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◦ Silicon is doped with element having a ◦ Silicon is doped with element having a
valence of 5. valence of 3.
◦ To increase the concentration of free ◦ To increase the concentration of holes
electrons (n). (p).
◦ One example is phosophorus, which is ◦ One example is boron, which is an
a donor. acceptor.
N-type
ni2
(eq3.7) np
nA
ni2
(eq3.5) pn
nD
◦ pn will have the same dependence on ◦ np will have the same dependence on
temperature as ni2 temperature as ni2
◦ the concentration of free electrons (nn) ◦ the concentration of holes (pn) will be much
will be much larger than holes larger than free electrons
◦ electrons are the majority charge carriers ◦ holes are the majority charge carriers
◦ holes are the minority charge carrier ◦ free electrons are the minority charge carrier
Let
no : thermal-equilibrium concentration of electrons
po : thermal-equilibrium concentration of holes
Nd : concentration of donor atoms
Na : concentration of acceptor atoms
Nd+ : concentration of positively charged donors (ionized donors)
Na- : concentration of negatively charged acceptors (ionized acceptors)
𝑛𝑖 2
The concentration of the minority holes is 𝑝𝑛 ≃
𝑁𝐷
1.5 × 1010 2
𝑝𝑛 ≃ = 2.25 × 103 /cm3
1017
Observe that 𝑛𝑛 ≫ 𝑛𝑖 and that 𝑛𝑛 is vastly higher than 𝑝𝑛 .
Drift Current.
Diffusion Current.
v pdrift p E vndrift n E
HOLES
ELECTRONS
.E (volts / cm)
and in general
Ip Aqp p E
J p qp p E
(eq3.12) Jn qnn E
1
q p p n n
Q(a): Find the resistivity of intrinsic silicon using following values – n = 1350cm2/Vs, p =
480cm2/Vs, ni = 1.5x1010/cm3.
Q(b): Find the resistivity of p-type silicon with NA = 1016/cm2 and using the following values – n
= 1110cm2/Vs, p = 400cm2/Vs, ni = 1.5x1010/cm3
𝑛𝑖 2 1.5 × 1010 2
𝑛𝑝 ≃ = 16
= 2.25 × 104 /cm3
𝑁𝐴 10
1 1
q ( p p n n ) 1.6 10 19 (1016 400 2.25 10 4 1110)
1.56 .cm
𝑑𝑖𝑠𝑡𝑎𝑛𝑐𝑒 2 × 10−6
= = = 30ps
𝑣𝑑𝑟𝑖𝑓𝑡 6.75 × 104
1
= 1.6 × 10−19 × 1016 × 1350 × −4
= 1.08 × 104 A/cm2
2 × 10
d. Drift current 𝐼𝑛 = 𝐽𝑛 𝐴
𝐼𝑛 = 0.25 × 10−8 × 1.08 × 104 = 27μA
concentration
profile arises
dp(x)
(eq3.19) hole diffusion current density : Jp qDp
2
dx
Unit: A/cm
dn(x)
(eq3.20) electron diffusion current density : Jn qDn
dx
Jn current flow density attributed to free electronsJpp
Dn diffusion constant of electrons (35cm2 /s for silicon)Jpp
n( x ) free electron concentration at point xJpp
dn / dx gradient of free electron concentrationJpp
dp x
J p qD p
dx
qD p
d
dx
po e
x / Lp
Dp
J p ( 0) q p0 192 A/cm 2
Lp
I p J p A 192 A
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
barrier voltage
(Vo )
p-type n-type
location (x)
p-type n-type
Figure: The pn junction with no applied voltage (open-circuited terminals).
x n NA
qAxp NA qAxnND (eq3.25)
xp ND
2 S 1 1
(eq3.26) W xn x p V0
q NA ND
ND
(eq3.28) x p W
NA ND
LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 60
4.2. Operation with Open-Circuit Terminals
Note, also, the charge on either side of the depletion region may be calculated via the
following equations
NAND
(eq3.29) QJ Q Aq W
NA ND
NAND
(eq3.30) QJ A 2 S q V0
NA ND
The PN junction can be viewed as a capacitor. By varying VR, the depletion width changes,
changing its capacitance value; therefore, the PN junction is actually a voltage-dependent
capacitor.
LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 72
Example 7: PN junctions
P-type N-type
Figure: The pn junction with applied voltage.
10/27/2021 LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 76
step #2: As the magnitude of VF increases, the depletion zone becomes thin enough
such that the barrier voltage (V0 – VF) cannot stop diffusion current – as described in
previous slides.
VF
P-type N-type
Figure: The pn junction with applied voltage.
10/27/2021 LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 77
step #3: Majority carriers (free electrons in n-region and holes in p-region) cross the
junction and become minority charge carriers in the near-neutral region.
VF
diffusion drift
current (ID) current (IS)
P-type N-type
Figure: The pn junction with applied voltage.
10/27/2021 LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 78
step #4: The concentration of minority charge carriers increases on either side of
the junction. A steady-state gradient is reached as rate of majority carriers crossing
the junction equals that of recombination.
VF
np 0 pn 0
P-type location (x) N-type
Figure: The pn junction with no applied voltage (open-circuited
10/27/2021
Figure: The pn junction with applied voltage.
terminals).
LECTURE 03 - SEMICONDUCTOR PHYSICS PART II 79
step #4: The concentration of minority charge carriers increases on either
side of the junction. A steady-state gradient is reached as rate of majority
carriers crossing the junction equals that of recombination.
VF
minority carrier
concentration
P-type N-type
Figure: The pn junction with applied voltage.
Conduction band
Valence band
N type P type
the concentration of the minority holes increases from the equilibrium value of 𝑝𝑛𝑜 to the much
larger value determined by the value of V
Dp Dn V / VT
(eq3.40) I Aqni
2
(e 1) I (eV / VT
1)
L N L N S
p D n A
IS
(eq3.40) I IS (eV / VT 1)
Q(a): Calculate IS .
Q(c): Component of current I due to hole injection and electron injection across the junction.
The carriers liberated by this process may have sufficiently high energy to be able to cause other
carriers to be liberated in another ionizing collision.
This process keeps repeating in the fashion of an avalanche, with the result that many carriers
are created that are able to support any value of reverse current, as determined by the external
circuit, with a negligible change in the voltage drop across the junction.
2. Diffusion Capacitance
Where
When a pn junction is forward biased