Benzen va ng ng

Ly thuyt
Cu1 Cho s bin ho: A1 + Cl2 A as B1
+NaOH, to + CuO, to + Ag2O/NH3,to

A2 B2

A3 B3

A4 polime

+NaOH, to

+H2SO4 c 170 C
o

Trng hp

Bit A l etylbezen. T l mol ca A vi Cl2 l 1:1. Xc nh A1, A2, A3, A4, B1, B2, B3 v hon thnh s phn ng trn.

Cu 2 a) T than , vi v cc cht v c cn thit, vit phng trnh iu ch o-bromonitrobenzen v pbromonitrobenzen. b) Dng mt thuc th hy nhn bit 3 cht lng benzen, toluen, stiren ng trong ba l ring bit. Cu 3 Cho cc cht: C6H5-CH3 ; C6H5-CH2-CH3 ; C6H5Br ; C6H5NO2 ; C6H5COOH Vn dng quy tc th vng benzen, vit cc phng trnh phn ng (dng cng thc cu to) khi cho cc cht trn ln lt tc dng vi: 1- Br2 lng, xc tc bt Fe v un nng? 2- Dung dch HNO3 c, xc tc H2SO4 c v un nng? Cu 4 Tnh cht no khng phi ca benzen? a.Tc dng vi dung dch Br2 (Fe) c.Tc dng vi dung dch KMnO4 b.Tc dng vi HNO3 /H2SO4() d.Tc dng vi Cl2 (as) Cu 5. Tnh cht no khng phi ca toluen? a.Tc dng vi dung dch Br2 (Fe) c.Tc dng vi dung dch KMnO4, t0 b.Tc dng vi Cl2 (as) d.Tc dng vi dung dch Br2 Cu 6. Toluen + Cl2 (as) xy ra phn ng: a.Cng vo vng benzen c.Th nhnh, kh khn hn CH4 b.Th vo vng benzen, d dng hn d.Th nhnh, d dng hn CH4 Cu 7. Tin hnh th nghim cho nitro benzen tc dng vi HNO3/H2SO4 (), nng ta thy: a.Khng c phn ng xy ra b.Phn ng d hn benzen, u tin v tr meta c.Phn ng kh hn benzen, u tin v tr meta d. Phn ng kh hn benzen, u tin v tr ortho Cu 8. Dy cc nhm th lm cho phn ng th vo vng benzen d dng hn v u tin v tr o- v p- l: a.-CnH2n+1, -OH, -NH2, c.CH3, -NH2, -COOH b.OCH3, -NH2, -NO2 d.NO2, -COOH, -SO3H Cu 9. Dy gm cc nhm th lm cho phn ng th vo vng benzen u tin v tr m- l: a.-CnH2n+1, -OH, -NH2 c.CH3, -NH2, -COOH b.OCH3, -NH2, -NO2 d.NO2, -COOH, -SO3H Cu 10. A l dn xut benzen c cng thc nguyn (CH)n. 1 mol A cng ti a 4 mol H2 hoc 1 mol Br2(dd). Vy A l: a.etyl benzen b.metyl benzen c.vinyl benzen d.ankyl benzen Cu 11. Tnh cht no khng phi ca benzen? a.D th b.Kh cng c.Bn vi cht oxi ha d.Km bn vi cc cht oxi ha Cu 12. phn bit c cc cht Hex-1-in,Toluen,Benzen ta dng 1 thuc th duy nht l: a. dd AgNO3/NH3 b.dd Brom c.dd KMnO4 d.dd HCl Cu 13D phn bit d dng Hex-1-in,Hex-1-en,benzen ta ch dng 1 thuc th duy nht l: a. dd Brom b. dd AgNO3/NH3 c.dd [Ag(NH3)2]OH d.dd HCl

