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A Spontaneous Potential Measurement

Spontaneous Potential
and
Gamma Ray

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Schlumberger 1999 1
Spontaneous Potential Measurement

SP Theory 1
SP results from electric currents flowing in the
drilling mud.

There are three sources of the currents, two


electrochemical and one electrokinetic.

Membrane potential - largest.

Liquid - junction potential.

Streaming potential - smallest.

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Spontaneous Potential Measurement

SP theory 2
Membrane and Liquid Potential

These two effects are the main components of the SP. They are
caused because the mud flitrate and the formation waters contain
NaCl in different proportions.
Firstly, shales are permeable to the Sodium ions but not the
Chlorine. Hence there is a movement of charged particles through
the shale creating a current and thus a potential.
The ions Na+ and Cl- have different mobilities at the junction of
the invaded and virgin zones. The movement of the ions across this
boundary creates another current and hence a potential.

Streaming Potential

This is generated by flow of the mud filtrate through the mud


cake. As this does not normally occur this effect is small. It will
only become important if there are high differential pressures
across the formations.

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Spontaneous Potential Measurement

SP theory 3

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Spontaneous Potential Measurement

log-1
The SSP is the
quantity to be
determined.

It is the deflection
seen on the SP
from the Shale
Base Line (zero
point) to the Sand
Line (max.
deflection)

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Spontaneous Potential Measurement

example log 2

The maximum
SP deflection in
this example
occurs at the
same depths as
the resistivity
curves show a
separation.
The minimum
point on the SP
corresponds to
where all the
resistivity
curves overlay,
no invasion, a
shale.

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Spontaneous Potential Measurement

SP uses

Differentiate potentially porous and permeable


reservoir rocks from impermeable clays.

Define bed boundaries.

Give an indication of shaliness (maximum


deflection is clean; minimum is shale).

Determine Rw in both salt and fresh muds.

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Spontaneous Potential Measurement

Rw from the SP
Rw is often known from client information or
local knowledge.

The SP can be used to check the value or compute


it when it is unavailable.

It is especially useful when there are variations


along the borehole.

Rmfe
SSP k log
Rwe

K is a constant - depending on the temperature.

K = 61 + .133T ( 0F )

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Spontaneous Potential Measurement

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Spontaneous Potential Measurement

Salinities chart

Grains/gal
10

at 75F
8

ppm
6
5
20 0
4 10

3 30 0
15
40 0
2 20
50 0
25
60 0
30

NaCl Concentration (ppm or grains/gal)


70 0
80 0
1 40
Resistivity of Solution ( - m)

0
10 0
0.8 0 50
12 0
0
14 0
0.6
0 0
0.5 17
0
20 0
100
0.4
0
0.3 30 0
150
0
40 0
200
0.2 50 0
0
00 250
0
6 0
70 000 300
80
400
0 00
0.1 10 , 0 500
00
12 , 0
0.08 ,
14 0
0 0

7 ,00
1
0.06 0 00
20 , 1000
0.05
00
30 ,0
0.04 1500
00
40 ,0 2000
0.03 0
50 , 0
00
0 2500
60 ,0 0 3000
0
70 ,0 00
0.02 80 ,0 4000
000
10 0, 5000
0, 000
, 000 12 , 000
30 0 0
14 00
0
17 0, 0
0.01 0,0000
2 00 0
10,000
,
25 000
28 0, 15,000
50 75 100 125 150 200 250 300 350 400
20,000
10 20 30 40 50 60 70 80 90 100 120 140 160 180 200

Temperature (F or C)
This chart is used to compute salinities from
resistivities of solution e.g. mud, and vice versa.
It is also used to find the resistivities at a given
temperature.
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Spontaneous Potential Measurement

Rw from the SP
Knowing the SSP (the maximum deflection) from
the log and the temperature, the ratio of
resistivities is obtained from Log Interpretation
Chart SP-1.
Rmfe
output =
Rwe

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Spontaneous Potential Measurement

Rw from SP 2

Rmf is measured, using the mud cell.


