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1D and 2D Motion
1D and 2D Motion
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5. A particle is moving east ward with a velocity of
5m/s. In 10sec the velocity changes to 5m/s North-
TOPIC : Motion in a plane & Motion in straight Line ward. The average acceleration in this time is/
are:
[SECTION-A] [SECTION-A]
(1) Zero
1. A person throws balls into the air one after the 1.
other an interval of one second. the next ball is
1
thrown when the velocity of the ball thrown (2) m/s2 toward north east
earlier is zero. To what height the ball rise ? Take 2 (g=10
g = 10 ms–2
(1) 5 m 1
(1) 5 m (3) m/s2 toward North-west
2
(2) 10 m
(2) 10 m
1
(3) 20 m (4) m/s2 toward north-west
(3) 20 m 2
(4) 40 m (4) 40 m
6. Identfiy the correct statement related to projectile
motion:
2. Two body are thrown with same intial velocity at 2. (90o- θ )
angle and (90 o - θ ) respectively with the (1) It is uniformally acclerated every where
horizontal then their maximum height are in the
(2) It is uniformally accelerated everywhere expect at
ratio:
the highest position where it is moving with
(1) 1:1 constant velocity
(1) 1:1
u te (3) Acceleration is never perpendicular to velocity
(2) sin :cos
t
t(2)i sin :cos
n s (4) None of these
I
ht
2 2
(3) sin2 :cos2 (3) sin :cos
7. A body is thrown horizontally from the top of the h
g ig
(4) cos :sin Li tower and strike the ground after three second at
(4) cos :sin o
L
ew w
an angle of 45 with the horizontal. Find out the
e
height of the tower and the speed with which
3. A 100m long train is moving with a uniformN 3. 100 45
body was projected. / N the
velocity of 45 km/hr .The time taken by the train 1
to cross a bridge of length 1 km is: (Take g=9.8 m/s2)
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9. Two particle A & B are projected in Air. A is thrown 9. 12. A particle is
Aprojected
B Afrom30 the /horizontal making
with a speed of 30m/s and B with a speed of 40m/ an angle 60Bo with40the /intial velocity 40m/s find
the time taken to the particle
1 makes angle 45o
sec as shown in the figure what is the separation
from horizontal:
between them after 1 second:
(1) 1.5 Second
30
30 40 2.5 Second
(2)
40
VB(3) 3.5 Second VA
VB VA B A
B A
0
(4) 4.5 Second
530 370
53 0 37
13. A Body moves along a straight line with an
acceleration 3m/s2 for 2 second and then with an
(1) 10
(1) 10m acceleration 4m/s2 for 3 second. What is the
average acceleration:
(2) 20m (2) 20
(1) 3.5m/s2
(3) 40m (3) 40
(2) 3.6m/s2
(4) 50m (4) 50
(3) 3.7m/s2
10. Six particle situated at the corner of a regular 10. (4) 3.8m/s2
hexagon of side a move at a constant speed V.
Each particle maintain a distance toward the 14. The Acceleration of a particle as seen from two
particle at the next corner. Calculate the time the
u te frame S1 and S2 have equal magnitude 5:
particle will take to meet each other:
ti t (1) The frame must be at rest with respect to each
s
6a t In 6a
other.
(1)
g h (1)
v (2) The frame may be moving with respect to each
gh
Li i
v other but neither should be accelerated with
respect to the other. L
4a ew 4a ew
(2)
3v
N (2)
3v be zero or 10m/s2
N
(3) The acceleration of S2 with respect to S1 may either
(3) 50 m (3) 50
l m
(3) (4)
m l
(4) 25 m (4) 25
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17. A Car starts from rest moves with an acceleration 17. a
20. A Particle is moving with speed V = b x along the
(Deaccelarate) b Calculate the speed of the particle
positive x-axis.
a then dccelerates at a constant rate b for some
t is at origin
at time t= (assume that the particle
time to come to rest. If the total time taken is t.
at t=0)
The maximum velocity of the Car is given by:
2 b2
abt (1) b (2)
abt (1) 4 2
(1) (a b)
(a b)
b2
2 a 2 t (3) b 2 (4)
a t (2) 2
(2) (a b)
(a b)
21. A person moves 30m north, then 20m east and
(1) 10iˆ
b2 t b2 t
(4) (4)
ab ab
(2) 10iˆ
18. A particle is moving according to graph is shown 18.
in figure. What is the average velocity in the 3 (3) 15iˆ8
interval of 3sec to 8sec:
(4) 15iˆ
u te
t
ti 22. A man standing on a hill top projects a stone
s
t In horizontally with speed v0 as shown in the figure.
Taking/ the co-ordinate system as shown in the
10m/s
gh gh
10
1 1
1 1 (1) tan 2v 0 2 tan v 0 2 tan2
(1) tan
4 (1) 4 ,
g g
1 1 1 1 2
(2) tan 2v
2
(2) tan 0 g 2v 0 tan
2 (2) 2 ,
tan g
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23. A particle moves a distance x in time t according 27. A train is moving on a track at 30 m/s. A ball is
23.
thrownxfrom 5)-1perpendicular to
= ( t +its t x-
direction of
to equation x = ( t + 5)-1 the accelartion of the
motion at 30 m/s at 45o from horizontal. Find the
particle is proportional to: distance of ball from the point of projection on
train to the point where its strike the ground:
(1) (Velocity)3 / 2 (1) 3/2
(1) (Velocity) 90 m
(2) 90 3
(2) (dis tance)3 (2) (dis tance)3
(3) 60 m
(3) 16 : 25 (3) 16 : 25
te 2 2
(4) 1 : 1 (3) t
u
2
(4) 1 : 1
ti t
25. A ball rolls off the edge of a horizontal table top 25.ns 4
4m high If it strike the floor at a point 5m t I (4) 2 2 5
horizontally away from the edge of the table whatg h gh
was its speed at instant it left the table: L i 29. A average velocity of a particle in projectile L i
w motion between its starting point and w
highest
Ne Ne= u and
(1) 15.55
(1) 15.55 m/s point of its trajectory is (projection speed
(2) 10.55 angle of projection from horizontal = θ ):
(2) 10.55 m/s
u
(4) 1 cos2
2 D E F
D E F c
c t2
t
V dt represents:
t 30. The quantity
time t1
h (2) S2 = 4S1
h
(2) (2)
