BAED-CHEM2122 General Chemistry 2

Question 1
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The lower the concentration of the weak acid decreases the pH of the buffer solution.

a.
True

b.
False
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Question 2
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What happens to the internal energy of the system if work is done on the system?

a.
Internal energy remains constant

b.
Internal energy will decrease

c.
Internal energy will increase
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Question 3
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Total change in energy is equal to the sum of the heat and work transferred between the
systems and surroundings.

a.
Second Law of Thermodynamics

b.
Third Law of Thermodynamics

c.
First Law of Thermodynamics
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Question 4
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 Question text
Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from
liquid at 10° C to vapor at 30° C.

a.
126Kj

b.
119kJ

c.
120kJ

d.
130kJ
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Question 5
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If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees
Celsius, what is the specific heat of substance B?

a.
0.167 J/g. C

b.
1.67 J/g. C
c.
1.76 J/g. C

d.
0.176 J/g. C
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Question 6
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In thermodynamics, an ___process is a type of thermodynamic process in which the pressure
P of a system remains constant.

a.
Isometric

b.
Isochoric

c.
Isobaric

d.
Isothermal
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Question 7
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Freezing and condensation are examples of exothermic process.

a.
True

b.
False
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Question 8
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In exothermic reaction, heat is liberated into the surroundings.

a.
False

b.
True
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Question 9
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Chemical equilibrium is described as a dynamic process because there is a movement in
which the forward and reverse reactions occur at the same rate to reach a point where the
amounts or concentrations of the reactants and products are unchanging with time.

a.
True

b.
False
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Question 10
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____ constant tells how far the reaction has proceeded once the equilibrium is reached.

a.
Universal gas

b.
Equilibrium
c.
Dielectric

d.
Cell
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Question 11
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The higher the number of types of molecules, the higher is the degree of disorder.

a.
True

b.
False
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Question 12
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Melting and vaporization are examples of exothermic process.
a.
False

b.
True
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Question 13
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Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a
coffee cup calorimeter and the temperature drops from 295 oC to 285 o C. Find the value of
q for the calorimeter.
(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)

a.
5500 J

b.
-5430 J

c.
-5300 J

d.
5430 J
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Question 14
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Predict the entropy change (ΔS) if the temperature of crystal is increased.

a.
ΔS = 0

b.
ΔS will increase

c.
ΔS remains constant

d.
ΔS will decrease
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Question 15
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What kind of thermodynamic system is coffee held in a cup?
a.
Closed system

b.
Open system

c.
Isolated system
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Question 16
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Which one of the following thermodynamic quantities is not a state function?

a.
Gibbs free energy

b.
Work

c.
Internal energy

d.
Entropy
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Question 17
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Which phase of matter has the greatest motion and least orderly arrangement?

a.
Liquid

b.
Solid

c.
Gas
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Question 18
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The increased in internal energy of the system is 80 J and has 70 J of work done on it. What
is the heat change of the system?

a.
+0.10 J
b.
-10 J

c.
+10 J

d.
-0.10 J
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Question 19
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A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work
done on it. What is the heat change of the system?

a.
+30 J

b.
-130 J

c.
-30 J

d.
+130 J
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Question 20
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Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298
K.

a.
0.45KJ

b.
+0.45 J

c.
-0.45 kJ

d.
0.50Kj
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Question 21
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A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of
methanol is 64.7 o C and the molar enthalpy of vaporization if 71.8 kJ/mol. The value of ΔS
when 2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.

a.
5.21x107

b.
457

c.
0.457

d.
2.39x10 3
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Question 22
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A photochemical reaction is one of the examples of non-spontaneous reaction.

a.
False

b.
True
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Question 23
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If the reaction quotient Q has a smaller value than the related equilibrium constant, K,
__________

a.
The value of K will decrease until it is equal to Q

b.
The reaction is at equilibrium.

c.
The reaction is not at equilibrium, and will make more reactants at the expense of
products.

d.
The reaction is not at equilibrium, and will make more products at the expense of
reactants.
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Question 24
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 Question text
In thermodynamics, an ___process, also called a constant-volume process.

a.
Isochoric

b.
Isobaric

c.
Isometric

d.
Isothermal
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Question 25
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The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is
at a certain temperature.
H2(g) + I2(s) ⇌ 2 HI(g) K = 45
Which of the following is true regarding this equilibrium?
I. The reaction is product favored.
II. The reaction is reactant favored.
III. Equilibrium lies to the right.
IV. Equilibrium lies to the left.
a.
II and III

b.
II and IV

c.
I and III

d.
I and IV
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Question 26
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___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy
change for the reaction is the sum of all changes.

