Sec: Jr.

COIPL Date: 10-12-16

Time: 07:30 AM to 10:30 AM WTM-31 Max.Marks:360

CHEMISTRY:
Strengths of acids, Strengths of bases, Tautomerism (including mechanism of acid & base
catlayzed tautomerizations) (70%)
Aromaticity, Hyperconjugation, Electromeric effect, Electrophiles and nucleophiles, Reactive
intermediates (Carbocations, Carbanions, Free radicals, Carbenes, nitrenes) (30%)
61. Which of the following is stronger acid?
1) CH2=CHCOOH
2) FCH2COOH
3) BrCH2COOH
4) F2CHCOOH
62. Arrange the following compounds in correct order of acidity

1) I > II > III > IV

2) III > I > II > IV
3) I > III > II > IV
4) None of these
63. In which of the following compounds the methylene hydrogens are most acidic?
1) CH3COCH2CH3
2) CH3CH2COOEt
3) CH3CH2CH(COOEt)2
4) CH3COCH2CN
64. Arrange the following compounds in correct order of acidity

(a) (b)

(c) (d)
1) d > c > a > b 2) d > a> c> b
3) d > c > b > a 4) d > b> a > c
65. Which order is correct about acidity
1) CH3COOH>PhCOOH>PhOH
2) PhCOOH > CH3COOH > PhOH
3) PhOH> PhCOOH > CH3COOH
4) PhOH> CH3COOH > PhCOOH
66. The enolic from of acetone contains:
1) 9 s bonds, 1 p –bond, and 2 lone pairs.
2) 8 s bonds, 2 p –bonds, and 2 lone pairs.
3) 10 s bonds, 2 p –bonds, and 1 lone pair
4) 9 s bonds, 2 p –bonds, and 2 lone pairs.
67. Tautomerism is not exhibited by:

1) 2)

3) 4)

D2O / DO
D2O / DO
68. Prolonged treatment of (A) with given:

1) 2)

3) 4)
69. Order of enol content for the following compounds:

(a)

(b)

(c)
1) a > b > c 2) b > a > c
3) b > c > a 4) c > b > a
70. Correct relationship between the two structures given below is

1) Chain isomers
2) Tautormers
3) Geometrical isomers
4) Position isomers
71. The IUPAC name of the given compound

1) 2-Bromo-4-carbamoyl-5-chloroformyl-3-formylhexanoic acid
2) 5-Bromo-3-carbamoyl-2-chloroformyl-4-formylhexanoic acid
3) 4-Formyl-2-chloroformyl-3-carbamoyl-5-bromohexanoic acid
4) 2-Chloroformyl-3-carbamoyl-4-formyl-5-bromohexanoic acid
72. The correct statement(s) concerning the structures E,F and G is /are:

(i) E and G are functional isomers

(ii) E and F are tautomers
(iii) F and G are geometrical isomers
(iv) F and G are rotamers
1) (ii) & (iv)
2) (i) & (iii)
3) (i),(ii) & (iii)
4) (i),(ii),(iii) & (iv)11.
73. How many structural isomers of C5H10O show ENOLIZATION?
1) 4 2) 5
3) 6 4) 7
74. The compound with highest enol content among the following is

1)

2)
 O O

3) H3CO OCH3
O O

4) H2N NH2

75. Among the following the strongest base is

1) 2)

3) 4)
76. In which molecule, the N in the circle is less basic than other nitrogen atoms within the
molecule?

1) 2)

3) 4)
77. Which of the following compound option is correctly matched?

1)

2)

3)

4)
78. Among the following most acidic compound is:

1) 2)

3) 4)
79. The weakest base, among the following molecules is

1) 2)

3) 4)
80. In which of the following molecule electron density on the benzene is maximum?

1)

2)

3)

4)
81. Which of the following compounds will have the largest Ka value?
1) Acetone 2) Acetaldehyde
3) water 4) hydrogencyanide
82. the most basic among the following molecules is

1) 2)
 3) 4)
83. ‘a’ and ‘b’ and ‘c’ are represents bond length of ‘C=C’; then what is the correct order of
bond length?

1) a = b = c 2) a > b> c
3) a = c < b 4) Unpredictable
84. The maximum number of nonbonding electrons are involved in delocalization
in ADENINE is

1) 1 2) 2
3) 4 4) 5
85. Which of the following is (are) Aromatic?

i) (Benzyne)
ii) [4]-Annulene
iii) [8]-Annulene
iv) [10]-Annulene(with two trans double bonds)
1) i 2) iv
3) i & iv 4) i,iii & iv
86. Which is least polar?

1) 2)

3) 4)
87. How many of the following compound(s) have their net dipole moment moving outward
from the aromatic ring?
 1) 7 2) 6
3) 5 4) 4
88. How many of the following ion(s) has/have at least one canonical structure in which all
atoms (except hydrogen) have their octet complete?

1) 3 2) 4
3) 5 4) 6
89. How many of the following group(s) shows both (-I) and (-M) effect, if attached to phenyl
ring?
i) –Cl ii)-NH-COR iii)-OCH3
iv) -CN v)-NO2 vi)-COOR
+
vii) − N R3 viii) −CCl3 ix) −SO3 H
1) 3 2) 4
3) 5 4) 6
90. Glycerol can be separated from spent-lye in soap industry by?
1) steam distillation
2) fractional distillation
3) distillation under reduced pressure
4) ordinary distillation

CHEMISTRY:
61 4 62 3 63 4 64 1 65 2 66 1
67 2 68 2 69 3 70 3 71 2 72 3
73 4 74 3 75 3 76 4 77 3 78 1
79 2 80 3 81 4 82 2 83 3 84 2

85 1 86 2 87 3 88 3 89 3 90 1