JEE

Manzil JEE (2024)

Chemistry
Atomic Structure

Q1 A radio station broadcasts at a frequency of Q5 How far from the nucleus is the electron in a
2965 kilo Hertz. Another radio station hydrogen atom if it has energy of –0.850 eV.
broadcasts at a frequency of 56.9 mega Hertz. (A) 8.46 Å (B) 9.5 Å
What are the wavelength of radiations from (C) 10.12 Å (D) 6.43 Å
each station respectively?
Q6 Calculate the ratio of the radius of Be3+ ion in
(A) 120.16 m, 4.32 m
second energy level to that of Li2+ ion in the
(B) 432 m, 3.09 m
third energy level.
(C) 101.18 m, 5.27m
(A) 1 : 2 (B) 1 : 3
(D) 200.56 m, 8 m
(C) 16 : 27 (D) 3 : 1
Q2 The mass of electron is 9.11 × 10–31 Kg. Calculate
Q7 The threshold frequency for a metal is 7.0 × 1014
the uncertainty in its velocity if the uncertainty
s–1. Calculate the kinetic energy of an electron
in its position is of the order of ±10 pm. (h = 6.6 ×
emitted when radiation of frequency 1.0 × 1015 s–
10–34 kg m2 s–1)
1 hits the metal.
(A) 1.19 × 106 ms–1
(A) 1.98 × 10–18 J
(B) 4.76 × 106 ms–1
(B) 1.98 × 10–19 J
(C) 5.76 × 106 ms–1
(C) 2 × 10–16 J
(D) 3.58 × 106 ms–1
(D) 2 × 10–19 J
Q3 What is the frequency of a photon emitted
Q8 How many electrons in sulphur (Z = 16) can have
during a transition from n = 6 to n = 3 state in
n+l=4?
the hydrogen atom.
(A) 2 (B) 1
(A) 9139.75 s–1
(C) 3 (D) 4
(B) 2.741 × 1014 s–1
(C) 109.41 × 10–6 s–1 Q9 Which of the following has same value of
(D) 34.5 × 10–6 s–1 angular momentum?
(A) 2s ,4f (B) 2p ,3p
Q4 Calculate the de Broglie wavelength of an
(C) 4f, 5p (D) 2s, 2p
electron that has been accelerated from rest
through a potential difference of 1 kV Q10 The isoelectronic pair is
(A) 3.87×10–11 m (A) C l 2O, ICl
−
2

