MATTER - anything that has mass and takes up DEMOCRITUS- he believed that all matter is made space. of a very small particles called ATOMS. CHEMISTRY- a science that deals with matter: the structure and properties of matter and the transformations from one form of matter to another. CHEMICAL CHANGE- more commonly called as CHEMICAL REACTION, some substances are used up (disappear) and others are formed to take their place. PHYSICAL CHANGE- the identities of the substances do not change. PHYSICAL PROPERTIES- are all properties that do not involve chemical reactions. (density, color, melting point and physical state (solid, liquid & gas) ELEMENTS-is a substance that consist of identical CHEMICAL PROPERTIES - the chemical reaction atoms. undergoes COMPOUND- is a pure substance made up two or SCIENTIFIC METHOD - it is a tool used by more elements in fixed ratio by mass. scientist to learn and testing the theories. MIXTURES- is a combination of two or more pure - heart of scientific method is the testing of theories. substances. FACT - a statement based on direct experience Ex. Blood, butter, gasoline, soap, etc. HYPOTHESIS - a statement that is proposed, w/o HETEROGENOUS MIXTURE- where at least two actual proof, to explain the facts and relationship. components can be observed. THEORY-formulation of an apparent relationship HOMOGENOUS MIXTURE- no amount of among certain observed phenomena, which has magnification will reveal the presence of difference been verified to some extent. substances. WILLIAM HARVEY (1578-1657)-he tested Galen's DALTON’s ATOMIC THEORY hypothesis by dissecting human and animal hearts JOHN DALTON- put forth a model of matter that and blood vessel. underlies modern scientific atomic theory. FABRICIUS (1537-1619)- Harvey's teacher, had MOLECULE- is a tightly bound combination of two previously observed that one-way valves exist in or more atoms act as a single unit. veins, so that blood in the veins can travel only ANTOINE LAURENT LAVOISIER- he discovered toward the heart and not the other way. the LAW OF CONSERVATION OF MASS, which MALPIGHI (1628-1694)-using the newly invented states that all matter can be neither created nor microscope, found in tiny vessels, which are now destroyed. called capillaries. JOSEPH PROUST- demonstrated the LAW OF Exponential Notation- based on powers of 10 CONSTANT COMPOSITION, which states that any MEASUREMENTS compound is always made up of elements in the - consist of 2 parts: number and unit. same portion by mass Metric System- system that originated in France MONATOMIC ELEMENTS- elements consist of about 1800 and that has since spread throughout single atoms that are not connected to each other. the world Ex. Helium and neon International System of Units (SI) - based on metric DIATOMIC MOLECULES- the only 7 elements, system and uses some of the metric units. SI is such as O,H, N,F,Cl, Br and I. more restrictive and it discourages the use of POLYATOMIC MOLECULES- one form of sulfur, certain metric units and favors others. S8. THREE SUBATOMIC PARTICLES STATES OF MATTER 1. PROTON- has a positive charge. Matter can exist in 3 states: gas, solid, liquid - ATOMIC MASS UNIT (amu)- a unit of a Gases- no definite shape or volume, highly scale of relative mass: 1amu= 1.6605x −24 compressible and can be forced into small 10 g containers 2. ELECTRON- has a negative charge. Liquids- no definite shape but have definite volume, 3. NEUTRON- has no charge. Solids- definite shape and volume, incompressible
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Protons and neutrons are found in a tight cluster in number of electrons in the valence shell of an atom the center of an atom called NUCLEUS. of that element MASS NUMBER= the number of protons + ION- an atom with unequal number of protons and neutrons in the nucleus of an atom. electrons. ATOMIC NUMBER- the number of protons in the IONIZATION ENERGY- the energy required to nucleus of an atom. remove the most loosely held electrons from an ISOTOPES-atoms with the same number of atom in the gas phase. protons but different number of neutrons. ATOMIC WEIGHT- the weighted average of the CHAPTER 3: (CHEMICAL BONDS) masses of the naturally occurring isotopes of the OCTET RULE- when undergoing a chemical element. reaction, atoms of group 1A-7A elements tend to DMITRI MENDELEYEV gain, lose, or share sufficient electron configuration