BI TP PHC CHT

Bi tp trc nghim danh php hp cht ha v c

Cu 1. Cho bit tn hp cht K2[Co(NH3)2Cl4]
a Kali diammintetraclorocobaltat(II)
b Kali tetraclorodiammincobaltat(II)
c Kali tetraclorodiammincobalt(II)
d) Kali tetraclorodiamincobaltat(II)
Cu 2. Chn phng n sai. Tn ca cc phi t l:
1 Br- - bromo
2) CN- - cyano
3) S2- - sulfo 4) CH3COO- - aceto
a 3&4
b) 3
c) 4
d) 2 , 3 & 4
Cu 3. Tm danh php phc cht ca H2SO4 v Na2SO4
a Dihydroxodioxo luhunh(VI) ; natri tetraoxosulfat(VI)
b Dihydroxodioxosulfat(VI) ; Natri tetraoxosulfat (VI)
c) Hydro tetraoxosulfat(VI) ; Natri tetraoxosulfat(VI)
d) Dihydroxodioxo luhunh(VI) ; natri tetraoxosufur(VI)
Cu 4. Cho bit tn truyn thng hp cht H2S2O4
a) acid disulfurous
b) acid ditiosulfurous
c) acid ditionic
d) acid ditionous
Cu 5. Cho bit tn cc hp cht Al(OH)Cl2 , HAlO2
a Nhm cloride base ; acid metaaluminic
b Nhm hydroxyl dicloride ; acid metaaluminic
c Nhm hydroxylcloride ; acid aluminic
d Nhm hydroxydicloride ; acid metaaluminic
Cu 6. Chn cu ng
1 Tn phi t l cht hu c: gi nguyn tn hp cht.
2 IUPAC ngh cch vit tn phi t l anion theo quy lut: b e cm ri cng thm o.
3 Tn phi t VO2+: Vanadyl
4 Tn phi t PCl3: gi nguyn tn hp cht.
a 1&3
b) 1 , 3 & 4
c) 1 & 4
d) 1, 2 ,3 & 4
Cu 7. Cho bit cng thc cc hp cht acid selenous v kali vonframat
a H2SeO3 ; K2WO4
b) H2SeO4 ; K2WO3
c) H2SeO3 ; K2WO3
d) H6SeO6 ; K2WO4
Cu 8. Cho bit cng thc cc ion tetrathiovanadat(V) v bis(etylendiamin)platin(II)
a [VS4]3- ; [Pt(en2)2]2+
b) [VS4]2- ; [Pt(en)2]2+
c) [VS4]3- ; [Pt(en)2]2+
d) [VS4]2- ; [Pt(en2)2]2+
Cu 9. Chn cu sai: Tn thng dng ca cc hp cht sau l:
a H2S2O2 acid thiosulfurous
b b) Na3PO3S natri thiophosphat
b) SO2Cl2 lu hunh(VI) dioxide cloride
d) NaHCO3 natri hydrocarbonat
Cu 10. Chn cu sai:
a Th t c tn ion phc: c t phi qua tri.
b i vi cc hp cht phc tp IUPAC chn danh php phc cht lm danh php
h thng, tr nhng cht c tn thng dng.
c Tn hp cht gia cc kim loi: vit tn cc kim loi theo danh php a phng
c gch ni gia chng v h s t lng ca cc kim loi trong du ngoc n.

Cch vit danh php chnh xc: Tt c cc hp cht phc tp phi vit theo danh
php phc cht.