(B) 4.62×10–10 m (B) C l 2 ,

−
C lO2

(C) 6.3×10–10 m (C) I F2 +

, I
−
3

(D) 5.11×10–11 m

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(D) C lO−
2
, C lF
2
+
(A) 1s2, 2s2, 2p1x, 2p1y, 2p1z (for Nitrogen)
(B) 1s2, 2s2, 2p2x, 2p2y, 2p1z (for Oxygen)
Q11 Electron will first enter into the orbital with the
(C) 1s2, 2s2, 2p6, 3s2, 3p6, 3d4, 4s2 (for Chromium)
set of quantum number
(D) 1s2, 2s2, 2p6, 3s2, 3p6, 3d6, 4s2 (for Iron)
(A) n = 3, l = 2 (B) n = 4, l =1
(C) n = 5, l = 0 (D) Any of these Directions (18) Read the following passage and
answer the given questions.
Q12 Which of the following statement is not correct?
The uncertainty in the position of a flying dust
(A) 2p orbital has no spherical nodes
particle of mass 0.1 mg is found to be 10–4 m.
(B) The opposite lobes of a p orbital have
The uncertainty in the position of another flying
opposite sign whereas opposite lobes of d
dust particle of mass 0.5 mg is also found to be
orbital have the same sign.
same.
(C) The number of radial nodes in 3s and 4p
orbital is not equal. Q18 The uncertainty in the velocity of the
(D) All p orbitals have only one planar node. lighter dust particle is nearly
(A) 5 × 10–24 ms–1
Q13 The transition of electrons in H atom that will
(B) 2.5 × 10–24 ms–1
emit maximum energy is
(C) 1.25 × 10–24 ms–1
(A) n3 → n2
(D) 5 × 10–25 ms–1
(B) n4 → n3
(C) n5 → n4 Directions (19) Read the following passage and
(D) All the transitions have same energy. answer the given questions.
The uncertainty in the position of a flying dust
Q14 A gas absorbs a photon of 240 nm and emits at
particle of mass 0.1 mg is found to be 10–4 m.
two wavelengths. If one of the emissions is at
The uncertainty in the position of another flying
523 nm, the other is at
dust particle of mass 0.5 mg is also found to be
(A) 325.62 nm (B) 443.53 nm
same.
(C) 518.11nm (D) 1035 nm
Q19 The uncertainty in the velocity of the
Q15 Which of the following is the energy of a
heavier dust particle as compared to the
possible excited state of Li2+?
lighter dust particle is
(A) –6.8 eV (B) +35.4 eV
(A) 5 times (B) 1/5th times
(C) +6.8 eV (D) –30.6 eV
(C) Same (D) 50 times
Q16 Which of the following are matched correctly?
Directions (20) Read the following passage and
(A) 3pz — (n = 3, l = 0, m = –1)
answer the given questions.
(B) 3dxz, 3dyz — (n = 3, l = 2, m = ±1)
The uncertainty in the position of a flying dust
(C) 2px,2py — (n = 2, l = 1, m = ± 1)
particle of mass 0.1 mg is found to be 10–4 m.
(D) 3dxy , 3d x 2 − y 2 — (n = 3, l = 1, m = +2)
The uncertainty in the position of another flying
Q17 Which of the following electronic configuration dust particle of mass 0.5 mg is also found to be
is/are wrong? same.

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Q20 If a third flying dust particle of mass 1 mg A → R, B → S , C → P , D → T , E

had the same uncertainty in position as → Q

in its velocity, the uncertainty in its (B) A → P , B → R, C → S , D → Q, E

momentum would be → T

(C) A → R, B → P , C → S , D → T , E
(A) 5.2 × 10–28 kg ms–1
→ Q
(B) 5.2 × 10–34 kg ms–1
(D) A → P , B → R, C → S , D → Q, E
(C) 7.2 × 10–15 kg ms–1
→ T
(D) 7.2 × 10–21 kg ms–1
Q23 The number of pairs having same electronic
Q21 Match the atom/ions with the characteristics of configuration is_______.
the electron they contain. (Fe3+, Mn2+); (Sc2+, Ti3+); (V2+, Ti+), (Cu2+, Ni2+);
(Zn2+, Cu+)

Q24 Magnetic momentum of an ion A3+ is 4.90 ​B.M.

Then, number of unpaired electron in d orbital
of element A3+ is “X” and number of unpaired
electron in Cu2+ is “Y”. Then, the value of X +Y
will be___.

Q25 No. of paramagnetic and diamagnetic ions are

respectively _____ and ______.
Co2+, Mn7+, Ni2+, Ti+, Cr3+, V2+, Cu+, Sc+, Fe2+

(A) A → P , B → Q, C → (R, S ), D → T

(B) A → S , B → P , C → (P , T ), D → S

(C) A → R, B → Q, C → (P , T ), D → S

(D) A → P , B → Q, C → (S , T ), D → R

Q22 Match the following:

(A)

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Answer Key
Q1 (C) Q14 (B)

Q2 (C) Q15 (D)

Q3 (B) Q16 (B, C)

Q4 (A) Q17 (B, C)

Q5 (A) Q18 (A)

Q6 (B) Q19 (B)

Q7 (B) Q20 (D)

Q8 (D) Q21 (C)

Q9 (B) Q22 (C)

Q10 (D) Q23 3

Q11 (A) Q24 5

Q12 (C) Q25 7, 2

Q13 (A)