8g 8g (3) S = S
2 1
u te (4) S = 2S
(3) 8gh t
ti 37.8gh A particle is fired horizontally from an inclined
(3) 2 1
s
(4) 2gh t In (4) 2gh plane of inclination 30 with the horizontal with
o
33. L 33.
Which of the following represent uniformly
along the inclined plane is: Li
accelerated motion: e w (1) 500 m e w
N ta
N
ta (1) X 1000
(1) X b
(2) m
b 9
tb
tb (2) X 1000
(2) X a(3) m
a 3
xa x a500
(3) t (3) t (4) m
b b 3
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39. Two stone are projected with same speed but 39. 42. Two projcetile A & B are projected with angle of
making different angle with the horizontal. Their projection 15o for the projected A. and 45o for the
projcetile B. If RA and RB be the horizontal range
horizontal range are equal.The angle of
for the two projectile then:
3
projection of one is and the maximum height
3 102 (2) RA<RB
reached by it is 102m then maximum height
reached by the other in meter to: (3) RA=RB
(1) 33
(1) 33 m (4) RA>RB
(2) 22
(2) 22 m
(4) The information is insufficient to decide the relation
(3) 56 m (3) 56 of RA with RB
(4) 34 m (4) 34
43. A Aeroplane is flying in a horizontal direction with
40. A point traversed half the distance with velocity 40. a velocity v 600 km/hours at a height 1960 m when
0
v0. The remaning part of the distance was covered it is vertically above
v1 the point A on the ground a
with velocity v1 for half the time and with velocity body isv2 dropped from it. The body strike the gound
v2 for the other half of the time. Find the mean at point B. Calculate the distance AB:
velocity of the point averaged over the whole time
of motion:
(1)
2v1v0v2 4.33 km
2v1v0v2 (1) 2v v v
0 1 2
(1) 2v v v (2) 3.33 km
0 1 2
u t2ve0 (v1 v2 )
2v 0 (v1 v 2 ) t t
i 2v0 (3)
(2) 2.33 km
v1 v 2
(2) 2v v v
0 1 2 Ins
ht (4) 1.33 km
2v 0 (v1 v 2 ) ig 2v 0 (v1 v 2 )
(3) v 2v v igh
(3) v 2v v L 44.0 A1ball2is projected upward from the top of L the
0 1 2
ew tower with velocity 50 m/s making an angle
ew 30 o
hu2 hu2
(1) (4) 9 Second
(1)
gb2 gb2
45. Which the usual notation, the following equation
u2 g u2 g 1
(2) S=u+ a(2t-1)
(2) 2
gb2 gb2
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46. If particle accelerates with a=kv and intial 46. a=kv2, u
TOPIC : Chemical Bonding and Molecular Structure
velocity u then find velocity after s displacement: s
Organic Chemistry – Some Basic Principles
(1) v = uekx (1) v = uekx Atomic Masses : H=1, He=4, C=12, N=14, O=
K=39, Ca=40, Fe=56, Cu=63.5, Br=80
(2) v = 2uekx (2) v = 2uekx
SECTION-A
(3) v = 2ue–kx (3) v = 2ue–kx
51. Two elements P and Q combine to form a
(4) None of these (4) compound. If P has 2 and Q has 6 electrons in
their outermost shell what will be formula of the
47. A gun is firing bullet with speed v0 by rotating 47. 360o
compound formed : v0
through 360o in the horizontal plane the maximum
area covered by the bullet is: (1) PQ
2
(2) P2Q
a2 2v0 a2 2v0
2
(1) (2) (1) (3) P2Q3 (2)
g g g g
(4) PQ2
4 4
v 0 2v0 4
v 0 The correct decreasing
52.
4
2 v 0 order of priority for the
(3) (4) (3) (4)
g2 2g2 2
2g2
g functional group of organic compound in the IUPAC
system of nomenclature is :
48. A car accelerates from rest at 5 ms–2 and then 48. 5 ms–2
retards to rest at 3 ms–2. The maximum velocity (1)
–2
–CONH2, –CHO, –SO3H, –COOH
3 ms .
of the car is 30 ms–1, what is the distance covered
by the car
u te
30 ms–1 (2) –COOH, –SO3H, –CONH2, –CHO
t
t(1)i 150 m(3) –SO H, –COOH, –CONH , –CHO
(1) 150 m s 3 2
(2) 125m (2) 125 (2) MgCl2 < NaCl < AlCl3
(3) 130m (3) 130 (3) AlCl3 < MgCl2 < NaCl
(4) 135m (4) 135 (4) NaCl < AlCl3 < MgCl2
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55. Given below is the table showing shapes of some 55. 58. The conditions for the combination of atomic
molecules having lone pairs of electrons. Fill up orbitals to form molecular orbitals are stated
the blanks left in it : below. Mark the incorrect condition mentioned
:
here :
–––––––––––––––––––––––––––––––––––––––––––
–––––––––––––––––––––––––––––––––––––––––––
(1) The combining atomic orbitals must have nearly
Molecule type bp lp Shape Example
bp lp
same energy.
––––––––––––––––––––––––––––––––––––––––––– (2) The combining atomic orbitals must overlap to
–––––––––––––––––––––––––––––––––––––––––––
AB2E2 2 P Bent H2O maximum extent.
AB2E2 2 P H2O
AB3E2 3 2 Q ClF3 (3) Combining atomic orbitals must have same
AB3E2 3 2 Q ClF3
symmetry about the molecular axis.
AB5E 5 R S BrF5 AB5E 5 R S BrF5
(4) Pi () molecular orbitals are symmetrical around
AB4E2 4 2 T U AB4E2 the bond4 axis.2 T U
––––––––––––––––––––––––––––––––––––––––––– 59. Which of the following formulae does not show
–––––––––––––––––––––––––––––––––––––––––––
P Q R S T U the correct relationship :
P Q R S T U
1
(1) 2 Square 2 T-shaped Square H2O2 (1) 2 (1) B.O = (Nb Na )
2 2 T- H2O2
Pyramidal Planar 1
(2) B.O
Bond length
(2) 4 T-shaped 5 Square Square SO3 (2) 4 T- 5 SO3
1
Planar Pyramidal (3) B.O
Bond dissociation energy
(3) 2 T-shaped 1 Square Square XeF4 (3) 2 T- (4) N > 1N , B.O = +ve XeF4
te
b a
Pyramidal Planar.
tu60. Isostructural species are those which have the
(4) 3 Square 2 T-shaped Square BrCl s ti 3
(4) 2 T-and hybridisation. Among
same shape BrCl3 the given
In
3
species, identify the isostructural pairs.