4. L THUYT V PHC CHT

Cu 1. Cho cc phc cht :
[Co(NH3)6]Cl3, [Cr(H2O)6]Cl3, [Ni(CO)4], Na[BF4], FH2+, K4[Fe(CN)6], Fe(CO)5 .
Chn cu ng:
a Phc cation: FH2+, [Co(NH3)6]Cl3; [Cr(H2O)6]Cl3; Phc trung ha: [Ni(CO)4], Fe(CO)5;
Phc anion: Na[BF4], K4[Fe(CN)6]
b Phc cation: Na[BF4], FH2+ ; Phc trung ha: [Ni(CO)4], Fe(CO)5; Phc anion:
[Co(NH3)6]Cl3 , K4[Fe(CN)6]
c Phc cation: Na[BF4], K4[Fe(CN)6]; Phc trung ha: [Ni(CO)4], Fe(CO)5; Phc anion:
[Co(NH3)6]Cl3 , [Cr(H2O)6]Cl3
d Phc cation: FH2+, K4[Fe(CN)6]; Phc trung ha: Na[BF4], Fe(CO)5; Phc anion:
[Co(NH3)6]Cl3, [Ni(CO)4]
Cu 2. Cho cc phc cht: [CO(NH3)6]Cl3, [Cr(H2O)6]Cl3, [Ni(CO)4], Na[BF4], phc NH4+,
phc floroni FH2+, K4[Fe(CN)6], [CO(NH3)3Cl3]. Chn cu ng:
a Phc cation l: phc floroni FH2+, [CO(NH3)6]Cl3, [Cr(H2O)6]Cl3. Phc trung ha l
[Ni(CO)4], [CO(NH3)3Cl3]. Phc anion: Na[BF4], K4[Fe(CN)6].
b Phc cation l: phc NH4+, Na[BF4]. Phc trung ha l [Ni(CO)4], [CO(NH3)3Cl3].
Phc anion: [CO(NH3)6]Cl3 , K4[Fe(CN)6].
c Phc cation l: Na[BF4], K4[Fe(CN)6]. Phc trung ha l [Ni(CO)4], [CO(NH3)3Cl3].
Phc anion: [CO(NH3)6]Cl3 , [Cr(H2O)6]Cl3.
d Phc cation l: phc floroni FH2+, phc NH4+. Phc trung ha l Na[BF4],
K4[Fe(CN)6]. Phc anion: [CO(NH3)6]Cl3, [Ni(CO)4].
Cu 3 Chn cu ng. Ion phc c to thnh nh nhng loi lin kt:
a Ch cng ha tr v ion
c Ch ion
b Ch cng ha tr
d Cng ha tr, ion v Van der Waals.
Cu 4. Phc cht no di y c tnh ion ln nht?
a [AlF6]3b [Cu(CN)4]2+
c [Co(H2O)6]2+
d [HgI4]2Cu 5. Phc cht no l t ph bin nht:
a Tam gic
b Bt din
c T din
d Vung phng
Cu 6. Chn phng n ng: Cc phc c ng phn hnh hc:
1 Bt din
2) T din
3) Hnh vung
a 1 v 3
b Ch 1
c Ch 2
d Ch 3
Cu 7. Chn phng n ng:
1) S phi tr ca phc cht l s phi t bao quanh cht to phc trong cu ni.
2) S phi tr ca phc cht khng th ln hn 6.
3) S phi tr 6 ca nguyn t trung tm ch ng vi cu hnh bt din.
4) S phi tr 4 ca nguyn t trung tm ch ng vi cu hnh t din.
a Ch 1,3 ng
c Ch 2,3,4 ng
b Ch 2,4 ng
d Tt c cng ng
Cu 8. Chn phng n ng:

1) Cht to phc c th l ion (anion, cation) hay nguyn t v thng c gi chung l

nguyn t to phc.
2) Ligand l ion ngc du vi cht to phc (cation, anion) hay phn t trung ha in,
c phi tr xung quanh nguyn t trung tm.
3) in tch ca cu ni l tng in tch ca cc ion trong cu ni. Cu ni c th l cation,
anion hoc phn t trung ha in.
4) Nhng ion nm ngoi v ngc du vi cu ni to nn cu ngoi.
5) Phc cht c th c hoc khng c cu ni.
a Ch 3,4 ng
b Ch 1,2,3,4 ng c Ch 1,2 ng
d Tt c cng ng
Cu 9. Chn phng n ng:
+
+