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Hints & Solutions

Q1 Text Solution: E = – 0.850 eV
n1 = 2965 kHz = 2965 × 103 Hz
2

E = – 13.6 ×
Z
2
eV = −0. 850 eV
n
c c 2
ν = ; λ = −13.6×(1)
λ
8
ν
−1
For H-atom, Z = 1; n2 =
−0.850
2
; n = 16
3×10 ms
∴ λ1 =
2965×10
3
Hz n=4
= 101.18 m 2

Å
n
r = 0. 529 ×
n2 = 56.9 MHz = 56.9 × 106 Hz
Z

= 0.529 × Å
16
8 −1 1
3×10 ms
λ2 =
56.9×10
6
Hz = 8.464 Å
= 5.27 m
Q6 Text Solution:
Q2 Text Solution: r
Be
3+

= (
n
2

× (
Z
∵ r ∝
n
2

) )
me = 9.11 × 10–31 kg; Δx = 10 pm = 10 × 10–12 m
r 2
Li
2+ Z 3+ n 2+ Z
Be Li
2
(2) 3 1
x × Δp =
h
Δ ⇒ × =
4 2 3
4π (3)
−11 h
⇒ 10 m ⋅ me ΔV =
−34
4π
2 −1
Q7 Text Solution:
6.6×10 kg m s
⇒ ΔV =
4×3.14×10
−11
m×9.11×10
−31
kg
v0 = 7 × 1014 s–1; v = 1015 s–1
= 5.76 × 106 ms–1 K.E = h(v – v0)
K.E = 6.63 × 10–34 Js (1015 – 7 × 1014) s–1
Q3 Text Solution:
= 1.98 × 10–19 J
RH 1 1
ν = ( − ); (ni = 6 → nf = 3)
Q8 Text Solution:
h 2 2
n n
i f

Z = 16;
−18
2.18×10 J 1 1
= ( − )
−34 2 2
6.63×10 Js 6 3

15 1 1 −1
= 3. 29 × 10 ( − )s
36 9

15 1−4 −1
= 3. 29 × 10 ( )s
36

= – 0.2741 × 1015 s–1; (–) sign signifies emission

= 2.741 × 1014 s–1

Q4 Text Solution:
V = 1 KV; λ = ?
h h h
Q9 Text Solution:
λ = = = − −− −−− − −−−−−−
P √2mE √2mqV 1. 2s = √ l(l + 1)ℏ = √ 0(0 + 1)ℏ = 0
− −−−−−− −−
6.63×10
−34
J .s 4f = √ 3(3 + 1)ℏ = √12 ℏ
= [C × V = − −−−−−− –
√2×9.11×10
−31
kg×1.6×10
−19
CV 2. 2p = √ 1(1 + 1)ℏ = √2 ℏ
− −−−−−− –
3p = √ 1(1 + 1)ℏ = √2 ℏ
− −−−−−− −−
J] 3. 4f = √ 3(3 + 1)ℏ = √12 ℏ
− −−−−−− –
5p = √ 1(1 + 1)ℏ = √2 ℏ
−9
1.227×10 m − −−−−−−
=
√V
4. 2s = √ 0(0 + 1)ℏ = 0
−9 − −−−−−− –
1.227×10 m
= = 3. 88 × 10– 11 m 2p = √ 1(1 + 1)ℏ = √2 ℏ
√103

Q10 Text Solution:

Q5 Text Solution:

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Hence, the statement is incorrect

1. Cl2O ⇒ 17 × 2 + 8 = 42
4. Px, Py, Pz
ICl
⊖
2
⇒ 53 + 17 × 2 + 1 = 88 No. of planar node = l = 1
2. Cl
⊖
2
⇒ 17 × 2 + 1 = 35 Q13 Text Solution:
ClO2 ⇒ 17 + 8 × 2 = 33 ΔE ∝ (
1
2
−
1
2
)
n n
i f

