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Thesnodynumits

Extenfve pao pe>tieg depend spon


mattei (ontaPned P 4he system.
e ' mcss qUolum I enesqie entsopy
entaley 9bbs fer eneAg) no o of
mole 9 foacf, aaeg
etc.
Tntent PnopexHYe doesn4 deper
o n madte> conta?ned fn thp
ysttm e 9 Temp Vcoy , Ref>cet
9nd A Conc. Heam pessUA |
ent+y9et.
ExtenaYve Idenstr
|Exttns fue
Path Fvrction» Meat , Woa K eny
()
tate functron UoloreTemP ttan/
enegyetc.
(AO
Aba+c f^ocess

Adbec Expanionlemp decas.


AJdbaHc Compaeasfon Tenp rcae
Veay sb0
Kevesstblk Pocess equtb>fo m
Taaevetble socess vey fost
ESTIMATE leat (2) =m$AT)
taa aheAMol{ocess Specc

ExpansionAV-ive,=-ve Wosk
doneb by t Systt
ompaeshn= Av=-Ve =tVe 1e Woak|
? done ôn dhe &4Stime
Pit la dhexmodymmice
A= q t 9
Endraf n=
Endhalpy Laessu
LMeat chonge at on

L=A9 PAV
An A + nRATANRT
Annela)-Dela
An= phg-

Np<MA AN=-ve (ieexthe


d=auATI AM AT S

dM AT
ok done P-V soph
Naeq hdex cUav?

&aTAe
Wsobos sohem abetfe socke
A

Adtabotc Pxocess Cy
PyECondTV=con^4.
PaT/
QU

*Revesstble sotAeama)n
= -n RTAn Vg=-o RTa P
V
T vacoun fex o

Reveble Adtabgt
ESTIMATE V-,v
ARAT

la a AN A Sct for 0aB

O-Dpaoducts) ZAResctant
Cpplle a eveyhexe except
AM 0:Egratot Z8pxouy
AY= Aneombushlon
oReaetUat* pxodort7
Entto py ofruaa1fkadian
Shen 1male o b a a e

As=-SAK
omb CalosfmeteAHeaLaeleage duaing romhusb
of 09gente combeund

AU=Meat absase bsn,0 eat chsnk


bomb ccalonie9
.oSn.n+ecd eof Bomb
Copty
Calo tme tes) xAT
No ofmole ot og (ompound
Spontaneou P>ocesS dore by themselues
Don-Spontanaus doneby extean
fonce
Entsep s)
N

n+
AS LaPv- îuo exe
entopy
bot exdenei
un of ensogy
ote Hoxe tke nor dt gauedS
ole wles moxe i hefmopy
So fd
Rundomness PnCA
endaoH nc N
Excep4tonNI btlig o
endro
ente py
denatuna49on f
ncAr due
po4en
to

Mole colej moe is the eropy


AS o ASsstt +suspadh
ESTIMATE fox Pontonfouy ocess
(ASAtotal +ve[Alwqy
d £ faocesse
Fes
Ts0theamal Kevesatblp
ARR Vg=
ASs=-ASu
fon Qdin.badHc Reueactbles
4S4yp AS

Fos Isobcaic aacess


AS=

4 F Ioches ocess
T
* T both demp: VOl aae Chansedl
As=oClaThR ln Va
both temp» p>essu 0e cken4

Entaopy ef fusen (ASsuston)


A o Mfuston enthulyoffuto
m
Enopy Vepeuaikollon
va pousisatton ye
Te0.p
CRbs fee Eresgy
of the cystem ushiek con br
ene9.
ene9H
Conueted
usetu e
t o useful wonk
-AG= Wmaximu
A An-TAS
R- V?

A2
forraton
of heaclorh
ofPoduct
AElementc elementasy J4de
haue
ACfoamatiun
ESTIMATE foa Pontaneous Kxn
A=-Ve
hx roppOAdaneaus AG= AvMe
T AC=o Rxn. is at equil

Te TAn
AS
Aboue dhiy ten nis
Spondaneovs
AG=0
rOAApontarew

foa
Oa=-TStetay)
spanlaneouS
Sn ? AS4otaEvei
for non-Sondaneous An As4to V
Caces
4S=4ue, An=-ve Ran. dpontareaus
at a tem p.
AlAS = -ve,y-Ve On incau demp
Spo nanity decsM

S=-Ve, Ahz4u > Rxn Aon=


Sonmaneovs at 4ll teme
lau TheamodyAmiS
Pefecdly taySall%e Sestance

Kelo

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