Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-5(N) Date: 02-01-24

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 C 2 D 3 B 4 B 5 B
6 C 7 A 8 C 9 D 10 A
11 B 12 C 13 C 14 D 15 C
16 D 17 C 18 B 19 D 20 B
21 -13 22 9 23 8 24 701 25 25
26 10 27 79 28 1 29 20 30 328

CHEMISTRY
31 D 32 C 33 B 34 C 35 B
36 D 37 C 38 C 39 D 40 B
41 C 42 D 43 B 44 B 45 C
46 C 47 C 48 C 49 B 50 B
51 3 52 8 53 4 54 6 55 1
56 2 57 7 58 2 59 5 60 2

MATHEMATICS
61 D 62 C 63 D 64 C 65 D
66 C 67 C 68 D 69 D 70 B
71 C 72 B 73 C 74 B 75 A
76 C 77 B 78 C 79 B 80 B
81 20 82 4 83 10 84 64 85 2
86 3 87 5 88 46 89 3 90 1

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 Narayana IIT Academy 02-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-5(N)_KEY&SOL
SOLUTIONS
PHYSICS
^ ^
 ^ ^

1. Initial velocity of stone w.r.t lift  20sin 300 j  20cos300 i   10 3 i  10 j  m / s
 

 ^ ^

Initial velocity of stone w.r.t ground  10 3 i  12 j  m / s
 
The initial position of stone and lift are same and when they again meet their final positions will also
be same. So both will have same displacement in vertical direction in same time
1 t2
Displacement of lift  2  t    1  t 2  2t 
2 2
1
Displacement of stone  12  t    10  t 2  12t  5t 2
2
2
t
So 2t   12t  5t 2
2
2
11t 20
 10t or t  sec
2 11
20
So time taken by stone to return to the floor of lift is sec
11
dW
2. For W to be maximum;  0;
dx
i.e., F  x   0  x  l , x  0
Clearly for d  l , the work done is maximum.
Alternate Solution:
External force and displacement are in the same direction
 work will be positive continuously so it will be maximum when displacement is maximum.
 I 4  107  18
3. B 0  T  18t
2 r 2  0.2
I I
Now, T  2 and T   2 d
MBH M  BH  B 
T BH T 24
Dividing  or  2
T BH  B T 24  18
T   2  0.1s  0.2 s
4. In the circular motion around the earth, the centripetal force on the satellite is a gravitational force.
Therefore, v 2  GM / R , where M is the mass of the Earth, R is the radius of the orbit of satellite and
G is the universal gravitational constant. Therefore, the kinetic energy increases with the decrease in
the radius of the orbit. The gravitational potential energy is negative and decreases with the decrease
in radius.
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5. For an adiabatic process,
0 = dU + PdU
or d(a+bPV) + PdV=0
dV dP
or  b  1 b 0
V P
or (b+1) log V + b log P = constant
V b 1 p b  constant
b 1
or PV b
 constant
b 1
 
b
3RT
6. vrms  . According to problem T will becomes 2T and M will become M/2 so the value of vrms
M
will increase by 4  2 times i.e., new root mean square velocity will be 2v .
7. When sources are coherent, then I R  I1  I 2  2 I1 I 2 cos 
At middle point of the screen,   0 then
I R  I  I  2 II cos 0  4 I
When sources are in coherent, then I R '  I1  I 2  I  I  2I
I R 4I
 =2
I R' 2I
l
8. T 2  4 2
g
4 2l
g
T2
g l T
  100   100  2  100
g l T
g
  y  2x
g
9. Using perpendicular axis theorem I = I1 + I2 and I = I3 + I4 also, I1 = I2 = I3 = I4 hence option 4 is
wrong.
10. We know that
1
PB  PA   2 a 2
2
PD  PA   ga
1 1
PC  PD   2 a 2  PA   ga   2 a 2
2 2
Therefore,
Pc  PA for all the values of  and PB  PD only
2g
If  
a
^
11. For p k it is equatorial point
1 P ^
 E1  k 
4 0 1  
P^
For k it is axial point
2

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P   ^
 2 k 
1 2    1 p k^
 E2 
4 0 23 4 0 8
7p ^
 E  E1  E2   k
32 0

mv
12. Radius of circular orbit R 
qB
2mKE 2mT
 
qB qB
2
If T becomes double & ‘B” becomes tripled then radius becomes R
9
13. de  B  x  dx