b ,[ Ag(NH 3 )2 ]
b ,[ Ag(NH 3 )2 ]
b ,[ Ag(CN )2 ]
8
Cho
= 110 ;
K
K
K

b ,[ Ag(CN )2 ]
K

7.041019; TAgI = 8,310-17. Tnh tan ca AgI trong dung dch NH3 v trong dung dch NaCN:
a Hu nh khng tan trong NH3 nhng tan tt trong NaCN
b Tan tt trong NH3 nhng hu nh khng tan trong NaCN
c Hu nh khng tan trong c hai dung dch
d Tan tt trong c hai dung dch.
Cu 10. Chn pht biu ng v phc c cng thc phn t l Co(NH3)5Cl3
1) Phc c th c cng thc cu to l [Co(NH3)5Cl]Cl2 v c tn l:
cloridopentaammincobalt(III) cloride.
2) Phc c th c cng thc cu to l [Co(NH3)5]Cl3 v c tn l: pentaammincobalt(III)
cloride.
3) Hai phc [Co(NH3)5]Cl3 v [Co(NH3)5Cl]Cl2 u l phc bt din.
4) Hai phc [Co(NH3)5]Cl3 v [Co(NH3)5Cl]Cl2 u khng mu
a Ch 1, 2 ng
c Tt c cng ng
b Ch 3, 4 ng
d Khng c p n ng
Cu 11. Chn pht biu ng v cc gii php n gin phn bit 2 phc [Co(NH3)5]Cl3
v [Co(NH3)5Cl]Cl2
1) Hai phc trn khng th phn bit c.
2) C th phn bit bng cch cho dung dch c cng nng ca hai phc trn tc dng vi
dung dch AgNO3 v xc nh phc thng qua lng kt ta AgCl thu c.
3) Xc nh thng qua dn in ca dung dch bng cch o dn ca dung dch c cng
nng ca hai phc trn cng iu kin, phc [Co(NH3)5]Cl3 c dn cao hn phc
[Co(NH3)5Cl]Cl2
a 2, 3 ng
b 1 ng
c Ch 2 ng
d Ch 3 ng
Cu 12. Chn cu ng v thuyt lin kt ha tr:
1) Khng gii thch c v sao cc phc ca nguyn t chuyn tip d v f thng c mu
trong khi phc nguyn t khng chuyn tip (nguyn t p) thng khng c mu.
2) Khng gii thch c v sao cc nguyn t chuyn tip to c nhiu phc cht hn hn
cc nguyn t khng chuyn tip.
3) Khng gii thch c v sao c s tch mc nng lng trong phn lp d.
a Tt c u ng. b Ch 1 ng
c Ch 2 ng
d Ch 3 ng
2
Cu13. Theo thuyt lin kt ha tr, s lai ha dsp to thnh hnh dng g v do cc orbital p,
d no tham gia li ha (chn trc x lm trc lin kt):
a Dng hnh vung phng, s, p , p , d x y .
y

b Dng t di n, s, pz, px, d x y .

2

Dng t di n, s, py, px, d x y .

2

d Dng hnh vung phng, s, py, px,

d z2

.
[Co( NH 3 )6 ]3

Cu 14. Chn pht biu ng v phc

theo thuyt lin kt ha tr, bit phc
ny nghch t.
a Phc dng t di n, c lai ha sp2d.
b Nguyn t trung tm lai ha sp3d2, trong cc oribital tham gia lai ha l 4s;
4 p x ; 4 p y ; 4 p z 4 d x 2 y 2 ; 4d z 2
;
v c cu trc bt din.
3
[Co( NH 3 )6 ]
c
l phc spin cao.
3d x 2 y 2 ; 3d z 2
2
3
d Nguyn t trung tm lai ha d sp , trong cc oribital tham gia lai ha l
4 p x ; 4 p y ; 4 pz
; 4s;
; v c cu trc bt din.
Cu 15..Bit phc hnh vung tng ng vi trng thi lai ha dsp 2. Trong cc ion kim loi
sau kim loi no c th to c phc hnh vung.
a 46Pd2+
b 27Co2+
c 23V3+
d 26Fe3+
Cu 16. Chn phng n ng:
Phc [CoF6]3- thun t. Theo thuyt VB, [CoF6]3- l
a Phc bt din spin cao, Co3+ lai ha sp3d2.
b Phc bt din spin thp, Co3+ lai ha d2sp3.
c Phc bt din spin thp, Co3+ lai ha sp3d2.
d Phc bt din spin cao, Co3+ lai ha d2sp3.
Cu 17. Chn phng n ng:
Phc [Co(NH3)6]3+ l nghch t. Theo thuyt lin kt ha tr, cu trc ca phc cht l:
a Co3+ trng thi lai ha d2sp3 to phc orbital ni
b Co3+ trng thi lai ha sp3d2 to phc orbital ni
c Co3+ trng thi lai ha d2sp3 to phc orbital ngoi
d Co3+ trng thi lai ha sp3d2 to phc orbital ngoi
Cu 18. Chn phng n ng:
Da vo thuyt VB c th d on [Cu(NH3)4]2+ c cu hnh:
a T din, Cu2+ lai ha sp3.
b T din, Cu2+ lai ha trong dsp2.
c Vung phng, Cu2+ lai ha trong dsp2.
d Vung phng, Cu2+ lai ha sp3.
Cu 19. Chn phng n ng:
Phc [NiCl4]2- (1) l thun t vi 2 electron c thn, phc [Ni(CN)4]2- (2) l nghch t. Theo
thuyt lin kt ha tr, cu trc ca 2 phc cht l:
a (1) Ni2+ trng thi lai ha sp3, (2) Ni2+ trng thi lai ha dsp2
b (1) Ni2+ trng thi lai ha dsp2, (2) Ni2+ trng thi lai ha sp3
c Ni2+ trng thi lai ha sp3 trong c 2 phc cht
d Ni2+ trng thi lai ha dsp2 trong c 2 phc cht