Rmfe is computed from Log Interpretation Chart
SP-2.
Rwe is computed, from the ratio from SP1 and
Rmfe.
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Chart SP-2 output is Rw. 12
Spontaneous Potential Measurement

Rw Calculation Procedures
1 . Read SSP in Clean H20 zone greater than 10 ft. thick,
close to Zone of Interest

2. Calculate Formation temperature at ZOI

3. Convert Rmf at Surface Temp. to Rmf at Formation Temp.

4. Convert Rmf to Rmfeq Rmfeq = Rmf x .85

5. Use SP-1 to determine Rweq

6. Use SP-2 to determine Rw


Practice
Rmf = .9 @ 80
TD = 12000 ft
-120 +30
BHT = 210 0F
10400
SSP = ___

Form. Temp. _______


Rmf @ FT _______
Rmf eq _______
10500
Rweq ________
Rw __________
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Spontaneous Potential Measurement

Calculate Rw from SP
Shale base line
.14 & .42
Por - .33
= 7 Sw=.21 A .09 & .48
7 Sw= .19 B por = .35

0 Sw = .17 C Por = .34

8 Sw = .17 D Por = .36

5 Sw = .23 E Por = .36

.26 Sw = 1 F Por = .35

Rmf = .5 @ 90 0F
BHT = 202 0F
TD = 12500 ft.

Rw @ 11222 = ______

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Spontaneous Potential Measurement

Calculate Rw at 13850

Rmf = 1.80 @ 70F


BHT = 2350F @ 13920

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A Spontaneous Potential Measurement

Gamma Ray Measurement

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Schlumberger 1999 16
Spontaneous Potential Measurement

Gamma Ray Principles

The Gamma Ray log is a measurement of the


formation's natural radioactivity.
Gamma ray emission is produced by three
radioactive series found in the Earth's
crust.

Potassium (K40) series.


Uranium series.
Thorium series.

Gamma rays passing through rocks are slowed


and absorbed at a rate which depends on the
formation density.
Less dense formations exhibit more radioactivity
than dense formations even though there may be
the same quantities of radioactive material per
unit volume. 17
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Spontaneous Potential Measurement

Basic Gamma Ray Uses


Bed definition:
The tool reacts if the shale
is radioactive (usually the
case), hence show the
sands and shales, the
permeable zones and the
non-permeable zones.

Computation of the
amount of shale:

The minimum value gives


the clean (100%) shale free
zone, the maximum 100%
shale zone. All other points
can then be calibrated in
the amount of shale.

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Spontaneous Potential Measurement

GR Uses
The gamma ray log is used for:

Lithology/mineralogy, e.g. shaliness.

Correlation:
A major use of the tool is to identify marker beds and thus allow
well-to-well correlation. Marker beds can be the top or bottom of
the reservoir or a specific shale giving a high reading.

Determination of Shale Content


A comparison is made of the GR reading in Shales, Clean Zones
and Shaly Zones . A linear estimate can be made of the shale
content in these Shaly sections.

Tracer logging:
A radioactive fluid is ejected by a tool at a chosen level. The fluid
movement is monitored by the gamma ray and will show thief
zones and channels in the cement behind the casing.

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Spontaneous Potential Measurement

NGT
The NGT tool measures a spectrum that is the
result of the three naturally occurring radioactive
series.

The Potassium has a sharper shape than the other


two as it decays through a single reaction to a
stable element. The other two decay through a
number of daughter elements each with some
contribution to the final picture. 20
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Spontaneous Potential Measurement

NGT Log

Outputs are the relative amounts of Thorium,


Uranium and Potassium in the formation.
With:
Thorium in ppm.
Uranium in ppm.
Potassium in %.
Additional curves are the total gamma ray (SGR)
and a Uranium-corrected gamma ray (CGR).
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Spontaneous Potential Measurement

NGT uses
This tool has many applications:

Lithology identification.
Study of depositional environments.
Investigation of shale types.
Correction of the GR for clay content
evaluation.
Identification of organic material and
source rocks.
Fracture identification.
Geochemical logging.
Study of a rock's diagenetic history.

A major application was to solve North Sea log


interpretation problems in micaceous sands.

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Spontaneous Potential Measurement

NGT uses
The three radioactive elements measured by the
NGT occur in different parts of the reservoir. If
we know the lithology, we can obtain further
information.

In Carbonates:

U - indicates phosphates, organic matter


and stylolites.

Th - indicates clay content.

K - indicates clay content, radioactive


evaporites.

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Spontaneous Potential Measurement

NGT in Clastics
In Sandstones:

Th - indicates clay content, heavy


minerals.

K - indicates micas, micaceous clays and


feldspars.

In Shales:

U - in shale, suggest a source rock.

Th - indicates the amount of detrital


material or degree of shaliness.

K - indicates clay type and mica.