PERIOD- the elements in a horizontal row of the having eight valence electrons. periodic table ANION- in gaining electrons, the atom becomes FAMILIES- the elements in the vertical columns of negatively charge. the periodic table. CATION- in losing electron, the atom becomes MAIN GROUP ELEMENTS- the elements in the A positively charge. groups (groups 1A, 2A, and 3A-8A) of the periodic MONATOMIC CATION- containing only one atom. table. POLYATOMIC CATION- contains more than one 3 CLASSES OF ELEMENTS atom. 1. METALS- elements that are solid at room 2 MAJOR TYPES OF CHEMICAL BOND temperature (except mercury, which is 1.) IONIC BOND- a chemical bond resulting liquid) from the attraction between positive and 2. NONMETALS- elements that do not have negative ions. the characteristic properties of a metal and, in their reactions, tend to accept electrons. ( 2. COVALENT BOND- a chemical bond 18 elements) resulting from the sharing of electrons between 3. METALLOIDS-elements that display some atoms of the properties of metals and non metals. ( ELECTRONEGATIVITY-is a measure of an atom’s 6 elements such as B, Si, Ge, As, Sb, Te) attraction for the electrons it shares in a chemical bond with another atom. HALOGENS- the elements in group 7A of the IONIC COMPOUND- the compound formed by the periodic table. electrostatic attraction of positive and negative ions. ALKALI METALS- the elements, except hydrogen, BINARY COMPOUND- contains only two in group 1A of the periodic table. elements. NOBLE GASES – elements in group A8 BINARY IONIC COMPOUND- both elements are GROUND STATE- the electron configuration of the present as ions lowest energy state of an atom. SINGLE BOND- a bond formed by sharing one pair PRINCIPAL ENERGY LEVELS- the energy levels of electrons and represented by a single line containing orbitals of the same number. between two atoms. SHELLS- all orbitals of a principal energy of an NONPOLAR COVALENT- a covalent bond atom. between two atoms whose difference in SUBSHELLS- all the orbitals of an atom having the electronegativity is less than 0.5 same principal energy level and the same letter POLAR COVALENT- a covalent bond between two designation. atoms whose difference in electronegativity is ORBITALS- the regions of space around nucleus between 0.5 and 1.9 that can hold a maximum of two electrons BONDING ELECTRONS- valence electrons ELECTRON CONFIGURATION- a description of involved in forming a covalent bond that is shared the orbitals of an atom or ion occupied occupied by electrons. electrons. NONBONDING ELECTRONS- valence electrons VALENCE ELECTRONS- the electrons in the are not involved in forming covalent bonds that is outermost occupied shell of an atom. unshared. VALENCE SHELL- the outermost occupied shell of DOUBLE BOND- a bond formed by sharing two an atom. pairs of electron and represented by three lines LEWIS DOT STRUCTURE- the symbol of element between the two bonded atoms. surrounded by a number of dots equal to the Prepared by Ma. Carmen Cano RESONANCE- a theory that many molecules and ions are best described as a hybrid of two or more Avogadro’s Number- The number of formula units lewis contributing structures. in a mole. CONTRIBUTING STRUCTURES- representations Amadeo Avogador (1776-1856) - Italian physicist of a molecule or ion that differ only in the who first proposed the concept of a mole but was distribution of valence electrons. not able to experimentally determine the number of VSEPR ( VALENCE SHELL ELECTRON PAIR units it represented. REPULSION) MODEL Respiration – the oxygen in the air we breathe BOND ANGLE- the angle between two bonded oxidizes carbon-containing compounds in our cells atoms and a central atom to produce CO2 and H2O. Bleaching- most bleaching involves oxidation and CHAPTER 4: CHEMICAL REACTIONS common bleaches are oxidizing agents. The Spectator Ions - Ions that do not react. colored compounds being bleached are usually Net Ionic Equation - Ions that react. Both charges organic compounds oxidation converts them to and the number of atoms must be balanced. colorless compounds. Oxidation - is the loss of electrons. Can be also Batteries – a voltaic cell is a device in which defined as the gain of oxygens. electricity is generated from a chemical reaction. Reduction - is the gain of electrons. Aqueous solution – a solution in which the solvent Exothermic - a reaction that