Name:Esra Belhaj

ID:3115128
HW#1

Q#(4-1)

o
API 34
o
TBP 320 C
593.15 K
o
608 f
1067.67 R
TBP=MeABP
s 60/60 0.854985 From eq(4-2)
Kw 11.954201 From eq(4-3)
Mw 257.123572 from eq(4-13)
log(ⱱ100) 0.765144 ⱱ100 5.8230 cst From eq(4-15)
log(ⱱ210) 0.282307 ⱱ210 1.9156 cst From eq(4-14)
Tc 764.062262 K from eq(4-18)
Pc 15.281744 bar from eq(4-19)
Tbr 0.776311
Pbr 0.066305
ω 0.794011683 from eq(4-20),for (Tbr<0.8)
cp at 100 of= A+BT+CT2
A 0.061084
B 0.000867
C 0.000000
Cp 0.730213
PP 427.140450 R from eq(4-30)
AP 629.282168 R from eq(4-31)
SP 17.194781 mm from eq(4-32)
CP 499.583185 R from eq(4-33)

1
 Name:Esra Belhaj
ID:3115128
HW#1

Q#(4-2)

VOL% TBP(OC)
0.00 -9.44 (VOL%) TBP(OC)
4.50 32.22 IBP 0.00 -5.60701
9.00 73.89 EP 100 723.0006
14.50 115.56 interval(10) 72.86076
20.00 154.44
30.00 223.89
40.00 273.33
50.00 326.67
60.00 393.33
70.00 473.89
76.00 520.56
80.00 546.11
85.00 565.56

TBP vs. vol% to determine Kw

TBP,oC
From eq
of
VOL% figure(a) TBP,R a b D68,R D68,of
10 1.788041 494.8885 0.5277 1.09 532.986 73.31602
30 3.904136 498.6974 0.7429 1.0425 514.8268 55.15684
50 6.189624 502.8113 0.892 1.0176 505.1953 45.52531
70 8.631783 507.2072 0.8705 1.0226 506.1736 46.50358
90 11.21789 511.8622 0.949 1.011 503.6897 44.01967

VABP 52.90429
SL 0.366204
∆ 3.113919
MeABP 49.79037
s(avg) 0.88162
Kw 9.059176
By using the s(avg) and MeABP get on the Kw (to calculate the specific gravity
function of NBP,R).

2
 Name:Esra Belhaj
ID:3115128
HW#1

TBP(oC) NBP(oC)
-5.60701 NBP(k) NBP(R) s Kw Mw d ,kg/m3 Tc,K Pc,Kpa
67.25375 30.823 303.973 547.1521 0.902847 9.059176 57.98355 902.8466284 505.4658 144.6265
140.1145 103.684 376.834 678.3014 0.969882 9.059176 79.11251 969.8819488 607.8532 139.7944
212.9753 176.545 449.695 809.4508 1.028746 9.059176 104.2323 1028.745897 699.1407 135.1566
285.836 249.406 522.556 940.6002 1.081549 9.059176 134.7122 1081.549284 783.1945 130.6369
358.6968 322.266 595.416 1071.75 1.129646 9.059176 172.2868 1129.646075 862.2212 126.1701
431.5575 395.127 668.277 1202.899 1.173963 9.059176 219.179 1173.962809 937.589 121.6953
504.4183 467.988 741.138 1334.048 1.215165 9.059176 278.2701 1215.164696 1010.2 117.1523
577.279 540.849 813.999 1465.198 1.253747 9.059176 353.3273 1253.747361 1080.678 112.4791
650.1398 613.709 886.859 1596.347 1.290091 9.059176 449.3112 1290.091149 1149.471 107.6091
723.0006 686.570 959.720 1727.496 1.324495 9.059176 572.7901 1324.49506 1216.909 102.4687

TBP,oC = 0.0005190796(Vol%)3 - 0.0696333111(Vol%)2 + 9.0586107719(Vol%) -

5.6070070997
R² = 0.9984801479
800

700

600

500

400
TBP,oC

300

200

100

0
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00
-100
VOL%

Figure(a):

3
 Name:Esra Belhaj
ID:3115128
HW#1

Q#(4-3)

VOL% D86 D86 a b TBP TBP TBP

o
°C R R °F C
0 138.8 598.8 0.9167 1.0019 555.6302 95.96022 35.53346
10 149.6 609.6 0.5277 1.09 572.9096 113.2396 45.13311
30 158.8 618.8 0.7429 1.0425 604.1177 144.4477 62.47094
50 165.8 625.8 0.892 1.0176 625.1981 165.5281 74.1823
70 169.9 629.9 0.8705 1.0226 634.3135 174.6435 79.24636
90 178.1 638.1 0.949 1.011 650.1428 190.4728 88.04042
95 180.4 640.4 0.8008 1.0355 645.0664 185.3964 85.22021

