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    AliahJoy Delos Santos Junio
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    This document contains calculations to determine the enthalpy of dissolution (ΔHdiss) and percent error for dissolving NaCl and NH4NO3 in water. For NaCl, ΔHdiss was calculated to be -1.264 kJ/mol with a 66.6% percent error. For NH4NO3, ΔHdiss was -0.632 kJ/mol with a 97.6% percent error.

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    computation enthalpy of dissolution

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    This document contains calculations to determine the enthalpy of dissolution (ΔHdiss) and percent error for dissolving NaCl and NH4NO3 in water. For NaCl, ΔHdiss was calculated to be -1.264 kJ/mol with a 66.6% percent error. For NH4NO3, ΔHdiss was -0.632 kJ/mol with a 97.6% percent error.

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    © All Rights Reserved
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    6 views3 pages

    Computations

    Uploaded by

    AliahJoy Delos Santos Junio
    This document contains calculations to determine the enthalpy of dissolution (ΔHdiss) and percent error for dissolving NaCl and NH4NO3 in water. For NaCl, ΔHdiss was calculated to be -1.264 kJ/mol with a 66.6% percent error. For NH4NO3, ΔHdiss was -0.632 kJ/mol with a 97.6% percent error.

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    © All Rights Reserved
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    of 3

    For NaCl

    TF= 29 TI=29.5 C=35.289 J

    q= [53g (4.184 J/g°C) +C] (TF-TI)


    q= [53g (4.184 J/g°C) +35.289 J] (29°C-29.5°C)
    q= [217.568 J/°C + 35.289 J] (-0.5°C)
    q= [252.857 J/°C ](-0.5°C)
    q= -126.429 J

    −126.429 J 1𝑘𝐽
    ∆Hdiss = ( 0.100 mol ) (1000𝐽)

    ∆Hdiss = -1.264 kJ/mol

    qrxn= -qsoln therefore q= 126.429 J

    𝑇𝑟𝑢𝑒 𝑉𝑎𝑙𝑢𝑒−𝐸𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 𝑉𝑎𝑙𝑢𝑒


    %error= x 100
    𝑇𝑟𝑢𝑒 𝑉𝑎𝑙𝑢𝑒
    𝑘𝐽 𝑘𝐽
    3.9 −1.264
    %error= 𝑚𝑜𝑙
    𝑘𝐽
    𝑚𝑜𝑙
    x 100
    3.9
    𝑚𝑜𝑙

    %error= 66.6%
    For NH4NO3
    TF=29.25 TI=29.5 C=35.289 J

    q= [53g (4.184 J/g°C) +C] (TF-TI)


    q= [53g (4.184 J/g°C) +35.289 J] (29.25°C-29.5°C)
    q= [217.568 J/°C + 35.289 J] (-0.25°C)
    q= [252.857 J/°C ](-0.25°C)
    q= -63.214 J

    −63.214 J 1𝑘𝐽
    ∆Hdiss = (0.100 mol) (1000𝐽)

    ∆Hdiss = -0.632 kJ/mol

    qrxn= -qsoln therefore q= 63.214 J

    𝑇𝑟𝑢𝑒 𝑉𝑎𝑙𝑢𝑒−𝐸𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 𝑉𝑎𝑙𝑢𝑒


    %error= x 100
    𝑇𝑟𝑢𝑒 𝑉𝑎𝑙𝑢𝑒
    𝑘𝐽 𝑘𝐽
    3.9 −0.632
    %error= 𝑚𝑜𝑙
    𝑘𝐽
    𝑚𝑜𝑙
    x 100
    3.9
    𝑚𝑜𝑙

    %error= 97.6%

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