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Previous Year JEE Questions: Chemical Equilibrium
wassimbhatt
Previous Year JEE Questions
CHEMICAL EQUILIBRIUM
wassimbhatt
The equilibrium constant at 298 K for a reaction, A + B ⇋ C + D is 100. If the initial

concentrations of all the four species were 1 M each, then equilibrium
concentration of D (in mol L-1 ) will be
0.818
1
1.818
2
1.182
3
0.182
4 (26th Aug 2021, 2016 Main)
wassimbhatt
The equilibrium constant at 298 K for a reaction, A + B ⇋ C + D is 100. If the initial

concentrations of all the four species were 1 M each, then equilibrium
concentration of D (in mol L-1 ) will be
0.818
1
1.818
2
1.182
3
0.182
4 (26th Aug 2021, 2016 Main)
wassimbhatt
Solution
wassimbhatt
When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27°C,
20% of the solid decomposes into gaseous ammonia and hydrogen sulphide. The
Kp for the reaction at 27°C is x × 10–2 . The value of x is _______. (Integer
answer) [Given R = 0.082 L atm K–1 mol–1 ]
(27th Aug 2021 Main)
wassimbhatt
When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27°C,
20% of the solid decomposes into gaseous ammonia and hydrogen sulphide. The
Kp for the reaction at 27°C is x × 10–2 . The value of x is _______. (Integer
answer) [Given R = 0.082 L atm K–1 mol–1 ]
Solution: 6
(27th Aug 2021 Main)
wassimbhatt
N2O4(g) ⇋ 2NO2(g)
Value of Kp for the given reaction at 288 K is 47.9. The Kc for this reaction at same
temperature is ___________ . (Nearest integer) (R = 0.083 L bar K-1 mol-1)
(22nd July 2021 Main)
wassimbhatt
N2O4(g) ⇋ 2NO2(g)
Value of Kp for the given reaction at 288 K is 47.9. The Kc for this reaction at same
temperature is ___________ . (Nearest integer) (R = 0.083 L bar K-1 mol-1)
Solution: 2
(22nd July 2021 Main)
wassimbhatt
For the reaction A + B ⇋ 2C, the value of equilibrium constant is 100 at 298 K. If
the initial concentration of all the three species is 1 M each, then the equilibrium
concentration of C is x × 10–1 M. The value of x is _____. (Nearest integer)
(25th July 2021 Main)
wassimbhatt
For the reaction A + B ⇋ 2C, the value of equilibrium constant is 100 at 298 K. If
the initial concentration of all the three species is 1 M each, then the equilibrium
concentration of C is x × 10–1 M. The value of x is _____. (Nearest integer)
Solution: 25
wassimbhatt
2SO2(g) + O2(g) ⇋ 2SO3(g)

In an equilibrium mixture, the partial pressures are PSO3 = 43 kPa, PO2 = 530 Pa
and PSO2 = 45 kPa. The equilibrium constant Kp = _____ x 10-2 . (Nearest integer)
wassimbhatt
2SO2(g) + O2(g) ⇋ 2SO3(g)

In an equilibrium mixture, the partial pressures are PSO3 = 43 kPa, PO2 = 530 Pa
and PSO2 = 45 kPa. The equilibrium constant Kp = _____ x 10-2 . (Nearest integer)
Solution: 172
wassimbhatt
N2O4(g) ⇋ 2NO2(g); △H0 = +58 kJ ,For each of the following cases (i), (ii), the
direction in which the equilibrium shifts is:
(i) Temperature decreases
(ii) Pressure is increased by adding N2 at constant T.
(i) towards product, (ii) towards product

1
(i) towards reactant, (ii) towards product

2
(i) towards reactant, (ii) no change

3
(i) towards product, (ii) no change

4 (2020, 5th Sep Main)
wassimbhatt
N2O4(g) ⇋ 2NO2(g); △H0 = +58 kJ ,For each of the following cases (i), (ii), the
direction in which the equilibrium shifts is:
(i) Temperature decreases
(ii) Pressure is increased by adding N2 at constant T.
(i) towards product, (ii) towards product

1
(i) towards reactant, (ii) towards product

2
(i) towards reactant, (ii) no change

3
(i) towards product, (ii) no change

4 (2020, 5th Sep Main)
wassimbhatt
Solution
wassimbhatt
The value of Kc is 64 at 800 K for the reaction