a.
Calorimetry

b.
Hess's Law

c.
Second Law of Thermodynamics
d.
Gibbs Free Energy
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Question 27
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What happens to the internal energy of the system if work is done by the system?

a.
Internal energy remains constant

b.
Internal energy will decrease

c.
Internal energy will increase
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Question 28
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The standard enthalpy of formation for a simple substance in its most stable state must be
non-zero
a.
False

b.
True
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Question 29
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If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees
Celsius, what is the specific heat of substance A?

a.
250 J/g. C

b.
10 J/g. C

c.
2.5 J/g. C

d.
0.250 J/g. C
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Question 30
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Reactions in which the products can react to form back the reactants are said to be ___.

a.
Decomposition

b.
Combination

c.
Reversible

d.
Irreversible
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Question 31
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A chemical equilibrium may be established by starting a reaction with __________

a.
Products only

b.
All the above

c.
Reactants only

d.
Any quantities of reactants and products.
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Question 32
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___ is the state at which the concentration ratio of products to reactants is observed to be
constant.

a.
Solid

b.
Equilibrium

c.
Liquid

d.
Oxidation
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Question 33
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Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum
from 45 to 65 degrees Celsius. Molar heat capacity of aluminum is 24 J/mole.K.

a.
1.35kJ

b.
1.44 KJ

c.
1.065kJ

d.
1.25 kJ
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Question 34
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The equilibrium constant for the reaction is 10. What will be the value of ΔG?

a.
7544 J

b.
4457 J

c.
4475 J

d.
-5744 J
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Question 35
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In thermodynamics, an ___process is a type of thermodynamic process in which the
temperature T of a system remains constant.

a.
Isochoric

b.
Isometric

c.
Isothermal

d.
Isobaric
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Question 36
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The equation that relates enthalpy, temperature and entropy is

a.
Hess's Law

b.
Gibbs Free Energy

c.
Second Law of Thermodynamics

d.
Calorimetry
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Question 37
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Which of the following is true regarding the concentration of products, for a chemical
reaction that is already at equilibrium, assuming no disruptions to the equilibrium?

a.
The concentrations of products will change continually because of reversibility

b.
The concentrations of products will not change because the limiting reagent is gone.

c.
The concentrations of products will not change because the forward and reverse rates
are equal.

d.
The concentrations of products will not change because there are no more reactants.
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Question 38
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Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.
a.
ΔS remains constant

b.
ΔS > 0

c.
ΔS = 0

d.
ΔS < 0
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Question 39
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Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from
graphite and oxygen:
C(s) + O2(g) → CO2(g)
Standard Entropy in J/mol.K for: C= 5.740 O2 = 205.14 CO2=213.74

a.
5.31 J/mol.K

b.
2.86 J/mol.K

c.
1.76 J/mol.K
d.
3.35 J/mol.K
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Question 40
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Non-spontaneous processes are those that do not take place by themselves or is a type of
reaction which cannot occur without the input of work from an external source.

a.
False

b.
True
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Question 41
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A reversible reaction has ΔG negative for forward reaction. What will be the sign for the
backward reaction?
a.
No sign

b.
Negative

c.
Positive
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Question 42
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An equilibrium that strongly favors products has __________

a.
a value of K >> 1.

b.
a value of K << 1.

c.
a value of Q << 1.

d.
K = Q.
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Question 43
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If ΔG is positive, the reaction is spontaneous in the reverse direction.

a.
False

b.
True
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Question 44
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Spontaneous processes are those that can proceed with any outside intervention.

a.
False

b.
True
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Question 45
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The standard free energy is found to be zero. What is its equilibrium constant?

a.
10

b.
0

c.
1

d.
5
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Question 46
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If ΔG is 1, the system is at equilibrium.
a.
True

b.
False
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Question 47
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Which of the following is true for a chemical reaction at equilibrium?

a.
Only the forward reaction stops

b.
The rates of the forward and reverse reactions are equal

c.
Both the forward and reverse reactions stop

d.
Only the reverse reaction stops

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Question 48
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An isometric process, is a thermodynamic process during which the volume of the closed
system undergoing such a process remains constant.

a.
False

b.
True
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Question 49
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The ____ of a substance is the amount of energy required to raise the temperature of 1 gram
of the substance by 1 degree Celsius.

a.
Volume

b.
Mass
c.
Temperature

d.
Specific heat
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Question 50
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The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of
1 cm³ of water by one degree Celsius.

a.
Mole

b.
Watt

c.
Calorie

d.
Joule
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