﻤﺤﺎﻟﯿﻞ ﻓﻲ وﻋﺎء اﻟﻨﻔﺎﯾﺎت واﺷﻄﻒ اﻷﻧﺎﺑﯿﺐ ﻓﻲ اﻟﺤﻮض ﻗﺒﻞ وﺿﻌﮭﺎ ﻓﻲ ﺣﺎوﯾﺔ اﻷواﻧﻲ، ﻗﻢ ﺑﺈزاﻟﺔ أي ﺷﺮﯾﻂ ﻣﻦ أﻧﺎﺑﯿﺐ اﻻﺧﺘﺒﺎر. ﺳﺠﻞ ﻣﻼﺣﻈﺎﺗﻚ.ﺑﻤﻘﺪار اﻟﻤﺎدة اﻟﻤﺘﺮﺳﺒﺔ اﻟﻤﺘﻜﻮﻧﺔ
.اﻟﺰﺟﺎﺟﯿﺔ اﻟﻤﺘﺴﺨﺔ
13
Post-Lab Questions:
In the following table examples of some mixtures, write down the
proper method of separation the components of these mixtures.
Mixture Method of separation Explanation
Iron and Sulfur
Muddy river water
coffee
Salt, sand, water
Oil and water
Ethanol and water
Ink and water
Dyes in plants
14
( ﻗﺎﻋﺪﯾﮫ أو ﻣﺤﺎﯾﺪة، ﺗﺤﺪﯾﺪ اﻟﻤﺤﻠﻮل )ﺣﻤﻀﯿﺔ3 ﺗﺠﺮﺑﺔ
Experiment 3
Identification of Solutions (Acidic, basic or Neutral) اﻟﻐﺮض ﻣﻦ ھﺬه اﻟﺘﺠﺮﺑﺔ ھﻮ ﺗﺤﺪﯾﺪ:اﻟﮭﺪف
Objective: The purpose of this experiment is to identify an unknown solution ﻣﺤﻠﻮل ﻏﯿﺮ ﻣﻌﺮوف
Theoretical Background: . زاﺋﺪة+ H ( وطﻌﻢ ﺣﺎﻣﺾ وأﯾﻮﻧﺎت7.0>) ھﻮ اﻟﻤﺤﻠﻮل اﻟﺬي ﯾﺤﺘﻮي ﻋﻠﻰ درﺟﺔ ﺣﻤﻮﺿﺔ ﻣﻨﺨﻔﻀﺔ:اﻟﻤﺤﻠﻮل اﻟﺤﻤﻀﻲ
Acidic solution: is the solution which has low pH (<7.0), sour taste,
and excess H+ ions. -OH ( وطﻌﻢ ﻣﺮ وﻣﻘﺪار7.0 <) ھﻮ اﻟﺤﻞ اﻟﺬي ﯾﺤﺘﻮي ﻋﻠﻰ درﺟﺔ ﺣﻤﻮﺿﺔ ﻋﺎﻟﯿﺔ:اﻟﻤﺤﻠﻮل اﻟﻘﺎﻋﺪي
. ﺗﺴﺎوي ﺻﻔ ًﺮا+ H ﺣﺘﻰ ﻟﻮ ﻛﺎﻧﺖ ﻛﻤﯿﺔ، + H أﯾﻮﻧﺎت أﻛﺒﺮ ﻣﻦ ﻛﻤﯿﺔ
Basic Solution: is the solution which has high pH (> 7.0), bitter taste
and the amount of OH- ions are greater than the amount of H+, even
if the amount of H+ is equal to zero. أو أي ﻣﺤﻠﻮل.7.0 ﻣﺤﻠﻮل ﻣﺎﺋﻲ ﺑﺮﻗﻢ ھﯿﺪروﺟﯿﻨﻲ ﯾﺴﺎوي:ﻣﺘﻌﺎدل/ﻣﺤﻠﻮل ﻣﺤﺎﯾﺪ
.ﻣﺎﺋﻲ ﺗﺘﺴﺎوى ﻓﯿﮫ أﻧﺸﻄﺔ أﯾﻮﻧﺎت اﻟﮭﯿﺪروﺟﯿﻦ واﻟﮭﯿﺪروﻛﺴﯿﺪ
Neutral solution: an aqueous solution with pH equal to 7.0. or any
aqueous solution in which the activities of the hydrogen and
hydroxide ions are equal.