3. IF
2
+
⇒ 53 + 9 × 2 – 1 = 70 1 1 1 1 −5
ΔE ∝ ( − ) = − = = −0
2 2 9 4 36
I
3
⊖
⇒ 53 × 3 + 1 = 160 (3) (2)

. 14
4. C lO⊖
2
⇒ 17 + 8 × 2 + 1 = 34 (Isoelectronic 1 1 1 1 −7
ΔE ∝ ( − ) = − = = −0
species) (4)
2
(3)
2 16 9 144

. 05
C lF
+
2
⇒ 17 + 9 × 2 – 1 = 34 (Isoelectronic
1 1 1 1 −9

species) ΔE ∝ (
(5)
2
−
(4)
2
) =
25
−
16
=
400
=

Q11 Text Solution: −0. 023

Electron enters the orbital which has minimum Q14 Text Solution:
energy given by (n + l). If the value is same, then E =
hc
=
hc

λ 240

it is decided by smaller value of ‘n’. E = E 1 + E2

1. n = 3; l = 2 n+l=5
hc hc hc
= +
λ λ1 λ2

2. n = 4; l = 1 n+l=5 1

λ
=
1

λ1
+
1

λ2

3. n = 5; l = 0 n+l=5 240
1
=
1

523
+
λ2
1

1 1 1

∴ n : 5 > 4 > 3 ® Minimum value λ2

=
240
−
523

e– enters orbital n = 3; l = 2 (3d)

1 523−240
=
∴ λ2 523×240

1 283
= ⇒ λ2 = 443. 53 nm
Q12 Text Solution: λ2 523×240

1. 2p Q15 Text Solution:

2
Z
= No. of spherical node = n – l – 1 E n = −13. 6 ×
n
2
eV

=2–1–1
2
(3) −122.4
⇒ −13. 6 × 2
eV = 2
eV
=0
n n

If n = 1, E1 = – 122.4 eV
2.
E2 = – 30.6 eV
E3 = – 13.6 eV
E4 = – 7.65 eV

Q16 Text Solution:

1. 3pz (n = 3; l = 1; m = 0) ∴ incorrect
s, p, d, f PZ = 0
l = 0, 1, 2, 3 Px/Py = ±1
3. 3s ; 4p
2. 3dxz, 3dyz (n = 3; l = 2; m = ±1) ∴ correct
n–l–1 n–l–1
3. 2px, 2py (n = 2, l = 1; m = ±1) ∴ correct
⇒ 3–0–1=2 ⇒ 4–1–1=2
4. 3dxy, 3d x 2 −y 2 (n = 3; l = 2; m = ±2) ∴ incorrect

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2

Radius = 0. 529 × Å
n

Q17 Text Solution: Z

1. N : 1s2 2s
2 1
2px 2py 2pz →
1 1
Correct match A. H
2
(1)
2. O : 1s2 2s
2 2
2px 2py 2pz →
1 1
Incorrect match E 4 = −13. 6 × eV = −0. 85eV
16

3. Cr : 1s2 2s2 2p6 3s2 3p6 4s1 3d5 → Incorrect V3 = 2. 18 × 10

6
×
1
ms
−1

match (1)
2

E 2 = −13. 6 × eV = −3. 4eV

4. Fe : 1s2 2s2 2p6 3s2 3p6 4s2 3d6 → Correct (4)
4
2

match r4 = 0. 529 ×
1
Å = 0.53 × 16Å
= 0.53 × 16Å
Q18. Text Solution: (2)
2

m1 = 0.1 × 10–3 × 10–3 kg; Δx = 10–4m r2 = 0. 53 ×

1
Å = 0.53 × 4Å ∴ A → R

m2 = 0.5 × 10–3 × 10–3 kg; Δx = 10–4 m B. He+

2

Å
(4)
For lighter dust particle; r4 = 0. 529 ×
2

Δx ⋅ Δp =
h

4π
; Δx ⋅ mΔv =
h

4π
= 0.529 × 8Å
−34 2

Å Å
h 6.63×10 Js (2)
Δv = = r2 = 0. 529 × = 0. 529 × 2
−6 −4
4π⋅mΔx 4×3.14×0.1×10 kg×10 m 2

