M.

Tonic
Meltin loint Of Tonic Compounds
Con M.p Ionie ormpounds deped on:
) Latiee energ
i) Polariztign
Nete: theoratical Prediction of Mp can
Eteme CAe cg. ether ony be mmade a in
is neg iable or Polarizatioh is negliaitle or folarication
domindi ng
DPolarizato
glgbe
Oxide and flburide ions are vety ifeutt to
Small Siza ard palarite
high ededroneg ati vity ardonly a due to
Lit Be
Con PoloTce l
few cation liBa
Lothce + Sorne ettent, n is decded by
ereg
Lattice
-K

Oposite charges q,kg ose brougkt to

terde ar distone
lons z, 2 changes in te pasiti e an
ande isis, thethe, chage of Qn ektro n -Ve

Lattiea
Eretgy
Lattie Ergg
Vorioion in the Latice Erargy wth
chang in chage
ord distce yae dfeut stu tions
i) When Ttereeevar
Same & charqe farbr CgTrtemuclear
) is
stove. facor
varied
is ept

Compoun Na -2
Sc N

Lttice Enery order: Naf < Ma0 < ScN< TiC

Meltny oint order : Naf.a Mgo
CSaere
Ôr der
ith haralne
i) 4 is Constant avrditer ndlen distone factor ie
Vord

Beo

Lehe Energy Order: Be O> Myo Cao

>Sro r Bao
Meting Poit Order' Mao

Latic
Eregy Bef> MgF) CaF SrF, baf;
 relng Poirt al
a lieenetgy
Here P ’ Pola tizion
Athoh
nYg Palariziom afods Melting
But Point t Lattice Energy order
Variations may not be the Samme hene there S no
Charge in Lattie order.
Causes Polarnzaion for 9owne etet for F o
.. Be o A Bef are not in their espected posthon
Snilang how Mg shout wte polarieation towads F" ion
42

ercharges its posionwdh af in their

Note!
elting Poit deder.
Altheugh it ageats that foareion by Sare aition
is less than that of o bt effeot ofot on Fa
1S nOre in Cage
o4 FThis is
pslaraton on Metig oit
due o just doiuble value ot
97 4or orde(9)) than
Compatod to f lburid ())
Polorizai6n Covalent character
or
ordeis.Mo,>ME but
for Alkali metal hal ids,
is less due to where the fect of polorization
lower chorge'on Cotien eq HtA n
Lottice Erergy
Melting foit order

Nar
 Compounds
Polari zaion
lie Lix are'no in their oriqi nal
pastion o
Cuse
to
Some Li1 ALix, Nat also Cavses polarizatien
eLtent and the eHei
fet eis detod
erved ik relting Point
ii Melting Poi t ordor
: When(g factor t and the dotarte foctor r .
This Causos
‘ in Latiee energg and meing pcirt.
eg NaF
ng At
1 2

r oder Na A|
3+

Latce Enerqy Order NaF < Mg F, < AlF3

M.P NaF Mg Fi < Al s
945'c I261"C 1241

Their Po larizaion oden i9 the ame

2 When Polarization is domintinq factor

when f t and M.P dectecses . Again polarization wi vary
o y moti ple factors.
M)When
C
charaqe cn Cotion ‘ radi os
Covalerit Charocter Order: NaX <
Melting Po int Orden: Nel > Mgxy rAlk
where h,x, is equal to ,Br,
 Cationt hut Size ot cation ‘ the polankzattow
) When
charye
ond m.p
n

Covalet charater order be X. xMa, x xSrt> ota

Melting ivt Order BeX < Mg

ey
Lix, No kx
Covalent Chamcer Oyder: ix > NaX > KX7 Sh
where x Cl, Br I
Here M.f is not deided acordi mgly sine polorzitbh is
low enough due to ber chage on catlon
Size t anion ‘.The
The folaization 1 A Mf
folanieation
i ) When of
For Seris where M* is L; to Cst
Coalen handr: MFZ MOK Mr MT
order
Melting Poit: MF >MC y MOr M
Order
2t
For Series mt is Bet
where nt Got
Ba
egCavalent chaacter Order : MF, ncd, MBra4Mh

eq
eg for Serias whee AlKs
A\k
Cavalet character Order: AlFae AlCly A\Brs <ARg
M.P Afs
 Solubilitu OF TONTe Componds
on Sveral pararctr
The solobilty of Tonie Compourdt deperd
i) Latie netg
4

i) Packing fotten

There is no tor mula which Can core lcte al these pararetors

with Solobilit. Hene we have to tudy Selubi lity here
the potametes is domminsing
when foslarizatian is dori nali ng
In Pobr Solvent: ‘ olarization will ause less Solu bility
ey Ci) A,f > AqCl Ag Br Ag 2.

arder is
In Non Polor Solvet, e Acebnethe golubiity !

Na Cl <NaT Their Covalent characler orden

K) < KÊ is ale ume
Mote the Covalert Chancer, bighe wil be Slutility polor
Solvert. This information helps us choase the Corect tolent for
reation For ea finelstein reacton
CHsCl t+k1 in uater
CHyT + KCl
In acetore

In woter thereoction is teversi ble &the ield at CHg1 is not god

Houwerer in acetone 1he ield is veru gocd in actone Re hecase
is insoloble and ma Bes the dita yacto undiredional
 aYe the dominting
)when Lstice Ereqy ond hy draton eegy
Factors

The meehanism for isdion proces of ionic Compourd is show belsw.

MYG) Xn

-AHe

ANS ht

.Coa)

whee AHs : Hat at dissolio

Latce
: Total
lbbl hydratomeneg ot eati on J anio
for dissotos o M
ASs Tsal etropy chane for diseltioD of r .
Tempin kelvin
I al the abore thetvrod yrami culhetraheical data is
roun Con Predict if the tompourd is Sale ar ot