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Spontaneous Potential Measurement

NGT Crossplots - 1
The NGT data is interpreted using
three major crossplots. In order of
complexity:
Thorium versus Potassium:
Gives clay type

Photoelectric factor, Pe, versus


Potassium:
Gives clay type and micas.

Pe versus Thorium/Potassium
ratio:
Gives clay type and micas.

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Spontaneous Potential Measurement

NGT Crossplots - 2

This plot can be used to determine the type of


clay mineral or mica.

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Spontaneous Potential Measurement

NGT Crossplots - 3
This plot adds in the Thorium contribution
making it more precise than the previous one.

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Spontaneous Potential Measurement

NGT/GR parameters
Vertical resolution 18"

Depth of investigation 6"-8"

Readings in: API units

Limestone <20
Dolomite <30
Sandstone <30
Shale 80-300
Salt <10
Anhydrite <10

No formation is perfectly clean, hence the GR readings


will vary. Limestone is usually cleaner than the other two
reservoir rocks and normally has a lower GR.

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Spontaneous Potential Measurement

GR/NGT Limits
GR

- Organic materials (see the uranium as


"shale").
- Micas (sees micaceous sands as shaly).

NGT

- Barite in the mud (reduces the count rate


but can be partially corrected for).
- KCI mud (Potassium in the mud masks
the formation response but can be
partially corrected for).
- Large boreholes decrease the count rate
hence increase the statistics.
- Statistical errors.

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Spontaneous Potential Measurement

GR Correction 1

GR logs require correction for the effects of the


mud.

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Spontaneous Potential Measurement

GR Correction 2

An additional correction is needed if there is mud


in the borehole.

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A Spontaneous Potential Measurement

Shales

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Schlumberger 1999 32
Spontaneous Potential Measurement

shales

Matrix Shale Porosity

Clean formation Structural shale

Porosity Porosity

Shale
Matrix Matrix

Laminar shale Dispersed shale


Porosity Porosity Shale
Shale

Matrix Matrix

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Spontaneous Potential Measurement

clay minerals
b N (thermal) Pe

Kaolinite 2.54 59.6 1.85


Illite 2.52 47.9 3.97
Smectite 2.02 87 1.70
Chlorite 2.73 59.6 4.07

Most shales are comprised of these clay minerals.


Clay minerals frequently occur together in
"mixed layers", e.g. Illite - Montmorillonite.

Kaolinite Al, Si, little K


Illite K, Fe, Mg, Si
Smectite Very high porosity.
Chlorite Fe, Mg, no K

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Spontaneous Potential Measurement

Shale and Logs


Shales have properties that have important
influences on log readings:
They have porosity.

The porosity is filled with salted water.

They are often radioactive.

Resistivity logs exhibit shales as low resistivity


zones.

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Spontaneous Potential Measurement

Shale and Logs continued


Neutron porosity logs exhibit shales as high
porosity.

Density and sonic logs react to the porosity and


matrix changes.

Gamma ray logs react to shale radioactivity.

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Spontaneous Potential Measurement

Shale Corrections
The electrical properties of shales greatly
influence the calculation of fluid saturations.

A layer of water close to the clay surface is


electrically charged.

Archie's equation assumes that the formation


water is the only electrically-conductive material
in the formation.

The clay layer requires an additional term in the


saturation equation.

Porosity tools can be corrected for the shale


effect. An "effective porosity" can be computed as
compared to a "total porosity" which includes the
shale effect.

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Spontaneous Potential Measurement

Shale Volume 1
The volume of shale must be computed to correct
the tool readings.

This is achieved using simple equations such as:

GRlog GRmin
Vcl
GRmax GRmin

or

SPlog SPmin
Vcl
SPmax SPmin

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Spontaneous Potential Measurement

Vsh from GR
1
Ish = Vsh

.5
Vsh Clavier, et al

Steiber

0
0 .5 1
I sh

GR - GRcl
Ish =
GRsh - GRcl

Clavier Vsh = 1.7 - 3.38 - (Ish +.7)2

.5 Ish
Steiber Vsh =
1.5 - Ish
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Spontaneous Potential Measurement

Shale Volume 2

However, as every tool reacts to shale, each tool is


a shale indicator. For example:

b wS w h 1 S w ma 1 Vcl clVcl

Shale volume can be computed from different


sources and from crossplots of different kinds of
log data.

The ideal method of computing shale volume is to


use the Neutron Density plot.

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Spontaneous Potential Measurement

Calculate Ish - Vsh


0 GR 150

Calculate Vsh using Vsh = Ish at the indicated point

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