gives off heat. is atwer Endothermic - a reaction that absorbs heat. Spectator ion- an ion that appears unchanged on Heat of reaction- the heat given off or gained in a both sides of a chemical equation reaction. Net ionic – does not contain spectator ions Heat of combustion – he heat given off in a Oxidation reduction reaction- involves the combustion reaction. transfer of electrons form one species to another. Actual Yield- the mass product actually formed or Dissociation – When dissolve in water, the isolated in a chemical reactions. positive and negative ions separate form each Theoretical Yield - the mass of product that should other form in a chemical reaction. Combustion – burning in air Percent Yield- the actual yield divided by the theoretical yield times 100. CHAPTER 5: GASES, LIQUIDS, AND SOLIDS Intermolecular attractive forces help hold matter together; in effect they encounter another form of energy---kinetic energy---that tends to lead to a number of different ways for molecules to arrange themselves. Stoichiometry- is the study of the mass Kinetic Energy increases with increasing relationship. A balanced Chemical Equation tells us temperature. not only which substances react and which are - the higher temperature, the greater the tendency formed but also the molar ratios in which they react. of particles to have more possible arrangements. Limiting reagents - the reagent that is first used up first in reaction. GASEOUS STATE Chemical Equation- is an expression in which At a high temperature, molecules possess a high reactants are converted to which products. KE and move so fast that intermolecular attractive Balanced Chemical Equation- Shows how many forces between them are too weak to hold them moles of each starting material are converted to together. how many moles of each product according to law Molecules far apart and disordered. of conservation of mass. Negligible interactions between molecules. Formula Weight (FW)- Sum of the atomic weights of all atoms in the compound expressed in An LIQUID STATE atomic mass units (amu). Formula weights applies to both ionic and molecular compounds. Molecule move past to each other, but they travel Atomic Weight (AW)- also expressed in (amu) much more slowly than they do in gaseous state. applies to molecular compounds. Intermediate situation Mole (mol)- any substance is defined as SOLID STATE avogadro’s number. Temperature is low enough, molecules no longer have enough energy to move past each other. Prepared by Ma. Carmen Cano Molecules close together and ordered. Partial pressure - the pressure that gas in a Strong interactions between molecules. mixture of gases would exert if it were alone in the PRESSURE container. - The force per unit area exerted against a surface. KINETIC MOLECULAR THEORY Barometer - is an instrument to measure 1. Gases consist of particles, either atoms or atmospheric pressure. molecules, constantly moving through space in Millimeters of mercury (mmHg) - most commonly straight lines, in random directions, and with measured pressure. various speeds. torr - measured pressure 2. The average kinetic energy of gas particles is - named in honor of Evangelista Torricelli proportional to the temperature in kelvins. (1608-164), who invented the barometer. 3. Molecules collide with each other, bouncing off 1 atmosphere(atm) = 760 mmHg each other and changing directions. Manometer - measuring the pressure of gas in a 4. Gas particles have no volume. container. 5. There are no attractive forces between gas GAS LAWS particles. BOYLE'S LAW (Pressure and Volume) 6. Molecules collide with the walls of the container, - volume is inversely proportional to the and these collisions constitute the pressure of the applied pressure. gas. P1V1 = P2V2 Because of this 6 assumptions of kinetic molecular if the pressure doubles the volume decreases by theory a gas in called an ideal gas. one-half. Condensation- the change of a substance from the vapor or gaseous state to the liquid state. CHARLES' LAW (Temperature and Volume) Solidification- the change of a substance from - pressure is directly proportional to the liquid to the solid state. temperature in kelvin (K). Three types of Intermolecular Forces: V1 V2 A. LONDON DISPERSION FORCES = T1 T2 -Fritz London (1900-1954) - Increasing the temperature of the gas -only force attraction between non polar