اﻹﺟﺮاء
اﻟﻤﺎء-5 ، ھﯿﺪروﻛﺴﯿﺪ اﻟﺼﻮدﯾﻮم-4 ، اﻟﻤﺎء اﻟﻤﺎﻟﺢ-3 ، اﻷﻣﻮﻧﯿﺎ-2 ، ﺣﻤﺾ اﻟﮭﯿﺪروﻛﻠﻮرﯾﻚ-1 :* ﺗﺤﻀﯿﺮ اﻟﻤﺤﺎﻟﯿﻞ اﻟﺜﻤﺎﻧﯿﺔ اﻟﺘﺎﻟﯿﺔ
Procedure Na2CO3 -8 ، ﺳﻜﺮ7 ، ﺣﻤﺾ اﻟﺨﻠﯿﻚ-6 ، اﻟﻤﻘﻄﺮ
* Prepare the following 8 solutions:1- HCl, 2- Amonia, 3- Salt
water, 4- NaOH, 5- Distilled water, 6- Acetic acid, 7- Sugar, 8-Na2CO3
1- test each solution with litmus paper. Record the results in the data
table below. . ﺳﺠﻞ اﻟﻨﺘﺎﺋﺞ ﻓﻲ ﺟﺪول اﻟﺒﯿﺎﻧﺎت أدﻧﺎه. اﺧﺘﺒﺮ ﻛﻞ ﻣﺤﻠﻮل ﺑﻮرق ﻋﺒﺎد اﻟﺸﻤﺲ-1
. ﺳﺠﻞ اﻟﻨﺘﺎﺋﺞ ﻓﻲ ﺟﺪول اﻟﺒﯿﺎﻧﺎت. ﻗﻄﺮات ﻣﻦ ﻧﺘﺮات اﻟﻔﻀﺔ ﻟﻜﻞ ﻣﺤﻠﻮل5 ﺧﺬ اﻟﻘﻠﯿﻞ ﻣﻦ ﻛﻞ ﻣﺤﻠﻮل ﻓﻲ أﻧﺒﻮب اﺧﺘﺒﺎر وأﺿﻒ-2
2- Take little of each solution in a test tube and add 5 drops of silver
nitrate to each solution. Record the results in the data table.
Observations:
Unknown solution 1 2 3 4 5 6 7 8
No.
red
Litmus blue
test
Silver nitrate
(AgNO3)
Test
Sodium Carbonate
(Na2CO3) test
Phenolphthalein test
Methyl Orange Test
Identity of
Solution
15
أﻧﻮاع ﻣﻦ اﻟﺘﻔﺎﻋﻼت اﻟﻜﯿﻤﯿﺎﺋﯿﺔ4 ﺗﺠﺮﺑﺔ :أھﺪاف
دراﺳﺔ أﻧﻮاع اﻟﺘﻔﺎﻋﻼت اﻟﻜﯿﻤﯿﺎﺋﯿﺔ وﺗﻄﻮﯾﺮ اﻟﻤﮭﺎرات اﻟﻤﻌﻤﻠﯿﺔ ﻹﺟﺮاء ﺑﻌﺾ-
.اﻟﺘﻔﺎﻋﻼت اﻟﻜﯿﻤﯿﺎﺋﯿﺔ
Experiment 4 إﺑﺪاء اﻟﻤﻼﺣﻈﺎت ﺣﻮل ﻧﺘﺎﺋﺞ ھﺬه اﻟﺘﻔﺎﻋﻼت واﻟﺘﻌﺮف ﻋﻠﻰ اﻟﻌﻼﻣﺎت اﻟﺘﻲ ﯾﻤﻜﻦ-
Types of Chemical Reactions .ﻣﻼﺣﻈﺘﮭﺎ ﻟﻠﺘﻔﺎﻋﻞ اﻟﻜﯿﻤﯿﺎﺋﻲ
. اﻟﺘﻌﺮف ﻋﻠﻰ اﻟﻤﻨﺘﺠﺎت اﻟﻤﺘﻜﻮﻧﺔ ﻓﻲ اﻟﺘﻔﺎﻋﻞ اﻟﻜﯿﻤﯿﺎﺋﻲ-
Objectives: . ﻛﺘﺎﺑﺔ ﻣﻌﺎدﻟﺔ ﻛﯿﻤﯿﺎﺋﯿﺔ ﻣﺘﻮازﻧﺔ ﻟﻠﺘﻔﺎﻋﻼت اﻟﻤﺪروﺳﺔ-
- To study types of chemical reactions and to develop laboratory
skills for carrying out some chemical reactions.
