Date

Saath)

ALITATIVE

’Analysis of Catain ond anjon from gíven Mixture is

Caled Solt analysis.
Erample ’
NaOHt HCL
Cotion Comes < ’ anion Comes
om base 9om acid

Base aoical aciaic xacil

Pex
Test ot anion fe xmod fest betore Catain Test
be cause thexe aYe Sorme anions lKe loxde, Oxolato.
Boyote, Phosphate Aso etc htesfes In he
CPa, Avsenole
test ot CatHon S.
Page Nc.
 Test o anior fs not Systemetic as test ot
Cotain but we tzy to Systemjse test of
by dtding them in two Categoies anions

Anion S

Class-A Class-B

qives Volole Cives Non- Vblale

products with oducts with acd

CLASS-A

Subgroup-I ’
Subqpoup-I
Gives Votatile
Gives Volaile
pxoducts with Boductswh
dilute acds Con Centated
acidg

Cozbonate Co (o,t BoigR

effer
veScence
C
NHyOH
wnite NH,C
fmer white
Br Caxbonnte HCOg Co, dense
fumer
(onc B Redd sh.
Hydrogen
(orbonate 8r
 jee
Date
Saath
Sulphite
So,1
Sufocatinq
buning Solpher ike Sm1 1- Cont
HSoy IT vôlet
Bisuloite HSO
Hychogen Gxalote
sulohite
Salphide BO Borate
otemSme) Boon HBo,1 white tumes
Nibite NO, NO,
Brown gas NO Nitxate
NO Cons
Aeetae CH,C00 CH, (oOH
Vineqer Cike Smel
ThiosulohaleS0
yellow oz White
Ppt

black White
Ppt
ones

Paçe Ne.
 Saath)
Date

Conc
(onch ’X

onc
Bx HB Hasoy

(oncn Concn
I ’HI
Hsoy

* Nacl t HSOy

Br, and I, nd #8
Gnc HT wil not
tozm because onch
Ha Say oxoize HI and!
4B then form

Concentrated HSa acts as a Oxtidising agent

as well as
debydzoting gyent.
US Soluton
Brown oloux to the ageous
B impaztsdoes noto
while No

Page No.
 Saath
Date

Class- B

Subqzop-I Sob aroup-I

[ecpitaton JAedox
’SO Sujphate

P0 Phasphale
AsO Ainenake
Aso Aosenite

CO chaamate

Note i evexy element în their h-hest oxdisinc

aag state acts as Oxideng ogent
evesy ebment in hei lowest oxdoton state aos
as
educn agent .
Fage No.
 Saathi
Date l

’An element inthexe Pntermediate oxdotion State

as well as seducing aqent.
acts aS oxideing
Ctomily -4 to +4
N- Family -3 to +S

-2 to t6

Halogen fumily -1 to 7

tsfFaluagse2]
SoLURILITY CHARI

CO o n ’ all Gbonate fon are Water

?noluble Carboncte epexCe pti

Gmoniom Cox borate i, (o, (s.s)

Sien > All sulphide axe watex insduble

exept Thd andd NH

watex ins
Aln Sul phite aze watey inslwble
eXcept
Suloe.
 Saath
Date

*HCoh : ’ An biCax bonate oxe. Soluble exapt

Sodiurn Bi Caxbondte fAH; NaHCo

C : ’ Au axe wbtey Soluble except

Pbcla. Haz C2
Bi0cL SbocL, Cu Cly, 6Y CucL

Cupaic

Bx ’ all Bzemides are wotey Soluble

except i

I oll odices are Watey oube

Nitotes and Nitiies A) Nates and Ntrities

qye Woter Soluble
except Ne,
 Saathi
Date

* Phasphate ’ No,K RS, CG Soluble

Po
texty
Phosphate
HPO gtap Saluble
S- Phasphabe

H. Po Tond T foxup Soluble

Aimar4
Phrsghale
Acetote ’ al acetote are woter Soluble
CCH, Coo7 except
cJl SoLphate cne woter Soloble
 Saath
Date

Soluble and inSoluble

Houw nan8
mang
are

IS

IS

PbS

Sz Na,S
GyNo CL

IS

3 Bas S

lo9 Zn SOy
Ba S04 ES

Zng IS
IS
 Saathi
Date

H S0DA EXTRACT SOLUTION

’Whenever test of anion is Per formed Soda exoct

Solvion is fomed to oNverte insouble Salt into Soluble
Salt.

-Salt t No,COg
5-10 min bn then,

Pb so, + Na,co,
I.S

PB Co, + Na, soy ’ Na+socay)

>fites laper [Pb co,

Na Sly
ige Na
 Date
Saathi)

IS

’ Be Poye Perfoyming test of anion he Soda

extxact Solution is neutalise by Suitable
Acid Anonic Port cf Acid MUSt diffey Bom
Anion that has to be dected.

Strong Oxidizing Acid LKe Concentated HNO

and Con centrated 'Hsoy MUSt not be used.

Diluted Acetic Acid [CH,co0H] is Widhy vsed.

Page No.
 NaNg AsaS IS Na
S
S
S
oy IS tNacl
+ ’ Bacly Say Na,
S
NOg SNa Is AgNOs S NacOgt S
3
Ca(NO,)a S
Agcl+ AçNO, S t clq Ca
+NaNG S ’ AaNOs Nacl+ S ly
Example
+
Is.
+B A
nSovble IS
Soluble S:- CASE:-I
eXChange
Rxn TON REACTION
CR TATION PRECIPI Le
REPCTTON RGANTC
INORGANIC OF
TYPES H
Saath Date
 CASEI

SS I.S J.s

Exam ple>
BAS
BaS t Znso, |BaSyt Zns
I.S I.s

Lithaphone
CASE-L Not tozmed
X
C
I.s S

Example ’ nossage Methef

Na, to, + (a(oH)

Page No.
 Hcile ShrerhiC HgCo0H> HCO, > H,80,> HCN
DateI. Saath)

I.S

Bacog + HNO,
I.S S

Queston which are lassible oY Not

ssibtle
Bacla
Yossible

Passibte L

Not osib)e X

farc Nc.
 CSaath)
Date

*CASE2

A+ B ’ Not lossible
RISIS Not atrecioitotion R

A+B +-D
S S S

Not Precipitahion Rxn.

REDOX REACTION 8’

H 3+
CGeen]
O1Chzomate
Coranae OH

choomate

Prge No.
 Saathi)
Date

H, M Calouzless oz liaht k

tng’ Mao
basr Medium Green
ozple Neutrat +4
Mn (Broun
Cght bosie

Non Oxidising Acal i’

Anionic art coes not
act cS oxidising agent.
Example dilste HCL, Con HcL, onHPo,
dil &Soy

A c d c i d o in which Anionic
Oxidising Part act
Cxidising
as Cxicising
agent.
Example (onch 4, So, Conc HNO,, clikke HNG=
onch
Bx

HBx.