molecules. causes an increase in the volume. -weak intermolecular forces GAY LUSSAC'S LAW (Temperature and Pressure) - weak attraction causes by the electrostatic - pressure is directly proportional to attraction between temporary included dipoles temperature in kelvin (K). B. DIPOLE DIPOLE FORCES P1 P2 -attraction between the positive end of a dipole of = T1 T2 one molecule and the negative end of another - As the temperature of the gas increases, dipole in the same or different molecule. the pressure increases proportionally. -exist between two identical polar molecules or two COMBINED GAS LAW different polar molecules. P1V1 / T1 = P2V2 / T2 C. HYDROGEN BONDING relationship between mass of gas and its volume is - O, N or F described by Avogrado's law, which states that -attraction between the partial positive charge on a equal volume of gases at the same temperature hydrogen atom bonded to an atom of high and pressure contains equal molecule. electronegativity, most commonly O, N, and the Standard temperature and pressure (STP) 0oC partial negative charge on a nearby oxygen or (273K) and 1 atm nitrogen. IDEAL GAS LAW PV = nRT SUFRACE TENSION a gas whose physical properties are described energy required to increase the surface accurately by the ideal gas law. R = 0.0821 area of a liquid. 𝐿 𝑎𝑡𝑚 VAPOR PRESSURE 𝑚𝑜𝑙 𝐾 the partial pressure of a gas in equilibrium DALTON'S LAW OF PARTIAL PRESSURES with its liquid form in a closed container. states that the total pressure, Pt, of a Equilibrium- a condition in which two opposing mixture of gases is the sum of the partial pressure processes occur at an equal rate. of each individual gas: Relative Humidity -the vapor pressure of water in Pt= P1+P2+P3+ .... the atmosphere.
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D. BOILING POINT Saturated- a solvent contains all the solute it can - the temperature at which the vapor pressure of hold at a given temperature call the solution. liquid is equal to the atmospheric pressure. Unsaturated- any solution containing a lesser Normal Boiling Point - liquid boils under a amount of a solute. pressure of 1 atm. Supersaturated solution- a solution that contains Factors that affect boiling point: more than the equilibrium amount of solute at a 1. Intermolecular forces given temperature and pressure. 2.Number of sited for intermolecular interaction Seeding- a process called a way to crystallize the (surface area) excess solute is to add a crystal of the solute. 3. Molecular shape Henry’s law- the solubility of a gas in a liquid is directly proportional to the pressure. VARIOUS TYPES OF SOLIDS Percent concentration- the number of grams of Crystallization - the formation of solid from liquid. solute in 100ml of solution Crystalline solids- molecules have an 𝑤𝑒𝑖𝑔ℎ𝑡\𝑣𝑜𝑙𝑢𝑚𝑒 (𝑤\𝑣)% ordered arrangement extending over long range. 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 Amorphous solids- consist of random = × 100 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑜𝑡𝑖𝑜𝑛 arranged particles that have no ordered long-range 𝑤𝑒𝑖𝑔ℎ𝑡\𝑣𝑜𝑙𝑢𝑚𝑒 (𝑤\𝑣)% strucutre. 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 Allotropes- forms have different and physical = × 100 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑙𝑜𝑡𝑖𝑜𝑛 properties. 𝑣𝑜𝑙𝑢𝑚𝑒\𝑣𝑜𝑙𝑢𝑚𝑒 (𝑣\𝑣)% PHASE CHANGES -changes from one physical 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒 state to another. = × 100 HEAT FUSSION -the heat necessary to melt 1.0g 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑜𝑡𝑖𝑜𝑛 of solid Molarity- defined as a number of moles of a solute SPECIFIC HEAT- the heat required to raise the dissolved in 1L of solution. temperature of the unit mass of a given substance 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒(𝑛) by a given amount (usually one degree). 