Planar pyramidal t
56. Match the column I with column II and mark the igh56. I
(1) [NF3 and BF3]
II igh
appropriate choice :
L (2) [BF4– and NH4+] L
ew (3) ew
Column I Column II N I [BCl3 and BrCl3] II N
(4) [NH3 and NO3–]
A. C2H2 i. sp3d2 hybridisation A. C2H2 i. sp3d2
61. Hydrogen bonds are formed in many compounds
B. SF6 ii. sp3d3 hybridisation B. SF6 ii. sp3d3
e.g., H 2O, HF, NH 3. The boiling point of such
C. SO2 iii. sp hybridisation C. SO2 compounds depends iii. sp to a large extent on the
strength of hydrogen2 bond and the number of
D. IF7 iv. sp2 hybridisation D. IF7 iv. sp
hydrogen bonds. The correct decreasing order of
(1) A-i, B-iii, C-ii, D-iv (1) A-i, B-iii,
theC-ii, D-iv points of above compounds is :
boiling
(2) A-iii, B-i, C-iv, D-ii (1) C-iv,
(2) A-iii, B-i, HF >D-ii
H2O > NH3
64. Match the column I with column II and mark the 64. -I -II OMe
appropriate choice : Cl
(1) 2-Chloro-4-methylanisole
Column I Column II -I -II
CH3
A. CH3CH2OH, H3C–O–CH3 i. Position isomers A. CH3CH2OH, H3C–O–CH3 i.
B. C2H5COC2H5, C3H7COCH3 ii. Tautomers B. C2H5COC2H5, C3H7COCH3 ii.
NH2
OH O CH3
OH O
(2) 4-ethyl-2-Methylaniline
C. iii. Functional isomers C. iii.
, , C2H5
D. CH3CH2CH2OH, iv. Metamers
D. CH3CH2CH2OH, iv.
Cl
CH3 CH CH3
| CH3 CH
(3) CH3 4-Chloro-1, 3-dinitrobenzene
OH | O2N NO2
OH
(1) A-iv, B-iii, C-i, D-ii (1) A-iv, B-iii, C-i, D-ii
OH
(2) A-i, B-iii, C-ii, D-iv (2) A-i, B-iii, C-ii, D-iv
(3) A-iii, B-iv, C-ii, D-i (3) A-iii, B-iv,
(4)C-ii, D-i 3, 4-dimethylphenol
CH3
(4) A-iv, B-i, C-ii, D-iii (4) A-iv, B-i, C-ii, CH
D-iii3
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67. Match the column I with column II in which formula 67. 70.
I Structure
II of the compound whose IUPAC name is
for estimation of an element is given and mark
the appropriate choice : 3-ethyl-2-hydroxy-4-methyl hex-3-en-5-ynoic acid
is :
Column I Column II
I OH II
80 w1
(a) Estimation of carbon (i) 100 (1) COOH
188 w 80 w 1
(a) (i) x x100
188 w
62 w1
(b) Estimation of nitrogen (ii) 100
222 w 62 w1
(b) (ii) x x100
(2) 222 w
COOH
32 w1 OH
(c) Estimation of bromine (iii) 100
233 w 32 w1
(c) (iii) 100
OH 233 w
28 V
(d) Estimation of sulphur (iv) x x100
22400 w (3) 28 V
(d) (iv) COOHx x100
22400 w
12 w1
(e) Estimation of Phosphorus (v) 100
44 w OH 12 w1
(e) (v) 100
44 w
(1) (a) (v), (b) (ii), (c) (iv), (d) (i), (e) (iii)
(4)
(1) (a) (v), (b) (ii), (c) (iv),
COOH(d) (i), (e) (iii)
(2) (a) (v), (b) (iv), (c) (i), (d) (iii), (e) (ii)
u te
t
(2) (a) (v), (b) (iv), (c) (i), (d) (iii), (e) (ii)
ti 71. After understanding the assertion and reason,
(3) (a) (v), (b) (iv), (c) (ii), (d) (i), (e) (iii) s
In (a) (v),
(3) (b) (iv), (c) (ii), (d) (i), (e) (iii)
(4) (a) (iv), (b) (iii), (c) (i), (d) (ii), (e) (v) ht
choose the correct option :
i g (4) (a) (iv), (b) (iii), (c) (i), (d) (ii), (e) (v)
igh
68. Assertion : When inductive and electromeric L 68. Assertion : In the bonding molecular orbital (MO)
Lthe
w : of H , electron density is increased between w
Ne Ne
2
effects operate in opposite directions, the inductive
nuclei.
effect predominates.
: Reason : The bonding MO is A + B, which shows
Reason : Inductive effect is the complete transfer
destructive interference of the combining electron
of shared pair of electrons to one of the atoms. waves.
(1)
(1) If both assertion and reason are true and reason is (1) If both assertion and reason are true and reason is
the correct explanation of assertion. the correct explanation of assertion.
(2)
(2) If both assertion and reason are true but reason is (2) If both assertion and reason are true but reason is
not the correct explanation of assertion. not the correct explanation of assertion.
(1) 9, 4 (1) 9, 4(1) Li2 < Li2 < Li2
(3) 6, 6 (3) 6, 6(3) Li2 < Li2 < Li2
(4) 5, 5 (4) 5, 5(4) Li2 < Li2 < Li2
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73. The first organic compound prepared from 73. 78. In Carius method of estimation of halogens, 250
inorganic compounds was : mg of an organic compound gave 141 mg of AgBr.
:
The percentage of bromine in the compound is :
(1) Acetic acid (1) (at. mass Ag = 108; Br = 80)
74. Bond energies in NO, NO+ and NO— are such as : 79.+ A sample
74. NO, NO NO— of 0.5 g of an organic compound was
treated according to Kajeldahl's method. The
(1) NO— > NO > NO+ (1) NO— >ammonia
NO > NO+evolved was absorbed in 50 mL of 0.5
M H2SO4. The remaining acid after neutralisation
(2) NO > NO— > NO+ (2) NO > NO —
> NO+ consumed 80 mL of 0.5 M NaOH. The
by ammonia
percentage of nitrogen in the organic compound
(3) NO+ > NO > NO— (3) NO+ >isNO
: > NO
—
u te
(1) A80. 3
= spOn = sp2
, Bcomplete Y =8
combustion, 0.246 g of an organic
(1) A = sp3, B = sp2 and Y = 8
ti t compound gave 0.198 g of CO2 and 0.1014 g of
s (2) A = spH2,2O.
B =Percentage
sp Y = 9 compositon of carbon and
(2) A = sp 2, B = sp and Y = 9
t In hydrogen are respectively :
gh gh
3
(3) A = sp(1), B21.95, Y=9
= sp 4.58
(3) A = sp 3, B = sp and Y = 9
Li Li
(4) A = sp 2, B = sp2 and Y = 8 w (4) A = sp(2)
2
, B29.95,
= sp2 95.29
Y=8 w
N e (3) 20, 80 N e
76. The colour of the solution/precipitate obtained in 76. (4) 90, 10
the elemental analysis of an organic compound
81. In case of dinitrogen pi-bond is formed by the
and the molecule/ion responsible for the colour overlaping of :
are given below. Choose the incorrectly matched
(1) s – s atomic orbitals
pair.
