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Cations Recall that metallic elements tend to lose valence electrons. Lith- Rb Sr atomic ions and polyatomic ions
ium, sodium, and potassium in Group 1A lose one electron to form cations. might differ? (A monatomic ion has
Cs Ba 3A
All the Group 1A ions have a 1 charge (Li, Na, K, Rb, and Cs). Mag- one atom; a polyatomic ion has more
nesium and calcium are Group 2A metals. They tend to lose two electrons Al than one atom.)
Fr Ra
to form cations with a 2 charge (Mg2 and Ca2), as do all the other Group
2A metals. Aluminum is the only common Group 3A metal. As you might Reading Strategy L2
expect, it tends to lose three electrons to form a 3 cation (Al3). When
Compare and Contrast As students
the metals in Groups 1A, 2A, and 3A lose electrons, they form cations with
positive charges equal to their group number. Figure 9.1 shows some of the
read the section, have them make a
elements whose ionic charges can be obtained from their positions in the chart that compares monatomic ions
Figure 9.1 The representative
periodic table. The names of the cations of the Group 1A, Group 2A, and elements shown form positive ions and polyatomic ions as to charge, com-
Group 3A metals are the same as the name of the metal, followed by the with charges equal to their group position, and name endings.
word ion or cation. Thus Na is the sodium ion (or cation), Ca2 is the cal- numbers. Applying Concepts
cium ion (or cation), and Al3 is the aluminum ion (or cation). Are the ions anions or cations?
2 INSTRUCT
Section 9.1 Naming Ions 253
Answers to...
Figure 9.1 cations
254 Chapter 9
chem_TE_ch09_IPL.fm Page 255 Friday, August 6, 2004 9:48 AM
An older, less useful method for naming these cations uses a root word Figure 9.4 Many transition
with different suffixes at the end of the word. The older, or classical, name metals form brightly colored CLASS Activity
of the element is used to form the root name for the element. For example, compounds that are used in
making artists’ paints.
ferrum is Latin for iron, so ferr- is the root name for iron. The suffix -ous is Symbols for Monatomic Ions L2
used to name the cation with the lower of the two ionic charges. The suffix
Purpose Students use the periodic
-ic is used with the higher of the two ionic charges. Using this system, Fe2
is the ferrous ion, and Fe3 is the ferric ion, as shown in Table 9.2. Notice
table for writing symbols for mona-
that you can usually identify an element from what may be an unfamiliar tomic ions.
classical name by looking for the element’s symbol in the name. Thus fer- Materials Blank photocopy of the peri-
rous (Fe) is iron; cuprous (Cu) is copper; and stannous (Sn) is tin. A major odic table for each pair of students.
disadvantage of using classical names for ions is that they do not tell you
the actual charge of the ion. A classical name tells you only that the cation Procedure Have students work in
has either the smaller (-ous) or the larger (-ic) charge of the pair of possible pairs. Allow them to refer to their text-
ions for that element. books or other resource materials. In
A few transition metals have only one ionic charge. The names of these the element blocks on the blank peri-
cations do not have a Roman numeral. These exceptions include silver,
odic table, have them write the sym-
with cations that have a 1 charge (Ag), as well as cadmium and zinc,
with cations that have a 2 charge (Cd2 and Zn2). As Figure 9.4 shows, bols and names of the cations and
many transition metal compounds are colored and can be used as pig- anions of as many elements as possi-
ments. Pigments are compounds having intense colors that can be used to ble. Have them use their tables to iden-
color other materials. For example, compounds of chromium are pigments tify any trends in ionic charges.
used to make yellow, orange, red, or green paints. Various cadmium com-
Encourage them to keep their tables
pounds range in color from yellow to red and maroon. Prussian blue is an
important pigment composed of the transition element iron combined
for reference.
with carbon, hydrogen, and nitrogen. L2
Relate
Divide students into research teams to
Table 9.2
gather data about paint pigments from
Symbols and Names of Common Metal Ions with More than One different sources. Possible assign-
Ionic Charge
ments: (1) Examine the pigments avail-
Symbol Stock name Classical name
able at an art-supply store and try to
Cu Copper(I) ion Cuprous ion tell from the names what they contain.
Cu2 Copper(II) ion Cupric ion (2) Interview an art teacher about the
Fe2 Iron(II) ion Ferrous ion
pigments that he or she prefers. (3) Use
Fe3 Iron(III) ion Ferric ion
*
the library or Internet to research
Hg22 Mercury(I) ion Mercurous ion
which pigments were available and
Hg2 Mercury(II) ion Mercuric ion
popular during earlier eras; look for
Pb2 Lead(II) ion Plumbous ion
Pb4 Lead(IV) ion Plumbic ion
information about natural sources of
Sn2 Tin(II) ion Stannous ion
pigments. (4) Invite a curator or art
Sn4 Tin(IV) ion Stannic ion restorer from a local museum to talk
Cr2 Chromium(II) ion Chromous ion about using pigments to repair dam-
Cr3 Chromium(III) ion Chromic ion aged art, authenticate art, or unmask a
Mn2 Manganese(II) ion Manganous ion forgery.