Cu 20. Chn phng n ng:

Phc [NiCl4]2- l thun t. Theo thuyt lin kt ha tr, cu trc ca phc cht l:
a Ni2+ trng thi lai ha sp3 to phc t din
b Ni2+ trng thi lai ha sp3 to phc vung phng
c Ni2+ trng thi lai ha dsp2 to phc t din
d Ni2+ trng thi lai ha dsp2 to phc vung phng
Cu 21. Xc nh trng thi lai ha ion kim loi trung tm trong phc [Co(H 2O )6]2+, bit
phc ny thun t :
a sp3d2
b sp2d
c dsp2
d d2sp3
Cu 22. Chn cu sai trong cc cu sau theo thuyt trng tinh th:
a i vi cc nguyn t p c phn lp p hoc cn trng, hoc y e, khi to phc c
s tch mc nng lng trn phn lp d
b Nng lng tch ph thuc cu hnh ca phc cht, bn cht ca cht to phc v
bn cht phi t.
c T tnh ca phc cht l do cc e khng ghp i to nn.
d Phc cht tn ti v bn nh vo lc tng tc tnh in gia cht to phc v cc
phi t
Cu 23. Chn cu ng theo thuyt trng tinh th.
1) Vi phc bt din, tng tc gia ligand vi cc orbital dxy, dyz, dzx mnh hn tng tc vi
cc orbital dz, dx-y.
2) Vi phc t din, tng tc gia ligand vi cc orbital dxy, dyz, dzx yu hn tng tc vi
cc orbital dz, dx-y.
3) Vi phc bt din, cc ligand nm trn trc x, y, z.
a 3 ng
b Ch 1 ng
c Ch 2 ng
d 1 v 2 ng.
Cu 24. Chn cu ng
1) Vi cng nguyn t trung tm v phi t, nng lng tch ca t din T ln hn nng
lng tch ca bt din O.
2) Vi cng ion trung tm v cu hnh phc, cng ln nu phi t cng mnh.
3) Cc nguyn t chuyn tip c trng thi oxy ha dng v tun theo quy tc chn le
Mendeleev.
a Ch 2 ng
b 1 ng
c Ch 3 ng
d 2,3 ng.
Cu 25. Chn nhng cu ng.
1) Trong trng hp kch thc ion to phc kh nh so vi kch thc phi t, xu hng to
phc t din ln hn phc bt din.
2) Dy ha quang ph ch ng vi cc phc bt din
3) Phc lp phng ch bit i vi cc ion c kch thc rt ln so vi kch thc phi t.
a 1,3 ng
b 2 ng
c Ch 1 ng
d Ch 3 ng
Cu 26. Theo thuyt trng tinh th, nng lng tch trng tinh th ph thuc vo:
1) in tch ca nguyn t trung tm: nguyn t trung tm c in tch cng ln th nng
lng tch trng tinh th cng cao (vi cc phc c cng cu hnh v phi t).
2) Cu hnh ca phc cht, bn cht ca cht to phc v bn cht phi t
3) Trng thi lai ha ca nguyn t trung tm.
a 1, 2 ng
c 3 ng
b Ch 1 ng
d Khng c p n ng
Cu 27. Chn pht biu ng theo thuyt trng tinh th:
a Cc phc t din l cc phc spin thp.

b Cc phc c nng lng n nh trng tinh th cng m th cng bn.