(1) (2) s – p atomic – Fe4[Fe(CN)6]3.xH2O
orbitals
(1) Prussian blue – Fe4[Fe(CN)6]3.xH2O (3) p – p atomic orbitals
(2) – [Fe(CN)5NOS]4–
(2) Violet colour – [Fe(CN)5NOS]4– (4) all of these
(3) 82. Match the following :
– [Fe(SCN)]2+
(3) Blood red colour – [Fe(SCN)]2+
(i) Benzene (A) Aromatic (Bicyclic)
(4) Yellow – (NH4)2MoO4 (4) – (NH4)2MoO4
(ii) Naphthalene (B) Aromatic
(Monocyclic)
77. In Kjeldahl's method of estimation of nitrogen, 77. (Kjeldahl's)
(iii) Anthracene (C) Alicyclic
copper sulphate acts as :
(iv) Pyridine (D) Heterocyclic
(1) an oxidising agent (1) (v) Cycloalkane (E) Aromatic (Tricyclic)
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83. Which of the following has zero dipole moment: 83. 87. Among the following compounds, the decreasing
order of reactivity towards electrophilic
CH 3 CH3 CH 3 substitution
CH3 is :
(1) C=C cis-2-butene (1) C=C -2-
H H H H
CH3 H CH3 H
(2) C=C trans-2-butene (2) C=C CH3 -2- OCH3 CF3
H CH3 H CH3
(I) (II) (III) (IV)
(3) CH3–CH2–HC=CH2 1-butene (3) CH3–CH2–HC=CH2 1-
(1) III > I > II > IV
H H
(4) H3C–C=C 2-methyl-1-propene (2) IV > I > II > 2-
(4) H3C–C=C IV -1-
H H
CH3 CH3II > I > III > IV
(3)
84. Consider the following structures : 84. (4) I > II > III > IV :
88. The
increasing order of stability
of the following
I. H2C= CH II. CH3 – CH2 I. H2C= CH
free radicals is :II. CH3 – CH2
III. H2C=CH– CH2 IV. C6H5 – CH –C6H5 (1) CH
III. H2C=CH– 2 3)2 CH < IV.
(CH (CHC )6HC5 –<CH
(C6H
–C) CH < (C6H5)3 C
3 3 5 62H5
decreasing order of their stability : (2) (C6H5)3 C < (C6H5)2 CH <(CH3)3 C <(CH3)2 CH
(1) I, II, III, IV
IV (C6H5)2 CH < (C6H5)3 C < (CH3)3 C < (CH3)2 CH
(1) I, II, III,(3)
(2) IV, III, II, I
u te
(1) IV > II > III > I (1) IV > II (2) > I 3 )2 CH CCl3 CBr3 (CH3 )3 C
> III (CH
93. In PO43– ion, the formal charge on each oxygen 93. PO43– (4) lone pair - lone pair > bond pair - bond pair
atom and P–O bond order respectively are : P–O
> lone pair - bond pair
(1) –0.75, 1.25 (1) –0.75, 1.25
98. Among
(2) –0.75, 1.0 the followng, which one is a wrong
(2) –0.75, 1.0
statement :
(3) –0.75, 0.6 (3) –0.75, 0.6
(4) –3, 1.25 (1) PH5 and BiCl5 do not exist.
(4) –3, 1.25
94. Which of the following is the correct order of 94. : .
(2) p-dbonds are present in SO 2
dipole moment :
(1) NH3 < BF3 < NF3 < H2O
(1) NH3 < BF3 < NF3 < H2O
u te (3) SeF4 and CH4 have same shape.
(2) BF3 < NF3 < NH < H 2O
(2) BF < NF < NH < H O t
ti BF < (4)
3
3 3 3 2
n s
(3) NH I< NF
has <bent
H Ogeometry. 3 3 3
+
3 2
(2) (A) – (iv), (B) – (iii), (C) – (i), (D) – (ii) (2) (A) – (iv), (B) – (iii), (C) – (i), (D) – (ii)
(3) (A) – (ii), (B) – (iii), (C) – (iv), (D) – (i) (3) (A) – (ii), (B) – (iii), (C) – (iv), (D) – (i)
(4) (A) – (iii), (B) – (i), (C) – (iv), (D) – (ii) (4) (A) – (iii), (B) – (i), (C) – (iv), (D) – (ii)
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105. The circulatory system in which the cells and
TOPIC : THE LIVING WORLD, BIOLOGICAL CLASSIFICATION, PLANT KINGDOM, ANIMAL KINGDOM
tissues are directly bathed with blood is found in :
SECTION–A – [Part–1] SECTION–A – [Part–1]
(1) Earthworm
101. Match the following columns : 101.
Column–A Column–B (2) Cephalocordates
–A –B
a. Pristis i. Electric organ a. (3) Fasciola i.
b. Trygon ii. Flying fish b. ii.
(4) None of these
c. Carcharodon iii. Saw fish c. iii.
d. Torpedo iv. Great white shark d. 106. Which is a correct
iv. matching set :
e. Exocoetus v. sting ray e. Column–I v. Column–II
(1) a-iii, b-v, c-iv, d-ii, e-i (1) a-iii, b-v, c-iv, d-ii, e-i
a. Bilateral symmetry i. Coelenterates
(2) a-iii, b-v, c-iv, d-i, e-ii (2) a-iii, b-v, c-iv, d-i, e-ii
with metamerism
(3) a-iv, b-v, c-iii, d-i, e-ii (3) a-iv, b-v, c-iii, d-i, e-ii
(4) a-iii, b-v, c-i, d-iv, e-ii b. c-i,
(4) a-iii, b-v, Diploblastic
d-iv, e-ii ii. Annelida
102. Name the Annelid which is dioecious : 102. c. Cellular level of iii. Aschelminthes
(1) Earthworm (1)
organisation
(2) Leeches (2)
(3) Ascaris (3) d. Pseudocoelom iv. Sponges
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109. Which is the correct matching set 109. 113. Gills without operculum are not found in :
Column–I Column–II I(1) Dog fish II
a. Mollusca i. Second largest a. (2) Torpedo i.
phylum
b. (3) Trygon ii.
b. Annelida ii. Nephridia
c. (4) Exocoetus iii.
c. Aschelminthes iii. Spongocoel
d. 114. Agnatha are : iv.
d. Sponges iv. Pseudocoelom
(1) a-i, b-ii,
(1)c-iv, d-iii
Gnathostomata
(1) a-i, b-ii, c-iv, d-iii
(2) a-i, b-ii,
(2)c-iii, d-iv jaw, class - cyclostomata
Without
(2) a-i, b-ii, c-iii, d-iv
(3) a-i, b-iii,
(3)c-ii, d-iv jaw, class - chondrichthyes
Without
(3) a-i, b-iii, c-ii, d-iv
(4) a-iv, b-ii,
(4) c-iii, d-i
Tetrapoda
(4) a-iv, b-ii, c-iii, d-i
110. 115. Platypus is :
110. The phylum which exhibit organ-system level of
body organisation and bilateral symmetry, (1) Oviparous
ti
(4) t (1) Echinodermata
(4) Mollusca s
t
111. To which classes do the following animals belong? 111.
In (2) Ctenophora
g h g h
a–Petromyzon, b–Scoliodon, c–Pristis L i (3) Cephalochordata
Li
(4) b-
All of these c-
w a- w
(1) a–Cyclostomata,
Ne
b–Chondrichthyes,
Ne by
117. In subphylum vertebrata notochord is replaced
c–Chondrichthyes (1) a- a structure
b- in the adults.