Bai tp
Cu 14:t chy hon ton m g A ng ng ca benzen thu c 20,16 lt CO 2 (ktc) v 10,8 ml H2O (lng).Cng thc ca A l: a. C7H8 b. C8H10 c. C9H12 d. C10H14 Cu 15:t chy hon ton 0,1 mol CxHy thu c 15,68 lt CO2 (ktc) v 7,2 g H2O (lng).Cng thc ca CxHy l: a. C7H8 b. C8H10 c. C10H14 d. C9H12 as Cu 16:1 mol Toluen + 1 mol Cl2 A . A l: a.C6H5CH2Cl b. p-ClC6H4CH3 c. o-ClC6H4CH3 d.B v C u ng H 2 SO4 d Cu 17:1 mol nitrobenzen + 1 mol HNO3 B + H2O. B l: to a.m-initrobenzen b. o-initrobenzen c. p-initrobenzen d.B v C u ng. Cu 18:A(CxHy) l cht lng iu kin thng c dA/kk l 2,7. A chy mCO2 : mH2O = 4,9 : 1.Cng thc phn t ca A l: a. C7H8 b. C6H6 c. C10H14 d. C9H12 Cu 19:Stiren khng phn ng c vi nhng cht no sau y: a.dd Br2 b.khh H2 ,Ni,to c.dd KMnO4 d.dd NaOH Cu 20: Hiro ho etylbenzen ta c stiren;trng hp stiren ta c polistiren vi hiu sut chung 80%.Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l: a.13,52 tn b.10,6 tn c.13,25 tn d.8,48 tn Cu 21:t chy hon ton hi A(CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi.Cng thc phn t ca A l: a. C7H8 b. C8H10 c. C10H14 d. C9H12 Cu 22:t chy hon ton 1,3 g A(CxHy) 0,9 g H2O .Cng thc nguyn ca A l: a.(CH)n b.(C2H3)n c.(C3H4)n d.(C4H7)n Cu 29:A l 1 hp cht vng c to thnh t s trng hp axetilen,dA/kk l 3,59.C.thc phn t A l: a. C8H8 b. C6H6 c. C10H14 d. C4H4 Cu 23:A c cng thc phn t l C8H8 ,tc dng vi dd KMnO4 nhit thng to ra ancol 2 chc.1 mol A tc dng ti a vi: a.4 mol H2; 1 mol dd Br2 b. 3 mol H2; 1dd mol Br2 c.3 mol H2; 3 mol dd Br2 d. 4 mol H2; 4 dd mol Br2 Cu 24:5,2 g stiren b trng hp 1 phn tc dng va vi dd cha 0,0125 mol brom.Lng stiren cha b trng hp l: a.25% b.50% c.52% d.75% Cu 25:1 ankylbenzen A(C9H12),tc dng vi HNO3 c (c xt H2SO4 ) theo t l mol 1:1 to ra 1 dn xut mononitro duy nht . Vy A l: a. n-propylbenzen b.p-etyl,metylbenzen c.i-propylbenzen d.1,3,5-trimetylbenzen Cu 26:A l 1 hp cht vng c to thnh t s trng hp axetilen,dA/kk l 3,59.C.thc phn t A l: a. C8H8 b. C6H6 c. C10H14 d. C4H4 Cu 27:A c cng thc phn t l C8H8 ,tc dng vi dd KMnO4 nhit thng to ra ancol 2 chc.1 mol A tc dng ti a vi: a.4 mol H2; 1 mol dd Br2 b. 3 mol H2; 1dd mol Br2 c.3 mol H2; 3 mol dd Br2 d. 4 mol H2; 4 dd mol Br2 Cu 28: Cho cc cht: C6H5-CH3 ; C6H5-CH2-CH3 ; C6H5Br ; C6H5NO2 ; C6H5COOH Vn dng quy tc th vng benzen, vit cc phng trnh phn ng (dng cng thc cu to) khi cho cc cht trn ln lt tc dng vi: 1- Br2 lng, xc tc bt Fe v un nng? 2- Dung dch HNO3 c, xc tc H2SO4 c v un nng? Cu 29: T benzen, toluen vit cc phng trnh phn ng iu ch: Brombenzen; nitrobenzen; o-bromnitrobenzen; m-bromnitrobenzen; 1,3-dinitrobenzen bromtoluen ; o-nitrotoluen; xiclohecxan; metylxiclohecxan.