Professional Documents
Culture Documents
Salt Analysis JAdvanced Q. 21 To 44 Edited 2
Salt Analysis JAdvanced Q. 21 To 44 Edited 2
÷ :%÷g:3 :*:
: :
Be
Manoj
-
Mn
77
Oz
d- ← 4)
Mm
OI w¥÷ Mn Oz 3e
-
C -17) 443
Edis Mutt Se
-
Manoj
H) ft 2)
Halides (except F ) ,
CN ; scar) behave
as
deducing agent .
They reduce .
coppedIT ions
to copper and hence the equilibrium left
shifts towards
ions
side .
NH
,
can dissolve white ppt of Aga and
gives
deep blue solution with aft .
Cut
Ag No
,
→
Ag
+
E't Nos
(M ) ( N) blue
soheution
Agt t Naa →
Aga + Nat
ftgcnnsb )
Agf
-
a
+
Nits →
, soluble
"
Git +
Gouty →
[ GCN Hoda )
(blue )
" th ( Sa 82)
Ag Nos Ag But ale yellows
t →
HI
Ag Ag Iff yellow) soluble
+
Nos →
.
Ag Gwnaotpeffhnbk
HE )
Agnos
*
→ F
Pgt Naoteq , →
PHztNaHqP0g
(O) E3) fl )
then
disproportionation reaction is
occurring .
Reduction
Tt
Ksffeccnl , ] Is't Ruffeccnlo )
✓ blown yellow
oxidation
¥804
kgfusffeccnld.at
-
Is
white
ppt INgSa°3
A)
Option Yes fvisteeactionisdedox reaction
,
colourless
Now Iz colonise starch in
deep blue colour
't
option D) kaayffeccnld ,
Ending 't ND
soluble .
butq.fi }
"
( Black ) while Fe
- of
Black
ppt
At '3t(NHu7§ →
Alfons
White
gelatinous ppt
@ HIS
Mgmt →
Mg Da
Zn't @ Higgs → zffhiteppt
white ppt
two salts a P t Q .
Cpp H
filtrate
thot water
dissolves
Suchppr
is Pby
cedis
Inuring
No
change
Pgt ,
oxidising
agent
It is Cros
idaoeanaor -4¥ Glob n Nagao,
yellow
green
solution
Ppt
CRI
✓
kg ↳ Oy t KI Crist Ist Heo
X alkaline KMn Og t KI KI Mn
Oz t KO H
Og t
→
✓Cus
Og t KI →
Cuz Ig + Iz t Kgs Oy
✓KI t
those → KOH +
Iz
II t
Ug
→ KA t
Iq
✓KI Oz Ig
t t
H2O → KOH t t
Og
✓ Fe
Cf t KI →
Feck t
Iz t k U
↳ NO t KI → NO t Iz t
H2O + kN
Og
,
black
Mans Pink
,
Susa yellow (Artificial gold)
Q R
Tetrahedral ←
My Square planar
' 9
M, d d that
can hare either or
configuration so
it
form square planar
with
strong field
-
CN and
can
tetrahedral
complex ligand
complex with weak
field legend Ce :
hence Nih ,
Q Hee
'
[Aid3d R Ken
For Ma both
,
if is
complexes
"
with SFL and WFL have
tetrahedral ,
hence it d
configuration z
,
Ent't 2 KOH →
2n @
nzEn§n@tyg)
⑨
soluble .
Optional Fet 't Hzo , FE 't 02+110
FE 't Et 't
Option B) Nagnogeap →
Og +
the
option D)
Fet
'
¥7 X does notreduce in acidic
t
Nagy medium
it at; Pb ?
' "
Bit
will
precipitate -
Hg .
A- us Ind cation
.
C D
,
group
S2 Cus (black
-
optimal luck t
→
ppt)
SOE Cusogcsohrble )
-
ace , t →
S2 Bag
option B) Back
-
+ → csohebk)
Sof
-
Baa, + →
Bason ( white ppt )
S2
-
Pbs (blackppt
option c) Pb ( O
occupant
→
Pbcoocclez ) at →
Nag Fe + SO
→
Agt Sao} [Ages 03751
-
+ →
Karson ton) -
,
CX)
w..
Last
Ages ) Oz @ hitepptl
←
Hzsogt Ages ,
⑦ Cy
black
Ppt
A) NaOH Za GH)
option Ent the
→ t
,
-
option B) Aut Na CN
(Agan}) * NaOH
Fe
Option D)
t come
Hwoz →
passive layer of iron is
formed
along with No
, gas
doggy
•
Ans .
42 +2
"
Cock -
611204¥ @ Ug) G)
(blue anomaly
-13
Optional [ Aisd
HB THEM SFL
¥7,1 NHz
.
d 'T go > p
Liisa
dtp hybridisation
"
Cocke ) [6+2]
'
option )B SAY 3d
FH
( tetrahedral 3d
>
T
17¥
complex ,
"
(blue) (Pink)
In temperature ( nooo ) the
and ,
equilibrium is
shifted towards forward direction ,
hence the
the solution turns pink and at her
temperature ,
equilibrium is
shifted
backwards and the solution turns blue to
Kochi ]
'
ME and
"
Option A) Cu do not
give flame test .
B) Cutt ¥ Cees
Option acidic medium
black
ppt
"
Has
Mn aid X
' "
ME
-
"
Cut reduces
+
Borax bead test shows colour due to meta borate salt metal ion
of .
Gi 3+3 Na Bo →
G( Bog }
,
.