𝑚𝑜𝑙𝑎𝑟𝑖𝑡𝑦(𝑀) = HEAT OF VAPORIZATION- Amount of heat 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑜𝑡𝑖𝑜𝑛(𝐿) necessary to vaporize liquid at its normal boiling Solvated- general term for covering all solvents. point. Water of hydrogen- water molecules in a crystal HEATING CURVE - graphically represents the Hydrates-substance that contain water in their phase transitions that a substance undergoes crystal are themselves called____. as heat is added to it. Anhydrous- the crystal without its water of hydration SUBLIMATION- A transition from the solid state Hygroscopic- some anhydrous crystal become directly into the vapor state without going through hydrated upon standing in air crystal s that do so the liquid state. are called_____. A quantity of a substance that is PHASE DIAGRAM- where you can show all phase able to absorb water vapor from the air. changes for any substance. Cathode- cations migrate to the negative electrode Anode- anions migrates to positive electrode CHAPTER 6: SOLUTIONS AND COLLOIDS Electrolyte- a substance, such as potassium Alloys- homogeneous mixtures of 2 or more metals chloride, that conducts an electric current when Solvent- a solution consists of a solid or a gas dissolve in water or when water in the molten state. dissolved in a liquid, the liquid is called solvent Nonelectrolyte- a substance that does not conduct The distributing characteristics of a solution electricity. 1. The distribution of particles in a solution in uniform. Strong electrolytes- compounds that dissociate 2. The components of a solution do not separate on completely standing. Weak electrolytes- compounds that dissociate 3. A solution cannot be separated into its components only partially into ions by filtration. Tyndall effect- light passing through and scattered 4. For any given solute and solvent, it is possible to by a colloid viewed at the right angle. make solutions of many different compositions. Suspension- the system is unstable and separates 5. Solutions are almost always transparent. into phases 6. Solutions can be separated into pure components. Brownian motion- this motion of any colloidal Miscible- water and ethanol is ____. particle suspended in a solvent.
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Emulsions- systems such as fats in milk, reactants. It’s depicted with a red arrow. The consisting of a liquid with or without an emulsifying enthalpy change—ΔHΔH—of the reaction is agent in an immiscible liquid usually as droplets of depicted with a green arrow. So, now you should larger than colloidal size. be able to clearly differentiate between Colligative property- a property of a solution that E_{act}EactE, start subscript, a, c, t, end subscript depends only on the number of solute particles and and ΔHΔH on an energy diagram. not on the chemical identity of the solute. In the case of an endothermic reaction, the Osmosis- passage of the solvent molecules from a reactants are at a lower energy level compared to less concentrated solution across a semipermeable the products—as shown in the energy diagram membrane into a more concentrated solution. below. In other words, the products are less stable Osmotic pressure (II)- the amount of external than the reactants. Since we are forcing the pressure that must be applied to the more reaction in the forward direction towards more concentrated solution to stop the passage of unstable entities, overall ΔHΔH for the reaction is solvent molecules across a semipermeable positive, i.e., energy is absorbed from the membrane. surroundings. In the case of an exothermic reaction, the CHAPTER 7: REACTION RATES AND reactants are at a higher energy level as compared CHEMICAL EQUILIBRIUM to the products, as shown below in the energy diagram. In other words, the products are more How Do We Measure Reaction Rates? stable than the reactants. Overall ΔHΔH for the • The Rate of Reaction is the change in reaction is negative, i.e., energy is released in the concentration of a reactant or a product per unit form of heat. time. Some reactions are fast; others are slow. There are 4 methods by which you can increase Rate = Δconcentration the rate of a reaction: Δtime Nature of the Reactants • The rate of reaction is not constant over a long Increase the concentration of a reactant. period of time. At the beginning, Increase the temperature of the reactants. • In most reactions, the change in concentration is Add a catalyst to the reaction. directly proportional to time. Rate Constant- A proportionality constant, k, • Initial rate is the constant during time interval. between the molar concentration of reactants and Chemical Kinetics- The study of chemical rates of the rate of reaction; rate=k. chemical reaction. Catalyst- A substance that increases the rate of a Effective Collision- A collision between two chemical reaction by providing an alternative molecules or ions that results in a chemical pathway with a lower activation