c Kch thc ion trung tm khng nh hng n nng lng tch trng tinh th.
d Phc bt din lun c nng lng n nh trng tinh th m.
Cu 28. Chn phng n ng theo thuyt trng tinh th v thng s tch trng tinh th
:
1) Thng s tch trng tinh th l hiu nng lng ca cc phn mc d v d.
2) Nu c cng nguyn t trung tm v phi t, O ca phc bt din ln hn T ca phc t
din.
3) Vi cc phc c cng cu hnh v phi t, s cng ln khi cation to phc c in tch
cng ln.
4) Vi cc phc c cng cu hnh v nguyn t to phc, s cng ln khi ligand cng yu.
a Ch 1,2,3 ng
b Ch 1,3 ng
c Ch 3,4 ng
d Tt c cng ng
Cu 29. Chn phng n sai v thuyt trng tinh th:
a Thuyt trng tinh th coi cht to phc v phi t l cc in tch im cung cp trng
tnh in
b Thuyt trng tinh th coi s to phc l tng tc tnh in gia cht to phc v phi
t.
c Tng tc tnh in gia cht to phc v phi t c th lm thay i cu trc electron
ha tr ca cht to phc
d Di tc dng ca trng tnh in ca cc phi t, trng thi suy bin ca cht to phc
s gim
Cu 30. Chn pht biu sai theo thuyt trng tinh th.
a Nng lng n nh trng tinh th cng m th h cng bn
b S khc bit gia phc cht ca nguyn t p v d l phc cht nguyn t p khng c s
tch mc nng lng phn lp d, khng c nng lng n nh tinh th.
c Nng lng tch trng tinh th ch ph thuc cu hnh ca phc cht.
d Phc cht tn ti bn nh vo lc tng tc tnh in gia nhn trung tm v cc phi t.
Cu 31 .Chn nhn xt ng:
Trong phc bt din, nu s electron > 3 v < 8, ta c:
1) Nu > P th phc l phc spin thp.
2) Nu > P th phc l phc spin cao.
3) Nu < P th phc l phc spin cao.
a Khng c nhn xt no ng
c 2, 3 ng
b Ch 1 ng
d 1, 3 ng
Cu 32. Chn pht biu ng v phc cht:
4
9
1) Vi cng ion to phc v phi t, T =
O.
2) Khi O > P s to phc spin cao, sp xp sao cho s e c thn ln nht.
3) Khi O < P s to phc spin cao, sp xp sao cho s e c thn ln nht.
a 1 v 2
c Khng c pht biu ng
b 1 v 3
d Ch 3 ng
Cu 33. Tm cu sai theo thuy trng tinh th.
1) C tn ti phc t din c cu hnh d4 d0.
2) i vi nguyn t to phc M, M(II) c thng s tch trng tinh th ln hn M(III).
3) Thuyt trng tinh th gii thch c s c mu phong ph ca cc hp cht nguyn t
chuyn tip d v f.
4) Phc s cng bn khi nng lng n nh trng tinh th cng m.

a 1&2
b 1&3
c 2&4
d 1&4
Cu 34. Chn nhng cu ng.
1) Dy ha quang ph ch ng vi cc phc bt din.
2) Phc kim loi chuyn tip c xu hng to 8 e ha tr xung quanh nguyn t to phc.
3) Phc lp phng ch bit i vi cc ion c kch thc rt ln so vi kch thc phi t.
a Ch 3 ng
b Tt c cng ng
c Ch 1 ng
d Ch 2 ng
Cu 35. Chn pht biu ng trong cc pht biu sau y theo thuyt trng tinh th:
a Phc bt din c cu hnh d6 lun nghch t vi mi phi t.
b Phc bt din c cu hnh d8 lun nghch t vi mi phi t.
c Phc t din c cu hnh d6 lun nghch t vi phi t trng mnh.
d Phc bt din c cu hnh d4 lun thun t vi mi phi t.
Cu 36. Thuyt trng tinh th, khng nh no sau y sai?
a Trong trng bt din, electron trn phn lp d ca ion kim loi phi in vo orbital d
ht ri mi in n orbital d
b Ion kim loi nghch t khng th c s le electron.
c Phc spin thp c th nghch t.
d Trong phc spin cao, nng lng tch trng tinh th lun nh hn nng lng ghp
i electron.
Cu 37. Cu hnh phc cht [CoCl4]2- theo thuyt trng tinh th

Cu 38. S electron c thn ca phc [Cr(H2O)6]2+ l

a 4
b 0
c 2
d 3
Cu 39. Chn pht biu ng v cc phc Cu2+ theo thuyt trng tinh th:
1) Cc phc bt din ca Cu(II) c 2 cu hnh electron mc d khc nhau khi to phc vi
phi t trng yu v trng mnh.
2) Cc phc cht ca Cu2+ ch c 1 cu hnh duy nht l d6d4.
3) Cc phc cht ca Cu2+ c th thun t hay nghch t ty theo phi t trng mnh hay
yu.
a Tt c u sai.
b 1, 3
c 2, 3
d 2
Cu 40. Chn trng hp sai khi so snh nng lng tch trng tinh th ca cc phc
hexaaqua ca cc kim loi sau:

a Fe(II) > Os(II)