3L
e  B  x dx
2L

5 B L
2

2
14. I d  1mA  103 A
C  2 F  2  106 F
d dV
I D  I C   CV   V
dt dt
dV I D 103
Therefore,    500 Vs 1
dt C 2  106
Therefore, applying a varying potential difference of 500 Vs-1 would produce a displacement current
of desired value.
15. Radius of circular path described by a charged particle in a magnetic field is given
2mK q 2 B 2 r 2  e  eB 2 r 2
by r  ; Where K = Kinetic energy of electron  K   
qB 2m m 2
2
1  1 
 105   1  8  10 20 J  0.5eV
2
  1.7  1011  1.6 10 19  
2  17 
 12375 
By using  W0  E  K max    eV  0.5eV  4.5eV
 2475 

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16.

1. As mutual repulsive force between the particles is internal for the system and as there is no other
external force on the system, linear momentum of the system is conserved in any direction.
2. As the forces on the particles due to one on the other are equal in magnitude. Opposite in direction
and act along the line joining them always, net torque on the system due to these forces about any
point in space in zero. Therefore angular momentum of the system remains constant about any point
in space.
3. As center of mass of the system lies on the line joining the particles always and force on any of
them is passing through C.M always, torque due to this force on any particle about C.M is zero.
Hence angular momentum of any particle about C.M is conserved individually.
4. About any other point except C.M, torque on any individual particle is not zero. Hence angular
momenta of individual particles change but total angular momentum of the system remains constant.
17.

F  mg sin   mg tan   is small  .

dy 2x
i.e, F  mg   mg 
dx 40
x 1
 a    
2 2
18. Potential at any point inside the shell = potential at any point on the surface
 potential at A = potential at C due to ‘q’ and induced charges =
1 q 1 q 1  q  1 q
   
4 0 r 4 0 R 4 0  R  4 0 r
19. For A  B  C   ,  is the positive. This is because Eb for D and E is greater then Eb for F.

20. It is a case of resonance

X L  X C
Z R
Vrms 200
 I rms    2A
Z 100
 Pav  I rms
2
R  4  100  400W
21. Change in linear momentum P   Fdt
 
15
15  v f  u    40cos   t dt
0  10 
40  sin  / 10  t 
15
400
v f  4     4   1  12.5 m / s
15   / 10  0 15

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22. ‘O’ is off axis for axis for both the parts. Size of object for upper and lower parts is
2mm and 1 mm respectively.
1 1 1
 
f v u
1 1 1
   v  60Cm
20 v 30
v
m 2
u
 Distance between the two image points is 4 + 2 + 1 + 2 = 9mm
23. Because the collision is perfectly inelastic, the two blocks stick together. By conservation of linear
momentum.
v
2 mV  mv orV 
2
By conservation of energy,
1 v2
2mgh   2mv 2 or h 
2 8.g
 x8
T TL L
24. V & Y &   
 AL L
T Y L Y  
V   
A L 
1.3  1011  1.7  105  20
V  70 m / s
9  103
Cdl
25. dR 
l
l 1
dl dl
0 C l  C l l
1
2 l l0  2 l
l

2 l  22 l
4 l 2
1
 l   0.25m
4
26. The forward biased resistance of a diode is
V 0.7  06
R 
I 15  5   103
01
R  10
10  10 3
27. Energy required to remove first electron is 24.6 eV. After removing first electrons from this atom, it
will become He+
E1   13.6  2 
2
 as EZ 2
and Z  2 
= - 54.4 eV
 Energy required to remove this second electrons will be 54.4 eV.
 Total energy required to remove both electrons
= 24.6 + 54.4
= 79 eV
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1 12
28. Req = 0.3   0.3   1.5
1 1 1 10
 
2 4 12
Applying ohm’s law,
V  IR
1.5
I  1A
1.5
29. FBD of the spherical ball

For translation equilibrium

T cos150  Mg   N
T sin150  N
Alsot  L
   NR  t  I0
2
MR 20
t  5
 NR
Solving we get t = 20 s
1
30.  I 0  11
4
2
 I 0  27
4
2  1
 16 cm
4
 1 1 
V     0.64 m
 256 512 
 V  512  0.64 m / s
 328 m / s

CHEMISTRY
31. A) SO3 & CO3 ; Both are sp 2 & planar triangular

B) SO32  & NH 3 ; Both are sp3 & pyramidal

C) PCl5 : sp 3 d & trigonal bipyramidal
POCl5 : sp 3 & tetra hedral
D) XeF2 : sp 3 d & linear
ClF3 : sp 3 d & T–shape
As per M.O.T

