ADHYAY Batch Chemical Bonding LECTURE-4

Difference between
hybridization and
overlapping
overlapping Hybridization
①
It arbitals
occurs b/w two atoms. Itoccurs bow the of
same atom.

overalpinon only half

② I orbitals
Any type of
can
participate.
filled
se
a

part.
Ioccurs bond
during after
Itoccurs
before overlapping
3 -

formation oronly
hybridization.
 of Hybridization
I
i-
Different cases

① I
CH4
right than
vit were

6 -
i 2p2 My should not
form.
state T
ground
- ↑

.......

Til
excited state - i
-...
*e
sp3 hybrid arbitals
xa
x 4.
-

in

-
-x
H

Mass
(10928
I
C ->
tetrahedral

/ H

-
"10
↑L
H
..
②
#3,
-
B- Is22p
ground state -

D.__
excited state --"

sphybrid etitals.

qf +

is?,2,2p5
+
T2

Gr I
B
F

(1200

18⑰
,
↑ -F

·120 shape
-

trigonal planar
③ Bellz-4Be- Is, 2 2B
T 11
ground
excited state state ....

it "11

sp hybridization.

-se U

180
-
u -

B -
4 ->
shape linear
Bond 8
angl
-

of hybridization:
Calculation -

stelic lone
no
of
Bonds no
of pair of es.
-
- no

Lineas
2
Sp
=> =

3
sp2 trigonal planas
=

4
Sp3-
=>

2
tetraludral

dsp -
Square planas
d-> Actrahedral.
 5
spd
=
=

trigonal bilgeamidal.
octahedral
6 =
spd =

octahedral
deep3 =>

7
sp3d
= ->
pentagonal Gygamidal.
*
We do not consides a bonds in
hybridization.
- 2- bonds to love
pair-steric no = 2.

hybridization sp.
=

valence c
=

2x1
= + 0x2 2 =

Bellz
1800 e
Bondangle
or
-

-- Be-
- 4 -lineas.

call-2
-
->
3- Bonds +
o.lp-=stelic no 3.
=

hybridization =
sp
valence i 3x1 0x2
=
+ =
3.

3
in↳.... r angle=>120
Band
1200
B
r
acomety=trigonal planar
Case:4- Bonds + 0.1p steric
= no- 4

hybridization ep =

valence et 4x1 0x2

=
+
=
4

winlogz angle-logic
Band

tetrahedral
Geometry
-

-4 So Band +
0.1p -stericho = 5

hybridization spd
-

5
valence et 5x1 + 0x2
=

axial bond
s
PU5
-
-

4- Geometry- trigonin
-It'
......... u
camidal
:
7
- I
-
-
2 !
P I
-
120
(TBP)

egitorial .. I 180
W

a a

-
=
-

Bonds a - e 908
=

->
axial bonds e - e 120
=

-
-
car-5 6- Bond
+0.1p -steric no 6.
=

spod
-

hybridization
-

valence i
=
6x1 0x2
+ 6.
=

F6

,Y
90°
angle
-
Bond =

.....
1

F octahedral
Geometry pr
- -

!---- !
↑
=

--
I

S M
W
F
i bipyramidal
S
I

square
- -

-6 7- Bonds
to.lp=stelic 7 no=

hybridization= sp3dE
valence e
= 7x1+0x2=7

IfI / F
-
,
I
7

e- e = 728 I
" i
900
Ir
S
e a
*I
- =
S

a -
a 1808
=

FX
Geometry Pentagongramidal.i
"I -
-

!
 USEPR THEORY: (Valence shell electron
pairRepulsion theory)
① I
Bond
pair
of es. love
pair of es
interactions.
These will be three
types of (Refeulsions)
BP-BP. [B.P. LP. [L.P. L.P.

cases of hybridization.
A

⑪ Bond
20 to
lp. -sstelic no=2

hybridization =

sp
1808
example Belz Bond
angle
- => =

shape-time
② 2-Bondst steric
compair
I no =3.

hybridization=>sp2
valence 2x1 1x2 4. ↓
of
no et =
+
=

Trigonal planers
ex: sucz
carometry)
-

-
lone pail
⑰
F
repulsion
-

() - ·
I

0
u·u
S
/B &F
· -

0(1280
-

shape s bent
shape or
V-shape.
angular shape.
or

Geometry trigonal planar

-
③ 2 Bonds + Clone
pair - steric no-

-
4

hybridization
↓
sp3
tetrahedral
Geometry
valence 2x1 2x2 6-
of
no - =
+
=
-

ex:- H20
=C-- expulsion
bat
H

& Bu12
-,

/O - H
-
M
- loq928
H
104851
-

shape,*-* Bent
shape, V-shape or

angular shape.
Bond
angle-s
⑭ 2- Bonds 3 lone
+

pail -> steric no 5

=

hybridization sp3d =

value
-

t
noo 2x1+0x2 8
Geometry trigonalbifyiamidal.
=
-
=
I

pus
,
xel a
u
U

I
P
e
Tu
I
 F

18: Bond
angl
shape linear.
e
-180

I
In TBP
Geometry onepairs wayskept
the
*
as
at

a
equiturial position,

Rule: -

sule,
this lone
According
the
to
pailtends
Schatty. man hybeid
that obital which
having
is more

electronegative
I the element tends

axial
position (which
to
occupy having less-
is

character (double bond) also

occupy
* bonds tend to

equiturial position.
⑤ 2 Bond+4 love
pair] X.

valence es =2x1 + 4 x 103 which is

of
2
=

no

not
posible