b Mn(III) > Mn(II) c Ag(I) > Cu(I)
d W(III) > Cr(III)
Cu 41. Chn phng n ng:
So snh nng lng tch trng tinh th ca cc phc sau:
1) [CdCl4]2- < [CdCl6]4-.
3) HgCl4]2- < [ZnCl4]2-.
432) [Co(CN)6] < [Co(CN)6] .
4) [Fe(CN)6]3- < [FeF6]3-.
a 1,2
b 3,4
c 1,4
d 2,3
3Cu 42. So snh nng lng tch trng tinh th E1 ca [Ru(CN)6] v E2 ca [Fe(CN)6]3-.
d6
3+
3+
a E1 > E2 do Fe v Ru c cng cu hnh electron l
nhng trong cng mt phn
nhm nng lng tch trng tinh th tng khi tng kch thc AO ha tr d.
d6
3+
3+
b E1 = E2 do Fe v Ru c cng cu hnh electron l
d6
c E1 < E2 do Fe3+ v Ru3+ c cng cu hnh electron l
nhng trong cng mt phn
nhm ph nng lng tch trng tinh th gim dn do tng m in ca nguyn t.
d Khng th so snh do khng c gi tr tng ng vi tng cht.
Cu 43. Chn phng n ng:
Tnh nng lng n nh trng tinh th ca phc [Fe(CN)6]4-, bit P = 209,9 kJ/mol, =
403,2 kJ/mol.
a -547.88 kJ/mol
b -337.98kJ/mol
c -161.28 kJ/mol
d p s khc
Cu 44. Tnh nng lng n nh trng tinh th ca phc bt din [Fe(CN)6]3-. Bit
[Fe(CN)6]3- l phc spin thp :
b 0
a -10/5O + 2EP
c -12/5O + 2EP
d -6/5O
4Cu 45. Tnh nng lng n nh trng tinh th ca [Ni(SCN)6]
2
3
3
2
E 6
o 2 o
E 4
o 4 o
5

5
5

5
a
c
2
3
2
3
E 6 o 2 o 3E P
E 6
o 2 o 3E P
5
5
5

5
b
d
Cu 46. Cho bit t tnh v tnh nng lng n nh trng tinh th ca phc
hexaaquamagan(II). Bit O = 101 kJ/mol v P = 304,2 kJ/mol.
a Thun t, 0 kJ/mol
c Nghch t, 304,2 kJ/mol
b Nghch t, 0 kJ/mol
d Thun t, 304,2 kJ/mol

Cu 47. Tnh nng lng n nh trng tinh th ca phc [MnF6]4a 0 kJ

c -72,5 kJ
b 72,5 kJ
d Khng d liu tnh.
Cu 48. Tnh nng lng n nh trng tinh th ca [Co(NH3)6]3+, bit rng > P.
a E = 6(-2/5) + 2P
c E = 6(2/5) + 2P
b E = 6(2/5) + 3P
d E = 6(-2/5) + 3P
[CoF6 ]3Cu 49. Xc nh nng lng n nh trng tinh th ca phc
bit = 155 kJ/mol
v P = 250.5 kJ/mol, y l phc spin cao hay spin thp
a - 62 kJ/mol, phc spin cao.
c 129 kJ/mol, phc spin thp
b -154.68 kJ/mol, phc spin thp
d - 62 kJ/mol, phc spin cao.
Cu 50. Chn phng n ng:
Cc phc c gi tr nng lng n nh trng tinh th bng khng l:
1) Phc bt din d5 spin cao.
5) Phc t din d5.
10
2) Phc bt din d .
6) Phc t din d10.
3) Phc bt din d5 spin thp.
7) Phc ca nguyn t h p.
4) Phc bt din d6 spin thp.
a 1,2,5,6,7 ng
b Ch 1,2 ng
c Ch 1,2,5,6 ng d 3,4 ng.
Cu 51. Cht no sau y c nng lng n nh trng tinh th bng 0
a [FeCl6]4b [Fe(CN)6]2c [Fe(CN)6]3-

