PE BLUE PRINT oF SR CHEMISTRY

CHAPTER(Total Marks) VSAQ(2m) SAQ(4m) LAQ(8m) Total

Marks

1. SOLID STATE (4) 4 4

2. SOLUTIONS (6) 2 4 6

3.1 ELECTRO CHEMISTRY(10)

2 88 10%
3.2 CHEMICAL KINETICS

4. SURFACE CHEMISTRY (4) 4 4

5. GP OF METALLURGY (6) .2 4 6

6. P-BLOCK ELEMENTS (16) 2+2 (4) 8 16

2 4 6
7. d&f Block Elements (6)

8.POLYMERS(4) 2+2 b (4)

4
9. BIOMOLECULES (4)
10 CHEMISTRY IN EVERYDAY LIFE (4) 2+2 4

(2) 4 14
11.ORGANICCHEMISTRY(14)

The Blue print is prepared according to the 'Model Question Paper' issued by B.I.E.
Please, note that, at times, the public question paper gets slight deviation from the above
given Blue Print.
 SR.CHEMISTRY*
*BABY BULLET-Q

LAOHIT LIST
TOP 10* LAO
t**ELECTRO CHEMISTRY/CHEMICAL KINETICS[8 MARKS]tt**
LAQI. (a)State and explain Kohlrausch's law of independent migration of ions. [rP 13(1) 1
(b)What are Galvanic cells?Explain the working of Galvanic cell with a neat [rP 13(2) ]
sketch taking Daniel cell as example
LAQ2. (a)Give a detailed account of collision theory ofreaction rates of bimolecular [P 14(3)]
gaseous reactions.
(b)What is molecularity' ofareaction? Howis it different from 'order ofa reaction? [rP 14(4)]
Name one bimolecular and one trimolecular gaseous reactions.

***p-BLOCK ELEMENTS[8 MARKS]** *

LAQ3. How is ammonia manufactured by Haber's process? [P 15(5)]
How does ammonia react with (1) ZnSO4, ,() CusO4ta (ii) AgCl
LAQ4. How is nitric acid manufactured by Ostwald's process? [rP 16(6)]
How does Nitric Acidreact with (i)Copper (i) Zn (ii) Sg (iv) P4
LAQ5. How is 0zone prepared? How does ozone react with [rP 17(7)]
()C,H4 (i) Ag (ii) KI (iv) Hg (V) Pbs
LAQ6. Describe the manufacture of H,S04 by contact process. [P 18(8)]
LAQ7. How is Chlorine prepared in the laboratory? [rP 19(9)1
How Chlorine is prepared in Deacon's process?
Explain reactions ofchlorine with (a) Cold and dil. NaOH () hot. con. NaOH
(c) Excess NH3 (d) Slaked lime (e) NagS203
LAQ8. How is Chlorine prepared in the laboratory? How does chlorine react with [P 20(10)]
) Iron (ii) acidified FeSO4 (ii) Iodine (iv) H,S (v) KI
*** ORGANIC CHEMISTRY[8 MARKS]k**
LAQ9. Write the following named reactions with one example for each. [P 21(11)]
(a) Williamson's synthesis (b)Reimer- Tiemann reaction.
(c) Carbylamine reaction (d) Kolbe reaction
LAQ 10. Write the following named reactions with one example each: IP 22(12)]
(a) Decarboxylation (b) Wurtz -Fitting Reaction
(c) Cannizzaro reaction (d) Aldol condensation reaction.
LAQ 11. Explain the following named reactions. [P 23(13)]
(a) Diazotization (b) Sandmeyer reaction.
(c) Gattermann reaction. (d) HVZ eaction
LAQ 12. Explain the following named reactions. [P 24(14)]
(a)Esterification (b) Friedel Crafts Alkylation
(c) Friedel Crafts Acylation (d) Wurtz reaction
LAQ 13. (a) Explain the acidic nature ofphenolsand compare with that of alcohols frP 25(15)
(b)Write two methods of preparation of phenol.
* SR.CHEMISTRY 8