c- This structure are :
(2) a–Osteichthyes, b–Chondrichthyes, (1) Cartilaginous vertebral column
c –Chondrichthyes (2) a- b-vertebral column
(2) Bony c-
121. In the given below example how many animals 121. (1) a-iii, b-iv, c-ii, d-i
are poikilothermous : (2) a-iv, b-iii, c-ii, d-i
Carcharodon, Exocoetus, Ichthyophis, (3) a-ii, b-iv, c-iii, d-i
Pterophyllum, Testudo, Calotes, Pavo, (4) a-i, b-ii, c-iii, d-iv
Neophron, Struthio
126. The radial symmetry occurs in which phylum
(1) 6 (2) 7 (1) 6 (2) 7
a. Coelenterata
(3) 5 (4) 8 (3) 5 (4) 8
b. Ctenophora
122. Which one of the following statements are correct 122.
c. Adult antedon
with reference to given below animals :
d. Chordata
Bufo, Toad, Hyla, Neophron, Naja, Crocodilus,
Pavo, Pteropus, Felis, Panthera
u te (1) a, b, c
(1) All are from same class ti
(1) t (2) b, c, d
s
(2) All are from same super class
t In (2) (3) a, b, c, d
(3) All are cartilaginous cranium containing animals g h (3) (4) Only a, b gh
L i i
L:
(4) 127. Which one of the following matching are correct
(4) All of these
w
e as 123. w
123. How many of the following features are Nused (1) Polyp – Jelly fish Ne
the basis of animal classification :
(2) Gorgonia – Sea pen
a. Size of cells a.
(3) Pennatula – Sea fan
b.
b. Arrangement of cells (4) Meandrina – Brain coral
c.
c. Thallus symmetry 128. Which one of the following features are similar
d. among Earthworm, Roundworm, Hookworm,
d. Nature of coelom
e. Filariaworm :
e. Size of animal
(1) 2 a. All are dioecious
(2) 3
(1) 2 (2) 3
(3) 4 b. All are monoecious
(4) 5
(3) 4 (4) 5
124. c. Bilateral symmetry
124. Which is a correct matching set : d. Segmented body
II
Column–I Column–II (1) Only c
(a) (i)
(a) Cellular Collection (i) Mollusca (2) a, b
(b) (ii)
(b) Tissue formation (ii) Platyhelminthes (3) a, c, d
(c) (4) b, c, d (iii)
(c) Organ formation (iii) Ctenophora
(d) 129. In the given below (iv) example how many are
(d) Organ system (iv) Porifera
dioecious
(1) a-iv, b-iii, c-ii, d-i animals :
(1) a-iv, b-iii, c-ii, d-i
Leech, Earthworm, Hookworm, Fasciola,
(2) a-iii, b-iv, c-ii, d-i
(2) a-iii, b-iv, c-ii, d-i Tapeworm, Nereis
(3) a-ii, b-iv, c-iii, d-i (3) a-ii, b-iv,
(1) c-iii,
3 d-i (2) 4
(4) a-i, b-ii, c-iii, d-iv (4) a-i, b-ii,
(3)c-iii,
2 d-iv (4) 1
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130. Which one of the following feature of 130. 135. Go through the following statements
Echinodermata :
(1) (i) Starch containing bodies called pyrenoids are
(1) Exclusive marine, Excretory system absent found in the nucleus of the green algae
(2) Mostly marine, Excretory system absent (2)
(ii) Green algae have a rigid cell wall made of
(3) All are fresh water, Excretory system absent (3) an inner layer of cellulose and an outer layer
of pectose
(4) Rarely marine, Excretory system absent (4)
(iii) Asexual reproduction in all brown algae is by
131. Which one of the following is an example of chloro- 131. zoospores that have two unequal laterally
phyllous thallophyte attached flagella
(1) (iv) In Bryophytes, female sex organ called
(1) Pisum archegonium is flask-shaped and produces a
(2) single egg
(2) Spirogyra
Which of these are correct
(3)
(3) Adiantum (1) i, ii & iii
(4) (2) ii & iv
(4) Gnetum
(3) ii, iii & iv
132. It assumes that organisms belonging to the same 132.
(4) All are correct
taxa have a common ancestor. This statement is
SECTION–B – [Part–1]
mainly correct for
(1) 136. In which of the following groups all the organ-
isms contain chlorophyll 'c'
te
(1) Synthetic system of classification
(2)
tu (1) Cedrus, Chondrus, Volvox, Chlorella
(2) Natural system of classification
s ti (2) Macrocystis, Spirogyra, Polysiphonia, Chara
(3) Phylogenetic system of classification t In (3)
(3) Chlamydomonas, Dictyota, Ulothrix, Gelidium
134. Which of the following descriptions does not ap- 134. c. Foot and seta in its sporophyte absent
ply to brown algae
d. Is heterosporous in nature
(1) Dominant pigment is fucoxanthin (1) Which of these statements are correct
(3) Nearly all are brackish water forms (3) (2) c and d
(3) a, b and c
(4) Body is filamentous or thalloid (4)
(4) b and c
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139. In liverworts asexual reproduction takes place 139. 144. Space travellers used following as food
by the formation of specialized structures called supplements :
142. Natural classification system took under 142. (3) Haploid spore
consideration which features :
(4) Capsule
(1) External features, anatomy, embryology only
(1) 149. Match the following :
(2) Morphology, embryology, phytochemistry only
(2) Column–I Column–II
(3) Ultra structure, anatomy, em bryology, a. Chlamydomonas i. Filamentous
phytochemistry only (3)
algae
(4) External features, ultra structure, anatomy, (4) b. Volvox ii. Unicellular algae
embryology, phytochemistry.