d [FeCl

Cu 52. So snh nng lng n nh trng tinh th ca 2 phc (1) [Cu(NH3)4]+ v (2)
[Cu(NH3)6]+.
a E1 = E2.
c E1 < E2.
b E1 > E2.
d Thiu d liu so snh.
Cu 53. So snh nng lng n nh trng tinh th ca 2 phc sau: [Mn(H2O)6]2+ (E1) v
[Fe(H2O)6]3+ (E2)
a
c
E1 = E2 = 0
E1 < 0 < E2
b
d
Khng th tnh c do khng bit , P
E2 > E1 > 0
Cu 54. So snh nng lng n nh trng tinh th (E) ca cc phc sau y:
1) [MnCl6]4-,
2) [Fe(CN)6]3- ,
3) [FeBr6]3-.
a 1=3>2
c 1<2=3
b 1>2>3
d Khng so snh c.
Cu 55. So snh nng lng n nh trng tinh th E1 ca [Cr(H2O)6]2+v E2 ca
[Mn(H2O)6]2+
a
c
E1 < E2
E1 > E2
b
d
E1 = E2
Khng th so snh
Cu 56. So snh nng n nh trng trng tinh th E1 ca [Fe(CN)6]3- ( = 418kJ/mol ,P=
358kJ/mol) v E2 ca [MnCl6]4-.
E1 < E2
c E1 = E2
a
b E1 > E2
d Khng so snh c
Cu 57. Nhng cu hnh c th cho c phc spin cao v c phc spin thp l:
1) d5
2) d7
3) d4
4) d8
a Ch 1 , 2 & 3
b Ch 1 & 2
c Ch 2 & 3
d Tt c
Cu 58. Cc nguyn t mc oxy ha cho di y c th to phc bt din spin thp:
a Cr(II) ; Tc(III) ; Ru(IV)
c V(IV) ; Fe(III) ; Ni(IV)
b Hf(II) ; W(II) ; Os(VI)
d Nb(III) ; Mn(III) ; Co(III)
Cu 59. Chn cu ng: Cho phc [Co(NH3)6]3+ bit: = 273.2kJ/mol, P = 250.5kJ/mol

a Phc trn l phc spin thp, nghch t

c Phc trn l phc spin cao, thun t
b Cha d liu kt lun v phc cht d Phc trn l phc spin cao, nghch t
Cu 60. Vit cu hnh electron ca phc [CoF6]3- theo thuyt trng tinh th v kt lun y
l phc spin cao hay spin thp, bit y l phc thun t.
a

(d 4 )( d 2 )
spin thp
4

(d )( d )
b
c
d

spin cao
khng th xc nh

(d 4 )(d 2 )

spin cao
Cu 61. Chn pht biu ng v phc [MnBr4]2-:
1) Phc c tn gi: tetrabromomangan(II).
2) y l phc thun t.
3) Phc c th c cu hnh spin cao hay thp.
4) Phc l phc spin cao theo thuyt trng tinh th.
a Ch 2, 4 ng
b 1, 2, 4 ng
c 1, 3 ng
Cu 62. Chn phng n ng theo thuyt trng tinh th:
a Phc t din lun l phc spin cao.

d 2, 3 ng

b Phc t din c th l phc spin cao hay thp ty thuc phi t trng yu hay mnh.
c

Tt c phc spin thp lun thun t.

d Tt c phc spin cao u nghch t.

Cu 63. Hy cho bit phc no c tr tuyt i tng spin ln nht trong cc phc sau:
a Hexaaquamangan(II)
c Tetrafloronikelat(II)
b Hexaammincobalt(III)
d Hexatiocyanatovanadat(III)
3Cu 64. Xt phc [M(CN)6] , trong cc kim loi sau, kim loi no to c phc c tr tuyt
i tng spin cao nht
a Cr
b Mn
c Fe
d Zn
Cu 65. Chn phng n ng:
Trong s cc ion Fe2+, Co2+, Ni2+, ion d to phc t din nht l:
a Co2+
c Ni2+
b Fe2+

d Nh nhau cho c 3 ion

Cu 66. Chn phng n ng:

Hy d on v kh nng to phc t din v bt din ca Co(II) vi cc phi t trng yu:
1) Xc sut to thnh cu hnh bt din v t din l gn nh nhau v nng lng n nh
trng tinh th ca hai trng hp l xp x nhau.
2) Vi cc phi t trng rt yu ( I-, Cl-, Br-), Co(II) to phc t din v phc t din c cu
4 3
hnh d d bn vng hn.
3) Vi cc phi t trng khng yu lm (F-, H2O, NH3), Co(II) to phc bt din v phc bt
din c nng lng n nh trng tinh th m hn phc t din.

