2. Consider 1.2 moles of an ideal gas in a piston at 298 K and 0.

2
MPa and at volume V1 . The gas is expanded isothermally to
⑭ twice its original volume, then cooled isobarically to V1⑳. It is
then heated at constant volume back to T1③ . Demonstrate that the
net work is non-zero, and that the work depends on the path.

Pag
same V
- O
N

I
① V2 = 2x 14863cm
=29730c
,

no work ②
>V
P V,,
=

P2V2
PV nRT
P2
=

0 / MPa
314cm MPa
=

1 2 moles 298K I .

nRT
8
V
= = .
.

mole K 0 2 MPa
Work done at isobaric
.

=148632m3
W =

Pc(V2 -Vi)
Work done at is othermal
=0 .
1x104pa[29730am-14865cm]
W = -

/PdW =0 .
1x10°Pa[0 . 029738-0 .
014865m]
=- nRT , In Y =
1486 5] .

-
1 2moles 8 314cm MPa 298k
work done at constant V 0
.
.
-

in (2)
=

moleK
Network = - 2060 + 1486 5 .

2060]
=
-
=
573 5]
.