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32. B2 : By distributing 10 electrons only two electrons in   B .M .O are extra left without cancelling
with A.B.M.O electrons
C2 : By distributing 12 electrons, only 4 electrons in  B.M .O are extra left without cancelling with A
B M O electrons
N2 : By distributing 14 electrons only 4 electrons & 2  electrons in B M O & extra left without
cancelling with A B M O electrons.
 22.44
33. No of moles of M  g  formed =
374
 0.06 moles  0.06  6.023  10 23

 3.613 1022 atoms

At.wt.
 22.44  374
8
 At .Wt .  133.33 g .
34. Due to small B.L of N–N bond lp–lp repulsions on ‘N’ weaken the bond.
35. 0.1 moles of the complex – 28.7 g of AgCl
1 mole gives of complex – 287 g of AgCl
– 2 moles of AgCl
 2 Cl ions should be ionisable.
-

36. The complex cannot show hydration isomerism as no H 2O ligands are present.
37. The colour of KMnO4 is due to charge transfer phenomenon
38. nm.eq NH 3  nm.eq H 2 SO4
 10  1  2  20meq of NH3 = 20 m mol of NH3
1400  neq NH 3
%N 
wt.of organic compound
1400  20  10 3
  56% .
0.5
39.

40. Reactivity order IV > I > III > II > V on the basis of R and I effect of associated groups.

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41.
CH2 CH=CH2 Friedal- craft's aklylation
A=

CH2 CH2 CH2 OH Hydroboration -oxidation

B=

C=

42.

43. Cleavage of the double bond by Ozonolysis, iodoform Rxn, dry distillation of calcium salts to give
cyclopentanone, followed by wolf–kishner reduction to give cyclohexane.
44. Benzyllic oxidation to give potassium salt of Benzoic acid, followed by acidification to give Benzoic
acid.
45. Gabriel pthalamide synthesis

46. Keratin and myosin are fibrous proteins and insoluble in H 2O .

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4
1.382  10  1000
47.  61.9  76.3 
S
 S  10 3 M .
48. T f  K f  m
50 1000
9.3  1.86  
62 x
 x  161.29 g
 Amount of ice separated  200  161.29
 38.71g
49. Required energy = I1  I 2

I1  24.6eV

I 2  I H  Z 2  13.6  22  54.4eV

 E  24.6  54.4  79 eV

50. 3A B
t  4 min; a  3 x  x
a
 4x  a  x 
4
 At 4 min 75% of first order is completed.
2t1 t
 t75%   1  2 min .
2 2
51. X  12  Mg  ; Y  15  P 
52. conceptual
53. Greater the stability of carbanion, greater is the rate of decarboxylation.
Except  CH 3 3 C  COOH remaining are more reactive than CH 3COOH .
O
||
54. Except  C  O  R , remaining are ring activating groups.
55.

56. FCH2CHO, O2N CH2CHO are more reactive than acetaldehyde.

57. H 2 g   2 Haq   2e
0.059 2
0.413   log  H  
2
 pH  7 .

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58. E 0  E Ag
0

/ Ag
 0.06 log K SP

59. Number of moles of CH 3COOH  0.25  0.3  0.075 moles

Number of moles of CH 3COO   0.56  0.3  0.168
 Number of moles of CH 3COO  left = 0.168  0.006  0.162
Final number of moles of CH 3COOH  0.075  0.006  0.081
0.162
 pH  4.7  log .
0.081
60. NH 4 HS S   NH 3 g   H 2 S g 
x 1  x 
At equilibrium
1  x  x  3  x  1atm

 K P  2  1  2 atm 2 .
MATHS
61. Clearly ( x  1) 2  y 2  ( x  3)  i ( y  3)
 y  3 and ( x  1) 2  9  ( x  3) 2
1
 x
4
1
But    3i does not satisfy the given equation
4
 2k  k 4
62. Let f ( x)  x 2   x   0 by the given data, f (0)  0, f (2)  0, f (3)  0
 k 5  k 5
k 4
 0 ………. (1)
(k  5)
k  24
 0 …….. (2)
(k  5)
4k  49
 0 …….. (3)
(k  5)
 49 
From (1), (2) and (3), k   , 24 
 4 
63. Here A  A  A is an Idempotent matrix
2