T,oC = 0.000028554450(VOL%)3 - 0.009080043828(VOL%)2 +

1.147073073192(VOL%)+ 35.199091353316
R² = 0.995432326982
100
90
80
70
60
T,oC

50
40
30
20
10
0
0 20 40 VOL% 60 80 100

Figure(b)

from eqn (from figure (b)) the IBP & EP are:

Vol%
0
0 35.19909 IBP C
0
100 87.66041 EP C
Interval(10) 5.246132

Calculation of VABP to determine Kw :

4
 Name:Esra Belhaj
ID:3115128
HW#1

VOL% TBP,oC TBP,R a b D68,R D68,of

10 45.79037 574.0927 0.5277 1.09 610.7548 151.0848
30 62.21021 603.6484 0.7429 1.0425 618.3389 158.6689
50 73.42194 623.8295 0.892 1.0176 624.4537 164.7837
70 80.79617 637.1031 0.8705 1.0226 632.6089 172.9389
90 85.70351 645.9363 0.949 1.011 634.0162 174.3462

o
VABP 164.3645 F
o
SL 0.290768 F
∆ 0.820535 o
F
o
MeABP 163.544 F
s(avg) 0.801
Kw 10.66383

TPB,0C TPB,R s60/60 NBP,0C VOL%at cut end o

API
35.19909 555.0284
40.44522 564.4714 0.772831 37.82216 2.394311 28.65353
45.69136 573.9144 0.777153 43.06829 6.52065 27.70731
50.93749 583.3575 0.781427 48.31442 11.44103 26.7818
56.18362 592.8005 0.785655 53.56055 17.36793 25.87621
61.42975 602.2436 0.789838 58.80668 24.51386 24.98981
66.67588 611.6866 0.793977 64.05282 33.0913 24.12189
71.92201 621.1296 0.798074 69.29895 43.31276 23.27179
77.16815 630.5727 0.802128 74.54508 55.39072 22.43887
82.41428 640.0157 0.806142 79.79121 69.53767 21.62255
87.66041 649.4587 0.810117 85.03734 85.96612 20.82225

VOL% vs. s60/60

s60/60 = -0.0000000008(VOL%)4 + 0.0000002011(VOL%)3 -
0.0000193102(VOL%)2 + 0.0011724353(VOL%) + 0.7680393539
0.815 R² = 0.9999670394
0.81
0.805
0.8
0.795
s60/60

0.79
0.785
0.78
0.775
0.77
0.765
0 20 40 VOL% 60 80 100

5
 Name:Esra Belhaj
ID:3115128
HW#1

Q#(4-4-a)

o
API 34.2
s60/60 0.854

Fraction cut ,T,0C P,mmHg VOL% Cum,Vol% A T,oC T,of

IBP 82 576 0 1.8 0.001337 82.12767 179.8298
1 122 576 2.6 4.4 0.001337 122.1375 251.8476
2 167 576 2.3 6.7 0.001337 167.1476 332.8656
3 212 576 5 11.7 0.001337 212.1564 413.8815
4 257 576 7.9 19.6 0.001337 257.1641 494.8954
5 302 576 6.2 25.8 0.001337 302.1707 575.9072
6 347 576 4.9 30.7 0.001337 347.1761 656.9169
7 392 576 4.6 35.3 0.001337 392.1803 737.9245
8 437 576 5.2 40.5 0.001337 437.1834 818.9301
9 482 576 4.9 45.4 0.001337 482.1853 899.9335
10 527 576 6.2 51.6 0.001337 527.1861 980.9349
11 392 40 4.3 55.9 0.001768 518.7527 965.7549
12 437 40 5.2 61.1 0.001768 566.6665 1052
13 482 40 5.3 66.4 0.001768 613.9429 1137.097
14 527 40 3.2 69.6 0.001768 660.5943 1221.07
15 527 40 5.4 75 0.001768 660.5943 1221.07
Risedual 25 100
98.2

VOL% vs. T,oF

2500
T,oF = 0.0000026832(VOL%)5 - 0.0005546190(VOL%)4 + 0.0416738618(VOL%)3 -
1.4035948966(VOL%)2 + 34.7807410185(VOL%) + 130.0987405724
R² = 0.9950105884
2000

1500
T,oF

1000

500

0
0 20 40 60 80 100
VOL%