- Making observations about the results of these reactions and
become familiar with the observable signs of a chemical reaction.
- Identify the products formed in chemical reaction.
- Write a balanced chemical equation for the reactions studied.
Theoretical background: .ﯾﻤﻜﻨﻨﺎ ﺗﺠﻤﯿﻊ آﻻف اﻟﺘﻔﺎﻋﻼت اﻟﻜﯿﻤﯿﺎﺋﯿﺔ ﻓﻲ ﻓﺌﺎت ﻗﻠﯿﻠﺔ ﻣﻦ اﻟﺘﻔﺎﻋﻼت
.( ﺗﺘﺤﺪ ﻣﺎدﺗﺎن أو أﻛﺜﺮ )اﻟﻌﻨﺎﺻﺮ( ﻟﺘﻜﻮﯾﻦ ﻣﺎدة أﺧﺮى )ﻣﺮﻛﺐ.• ردود اﻟﻔﻌﻞ اﻟﻤﺮﻛﺒﺔ
. ﻣﺮﻛﺐ واﺣﺪ ﯾﻨﻘﺴﻢ إﻟﻰ ﻣﺎدﺗﯿﻦ أو أﻛﺜﺮ.• ﺗﻔﺎﻋﻼت اﻟﺘﺤﻠﻞ
. ﺗﺘﺒﺎدل اﻷﯾﻮﻧﺎت ﻓﻲ ﻣﺮﻛﺒﯿﻦ اﻷﺟﺰاء.• ردود ﻓﻌﻞ اﻟﻨﺰوح اﻟﻤﺰدوج
)أو. ﻣﺎدة واﺣﺪة )ﻋﻨﺼﺮ ﺑﺸﻜﻞ ﻋﺎم( ﺗﺰﯾﺢ ﺟﺰ ًءا ﻣﻦ ﻣﺎدة أﺧﺮى )ﻋﻨﺼﺮ( ﻣﻦ ﻣﺮﻛﺐ.(• ﺗﻔﺎﻋﻼت اﻟﻨﺰوح اﻟﻔﺮدي )أو ﺗﻔﺎﻋﻞ اﻻﺳﺘﺒﺪال
(.ﯾﺘﻢ إزاﺣﺔ أﺣﺪ اﻟﻌﻨﺎﺻﺮ ﻣﻦ ﻣﺮﻛﺐ ﺑﻮاﺳﻄﺔ ﻋﻨﺼﺮ آﺧﺮ
.( ﺗﻔﻘﺪ ﻣﺎدة واﺣﺪة اﻹﻟﻜﺘﺮوﻧﺎت )اﻷﻛﺴﺪة( ﺑﯿﻨﻤﺎ ﺗﻜﺘﺴﺐ ﻣﺎدة أﺧﺮى اﻹﻟﻜﺘﺮوﻧﺎت ﻓﻲ ﻧﻔﺲ اﻟﻮﻗﺖ)ﺗﺨﻔﯿﺾ.• ﺗﻔﺎﻋﻼت ﺗﻘﻠﯿﻞ اﻷﻛﺴﺪة
. ﺗﺘﺤﺪ أﯾﻮﻧﺎت اﻟﮭﯿﺪروﺟﯿﻦ ﻣﻦ اﻷﺣﻤﺎض ﻣﻊ أﯾﻮﻧﺎت اﻟﮭﯿﺪروﻛﺴﯿﺪ ﻣﻦ اﻟﻘﻮاﻋﺪ ﻟﺘﻜﻮﯾﻦ اﻟﻤﺎء.• اﻟﺘﻔﺎﻋﻼت اﻟﺤﻤﻀﯿﺔ اﻟﻘﺎﻋﺪﯾﺔ
16
There are often accompanying observable changes as a chemical reaction
occurs. These include:
• Color change.