1 SAQHIT LIST
TOP 30SAO
Ans-Page
t**soLID STATEJ4 MARKS]*** [P 27(16)]
SAQ1. Derive Bragg's equation.
IgP 271))
SAQ 2. Explain Schottky &Frenkel Defectsa mechanism.HrP 28(18)1
conduction
SAQ 3. Describe the two main types of semiconductors and'contrast their
**SOLUTIONSI4 MARKS]t* [rP 29(19)]
ofasolution containing Sg ofNaOH in 500ml ofsoluton.,
SAQ4. Deine Molarity. Calculate molarity [P 29(20)]
SAQ5. Defne Molality Calculate molality(m) of1 Ogm ofGlucose (CAHOp)in Water:k
90gmof
lGr 21)1
SAQ6. Define Mole fraction. Calculate the mole fraction ofHoSO in 98% H,SO4.
solute?rk 3022)1
SAQ 7. Whaisrkative loweringofvapour pressue? Howisitusefiui to deteuinethemokar mass ofa
***SURFACE CHEMISTRY4 MARKS] ***
SAQ8. Define adsorption? Give any four differences between Physisorption & Chemisorption r l 31(2>)N
SAQ9. What is catalysis?How is catalysis classified? Give two examples for each type of catalysis,r! 31(2b)N
IrP 32(27)]
SAQ 10. What areEmulsions? How are they classified?
**GENERAL PRINCIPLES OF METALLURGY[4MARKS]**
SAQ 11. Differentiate roasting and calcination with exxamples. [P 33(29)]
SAQ 12. Explain the purification of sulphide ore by froth floatation method.v [rP 33(30)]
SAQ 13. Explain briefly the extraction ofAluminium from Bauxite. [P 34(31)]
**P BLoCK ELEMENTS [4 MARKS]*t
SAQ 14. How are XeF and XeF4prepared? Give their structures. P37(38)1]
SAQ 15. How are XeO, and XeOF4 prepared? Give their structures. [P 38(39)}
***d&t BLOCK ELEMENTSI4 MARKS]***
SAQ16. Write the characteristics properties oftransition elements. [rP 3940)]
SAQ 17. Explain Werner's theory of coordination compoundswith suitable examples [rP 39(41)]
SAQ 18. Using IUPAC norms write the systematic names of the following:
OP(NH,)CNH, CH;)CI ( NC4 i) Kg[Fe(CN)Gl (iv) KZPdCI4) [P 40(43)1
t* POLYMERS[4 MARKS]**
SAQ 19. (a) What is addition polymer? Give example.(b) What is PHBV? Howis it usefultoman? [P 42(47)|
SAQ 20. Write the names and structures of the monomers of the following polymers [P 42(50)]
(i) Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene.
** BIOMOLECULEs[4 MARKS]**
SAQ 21, Name the sources and diseases caused by the deficiency of vitamins A, D, EK [aP 43(53)]
SAQ 22. Write notes on vitamins. [caP 43(54)]
SAQ 23. What are hormones? Give an example for each ofthe following: [P 44(55)]|
a) Steroid hormones b) Polypeptide hormones c) Amino acid derivatives
**CHEMISTRY INEVERYDAY LIFE[4 MARKSk *
SAO 24. Write notes on Antiseptics and Disinfectants.
SAO 25. Define and give examples of (a) Antacids bTranquilizers [P 45(60)1
P46(62)|
SAO26, Write notes on (a) Artificial sweetening agents (b) Food preservatives
tORGANIC CHEMISTRY[4 MARKS]k P46(63)|
SAO27. Explain SN reactionwith examples.
reactionwith examples. [rP 47(65)]
SAQ 28. Explain SN [P4766)
SAO 29. Explain (a) Carbylamine reaction (b) Sandmeyer reaction
SAO 30. Define() Recemic mixture(ii)
Enantiomers [P 48(67)1
[P 48(68)]
 HVSAQ NIT LIST
TOP 55* VSAO
***soLUTIONS[2MARKS]***
Ans-Page
VSAQ1. State Raoult's law. [P 50(69)1
VSAQ2. State Henry'slaw. [P 50(70)1
VSAQ3. What is Osmotic pressure? [P 50(71)]
VSAQ 4. What are isotonic solutions ? [rP 50(72)]
VSAQ 5. What is relative lowering ofvapour presSure? [rP 50(73)]