= 5.278 × 10–24 ms–1

2
(2)
E 2 = −13. 6 × eV
2
(2)

= – 13.6 eV
Q19. Text Solution: ∴ B → Q
h 2
Δx ⋅ Δp = (2)
4π E 4 = −13. 6 ×
2
h h (4)
Δx ⋅ m2 Δv2 = ; Δx ⋅ m1 Δv1 =
4π 4π
Δx⋅m 2 Δv2 = – 13.6 × 1

4
= 1
Δx⋅m 1 Δv1 6 2 −1
V3 = 2. 18 × 10 × ms
m1 3
∴ Δv 2 = × Δv 1

0.1
m2
C. Be3+
Δv 2 = × Δv 1 2

Å
0.5 (4)
Δv1 r4 = 0. 529 ×
4
Δv 2 =
5
= 0.529 × 4Å
Q20. Text Solution: (C → P)
m = 1 mg = 10–6 kg (2)
2

r2 = 0. 529 ×
If Δx = Δv ⇒ Δx.mΔv = h 4
4π
= 0.529Å
Δ x.mΔx = 4π
h

(4)
2

2 h E 2 = −13. 6 ×
(Δx) = (2)
2

4πm
−
− −
−
Δx = √
h = –13.6 × 4 eV
4πm 2
(4)
h E 4 = −13. 6 × = −13. 6eV
Δx ⋅ Δp = 2
4π (4)

h×√4πm √h×√m
(C → T )
Δp = =
4π×√h √4π 4
6 −1
−−−−−−−−
−34
−−−
−6 V3 = 2. 18 × 10 × ms
6.63×10 ×10 3
⇒ √
4×3.14
(∴ C → P, T)

= 7.2 × 10–21 kg ms–1 D. Li2+

2

Q21 Text Solution: r4 = 0. 529 ×

(4)
Å = 0. 53 ×
16
Å
2
3 3

Energy = −13. 6 n
Z 2
eV
Å Å
(2) 4
2
r2 = 0. 529 × = 0. 53 ×
3 3
Velocity = 2. 18 × 10 6
×
Z

n
ms
−1

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2

E 4 = −13. 6 ×
(3)
=
−13.6×9
eV
0 = n(n + 6) – 4 (n + 6)
2 16
(4)
2
0 = (n – 4) (n + 6)
(3) 9
E 2 = −13. 6 ×
(2)
2
= −13. 6 ×
4
eV
∴ n=4
6 3 −1
V3 = 2. 18 × 10 × ms
3
6 −1
V3 = 2. 18 × 10 ms

(D → S )
x+y=4+1=5
Q22 Text Solution: Q25 Text Solution:
A. Violation of Pauli’s rule → No 2e– can have
same four quantum number. A → R
B. Violation of Hund’s rule → All orbitals will be
singly occupied before any is doubly occupied.
B→P
C. Violation of Aufbau’s rule → Electrons in the
atomic orbital of any atom are filled in the
ascending order, of their energy. C → S (4p < 4d
< 5s < 5p)
D. ψ(Wave function) → Can be of (+) or (–) sign.

(D → T)
E. ψ2 (Probability density) → Is always +ve. (E →
Q)

Q23 Text Solution:

Fe3+ ⇒ 3d5; Mn2+ ⇒ 3d5 = Identical
Sc2+ ⇒ 3d1; Ti3+ ⇒ 3d1 = Identical
V2+ ⇒ 3d3; Ti+ ⇒ 4s13d2
Cu2+ ⇒ 3d9; Ni2+ ⇒ 3d8
Zn2+ ⇒ 3d10; Cu+ ⇒ 3d10 = Identical

Q24 Text Solution:

A3+ = 4.9 B.M.
−− −−−−−
4. 9 = √ n(n + 2)

24 = n2 + 2n
0 = n2 + 2n – 24
0 = n2 + 6n – 4n – 24

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