• Formation of a precipitate—noted as the formation of a
cloudy solution, formation of a gel, or an obvious solid.
• Evolution of a gas—noted as bubbling in the solution.
• Appearance or disappearance of distinct separation between
two or more liquids.
• Evolution of heat—noted as a temperature increase.
• Absorption of heat—noted as a temperature decrease.
• Decomposition, pitting, or the disappearance of a solid metal
One or more of these changes may occur in the reactions that are
performed in this experiment. .ﻗﺪ ﯾﺤﺪث واﺣﺪ أو أﻛﺜﺮ ﻣﻦ ھﺬه اﻟﺘﻐﯿﯿﺮات ﻓﻲ اﻟﺘﻔﺎﻋﻼت اﻟﺘﻲ ﯾﺘﻢ إﺟﺮاؤھﺎ ﻓﻲ ھﺬه اﻟﺘﺠﺮﺑﺔ
. أﻣﺜﻠﺔ وأوﺻﺎف ﻣﻦ ﻛﻞ ﻧﻮع ﺗﻈﮭﺮ أدﻧﺎه.ﺑﻌﺾ اﻷﻧﻮاع اﻟﺒﺴﯿﻄﺔ ﻧﺴﺒﯿًﺎ ﻣﻦ اﻟﺘﻔﺎﻋﻼت اﻟﻜﯿﻤﯿﺎﺋﯿﺔ ﻣﻮﺿﺤﺔ ﻓﻲ ھﺬه اﻟﺘﺠﺮﺑﺔ
Some relatively simple but common types of chemical reactions are
illustrated in this experiment. Examples and descriptions of each type
appear below. : اﻟﺘﻔﺎﻋﻼت اﻟﻤﺮﻛﺒﺔ اﻟﻤﺒﺎﺷﺮة-أ
A- Direct Combination Reactions:( ﺣﺮق ﻗﻄﻌﺔ ﻣﻦ اﻟﻤﻐﻨﯿﺴﯿﻮم ﻓﻲ اﻟﮭﻮاء ﺣﯿﺚ ﯾﺘﻜﻮن أﻛﺴﯿﺪ اﻟﻤﻐﻨﯿﺴﯿﻮم وﻓﻖ اﻟﻤﻌﺎدﻟﺔ اﻟﻜﯿﻤﯿﺎﺋﯿﺔ اﻟﺘﺎﻟﯿﺔ1
1) Burning a piece of Magnesium in air, where magnesium oxide is
formed according to the following chemical equation:
2Mg(s) + O2(g) → 2MgO(s)
2) Reacting iron with sulfur to produce ferrous sulfide ( ﺗﻔﺎﻋﻞ اﻟﺤﺪﯾﺪ ﻣﻊ اﻟﻜﺒﺮﯾﺖ ﻹﻧﺘﺎج ﻛﺒﺮﯾﺘﯿﺪ اﻟﺤﺪﯾﺪوز2
Fe(s) + S(s) → FeS(s)
: وﺗﺸﻤﻞ ھﺬه.ﻏﺎﻟﺒًﺎ ﻣﺎ ﺗﻜﻮن ھﻨﺎك ﺗﻐﯿﯿﺮات ﯾﻤﻜﻦ ﻣﻼﺣﻈﺘﮭﺎ ﻋﻨﺪ ﺣﺪوث ﺗﻔﺎﻋﻞ ﻛﯿﻤﯿﺎﺋﻲ
.• ﺗﻐﯿﯿﺮ اﻟﻠﻮن
. أو ﻣﺎدة ﺻﻠﺒﺔ واﺿﺤﺔ، أو ﺗﻜﻮﯾﻦ ﻣﺎدة ھﻼﻣﯿﺔ، ﯾُﻼﺣﻆ ﻋﻠﻰ أﻧﮫ ﺗﻜﻮﯾﻦ ﻣﺤﻠﻮل ﻣﻌﻜﺮ- • ﺗﻜﻮﯾﻦ راﺳﺐ
