天津大学研究生文献阅读记录表

Tianjin University
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学期第 篇文献

Semester 4th No. 05

姓名 Name Rupesh Chakma 学号 Student Number 6219000214
文献题目 Fabrication and evaluation of melamine formaldehyde resin crosslinked
Article Title PVA composite coating membranes with enhanced oxygen barrier
properties for food packaging

In this literature summery, it is described that PVA membrane is of limited use

for food packaging applications in moist conditions. So, polyvinyl
alcohol/melamine-formaldehyde resin (PVA/MF) composite coating membranes with
various contents of MF were fabricated by a chemical crosslinking method to reduce
the sensitivity of PVA to moisture. The morphology, chemical structure, thermal and
mechanical properties of the resultant PVA/MF composite coating membranes were
characterized by scanning electron microscopy (SEM), FT-IR spectrometer, X-ray
diffraction (XRD), thermal gravimetric analysis (TGA), differential scanning
文 calorimeter
文 (DSC) and universal testing machine. In addition, their hazes and OTRs
were also measured as a function of MF content.
献 献
核 核 Experimental results showed that –OH in the molecular chain of MF and PVA
心 could心be crosslinked at room temperature to form a dense polymeric structure, resulting
in the increase in viscosity and the decline in water absorption. The incorporation of
内 内 PVA gave rise to the enhancement of crosslinking through the C–O–C bonding
MF into
容 and 容strong interface interaction between MF and PVA that was beneficial to improving
Core Content

Core Content

its thermal stability, mechanical properties and barrier properties. Furthermore, the
PVA/MF composite coating membranes exhibited superior transparency due to their
good leveling and wettability on both BOPET and PLA substrates. The moisture
resistance and barrier properties of the MF/PVA composite coated BOPET and PLA
membranes under high humidity conditions have been greatly improved, and the
oxygen transmission rates (OTRs) under 75% RH could still remain at about 1.0 cm3
per m2 per day.

These characteristics of the PVA/MF composite coating membranes have

made them exhibit widespread application prospects for coating membranes in the food
packaging field.

（可另附页）
 This research work is directly interconnected with my research interest. They
have improved the physical and mechanical properties of PVA by crosslinking
technique. So, their job will be same as my research work too. Furthermore, they
对 incorporated some other materials 对 to impart better properties of modified PVA film. I
本 will do same work but a slight modified.
本 I have intended to induced catalyst which may
help to occur crosslinking reaction to remove water from inside of the PVA for making
人 人
it more hydrophobic and hydro-insoluble properties. Because, I have plant to apply
研 PVA as a food packaging film for研enhancing its service life. But PVA is extremely
究 water soluble which confines it 究 in many important applications. Due to having
excessive -OH groups which are water lover, PVA become readily soluble.
课 课
题 So, using crosslinker such题as citric acid, glutaraldehyde, succinic acid, etc.
的 cane be crosslinked with PVA by 的 esterification reaction. Thus, my plan is the
preparation of chemically crosslinked hydrophobic PVA film to open its potential use
启 启
of various field. So, this above summarized work directly guides me to research
发 发
pathway and the result of expectation.
Enlightenment to My Research Topic

Enlightenment to My Research Topic

（可另附页）
First author
Qingmei Zhu
Corresponding author
Xianghui Wang, Xiuqiong Chen, Changjiang Yu, Qi Yin
Journal
RSC advances
DOI
10.1039/d1ra01214b
Annual issue number
2021
Impact factor
8.12
Keywords
PVA films, crosslinker, citric acid, oxygen barrier