 A  A2  A3  ..........  A99
Hence ( I  A)99  I   299  1 A
64. We can take 3 cases namely four odd numbers, two odd numbers and zero odd numbers.
Let X be the number of odd numbers chosen
 P(sum is even)  P ( X  4)  P ( X  2)  P ( X  0)
4 2 2 4
2  2 1 1 41
    4 C2        
3  3   3   3  81
65. Let f ( y ) be the inverse of g ( y )
 f '  g ( y )  g '( y )  1
1 1
 f '  g (2)  g '(2)  1   g 1  y    
y 2 f '  1 14

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66. S1 and S2 are skew lines
cos x  x sin x
67. I  dx
x.cos x
Put x.cos x  t 2  I  2 x.cos x  c
 
x2 d x2
0 k  x d
d 0 k  x
d
68. I  lim  lim
 0    sin   0 (1  cos )
(By. L. Hospitals Rule)
  2

 
k  2
 lim  2   1  k  4

 0 2sin  / 2
 k
69. Given equation can be reduced to
dy 1
cos y    sin y   et (1  t )
dt  
1  t
dy dv
Put sin y  v  cos y 
dt dt
sin y
Hence the solution is   et  c 
(t  1)
 cot k  y   tan k  y  2  cot 1 k   0 has real roots
1 2 1 3/ 2 2
70.
 D  0  tan 1 k   / 3  k  3 and sum of roots  0, product of roots  0
 k  0 and k  3
71. Let Tr 1 be the Independent term of x then r  6,
 t61  84 3  6
72. Check for what values of x , g '( x)  0 or does not exist
x x   xi
2
i
2
i 
73. Mean  10 and Variance     4
n n  n 


x 2
i
 104 
x i

4
 102
n n n
 n  20
Hence new Variance = 3.96
1
74. From the graph of the functions, the required area = 2   
x  x 2 dx 
2
3
0

75. f  x   x sin x is differentiable at x  0

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 Narayana IIT Academy 02-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-5(N)_KEY&SOL
76. L.H.L.  lim  f ( )  0 and R.H.L.  lim  f ( )  
   
2 2
 lim f ( ) does not exist
  / 2
77.
x1/ 3  2  g  x 
 f  x  52  x  2  x  2  x 
2 3

 x 3  7 x 2  11x  2  f max  3
Clearly 1 is the root  a + b + c + = 0
x x x
 1   2   n 
     ....   1
 n 1   n 1   n 1 

0
1
78. Clearly k  cot 22  2  1
2
Hence 100 (k  1)   141
79. Use L11 . L22  0 for three sides of the triangle
80. Clearly a  2; b  1 and c  2 and

a1a2  b1b2  c1c2

Use   cos1
a a2
1
2
2

81. p 2  q 2  1 or p 2  q 2  0
1
 z 2018  z   z 2019  1
z
So there are total 2020 solutions
82. The inclination of the line L  x  y  1 is 1350 . So the slopes of the other two sides will be
tan 1350  600 

83. E  a  b  2c. a  c . b 
 a  b  2  c . a  c .b  a .b 
2 2

But  a  c  .  b  c   0
 a .c b . c  a .b 1
 E  8  2  10

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 Narayana IIT Academy 02-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-5(N)_KEY&SOL
84. Let the common ratio of G.P. be ‘ r ’ then x2  x1r , x3  x1r 2 , x4  x1r 3
And x1  x2  1, x1 x2  K , x3  x4  4, x3 . x4  L
 r  2 and x1  1
 K  2, L  32
t t2 1 t3
85. 2t 4t 2 1  8t 3  10
3t 9t 2 1  27t 3
1 1 1 1 1 1
 x 2 4 1  x 2 4 8  10
3 6

1 9 1 3 9 27
 6 x 6  x3  5  0  x 3  5 / 6 or x3  1
dt
86. I  2
dt
 1 
t 2 1  1  
 t
1
Put 1   U
t
 1 2
Then I  2 log 1  1    c
 t 
 1 1 1 
 
 t
2
 f (t ) 
 1
1  1  
 t
35  1
87. The number of un-ordered pairs of subsets of A is  122
2
88. If ‘Q’ is the foot of perpendicular and it divide AB in the ratio  :1 then
 3  4 5  7 3  1 
Q , , 
  1  1  1 
Now PQ perpendicular AB    7 / 4
 5 7 17 
  ,  ,     , , 
3 3 3 
 3  6   9  46
g (2 x) g ( x)
89. Using the derivative from the first principle g 1 ( x)  g (1) 
2x x
g 1 ( x) 1
 
g ( x) x
n (1 y )

90. Write (1  y ) 1/ y
as e y
and evaluate the limit

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