. ﯾُﺸﺎر إﻟﯿﮫ ﻋﻠﻰ أﻧﮫ ﻓﻘﺎﻋﺎت ﻓﻲ اﻟﻤﺤﻠﻮل- • ﺗﻄﻮر ﻏﺎز
.• ظﮭﻮر أو اﺧﺘﻔﺎء اﻟﻔﺼﻞ اﻟﻤﺘﻤﯿﺰ ﺑﯿﻦ ﺳﺎﺋﻠﯿﻦ أو أﻛﺜﺮ
. ﯾُﺸﺎر إﻟﯿﮫ ﻋﻠﻰ أﻧﮫ زﯾﺎدة ﻓﻲ درﺟﺔ اﻟﺤﺮارة- • ﺗﻄﻮر اﻟﺤﺮارة
. ﯾﻼﺣﻆ اﻧﺨﻔﺎض درﺟﺔ اﻟﺤﺮارة- • اﻣﺘﺼﺎص اﻟﺤﺮارة
• ﺗﺤﻠﻞ أو ﺗﺄﻟﯿﺐ أو اﺧﺘﻔﺎء ﻣﻌﺪن ﺻﻠﺐ
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• In the following table Write down all the observations you can
make about what happens in these reactions
Reaction Observation
Before the reaction After the Reaction
B- Double displacement:
1- Reaction between sodium sulfate and barium chloride
Na2SO4 + BaCl2 → 2NaCl + BaSO4 ↓
2- Reaction between silver nitrate and potassium iodide : إزاﺣﺔ ﻣﺰدوﺟﺔ-ب
AgNO3 (aqu) + KI(aqu) → KNO(3) + AgI ↓ ﺗﻔﺎﻋﻞ ﺑﯿﻦ ﻛﺒﺮﯾﺘﺎت اﻟﺼﻮدﯾﻮم وﻛﻠﻮرﯾﺪ اﻟﺒﺎرﯾﻮم-1
اﻟﺘﻔﺎﻋﻞ ﺑﯿﻦ ﻧﺘﺮات اﻟﻔﻀﺔ وﯾﻮدﯾﺪ اﻟﺒﻮﺗﺎﺳﯿﻮم-2
3- Reaction between Silver nitrate and sodium chloride اﻟﺼﻮدﯾﻮم اﻟﺘﻔﺎﻋﻞ ﺑﯿﻦ ﻧﺘﺮات اﻟﻔﻀﺔ وﻛﻠﻮرﯾﺪ-3
AgNO3 (aqu) + NaCl(aqu) → NaNO(3) + AgCl↓
• In the following table write down all the observations you can
make about what happens in these reactions
Reaction Observation
Before the reaction After the Reaction
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( اﻟﻨﺰوح اﻟﻔﺮدي )ﺗﻔﺎﻋﻼت اﻻﺳﺘﺒﺪال-ج
ﺗﻔﺎﻋﻞ ﻣﻌﺪن اﻟﺰﻧﻚ ﻣﻊ ﻣﺤﻠﻮل ﻛﺒﺮﯾﺘﺎت اﻟﻨﺤﺎس-1
ﺗﻔﺎﻋﻞ ﻣﻌﺪن اﻟﻤﺎﻏﻨﺴﯿﻮم ﻣﻊ ﺣﻤﺾ اﻟﮭﯿﺪروﻛﻠﻮرﯾﻚ اﻟﻤﺨﻔﻒ-2
C- Single Displacement (Substitution Reactions)
1- Reaction of Zinc Metal with Copper sulfate solution
