天津大学研究生文献阅读记录表

Tianjin University
Form for Summary of Literature Reading
学期第 篇文献

Semester 4th No. 03

姓名 Name Rupesh Chakma 学号 Student Number 6219000214
文献题目 Fabrication of Cationic Poly(vinyl alcohol) Films Cross-Linked Using
Article Title Copolymers Containing Quaternary Ammonium Cations, Benzoxaborole,
and Carboxy Groups

In this literature review summery, it is described that water-insoluble cationic

poly(vinyl alcohol) (PVA) films were fabricated using a mixed aqueous solution of
PVA and poly([2-(methacryloyloxy)ethyl]trimethylammonium chloride
(METAC)-co-methacrylic acid (MAAc)-co-5-methacrylamido-1,2- benzoxaborole
(MAAmBO)) copolymer (3D). The surface of the PVA film is typically negatively
charged, and simple fabrication methods for water-insoluble PVA films with cationic
surface charges are required to expand their application fields. METAC, which has a
permanent positive charge owing to the presence of a quaternary ammonium cation,
was selected as the cationic unit. The MAAc and MAAmBO units were used as two
types of cross-linking structures for the thermal cross-linking of the hydroxy and
carboxy groups of the MAAc unit (covalent bonding) as well as the diol and
文 benzoxaborole
文 groups of the MAAmBO unit (dynamic covalent bonding).
献 献 The films were thermally cross-linked at 135 °C for 4 h without the addition of
核 核 After immersion in surplus water at 80 °C for 3 h, the cross-linked PVA/3D
materials.
心 films心retained almost 100% of their weights. The ζ-potential of the water-insoluble
PVA/3D film was 9.4 ± 0.8 mV. The PVA/3D film was strongly dyed using anionic acid
内 red 1内(AR1) because of its positively charged surface. Interestingly, it could also be
容 容 dyed using cationic methylene blue (MB) and became transparent (original
slightly
Core Content

Core Content

state) after immersion in water for 2 days. These results suggested that positive and
negative charges coexisted in the PVA/3D film, and the surface properties were
positively inclined. Moreover, the degree of hemolysis of the PVA/3D films was similar
to that of the negative control, which showed high blood compatibility.

To our knowledge, this is the first report on the fabrication of water-insoluble

cationic PVA films using two types of cross-linking structures containing carboxy and
benzoxaborole groups. They have analyzed cross-linked PVA films using Fourier
transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC), and
contact angle (CA) and ζ-potential measurement, as well as by determining the
mechanical properties, adsorption of charged molecules, and biocompatibility. These
readily fabricated water insoluble PVA films with positive charges can show potential
applications in sensors, adsorption systems, and antimicrobial materials

（可另附页）
 This research work is directly interconnected with my research interest. They have
improved the physical and mechanical properties of PVA by crosslinking. So, their job
will be same as my research work too. Furthermore, they incorporated some other
对 materials to impart better properties对of modified PVA film. I will do same work but a
本 slight modified. I have intended本to induced catalyst which may help to occur
crosslinking reaction to remove water from inside of the PVA for making it more
人 人
hydrophobic and hydro-insoluble properties. Because, I have plant to apply PVA as a
研 food packaging film for enhancing 研 its service life. But PVA is extremely water soluble
究 which confines it in many important究applications.
课 Due to having excessive 课 -OH groups which are water lover, PVA become
题 题 such as citric acid, glutaraldehyde, succinic acid,
readily soluble. So, using crosslinker
的 etc. cane be crosslinked with PVA的by esterification reaction. Thus, my plan is the
preparation of chemically crosslinked hydrophobic PVA film to open its potential use
启 启
of various field. So, this above summarized work directly guides me to research
发 发
pathway and the result of expectation.
Enlightenment to My Research Topic

Enlightenment to My Research Topic

（可另附页）
First author
Kazuma Fujimoto
Corresponding author
Aika Yamawaki-Ogata, Yuji Narita, and Yohei Kotsuchibashi

Journal name
ACS Omega
DOI
https://doi.org/10.1021/acsomega.1c02013
Annual issue number
2021
Impact factor
10.2
Keywords
PVA films, crosslinker, cation, hydrophobic