***ELECTROCHEMISTRY/CHEMICAL KINETICs[2MARKS]***
VSAQ6. State Faradavs firstlaw ofelectrolysis? [ P51(78)1
VSAQ7. State Faradav's second law ofelectrolysis. [rP 51(79)]
VSAQ 8. What is a galvanic cel or voltaic cell? Give one example. [rP 51(80)]
VSAQ9. Define order ofa reaction.Give one example. [P 51(82)]
VSAQ 10. Give two examples for gaseous Zero order reactions. [P 52(83)]
VSAQ 11. What are pseudo first order reactions?Give one example. [P 52(85)]

** GENERAL PRINCIPLES OF METALLURGY[2MARKS]t*

VSAQ 12. Write any two ores with formulae of the following metals: [P 53(90)]
i) Aluminium ii) Zinc ii) Iron iv) copper
VSAQ 13. Explain 'poling' [rP 53(91)]
VSAQ 14. What is the role of cryolite in the metallurgy of aluminium? [rP 53(92)1
VSAQ 15. Give the composition ofthe following alloYS. [rP 53(93)]
i) Brass ) German silver ii) Bronze
VSAQ 16. What is matte?Give its composition. [rP 53(95)1|
VSAQ 17. What is blister copper? Why is it so called? [rP 53(96)]

***p-BLOCK ELEMENTS[2 +2 MARKS]***

VSAQ 18. What is Allotropy? [ P54(98))
VSAQ 19. Nitrogen molecule is highly stable. Why? IrP 54(99)]
VSAQ 20. PH3 bas lower boiling pointthan NH3. Why? [P 54(L00)]
VSAQ 21. What is a tailing ofmercurv? How is it rernoved? [P 54(103)]
vSAQ22. Why is H20aliquid while H,Sis agas? {P 55(L05))
VSAQ 23. What happens when Cl reacts with dry slakedlime? [rP 55(106))
VSAQ 24. Write the reactions of E and Ch with water. [P55(107))
SR.CHEMISTRY 10
BABY BULLET-Q*

VSAQ 25. How is chlorine manufactured by Deacon's method? [ P55(108)|

VSAQ 26 List out the nses ofneon. [rP 55(1o9)]
VSAQ 27. Write the structure of Xe03 [P 55(1i0)]
VSAQ 28. n modern diving apparatus, amixture of He and O, is used- Why? [rP 55(111)]

***d&f BLOCK ELEMENTS [2 MARKS]*t*

VSAQ29. Why Znt is diamagnetic whereas Mn2+ is paramagnetic? [P 56(113)]
VSAQ 30. What is an alloy? Give example. [P 56(115)]
VSAQ31. What is Lanthanide contraction? [rP 57(118)]
VSAQ 32. What is Mischmetal? Give its composition and uses. [P 57(119)1
VSAQ 33. What is a Ligand? (rP 57(120)]