energy. reaction. Heterogeneous Catalysts- catalysts in separate Activation Energy- The minimum energy necessary phase from the reactants. to cause a chemical reaction. Homogeneous Catalysts- catalysts in the same To summarize, the requirements for an effective phase as the reactants. collision (for a chemical reaction to occur): Dynamic Equilibrium- A state in which the rate of The reactants must collide with each other. the forward reaction equals the rate of the reverse The molecules must have sufficient energy reaction. to initiate the reaction (called activation Equilibrium Constant- the ratio of product energy). concentrations to reactant concentrations (with The molecules must have the proper exponents that depend on the coefficients of the orientation balanced equation). Relationship Between Activation Energy and Le Chatelier’s Principle- A principle stating that Reaction Rate when a stress Is applied to a system in chemical • The lower the activation energy, the faster the equilibrium, the position of the equilibrium shifts in reaction. the direction that will reliev e the applied stress. • An energy diagram shows the progress of a Five Types of Stress That Can Be Put On reaction. Chemical Equilibrium • The position at the top of the curve in an energy Addition of a Reaction Component diagram is called the transition state. -Causes the equilibrium to shift to the opposite The activation energy is the difference in the side. energy between the transition state and the Removal of a Reaction Component Prepared by Ma. Carmen Cano -Causes the equilibrium to shift to the side from The equilibrium of constant for the ionization of which the component is removed. water, Kw is called “ion product of water”. Change in temperature Ion product of water is equal to 1.0 x 10^-14. -Increasing the temperature drives an exothermic pH and pOH equilibrium to the side of the reactants; increasing Hydronium ion concentrations are generally the temperature drives an endothermic equilibrium expressed in pH units, with pH = -log [H3O+] to the side of the products. pH less than 7 are ACIDIC Change in Pressure pH greater than 7 are BASIC -Increasing the pressure of a mixture shifts the pH of 7 are NEUTRAL SOLUTION equilibrium in the direction that decreases the Equivalence point - The point in a titration at moles in the gas phase; decreasing the pressure of which there is a stoichiomentrically equivalent a mixture shifts the equilibrium in the direction that numberof moles of each reactants present. increases the moles in the gas phase. Buffer – a solution that resist change in pH when The effects of a Catalyst limited amount of an acid or a base are added to it. -Has no effect on the position of equilibrium Buffer capacity – The extent to which a buffer solution can prevent a significant change in pH of a CHAPTER 8: ACIDS AND BASES solution upon adding of a strong acid or a strong According to Arrhenius: base. ACID – are substances that produced H3O+ ions in aqueous solution. HEDERSON-HASSELBALCH EQUATION BASE – are substances that produced OH- ions in Is a mathematical relationship between pH the pKa aqueous solution. of a weak acid, and the concentration of the weak Hydronium ion – the H3O+ ion. acid and its conjugate base: Strong acid - an acid that ionizes completely in pH = pKa + log [A-] / [HA] aqueous solution. Weak acids – acids that are only partially ionized in aqueous solution. Strong bases – bases that ionize completely in aqueous solution, Weak base – a base that is only partially ionized in aqueous solution. According to Johannes Bronsted and Thomas Lowry: Acid – proton donor Base – proton acceptor Conjugate acid - base pair – A pair of molecules or ions that are related to one another by the gain or loss of a proton. Conjugate base – a substance formed when an acid donates a proton to another molecule or ion. Conjugate acid – a substance formed when a base accepts a proton. Monoprotic acids – acids that can give up only one proton. Diprotic acids – Acids that can give up two protons. Triprotic acid – an acid that can give up 3 protons. Amphiprotic – a substance that can act as either an acid or base. The strength of a weak acid is expressed by its “ionization constant, Ka. The larger the value of Ka, the stronger the acid. pKa = -log [Ka] ACIDIC AND BASIC PROPERTIES OF PURE WATER: Prepared by Ma. Carmen Cano