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学期第 篇文献

Semester 4th No. 02

姓名 Name Rupesh Chakma 学号 Student Number 6219000214
文献题目 Preparation and properties of poly(vinyl alcohol) films modified by
Article Title nanocrystalline cellulose and citric acid

In this literature review summery, poly(vinyl alcohol) (PVA) active packaging films
containing different amounts (1, 3, 5, 10 and 15% wt.) of unmodified cellulose
nanocrystals (CNC) and citric acid modified cellulose nanocrystals (mCNC) were
prepared by solvent casting and their effect on thermal, mechanical and wettability
behavior of the resulted films was investigated. Results showed that both CNC and
mCNC improved the thermal stability of the neat PVA matrix, but different mechanical
文 properties
文 and water wettability were found. Thermal stability of the materials was
found to enhanced, by measuring shift of onset and peak temperatures that moved,
献 献
respectively, from 251.5 to 298.1 °C and from 283.4 to 374.2 °C, in the case of
核 核
PVA/15CNC and PVA/15mCNC films. The presence of mCNC contribute to increase
心 the crystallinity
心 up to 52% for PVA/10mCNC film, while it was limited to 39% for
PVA/10CNC. Interestingly, PVA/mCNC composite films showed a clear UV shielding
内 内while no UV resistance behaviour was detected for PVA/CNC films.
effect,
容 容
Core Content

Core Content

Overall migration tests revealed that the migration value was well below the legislative
limits (60 mg kg−1) for food contact materials, PVA/mCNC composite films have
higher radical scavenging activity than PVA/CNC films and moisture content of PVA
films containing mCNC was reduced at high RH. In conclusion, they described
PVA/mCNC films could be considered as high-performance active food packaging
materials.

（可另附页）
 This research work is directly interconnected with my research interest. They have
improved the physical and mechanical properties of PVA by crosslinking with citric
acid. So, their job will be same as my research work too. Furthermore, they
对 对 properties of modified PVA film. I will do same
incorporated guar gum to impart better
本 work but a slight modified. I Have 本intended to induced catalyst which may help to
occur crosslinking reaction to remove water from inside of the PVA for making it more
人 人
hydrophobic and hydro-insoluble properties. Because, I have plant to apply PVA as a
研 food packaging film for enhancing 研its service life. But PVA is extremely water soluble
究 which confines it in many important究applications. Due to having excessive -OH groups
which are water lover, PVA become readily soluble.
课 课
题 题acid, glutaraldehyde, succinic acid, etc. cane be
So, using crosslinker such as citric
的 crosslinked with PVA by esterification
的 reaction. Thus, my plan is the preparation of
chemically crosslinked hydrophobic PVA film to open its potential use of various field.
启 启
So, this above summarized work directly guides me to research pathway and the result
发 of expectation. 发
Enlightenment to My Research Topic

Enlightenment to My Research Topic

（可另附页）
First author
Nao Hakuto
Corresponding author
Katsuya Saito, Masayuki Kirihara and Yohei Kotsuchibashi
Journal
Polymer chemistry
DOI
10.1039/d0py00153h
Annual issue number
2020
Impact factor
10.2
Keywords
PVA films, crosslinker, oxidizing agent