**POLYMERS [2 MARKSJ**
VSAQ 34. What is PHBY? How is it useful to man? [rP 58(124)]
VSAQ 35. What is yulcanisation of Rubber? [P 58(125)]
VSAQ36. What are conolymers? Give example.
VSAQ 37.
[rP 58(127)]
What are the repeating monomeric units ofNlon 6and Nvlon 6.6?
[P 58(128)]
VSAQ38. What is biodegradable nolvmer? Give one example.
VSAQ 39. What is PDIPoly Dispersity Index)
[rP 58(129)1
[P 58(130)]
**BIOMOLECULES I2 MARKSJ* *
VSAQ 40. What is Zwitter ion? Give an example.
VSAQ 41. What are amino acids?Give two examples. U [rP 59(131)]
VSAQ 42. What are essential and non-essential amino acids? Give one [rP 59(132)]
example for each. [rP 59(133)]
VSAQ 43. Differentiate between globular and fibrous proteins.
IrP 59(135)|
***CHEMISTRY IN EVERY DAY LIFE2+2 MARKS]* **
VSAQ 44. What are antacids? Give example.
VSAQ 45. What are antihistamines? Give example. [rP 60(136)1
VSAQ 46. What are antibiotics? Give examplen [rP 60(137)|
VSAQ47. What are antiseptics? Give example [P 60(138)1
VSAQ 48. What are artificial sweetening agents? Give example [rP 60(139)1
VSAQ 49. What are food preservatives? Give example. [P 60(140)1
VSAQ 50. What are Antifertility drugs? Give example. IrP 60(141))
VSAQ51. What are analgesics? How are they classified? IP 60(143)1
VSAQ 52. What are tranquilizers? Give example. [rP 45(61))
**ORGANIC CHEMISTRYI2 MARKST* [P46(62)1
VSAQ 53. What are ambident nucleophiles?
VSAQ 54. What are Enantiomers?
ySAQ 55. How is Grignard reagent prepared [oP61(144)1
VSAQ 56. Write about Carbylamine reaction. 1(145)1
ySAQ57. Write the structure of the following compounds (P61(1471
lP61(148)1
2-chloro-3-methyl pentane ()p-bromo chloro benzene
P65(I71))
 PROBLEMS HITLIST
TOP 15 PROBLEMS
Ans-Page
** SOLUTIONS **
P1. Define Molarity.
Calculate the molarity ofa solution containing 5 gof NaOHin 450 ml solution. [P 29(19)|
P2.
Calculate the molarity of asolution containing 5g ofNaOH in 500ml of solution. (P62(151)1
P3. [P62(152)1|
Calculate the molarity of asolution containing 10 gof NaOHin 500 ml solution.
P4. Define Molality. [P 29(20)1
Calculate molality(m) of 10gm of Glucose (CH120%) in 90gm of Water.
P5. Calculate molality of2.5 grams of EthanoicAcid (CH3 COOH) in 75 grams ofBenzene. [arP 62(153)1
P6, Define Mole fraction. [rP 29(21)}
Calculate the mole fraction ofH,SO4 in asolution containing 98% H2SO4 by mass.
P7. Calculate the mole fraction of sodium hydroxide in 10% (w/w) NaOH solution. [P 56(140)|
P8. Calculate the mole fraction of ethylene glycol (CH0) in a solution containing [P56(141)1|
20% of C2H602 by mass.
P9. Calculate the mass of anonvolatile solute (molar mass 40g mo-l) which should be IrP30(23)1
dissolved in 114pg Octane to reduce its vapour pressure to 80%.

PI0. The vapour pressure of pure benzene at a certain temperatur is 0.850 bar. [P30(24)]
Anon-volatile, non-electrolyte solid weighing 0.5g when added to 39.0 g of benzene
(molar mass 78 g mol-). Vapour pressure of the solution, then, is0.84S bar.
What is the molar mass of the solid substance?
*ELECTRO CHEMISTRY*
PIl. A first order reaction is found to have arate constant, k-5.5x10gl [P52(86)]
Find the half life of the reaction.
P12. A reaction has a life of 10 minutes. Calculate the rate constant for the [P 52(87)}
first order reaction.
PI3. Asolution ofCuSO4 is electrolysed for 10 minutes with a current of 1.5 amperes. [rP 52(88)|
What is the mass of copper deposited at the cathode?

*d&{ BLOCK ELEMENTS*

PI4. Calculate the magnetic moment of a divalent ion in aqueous solution if its [P57(122)1
atomic number is 25.
PI5. Calculate the'spinonly' magnetic moment of Fe(aa) ion. (P57123)|