c. Ulothrix and iii. Colonial algae
143. Hydrocolloids are produced by : 143. Spirogyra
(1) Fresh water green and red algae (1) (1) a-iii, b-i, c-ii
(2) Marine water green and red algae (2) (2) a-ii, b-iii, c-i
(3) Marine water brown and red algae (3) (3) a-iii, b-ii, c-i
(4) Fresh water brown and red algae. (4) (4) a-i, b-ii, c-iii
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150. Which of the following is correct 150. 156. Which of the following statement is correct:
(1) The stems are branched in cycas (1) (1) In gymnosperms the male and female gameto-
phytes have an independent free-living existence
(2) Coralloid roots are associated with N2-fixing algae (2)
(2) In gymnosperms the male gametophyte has an
(3) The gymnosperms are homosporous (3)
independent life where as female gametophyte is
(4) None of these (4) dependent
SECTION–A – [Part–2] (3)SECTION–A
In gymnosperms the male & female gametophyte
– [Part–2]
don't have an independent free living existence
151. Strobili are present in 151.
(4) All of these
(1) Sphagnum (1)
157. The megaspore mother cell in gymnosperms is
(2) Selaginella (2) differentiated from:
(3) Equisetum (1) Integument
(3)
(4) Both 2 & 3 (2)
(4) 2 3 Embryosac
152. Which of the following is correctly matched
152. (3) Nucellus
(1) Green algae – Volvox, chara
(1) (4) Endosperm
(2) Brown algae – Laminaria, Dictyota 158. The gametes of laminaria are :
(2)
(3) Red algae – Porphyra, (1) Pyriform and bear 2 apical flagella
Polysiphonia (3)
(2) Pear shaped and bear 2 apical flagella
(4) u te
(4) All of these
tit (3) Pyriform and bear 2 lateral flagella
(3) Fresh water organisms found in running water (3) (3) All the organisms included had a cell wall in their
cells
(4) Brackish water organisms found in stagnant water
(4) (4) None of these
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183. Which of the following are also known as fire 183. 189. Read care fully and findout the correct statement
algae from the given
(1)
(1) Gonyaulax (a) Twin characteristics of reproduction are in-
(2) crease in mass and number of individual
(2) Colletotrichum
(3) (b) A multicellular organism grows by cell division
(3) Diatoms
(c) Cell division occurs in all tissues to replace lost
(4) Trichoderma (4)
cells
184. Drosophila has been used to study animal 184.
(d) Taxonomical groups are morphological aggre-
genetics. In the same way plant genetics uses :
gates
(1) A deuteromycetes fungus (1)
(1) c, d
(2) A sporozoan protist (2)
(2) a, b
(3) A phycomycetes fungus (3)
(3) a, c
(4)
(4) None of these (4) Only b
185.
185. African sleeping sickness is due to : 190. Which of the following statement is incorrect :
(1)
(1) Plasmodium transmitted by Tse Tse fly (1) Plant growth is continuous throughout their life
(2)
(2) Trypanosoma lewisi transmitted by bed bug
(3)
u te (2) In animal growth is seen only up to a certain age
(3) Trypanosoma gambiense transmitted by Glossina palpalis ti t (3) Plant do not grow continuously through out their
n s
(4) Entamoeba gingivalis spread by housefly
t I (4) life
(3) Herbarium
(3) TEST SERIES
(4) (2) (3).
(4) Both (2) and (3)
196.
196. The individual statement of a key is :
(1) Test ID : 000
(1) Couplet
(4) Museum
(3)
(4)itu
te(1) (2)
b NE
n st
t I (1)
197. Which contains that actual account of habitat and 197.
distribution of plants of a :
g h
(1) Flora
Li (2)
(2) Monograph w
Ne
l
(3)
(3) Catalogue
(4)
(4) Key
198.
198. NBRI is located at :
(1)
(1) Lucknow
(2)
(2) Delhi
(3) England (3)
Na
(4) Dehradun (4)
199. Branch of biology dealing with classification of 199.
living organism is :
(1)
(1) Systematics
(2) Taxa (2) TEST DATE :
(3) Ecology (3)
(4) Genetics
(4)
200. Father of taxonomy is : 200.
(1) Aristotle (1)
SOLUT
(2) Linnaeus (2)
vf
[SECTION-A] [SECTION-A]
N v
vt
1. (1) [NC-48] 1. (1) W E
[NC-48]
v=0 v=0
v f vi V
a a
0=u-gt u=10×1, u=10m/sec 0=u-gt t u=10×1, u=10 t
0=u2-2gH 0=u2-2gH
| V | 5 2 1
| a | N.W
t 10 2
u2 u2
H= =5m H= =5
2g 6. 2g(1) [NC-45] 6.
7. (3) [NC-76] 7.
2. (3) [NC-78] 2. (3) [NC-78]
uy 0
u sin
2 2
u sin
2 2
H1 H1
2g ay g 9.8 m / s
2
2g
itu
y y y
H2 H 2
2g
st 2g
In 1
s 0 3 9.8 (3)
tI
2
ht
y
2
H1 sin
2
g
H
sin
1
2
g h
Li Li
2
H2 cos H cos s 44.1m
2
2
e w v y u y a y t 0(9.8)3 ew
3. (4) N [NC-78] 3. (4) [NC-78] N
Total length train and bridge is 1100 m [v y 29.4m / s] 1100
8. (3) [NC-76] 8.
Velocity of train is 12.5 m/sec 12.5
For vertically projected body,
Time taken train cross the bridge 1100/12.5
y1= ut – 1/2gt2, y1 = 16.8m and x1=0
o
= 88sec 1100/12.5 For the projecticle at 30
= 88
ux = ucos
4. (2) [NC-78] 4. (2) [NC-78]
uy = usin
y y
y2 = uyt – 1/2 gt2, x2 = uxt
20m/s 20m/s
R (y 2 y1 )2 (x 2 x1 )2 24m
x 9. (4) x [NC-45] 9.
a AB a A aB g g 0
For maximum range 45 45
This velocity highest position is only horizontal = VAB (30)2 (40)2 50m= ucos
ucos
sAB v AB t
1
1 u cos 45 20 0
14
ucos 450 20 14m /s sAB 50
2 1
2
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10. (3) [NC-48] 10. (3) 15. (2) [NC-48] [NC-48] 15
a1t1 a2 t 2 b
aav a1t1 t1a2 t 2 t
t1 t 2 aav ab
t1 t 2
ab
32 43 3 2v 4 3 t 2
aavg 3.6ms2 aavg a b3.6ms
23 23
The acceleration of S2 with respect to S1 may be In uniform motion average velocity equal to
S2 S1 0 10m/s2
anything between 0 and 10m/s2 instaneous velocity hence average velocity will be
10m/s.