N2(g) + 3H2(g) ⇋ 2NH3(g). The value of Kc for the following reaction is
NH3(g) ⇋ ½ N2(g) + 3/2 H2(g)
1/64
1
8
2
1/4
3
1/8
4 (2020 6th Sep Main)
wassimbhatt
The value of Kc is 64 at 800 K for the reaction

N2(g) + 3H2(g) ⇋ 2NH3(g). The value of Kc for the following reaction is
NH3(g) ⇋ ½ N2(g) + 3/2 H2(g)
1/64
1
8
2
1/4
3
1/8
wassimbhatt
For the reaction, Fe2N(s) + 3/2 H2(g) ⇋ 2Fe(s) + NH3(g)
Kc = Kp(RT)
1
Kc = Kp(RT)-1/2
2
Kc = Kp(RT)1/2
3
Kc = Kp(RT)3/2
wassimbhatt
For the reaction, Fe2N(s) + 3/2 H2(g) ⇋ 2Fe(s) + NH3(g)
Kc = Kp(RT)
1
Kc = Kp(RT)-1/2
2
Kc = Kp(RT)1/2
3
Kc = Kp(RT)3/2
wassimbhatt
In which one of the following equilibria, Kp = Kc ?
2C(s) + O2(g) ⇋ 2CO(g)

1
2HI(g) ⇋ H2(g) + I2(g)

2
NO2(g) + SO2(g) ⇋ NO(g) + SO3(g)

3
2NO(g) ⇋ N2(g) + O2(g)

4 (2019 Main, 12 April II)
wassimbhatt
In which one of the following equilibria, Kp = Kc ?
2C(s) + O2(g) ⇋ 2CO(g)

1
2HI(g) ⇋ H2(g) + I2(g)

2
NO2(g) + SO2(g) ⇋ NO(g) + SO3(g)

3
2NO(g) ⇋ N2(g) + O2(g)

wassimbhatt
Solution
wassimbhatt
S(s) + O2(g) ⇋ SO2(g); K1 = 1052 2S(s) + 3O2(g) ⇋ 2SO3(g); K2 = 10129

The equilibrium constant for the reaction, 2SO2(g) + O2(g) ⇋ 2SO3(g)
1025
1
1077
2
10154
3
10181
wassimbhatt
S(s) + O2(g) ⇋ SO2(g); K1 = 1052 2S(s) + 3O2(g) ⇋ 2SO3(g); K2 = 10129

The equilibrium constant for the reaction, 2SO2(g) + O2(g) ⇋ 2SO3(g)
1025
1
1077
2
10154
3
10181
wassimbhatt
Solution
wassimbhatt
K
In a chemical rxn, A+ 2B ⇋ 2C + D, the initial conc. of B was 1.5 times of the conc.
of A, but the equilibrium concentrations of A and B were found to be equal. The
equilibrium constant (K) for the aforesaid chemical rxn is
1/4
1
16
2
1
3
4
4 (2019 Main, 12 Jan I)
wassimbhatt
K
In a chemical rxn, A+ 2B ⇋ 2C + D, the initial conc. of B was 1.5 times of the conc.
of A, but the equilibrium concentrations of A and B were found to be equal. The
equilibrium constant (K) for the aforesaid chemical rxn is
1/4
1
16
2
1
3
4
4 (2019 Main, 12 Jan I)
wassimbhatt
Solution
wassimbhatt
A2(g) + B2(g) ⇋ 2AB(g); K1 6AB(g) ⇋ 3A2(g) + 3B2(g); K2

The relation between K1 and K2 is:
K2 = K13
1
K1 K2 = 3
2
K2 = K1-3
3
K1 K2 = 1/3
4 (2019 Main, 9 Jan II)
wassimbhatt
A2(g) + B2(g) ⇋ 2AB(g); K1 6AB(g) ⇋ 3A2(g) + 3B2(g); K2

The relation between K1 and K2 is:
K2 = K13
1
K1 K2 = 3
2
K2 = K1-3
3
K1 K2 = 1/3
4 (2019 Main, 9 Jan II)
wassimbhatt
Solution
wassimbhatt
For the chemical reaction 3X(g) + Y(g) ⇋ X3Y(g), the amount of X3Y at equilibrium
is affected by
temperature and pressure

1
temperature only
2
pressure only
3
temperature, pressure and catalyst

4 (1999, 2M)
wassimbhatt
For the chemical reaction 3X(g) + Y(g) ⇋ X3Y(g), the amount of X3Y at equilibrium
is affected by
temperature and pressure ● Both temperature and

1 pressure will change the
equilibrium amount of X3Y
(g).
temperature only
2 ● Temperature changes the
value of equilibrium
pressure only constant.
3
temperature, pressure and catalyst