Zn(s) + CuSO4 (aqu) → ZnSO4 (aqu) + Cu(s)↓
1
2
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ﺗﻔﺎﻋﻼت اﻷﻛﺴﺪة واﻻﺧﺘﺰال-د
D- Oxidation-Reduction Reactions ﻣﺜﺎل ﻋﻠﻰ ﺗﻔﺎﻋﻞ.ﯾﺤﺪث ﺗﻔﺎﻋﻞ اﻷﻛﺴﺪة واﻻﺧﺘﺰال ﻓﻲ وﻗﺖ واﺣﺪ ﺟﻨﺒًﺎ إﻟﻰ ﺟﻨﺐ
Oxidation and reduction reaction occur simultaneously side by side. :اﻷﻛﺴﺪة واﻻﺧﺘﺰال
Example for an oxidation-reduction reaction:
2Ag+(aq) + Cu(s) 2Ag(s) + Cu2+(aq)
.( )ﺗﻘﻠﯿﻞAg (s) إﻟﻰAg + (aq) ﺑﯿﻨﻤﺎ ﯾﺘﻐﯿﺮ.( )أﻛﺴﺪةCu2 ﯾﺘﺤﻮل إﻟﻰCu (s) ﯾﻤﻜﻨﻨﺎ أن ﻧﺮى أن
: أﺣﺪھﻤﺎ ﻟﻸﻛﺴﺪة واﻵﺧﺮ ﺗﻔﺎﻋﻞ اﻻﺧﺘﺰال، ﯾﻤﻜﻦ ﺗﻘﺴﯿﻢ ﺗﻔﺎﻋﻞ اﻷﻛﺴﺪة واﻻﺧﺘﺰال إﻟﻰ ﺗﻔﺎﻋﻠﯿﻦ ﻧﺼﻔﯿﻦ
2+ +
We can see that Cu(s) converts to Cu (Oxidation). While Ag (aq) changes
to Ag(s) (reduction). The oxidation-reduction reaction can be divided into
two half reactions, one for oxidation and the other is reduction reaction:
Cu(s) Cu2+ (aq) + 2e- (Oxidation)
2Ag+ (aq) + 2e- 2Ag (s) (Reduction)
ً
ﻋﻨﺪ وﺿﻊ، ﻟﺬﻟﻚ.ﺗﻔﺎﻋﻼ ﻛﮭﺮﺑﯿًﺎ ﻣﻦ اﻟﻨﺤﺎس ﻷن اﻟﺰﻧﻚ ﯾﻜﻮن أﻛﺜﺮ، ﻣﺜﺎل آﺧﺮ ھﻮ أن اﻟﺰﻧﻚ ﯾﺘﻔﺎﻋﻞ ﻣﻊ ﻛﺒﺮﯾﺘﺎت اﻟﻨﺤﺎس
: ﯾﺘﻢ "إذاﺑﺔ" اﻟﺸﺮﯾﻂ ﻓﻲ ﻣﺤﻠﻮل وﻓﻘًﺎ ﻟﻠﻤﻌﺎدﻟﺔ، ﺷﺮﯾﻂ ﻋﻠﻰ اﻟﺰﻧﻚ ﻓﻲ ﻣﺤﻠﻮل ﻛﺒﺮﯾﺘﺎت اﻟﻨﺤﺎس
Another Example is Zinc reacts with copper sulphate, because zinc is more
reactive electrochemically than copper. Therefore, when a strip on zinc in
placed in a copper sulphate solution, the strip is "solvated" into solution
according to the equation:
CuSO4(aq) + Zn(s) → Cu(s) + ZnSO4(aq)
Also we can write this reaction into two half reactions
Cu2+(aq) + 2e- → Cu (s) (reduction).