a Tt c cng ng.
c Cha c s d on.
b Ch 3 ng.
d Ch 1,2 ng.
Cu 67 .Chn phng n ng:
Da vo cu trc ca phc cht v s sp xp electron ca nguyn t trung tm c th d
on tnh oxy ha kh c trng ca cc ion phc bt din ca (1) Ti(aq)3+ v (2) Cr(aq)2+
a C 2 u c tnh kh c trng hn.
c (1) c tnh kh, (2) c tnh oxy ha.
b C 2 u c tnh oxy ha c trng hn.
d (1) c tnh oxy ha, (2) c tnh kh
Cu 68. Hy cho bit cc phc no di y nghch t:
a Hexaamminruteni(II)
c Hexaaquaniobi(III)
b Hexafloromolibdat(III)
d Hexaclorotitanat(III)
Cu 69. Hy cho bit phc no c tnh thun t mnh nht trong cc phc sau:
a Hexaaquamangan(II)
c Tetrafloronikelat(II)
b Hexaammincobalt(III)
d Hexatiocyanatovanadat(III)
Cu 70. Cc phc sau y l thun t hay nghch t (gi thit rng cc phc ny tn ti bn).
1. [Fe(CN)6]-4
2. [FeCl6]-3
3. [Co(CN)6]-4
4. [CoCl6]-3
5. [Ni(CN)6]-4
6. [Ni(CN)6]-3.
a Thun t: 2, 3, 4, 5, 6 ; nghch t: 1
c Thun t: 1, 5, 6 ; nghch t: 2, 3, 4
b Thun t: 1, 2, 3 ; nghch t: 4, 5, 6
d Thun t: 1, 3 ; nghch t: 2, 4, 5, 6
Cu 71. Cu trc khng gian v t tnh ca phc [Fe(CN)6]4- l:
a Bt din nghch t
c T din thun t
b T din, nghch t
d Bt din thun t
Cu 72. Cho phc M[(CN)6]4- nghch t, xc nh M
a Fe
b Cr
c Mn
d Zn
Cu 73. Chn phng n ng:
Cc phc no trong cc phc sau y c th l khng mu:
1) [Cu(NH3)4]2+
2) [CuCl2]3) [Zn(OH)4]24) [AlF6]35) [FeCl6]36) [TiOF4]2a 2,3,4,6 ng
b Ch 2,5 ng
c Ch 1,3 ng
d Ch 4,6 ng
Cu 74. Chn phng n ng:
D on dung dch ca cc ion sau c th l khng mu:
1) 26Fe3+
2) 29Cu2+
3) 24Cr3+
4) 25Mn2+
5) 13Al3+
+
2+
2+
2+
6) 29Cu
7) 30Zn
8) 82Pb
9) Ni
10) 57La3+
a Cc dung dch 5,6,7,8,10 khng mu
c Khng c c s d on
b Cc dung dch 1,2,3,4,9 khng mu
d Ch 5,8 khng mu
Cu 75. Phn nhiu cc hp cht ca cc nguyn t c s oxy ha di y u mang mu:
a 42Mo(II) ; 29Cu(II)
c 57La(III) ; 25Mn(III)
b 79Au(I) ; 46Pd(II)
d 80Hg(II) ; 74W(IV)
Cu 76 .Chn phng n ng:
a Cc hp cht c cu hnh d0 v d10 thng khng c mu
b Cc hp cht ca nguyn t p u khng c mu
c Cc hp cht ca nguyn t d u c mu
d Cc hp cht s thng c mu
Cu 77. Titan dioxide c mu trng. Hy chn khong nh sng (, nm) n hp th:
a < 400
b 480 490
c 435 480
d 595 605
3+
Cu 78. Nng lng tch ion phc bt din [V(H 2O)6] l 2.2eV. Tnh bc sng hp thu cc
i ca phc ny, bit h = 6.62610-34 J.s, 1eV =96485J/mol, c = 3108 m/s,
NA= 6,022.1023mol-1.
a 564nm
b 460nm
c 720nm
d 620nm

Cu 79. Chn pht biu ng v tnh cht ca cc phc: (1) K2[Zn(OH)4], (2)
HgII[Co(SCN)4]
1) K2[Zn(OH)4] l phc t din, nghch t, Hg[Co(SCN)4] l phc t din thun t.
2) Hg[Co(SCN)4] c nng lng n nh trng tinh th m hn phc K2[Zn(OH)4]
3) K2[Zn(OH)4] v Hg[Co(SCN)4] u c mu.
a 1, 2 ng
Cu 3. Chn pht biu ng v cc phc Ni2+ theo t
b 2, 3 ng
1) Cc phc bt din ca Ni(II) c 2 cu hnh electro
c 1, 3 ng
phc vi phi t trng yu v trng mnh.
d Khng c p n ng.
2. no di y sai.
Ru(III) c to phc t din spin thp.
Phc aqua ca Cr(II) km bn hn phc aqua
ca Cr(III).
Phc bt din spin thp ca
Mn(III) thun t.
e Phc ca Ti(III) thun t.

Cu
a
b
c
d

2) Cc phc cht ca Ni2+ ch c 1 cu hnh duy nh

thun t.
3) Ch c phc hnh thnh gia Ni2+ v cc phi t t
hnh vung, phn ln cc phc cn li ca Ni2+ l ph
a Ch 1, 3 ng
b Ch 2 ng
c Ch 2, 3 ng
d Tt c cng ng