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is non-vital, non-porous
and non-permeable
A good thermal insulator
Loss of enamel
Less thermal insulation
Deeper in dentin
More patent tubules, more permeability
Pulp approximation
High pulp irritation
Electric
Thermal
Chemical
Dentin
substitute
Mechanical Biological
Thermal
Restorative Chemical
material
Biological
Electric
Intermediary base material Resist degradation in the oral
environment
Easy to apply
Liquid Thin
(Varnish) (Sub-base)
Varnishes
• Syringe for
light curing.
Calcium hydroxide Ca(OH)2
Increase
dentin
Stimulates thickness
odontoblast
High pH 11 to deposit
tertiary dentin
Calcium hydroxide
Indications for use •
– Protects the pulp from chemical irritation
by its sealing ability.
– Stimulates the production of tertiary
dentin.
– Compatible with all types of restorative
materials.
• Application process
–Placed only on dentin.
–Placed directly over the deepest
portion of the preparation (indirect
pulp capping)
–Pinpoints exposure size (direct pulp
capping)
Disadvantages
Not to be
Needs a Easily Should be
placed
base for removed protected
directly
thermal during by a base
beneath
insulation placement or RM
amalgam
Cement base
• A thick layer of cement (>0.75mm) is applied
under restoration to protect pulp against
injuries.
• The base should be strong enough to resist
the condensation force during the placement
of restoration.
• Well insulation ability
• Good sealing
Cement bases
• Zinc Oxide\Eugenol
• Zinc Phosphate cement
• Zinc Polycarboxylate cement
• Glass ionomer
Compositions of simple ZOE\Eugenol
• Powder
– Zinc oxide
– Rosin : reduce the brittleness of the set cement
– Zinc stearate : plastcizer
– Zinc acetate : improve strength
• Liquid
– Eugenol and olive oil
Setting reaction
• Water accelerates the reaction
• Zinc eugenolate is easily hydrolized by
moisture
Advantages
• Sedative to slightly inflamed pulp.
• Good initial sealing ability.
Disadvantages
• Weak mechanical properties
• High solubility.
• Inhibit resin polymerization.
PRESENTATION
White powder
zinc oxide with up to 10%
magnesium oxide (reduce
reactivity)
Clear Liquid
45-64% aqueous solution of
phosphoric acid
Zinc phosphate cement
Setting reaction
PRESENTATION
White powder
zinc oxide with up to 10%
magnesium oxide
Clear Liquid
30-40% aqueous solution of
polyacrylic acid
Zinc polycarboxylate cement
SETTING REACTION
CROSSLINKING REACTION
Zinc polycarboxylate cement
ADVANTAGES DISADVANTAGES
• Their properties are highly
• They bond to enamel and dependent upon handling
dentine as well as some of procedures
the metallic cast restorations • They have short working times
and long setting times
• They have a low irritancy.
• An exacting technique is required
• Strength, solubility and film to ensure bonding
thickness are comparable to • Clean up is difficult and timing is
that of zinc phosphate critical
cement
Glass ionomer cement
• Conventional glass ionomer cement
• Resin-modified glass ionomer cement
[RMGICs]
• Metal reinforced
• Powder + Liquid
• Powder + water
• Encapsulated
Composition
• Powder
– Calcium aluminum fluorosilicate glass
• Liquid
– Polyacid
• Copolymer of polyacrylic / itaconic acid
• Copolymer of polyacrylic / maleic acid
• Add tartaric: accelerator
Properties
• Film thickness is similar or less than zinc
phosphate cement.
• Setting time 6 to 8 minutes from start of
mixing.
• Less pulpal irritation.
• Anticariogenic effect due to fluoride release.
• Good adhesion to tooth structure.
Strength
• The 24-hour compressive strength is greater
than zinc phosphate cement.
Bonding
• It can be chemically bonded to the tooth
structure.
Modified GI
• Metal reinforced
– Combination of glass and metal
– No significantly improve the strength
– More wear resistance and short setting time
• Resin-modified GI
Resin-modified glass ionomer cement
• Add polymerizable function groups
– Both chemical & light curing
– Overcome moisture sensitive & low early strength
– Names: Ligth cured GICs, Dual-cured GICs, Tri-
cured GICs, Hybrid ionomer, Compomers, Resin-
ionomers
Properties
• Higher strength than conventional GI
• Higher adhesion to resin material
• Less water sensitivity
– Can be polished after curing