Zn(s) → Zn2+(aq) + 2e- (oxidation).
Experimental procedure:
1. Your teacher is about to add Cu coil into a test tube containing
AgNO3 solution.
A. What do you expect will happen to the coil and to the solution
B. Watch the teacher's demonstration. Writ down your observations
C. Write down a balanced chemical equation for the reaction accrued.
:طﺮﯾﻘﺔ ﺗﺠﺮﯾﺒﯿﺔ
.AgNO3 ﻣﻌﻠﻤﻚ ﻋﻠﻰ وﺷﻚ إﺿﺎﻓﺔ ﻣﻠﻒ اﻟﻨﺤﺎس ﻓﻲ أﻧﺒﻮب اﺧﺘﺒﺎر ﯾﺤﺘﻮي ﻋﻠﻰ ﻣﺤﻠﻮل.1
ﻣﺎ اﻟﺬي ﺗﺘﻮﻗﻌﮫ ﺳﯿﺤﺪث ﻟﻠﻤﻠﻒ واﻟﺤﻞ.أ
اﻛﺘﺐ ﻣﻼﺣﻈﺎﺗﻚ. ﻣﺸﺎھﺪة ﻋﺮض اﻟﻤﻌﻠﻢ-ب
. اﻛﺘﺐ ﻣﻌﺎدﻟﺔ ﻛﯿﻤﯿﺎﺋﯿﺔ ﻣﺘﻮازﻧﺔ ﻟﻠﺘﻔﺎﻋﻞ اﻟﻨﺎﺗﺞ-ج
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2. Use the graduated cylinder to measure 100 ml of the CuSO4 solution
and transfer it to the beaker.
I A. What it the color of the solution?
2 B. Use the thermometer to measure the solution's temperature.
C. Write down the temperature.
D. Leave the thermometer in the beaker and add the Zn strip.
5 E. Watch the changes in temperature and color and write the temperature
every 20 seconds, until it stabilized and does not change any more.
6 F. What is the maximal temperature value?
7 G. Explain the color change during the experiment.
H. Write down a balanced chemical equation for the reaction accrued.
q I. Is it an endothermic or an exothermic reaction? Explain.
. واﻧﻘﻠﮭﺎ إﻟﻰ اﻟﺪورقCuSO4 ﻣﻞ ﻣﻦ ﻣﺤﻠﻮل100 اﺳﺘﺨﺪم اﻻﺳﻄﻮاﻧﺔ اﻟﻤﺘﺪرﺟﺔ ﻟﻘﯿﺎس.2
ﻣﺎ ﻟﻮن اﻟﺤﻞ؟.أ
. اﺳﺘﺨﺪم اﻟﺘﺮﻣﻮﻣﺘﺮ ﻟﻘﯿﺎس درﺟﺔ ﺣﺮارة اﻟﻤﺤﻠﻮل.ب
. اﻛﺘﺐ درﺟﺔ اﻟﺤﺮارة.ج
. اﺗﺮك اﻟﺘﺮﻣﻮﻣﺘﺮ ﻓﻲ اﻟﺪورق وأﺿﻒ ﺷﺮﯾﻂ اﻟﺰﻧﻚ3
. ﺛﺎﻧﯿﺔ ﺣﺘﻰ ﺗﺴﺘﻘﺮ وﻻ ﺗﺘﻐﯿﺮ ﺑﻌﺪ اﻵن20 راﻗﺐ اﻟﺘﻐﯿﺮات ﻓﻲ درﺟﺔ اﻟﺤﺮارة واﻟﻠﻮن واﻛﺘﺐ درﺟﺔ اﻟﺤﺮارة ﻛﻞ
4
-د
🫶 بالتوفيق،دعواتكم
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