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19. (3) [NC-48] 19. (3) 22. (3) [NC-48] [NC-45] 22
Given R = H R=H
R
u2 sin2 u2 sin2 u2 sin2 u2 sin2
2g g 2g g
Formula
2 v 02 s in
R
g cos2
20. (2) [NC-45] 20. (2) [NC-45]
2v 02 tan
X R cos
g
given v b x vb x
2v 02 tan 2
R sin
dx dx g
b x b x
dt dt (1)
23. [NC-45] 23
x (t 5)1
x dx b dt
1/ 2
x dx b dt
1/ 2 2
dx
a 0 2 2(t 5)3
te
0
dt
tu
2 x b[t]0
sti 2 x b[t] a (v )
3/2
In
0
t24I
24. (2) [NC-49]
t
v
igh v 1 g h
Li
x x u (2t 1)
b L b s
2 4
1
ew s5 u
1
(2t 2 1)
u=0
ew
2v
b
N 2v 2 N
b b
b s4 7
s5 9
b2 25. b(3)
2
[NC-76] 25
v v
2 2 1 1 2
h gt 2 h AB gt AB
2 2
Ao v
BC
S3 30iˆ 30ˆj V
S3 30iˆ 30ˆj t
5.0
Total displacement V
0.9
s ˆ
S S1 S2 S3 10iˆ
S S1 SV2 S5.5m
3 /10i
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26. (3) [NC-76] 26. (3) 30. (2) [NC-76] 30
27. (1) [NC-78] 27. (1) Displacement during t1 to t2 [NC-78]
The distance with respect put to from of train so
31. (1) [NC-78] 31
velocity of train not effected on the distance the
u2 sin2 u2 sin2
horizontal range = R for max 450
g g 2
u2 sin
=
g
2
(30)2 sin2 900 u
90m Rmax
(30)2 sin2 900 g
g 90m
g
1
28. (2) [NC-45] 28. (2) According to question R R[NC-45]
max
2
given
u2 sin2 1 u2
x t 3 ,y t 3
x t , y t 3g
3
2 g
dx dy
3 t 2 , 3 t 2 dx dy
dt dt 3t 2 ,sin23 t12
dt dt 2
VR 3t 2 v y 3t 2
VR 3t 2 2 300 v y 3t 2
v v 2x v 2y e
vt v v 15
tu 2 2 0
ti 32. (2)
x y
v 9 2 t 4 92 t 4 n s [NC-48] 32
t I v 9 t 9 t
2 4 2 4
I
h Initial velocity of stone which is thrown from theht
g g
v 3t 2 2 2
Li v 3t ground
2
it at the maximum hight.
2 2
Li
ew v u 2gH 2
0 u 2gH
2
e w 2
N N
29. (2) [NC-78] u2 2gH 4h = H
29. (2) [NC-78]
using pythagores theorem u 8gh
2
u 8gh .........(i)
2
= H
2
2 OA
Let h2 be 2 distance covered by the stone which
the
is thrown from the ground.
u2 sin2
R t be the time both cross each other.
u2 sin2Let
g R
g
1
S ut gt 2
u2 sin2 2
H u2 sin2
g H
g 1 1
h1 gt 2 h1 gt 2 ......(ii)
T u sin 2 2
t T u sin
2 g t
2 gh2 ut 1 gt 2 ................(iii)
2
displacement
Vaveg. Vaveg. = (ii) + (iii)
time
u We get h2 ut
u Vavg 1 3 cos
Vavg 1 3 cos 2 2
2
h
t
8g
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33. (3) [NC-45] 33. (3) 37. (3) [NC-45] [NC] 37
For uniform acceleration motion u = 50m/s
g = 10m/s2
2
dx 2
dx
constant 00
dt 2 dt 2
300
x a x a
t x bt 2 a t x bt 2 a2
b b Range u [sin(2 ) sin]
gcos2
d2 x d2 x
2b 2b
dt 2 dt 2 (50)2
R [2 sin300 ]
a =2b 10 cos2 30
a =2b
1000
R 3
34. (3) [NC-] 34. (3) [NC-]
0
Let the velocity of the particle when it makes 30 38. (4) 30 0
[NC-71] 38
with the horizontal then.
Let the velocity y makes angle , and with
v cos300 u cos 600
v cos 30 0
u cos
x,y and60
0
z-axis respectively then 600 , 600
[v 20 / 3 m / s] we have v = 20m/s and
[v 20 / 3 m / s]
r radius of curvature = (velocity) 2 / Radial cos2 cos 2
cos2 1
acceleration co = ( )2 /
r t
ti r g cos
g cos s 1
In cos
202 ht 20 2
2
htI
r g r g
3 10
3 Li 3 10
v3 v cos ˆi v cos ˆj v cos kˆ Li
2
ew 2
ew
N v 10iˆ 10 2kˆ 10ˆj N
r = 15.4 m r = 15.4 m
39. (4) [NC-78] 39
35. (4) [NC-42] 35. (4) [NC-42]
At t = 0 x=4 At t = 0 u sin x1 = 4 u sin 2
2 2 2 2
H1 ,H2
2g 2g
At t = 4 sec x=4 At t = 4 sec x=4
H1 sin2 1
44
avg. velocity = 0 H2 sin2 2 = 4 4 0
avg. velocity
4 4
1 2
3 2 3
SECTION-B SECTION-B
36. (2) [NC-45]
36. (2) [NC-45] 2
6
t1 10s t 2 20 sec, u 0
t1 10s t 2 20 sec, u 0
1 2 H sin2 1 sin2
s 2 a t 2 6H
1 2 1 2 s1 at1 and 3 2
s1 at1 and s 2 at2
1
H2
2 2
2 H2 2
2
1
sin2 sin
2 2
6 3
2 2 s1 t1 10 1
s1 t1 10 1
s2 t 2 20 14 4
s2 t 2 20 4 H2 102
4 3
s2 4s1
s2 4s1 H2 = 34 m
NLI / 10 NLI / 11
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[Solution]
40. (2) [NC-43] 40. (2) 44. (3) [NC-43] [NC-76] 44
S
S 1 2
=h t ut2t 2 gt
average velocity = t 2t
1
1
S 1
average velocity 70 25tS ( 10)t 2
S S 2
S S
2v 0 v1 v 2 2v v1 v 2
5t2 025t 70 0
2v 0 (v1 v 2 ) 70 (v 1 v2 )
t 2v sec
average velocity v v 2v
1 2 0 v1 v 2 2v 0
45. (1) [NC-0] 45
41. (3) [NC-48] 41. (3) [NC-48]
46. (1) [NC-43] 46
nb ut ..............(i) u te
nb ut ..............(i)
ti t a = kv 2
1 2
Ins nh 0 1 gtv dv........(ii)
nh 0 gt ........(ii)
tI
2
2
ht 2 dx
kv 2
h
g g
from i & (ii) Li from i & (ii)
v x
Li
1 ew dv
k dx ew
nh gt 2
2
N 1
nh gt 2 u
v 0 N
2
v
2hu2 2hu2 ln kx
n n u
gb2 gb2
v
ekx
u
42. (4) [NC-78] 42. (4) [NC-78]
kx
43. (2) [NC-76] 43. (2) [v = ue ] [NC-76]
47. (3) [NC-78] 47
1 1
h gt 2 h gt 2
2 2
v 2 sin2
R 450
g
2h 2h
t t
g g
V = V0
horizontal distance AB = VtOB AB =2 VtOB
v
R 0 ....................(i)
o v g o v
NLI / 12 NLI / 13
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[Solution]
48. (2) [NC-0] 48. (2) [NC-0]
CHEMIS
Distance travelled during acceleration is given by
SECTION-A
302 – 0 = 2 × 5 × X1 [X1 = 90m] 302 – 0 = 2 × 5 × X1 [X1 = 90m]
51. (1) [NCERT-XI-101] 51
Distance travelled during retardation
Valence electrons in P is 2; Valence electrons in
0 – 302 = 2 × (–3) × X2 0 – 302 = 2 × (–3) × X2
Q is 6
X2 = 150 X2 = 150
P–2 e P2+
Total distance X1 + X2 = 240 X1 + X2 = 240
49. (4) Q. + 2 e Q2- [NC–78]
49. (4) [NC–78]
Formula2of compound is PQ
gx 2 gx
y x tan y x tan 2
2u cos2
2
52. (2) 2u cos2 [NCERT-XI-344]
52
g = a tan P g = a tan The
Porder of decreasing priority for some functional
groups is
a a
q q
2u2 cos2 2u2 cos2 –COOH > –SO3H > –COOR > –COCl >–CONH2>
u = velocity of particle at origin u= –CN > –HC=O >> C=O > –OH > –NH2 >> C=C<
> –C C–
a(1 tan2 ) a(1 tan2 ) 53
u (4)
u53.
