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Research Article
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ISSN 1998-0124 CN 11-5974/O4

2022, 15(12): 10037−10043 https://doi.org/10.1007/s12274-022-4376-5
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Yalin Guo1,2, Yangyang Li1,2, Xiaorui Du3, Lin Li1, Qike Jiang4 ( Ⴃ), and Botao Qiao (Ⴃ) 1
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Selective hydrogenation of acetylene in excess ethylene is an important reaction in both fundamental study and practical
application. Pd-based catalysts with high intrinsic activity are commonly employed, but usually suffer from low selectivity. Pd
single-atom catalysts (SACs) usually exhibit outstanding ethylene selectivity due to the weak π-bonding ethylene adsorption.
However, the preparation of high-loading and stable Pd SACs is still confronted with a great challenge. In this work, we report a
simple strategy to fabricate Pd SACs by means of reducing conventional supported Pd catalysts at suitable temperatures to
selectively encapsulate the co-existed Pd nanoparticles (NPs)/clusters. This is based on our new finding that single atoms only
manifest strong metal–support interaction (SMSI) at higher reduction temperature than that of NPs/clusters. The derived Pd
SACs (Pd1/CeO2 and Pd1/α-Fe2O3) were applied to acetylene selective hydrogenation, exhibiting much improved ethylene
selectivity and high stability. This work offers a promising way to develop stable Pd SACs easily.
,&:803%4
selective hydrogenation of acetylene, Pd single-atom catalysts (SACs), weak π-bonding ethylene adsorption, strong
metal–support interaction (SMSI)
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10038 Nano Res. 2022, 15(12): 10037–10043
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2.1 Preparation
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2.2 Characterization
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Nano Res. 2022, 15(12): 10037–10043 10039
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