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Maths Pack 3
Maths Pack 3
Maths Pack 3
Class: ________________________
Date: ________________________
Time: 49 minutes
Marks: 42 marks
Comments:
Page 1 of 14
Q1.
A sample of 2.18 g of oxygen gas has a volume of 1870 cm 3 at a pressure of 101 kPa.
A 167 K
B 334 K
C 668 K
D 334 000 K
(Total 1 mark)
Q2.
Which of the following solutions would react exactly with a solution containing 0.0500 mol
sulfuric acid?
Q3.
30 cm3 of xenon are mixed with 20 cm3 of fluorine. The gases react according to the
following equation. Assume that the temperature and pressure remain constant.
A 50 cm3
B 40 cm3
C 30 cm3
D 20 cm3
(Total 1 mark)
Q4.
Page 2 of 14
A saturated aqueous solution of magnesium hydroxide contains 1.17 × 10 –3 g of Mg(OH)2
in 100 cm3 of solution. In this solution, the magnesium hydroxide is fully dissociated into
ions.
Q5.
Magnesium reacts with hydrochloric acid according to the following equation.
Mg + 2HCl MgCl2 + H2
A student calculated the minimum volume of 2.56 mol dm–3 hydrochloric acid required to
react with an excess of magnesium to form 5.46 g of magnesium chloride (Mr = 95.3).
Which of the following uses the correct standard form and the appropriate number of
significant figures to give the correct result of the calculation?
Q6.
There are 392 mol of pure gold in a bar measuring 10 cm by 10 cm by 40 cm.
What is the density of gold in kg dm −3?
A 193
B 19.3
C 1.93
D 0.193
(Total 1 mark)
Page 3 of 14
Q7.
The oxidising agent in solution A is sodium bromate(V), NaBrO3. A laboratory technician
wanted to make up enough of this solution for use in a class practical.
Calculate the mass of sodium bromate(V) needed to prepare 5.00 dm 3 of a 5.00 × 10–
3 mol dm–3 solution.
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(Total 2 marks)
Q8.
A student was given a powder made from a mixture of anhydrous barium chloride and
anhydrous magnesium chloride. The student dissolved 1.056 g of the powder in water in a
conical flask and added an excess of sulfuric acid.
A white precipitate formed and was filtered off, washed and dried.
The mass of this solid was 0.764 g.
Identify the white precipitate and calculate the percentage, by mass, of magnesium
chloride in the powder.
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(Total 4 marks)
Page 4 of 14
Q9.
Ethene reacts with steam in the presence of an acid catalyst to form ethanol.
(a) Write an expression for the equilibrium constant Kc for this equilibrium.
Deduce the units of Kc.
Expression _________________________________________________________
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Units ______________________________________________________________
(2)
(b) An equilibrium mixture was found to contain 0.700 mol of ethene, 1.20 mol of steam
and 4.40 mol of ethanol at a temperature T. The volume of the container was 2.00
dm3.
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(2)
(Total 4 marks)
Q10.
The diagram represents two glass flasks, P and Q, connected via a tap.
Flask Q (volume = 1.00 × 103 cm3) is filled with ammonia (NH3) at 102 kPa and 300 K. The
tap is closed and there is a vacuum in flask P.
(Gas constant R = 8.31 J K−1 mol−1)
Page 5 of 14
(a) Calculate the mass of ammonia in flask Q.
Give your answer to the appropriate number of significant figures.
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(3)
(b) When the tap is opened, ammonia passes into flask P. The temperature decreases
by 5 °C. The final pressure in both flasks is 75.0 kPa.
Calculate the volume, in cm 3, of flask P.
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(3)
(Total 6 marks)
Page 6 of 14
Q11.
2 mol of ideal gas X are stored in a flask of fixed volume.
Which of the following changes would lead to the greatest increase in pressure inside the
flask?
Q12.
Phosphoric(V) acid (H3PO4) is an important chemical. It can be made by two methods.
The first method is a two-step process.