Mn3 Manganese(III) ion Manganic ion
Co2 Cobalt(II) ion Cobaltous ion
Co3 Cobalt(III) ion Cobaltic ion
*A diatomic elemental ion.
Differentiated Instruction
Special Needs L1
For some students, the charge that results to represent protons and electrons in neutral
when electrons are transferred is counter- atoms. Remove or add electrons and ask stu-
intuitive — additions result in a negative dents to find the charge of the resulting
charge, subtractions result in a positive “ion.”
charge. Give students different-colored disks Answers to...
Figure 9.2 cations
Pharmacist
Pharmacist
Doctors provide written instruc- with on-the-job training. Advance-
Although pharmacists must often work tions to pharmacists about medi- ment to the position of pharmacist
in the evenings and on weekends, they cines they wish to have dispensed requires a college degree in phar-
are well paid and employment oppor- to their patients. It is the responsi- macy. This degree includes the
tunities for pharmacists during the bility of the pharmacist to prepare study of chemistry, biology, mathe-
coming decade are expected to grow the medicine and to advise the matics, and statistics. Pharmacists
patient about possible side effects. must also learn about the biological
faster than for many other professions. Pharmacists also make sure that effects of drugs and drug interac-
The American Association of Colleges physicians have not prescribed a tions (pharmacology). To obtain a
of Pharmacy (ASCP) operates the Phar- medicine or dosage that could license to dispense drugs, pharma-
macy College Application Service to harm the patient. cists are required to pass a state test
allow students to use a single web- A person with some knowledge of and must work for a specified period
For: Careers in Chemistry
chemistry and biology could of time under the supervision of Visit: PHSchool.com
based application for all applications
Practice
become Problems
a pharmacist’s assistant another pharmacist. Web Code: cdb-1091
to schools of pharmacy.
256 Chapter 9
chem_TE_ch09_IPL.fm Page 257 Sunday, August 8, 2004 7:51 PM
CLASS Activity
Shapes of Polyatomic Ions L2
Purpose Students visualize the geom- a b c
etry of some polyatomic ions.
Materials foam balls and wooden Figure 9.6 Hydrogen- When the formula for a polyatomic ion begins with H (hydrogen), you
containing polyatomic ions are can think of the H as representing a hydrogen ion (H) combined with
sticks part of many compounds that another polyatomic ion. For example, HCO3 is a combination of H and
Procedure Pairs of students can affect your daily life. a Sodium
CO32. Note that the charge on the new ion is the algebraic sum of the ionic
hydrogen carbonate, which
research the three-dimensional structure charges.
contains the HCO3 ion, can
of one of the polyatomic ions in Table 9.3. relieve an upset stomach. H CO32 hydrogen carbonate
¡ 2 HCO3
Have them prepare a ball-and-stick b The presence of dissolved ¡
carbonate HPO4 hydrogen carbonate
HCO3, HPO42, and H2PO4 ions hydrogen phosphate
model of the ion. They may wish to dif- H PO43 ¡ HPO42
in your blood is critical for your H2PO4
ferentiate atoms by size or color. Make health. c Crop dusters spread ¡
phosphate hydrogen phosphate
phate dihydrogen phosphate
sure that they pay attention to correct fertilizers containing HPO42 and H HPO42 ¡ H2PO4
Plasma TV
Plasma TV How it works A computer
controls the output of each Students may be interested in research-
pixel individually. Varying ing one or more of these topics:
Today, a TV can be mounted on the wall just as if it the electrical current flowing 5 in.
through the cells changes • What is the composition of plasma?
were a picture in a frame. The cathode ray tube (CRT), the intensity of the phosphor How is it produced? What is its role in
which bulges from the back of a conventional TV, has color in any cell to create
millions of colors. creating a colored TV picture? Are
been replaced by plasma. Plasma is a gaseous mixture there other ways in which plasma is
of high-energy electrons and ions that activates tiny used today?
fluorescent tubes in chambers called pixels. A TV
• What are the properties of phos-
picture is created by hundreds of thousands
phors? What kinds of substances are
of pixels, each contributing a single point of
they and how do they produce light?
colored light. Inferring Explain why
you don’t see the points of light.
• Color theory—how do red, green and
blue light produce all imaginable col-
ors of light?
• Plasma is considered a fourth state of
matter. Explore the meaning of this
statement.
Pixels A pixel is divided into three • Explore the quality of plasma TV as
cells containing phosphors of red,
green, and blue. A phosphor is a compared with conventional TVs.
substance that emits light when Does the technology of plasma TV
excited, in this case by plasma.
assure superior picture quality?
Pixel
Display electrode
Phosphor
Answers to...
Inferring They are too small.