4 (1999, 2M)
wassimbhatt
One mole of N2O4 (g) at 300 K is kept in a closed container under one atm. It is
heated to 600 K when 20% by mass of N2O4 (g) decomposes to NO2 (g). The
resultant pressure is
1.2 atm
1
2.4 atm
2
2.0 atm
3
1.0 atm
4 (1996, 1M)
wassimbhatt
One mole of N2O4 (g) at 300 K is kept in a closed container under one atm. It is
heated to 600 K when 20% by mass of N2O4 (g) decomposes to NO2 (g). The
resultant pressure is
1.2 atm
1
2.4 atm
2
2.0 atm
3
1.0 atm
4 (1996, 1M)
wassimbhatt
For the reaction , CO(g) + H2O(g) ⇋ CO2(g) + H2(g) , at a given temperature, the
equilibrium amount of CO2(g) can be increased by
adding a suitable catalyst

1
adding an inert gas

2
decreasing the volume of

3 the container
increasing the amount of CO(g )

4 (1996, 1M)
wassimbhatt
For the reaction , CO(g) + H2O(g) ⇋ CO2(g) + H2(g) , at a given temperature, the
equilibrium amount of CO2(g) can be increased by
adding a suitable catalyst ● Adding reactant will drive the

1 reaction in forward direction in
order to restore equilibrium.
● Therefore, addition of CO (g) will
adding an inert gas increase the equilibrium amount of
2
CO2 .
decreasing the volume of
3 the container
increasing the amount of CO(g )

4 (1996, 1M)
wassimbhatt
2 years 2 years 2 years
2700 3600 5400
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Previous Year JEE Questions: Chemical Equilibrium

Previous Year JEE Questions

The equilibrium constant at 298 K for a reaction, A + B ⇋ C + D is 100. If the initial

The equilibrium constant at 298 K for a reaction, A + B ⇋ C + D is 100. If the initial

(27th Aug 2021 Main)

(27th Aug 2021 Main)

(22nd July 2021 Main)

(22nd July 2021 Main)

(25th July 2021 Main)

(25th July 2021 Main)

2SO2(g) + O2(g) ⇋ 2SO3(g)

(20th July 2021 Main)

2SO2(g) + O2(g) ⇋ 2SO3(g)

(20th July 2021 Main)

(i) towards product, (ii) towards product

(i) towards reactant, (ii) towards product

(i) towards reactant, (ii) no change

(i) towards product, (ii) no change

(i) towards product, (ii) towards product

(i) towards reactant, (ii) towards product

(i) towards reactant, (ii) no change

(i) towards product, (ii) no change

The value of Kc is 64 at 800 K for the reaction

The value of Kc is 64 at 800 K for the reaction

For the reaction, Fe2N(s) + 3/2 H2(g) ⇋ 2Fe(s) + NH3(g)

For the reaction, Fe2N(s) + 3/2 H2(g) ⇋ 2Fe(s) + NH3(g)

In which one of the following equilibria, Kp = Kc ?

2C(s) + O2(g) ⇋ 2CO(g)

2HI(g) ⇋ H2(g) + I2(g)

NO2(g) + SO2(g) ⇋ NO(g) + SO3(g)

2NO(g) ⇋ N2(g) + O2(g)

In which one of the following equilibria, Kp = Kc ?

2C(s) + O2(g) ⇋ 2CO(g)

2HI(g) ⇋ H2(g) + I2(g)

NO2(g) + SO2(g) ⇋ NO(g) + SO3(g)

2NO(g) ⇋ N2(g) + O2(g)

S(s) + O2(g) ⇋ SO2(g); K1 = 1052 2S(s) + 3O2(g) ⇋ 2SO3(g); K2 = 10129

S(s) + O2(g) ⇋ SO2(g); K1 = 1052 2S(s) + 3O2(g) ⇋ 2SO3(g); K2 = 10129

A2(g) + B2(g) ⇋ 2AB(g); K1 6AB(g) ⇋ 3A2(g) + 3B2(g); K2

A2(g) + B2(g) ⇋ 2AB(g); K1 6AB(g) ⇋ 3A2(g) + 3B2(g); K2

temperature and pressure

temperature, pressure and catalyst

temperature and pressure ● Both temperature and

temperature, pressure and catalyst

adding a suitable catalyst

adding an inert gas

decreasing the volume of

increasing the amount of CO(g )

adding a suitable catalyst ● Adding reactant will drive the

increasing the amount of CO(g )

2700 3600 5400

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