(a) In the first step of the first method, phosphorus is burned in air at 500 ºC to produce
gaseous phosphorus(V) oxide.
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(4)
(b) In the second step of the first method, phosphorus(V) oxide reacts with water to
form phosphoric(V) acid.
Page 7 of 14
5.00 mol dm–3 phosphoric(V) acid solution.
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(3)
(c) In the second method to produce phosphoric(V) acid, 3.50 kg of Ca 3(PO4)2 are
added to an excess of aqueous sulfuric acid.
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(4)
(d) Explain whether the first method or the second method of production of phosphoric
acid has the higher atom economy.
You are not required to do a calculation.
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(1)
(Total 12 marks)
Q13.
Compounds containing Cu2 +, OH– and CO32− ions are sometimes described as basic
copper carbonates.
Page 8 of 14
A solution of copper(II) chloride is formed, together with two other products.
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(2)
(ii) Suggest one observation that could be made during the reaction.
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(1)
(b) A 5.000 g sample of a different basic copper carbonate contains 0.348 g of carbon,
0.029 g of hydrogen and 1.858 g of oxygen.
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(1)
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(3)
(Total 7 marks)
Page 9 of 14
Mark schemes
Q1.
B
[1]
Q2.
D
[1]
Q3.
C
[1]
Q4.
D
[1]
Q5.
B
[1]
Q6.
B
[1]
Q7.
Mr of sodium bromate(V) = 150.9
and
Mol sodium bromate(V) = 5.00 x (5.00 x 10 –3) = 0.0250 M1
Lose M1 if 151 used (final answer may appear as 3.78).
1
Q8.
Identifies precipitate as being BaSO4
1
Moles of Barium sulfate = mass/Mr
(= 0.764 / 233.4)
= 0.003273 moles
Allow conseq if Mr BaSO4 or BaCl2 incorrect
1
Page 10 of 14
Mass of Barium chloride = 208.3 × 0.003273 = 0.6818 g
1
Q9.
(a)
Penalise missing brackets or use of (); allow correct
molecular formulae in correct expression (and allow
CH2CH2); ignore powers shown as 1
1
M2 mol−1 dm3
Units must be in simplest form on one line (or dm 3 mol−1)
Units are consequential on expression in M1 (mol −1 dm3 only
scores if it is the units for the expression in M1)
1
(b)
10.5 (3sf) scores both marks;
Correct value to 2sf (10) or 4sf or more (10.476...) scores 1
mark
Volume not used is CE=0
If use incorrect expression for Kc in part (b) then no marks in
part (b)
1
Q10.
(a) n = PV/RT
If PV=nRT rearranged incorrectly then M3 only
1
Page 11 of 14
1
(b) If pV = nRT
= 1.34 × 10−3 m3
Inserts correct numbers (inc pressure in Pa)
1
Q11.
C
[1]
Q12.
(a) Correct conversion of temperature and pressure (773 and 101 × 10 3)
Correct answer with or without working scores 4 marks
1
No moles P = (220 / 4 × 31.0) = 1.77
Max 2 (M1 and M3) if 31.0 used
(=0.451 m3 or if 220/31 rounded to 2 sf ie 7.1 then 0.452)
1
V = nRT/P (correct rearrangement or insert of values V =
1.77 × 8.31 × 773/101 × 10 3 =0.1128 m3)
Max 2 (M1 and M3) if 284 (P4O10) used then 0.0493
1
V = 0.113 (m3)
Page 12 of 14
Must be 3 sig figs
1
(d) Method 1 / (a) & (b) because only one product / no other
products formed / atom economy = 100% (even though two
steps)
Allow calculations
Do not allow if P2O5 is formed
Allow converse explanation
1
[12]
Q13.
(a) (i) H2O + CO2 (as products in any equation)
Allow H2O + H2CO3
1
Page 13 of 14
Cu2(OH)2CO3 + 4HCl → 2CuCl2 + 3H2O + CO2
Allow multiples
Ignore states
1
Page 14 of 14