2q [NCERT-XI-108]
u te 2q
54
t t
i 54. (1) [NEET Mod.]
a(1 p )
ns u a(1 p2 )
2
u I tI
Cation size is decreasing in the order of Na+ >
ht
2q 2q +2 3+
Mg > Al h
g ig
50. (2) Li 50. (2)
[NC-48] effect and NaLhas
Al has maximum Polarisation[NC-48]
3+ +
e w the
Let the time t takes the time particle reach minimum Polarisation ew
N H effect. N
ground and hight of the tower H.
55. (3) t [NCERT-XI-115] 55
1 2
h gt ................(i) t = 3sec 56. 1 (2) [NCERT-XI-123] 56
2 h gt 2 ................(i) t = 3sec
2
57. (4) [NCERT-XI-126] 57
1 9
h g(3)2 g ............(i) 1
2 2 h g(3)2MO 9 B
g A............(i)
2 2
v ' 0 g(t 1) [v g(t 1)] A B
v ' 0 g(t 1) [v g(t 1)]
A B
1 2
h' ut gt t=1 1 2
2 58. ut(4)
h' gt t=1 [NCERT-XI-127] 58
2
Sigma molecular orbitals are symmetrical around
1
h' g(t 1)(1) g(1)2 the 1 axis
bond
2 h' g(t 1)(1) g(1)2 while pi molecular orbital are not
2
symmetrical.
1 59
h' g(t 1) g...........(2) (3) 1) 1 g...........(2)
59. g(t
h' [NCERT-XI-129]
2 2
Bond order -Bond dissociation Energy.
from 1 & 2 from 1 & 2
60. (2) [NCERT-XI-121 Examplar] 60
[t = 5m] [t = 5m]
1 4
BF – – Tetrahedral
h 10 (5)2 125 1
h 10NH
(5)–2–Tetrahedral
125 m
2 2 4
NLI / 14 NLI / 15
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[Solution]
= e(50 – 40)
3
69. (2) HC C CH CH CH3 N [NCERT-XI-335]
Acid used for adsorption
bond 10
of ammoniaN
mL of 1NH2SO4
bond 10 bond 3
bond 3 70. (4) [NCERT-XI-344]
1.4 N1 V 1.4 1 10
70. (4) [NCERT-XI-344] % of N = =
71. (3) W 0.5
[NCERT-XI-126]
71. (3) [NCERT-XI-126] = 28%
Bonding molecular orbital involves constructive 80. (1) [NCERT-XI-364] 80
interference. 72. (2) 12 0.198 100[NCERT-XI-129]
%C= 21.95%
72. (2) [NCERT-XI-129] 44 0.246
73. (3) [NCERT-XI-344] 73. (3) iv > iii > ii > i [NCERT-XI-344]
NLI / 16 NLI / 17
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[Solution]
85. (1) [NEET Mod.] 85. (1) 95. (4) [NEET Mod.]
[NEET 2016] 95
86. (3) [NCERT-353, NEET Mod.] 86. (3) 97. (3) [NCERT-353, NEET Mod.]
[NCERT-XI-113] 97
Nitrogen has five bonds which is not possible. 98
98. (3) [NEET 2016]
87. (1) [NCERT-XI-351, NEET Mod.] 87. (1) [NCERT-XI-351, NEET Mod.]
99. (4) [NEET 2019] 99
Reactivity towards electrophilic substitution
M, I C2 contains 2 bonds as it has 4 electrons in two
M, I Pi-Molecular orbitals.
M, I
M, I
88. (1) [NCERT-XI-350] 100. (3) [NEET 2016] 10
88. (1) [NCERT-XI-350]
89. (3) [NCERT-XI-350] H 2 O 2 , HCN and conc. CH 3 COOH form
89. (3) [NCERT-XI-350]
intermolecular H-bonding while cellulose has
I intramolecular H-bonding.
Stability of carbanions I
I
I
90. (1) [NEET Mod.]
90. (1) [NEET Mod.]
M, I
Acidic strength M, I M, I
M, I
91. (1) [NCERT-XI-364]
91. (1) [NCERT-XI-364]
P1V1 P2 V2
u te
T1 T2 t t
i V P V
P 1 1 2 2
Ins T T 1 2
I
V
P V T (725 25) 40 273
1 1 2
33.52 ml ht P V T (725 25) 40 273 ht
g g
Li Li
2
TP 300 760
1 2 V 2 33.52 ml
1 1 2
TP 300 760 1 2
% of N =
28
Vol of N at STP ew
N100
2
28 Vol of N at STP N ew
22400 mass of org. comp % of N = 100 2
22400 mass of org. comp
28 33.52
= 100 28 33.52
22400 0.25 = 100
22400 0.25
= 16.76
= 16.76
92. (2) [NEET 2015]
92. (2) [NEET 2015]
93. (1) [NCERT-XI-104]
93. (1) [NCERT-XI-104]
O
|| O
P ||
O– O– P
O– O– O–
O–
Total charge = –3
= –3
Average formal charge = –3/4 = –0.75
Average P–O bond order = = –3/4 = –0.75
5 5
= = 1.25 = = 1.25
4 4
u te
Plant Datura is placed in family Solanaceae
ti t
s
195. (2) [NCERT-I-13]
t In (2)
195. [NCERT-I-13]
igh
A place where wild animals are kept in protected
L
environments under human care Zoological w park.
196. (2)
Ne
[NCERT-I-13] 196. (2) [NCERT-I-13]
NLI / 30